Design of a hybrid polygeneration system with solar collectors and a Solid Oxide Fuel Cell: Dynamic simulation and economic assessment

Solid Oxide Fuel Cells (SOFC) are very promising energy conversion devices, producing electricity and heat from a fuel directly via electrochemical reactions. The electrical efficiency of SOFCs is particularly high, so that such systems are very attractive for integration in complex polygeneration systems. In this paper, the integration of SOFC systems with solar thermal collector is investigated seeking to design a novel polygeneration system producing: electricity, space heating and cooling and domestic hot water, for a university building located in Naples (Italy), assumed as case study. The polygeneration system is based on the following main components: concentrating parabolic through solar collectors, a double-stage LiBr-H₂O absorption chiller and an ambient pressure SOFC fuel cell. The system also includes a number of additional components required for the balance of plant, such as: storage tanks, heat exchangers, pumps, controllers, cooling tower, etc. The SOFC operates at full load, producing electric energy that is in part self-consumed for powering building lights and equipments, and in part is used for operating the system itself; the electric energy in excess is eventually released to the grid and sold to the public Company that operates the grid itself. The system was designed and then simulated by means of a zero-dimensional transient simulation model, developed using the TRNSYS software; the investigation of the dynamic behavior of the building is also included. The results of the case study were analyzed for different time bases, from both energetic and economic points of view. Finally, a thermoeconomic optimization is also presented aiming at determining the optimal set of system design parameters. The economic results show that the system under investigation may be profitable, provided that it is properly funded. However, the overall energetic and economic results are more encouraging than those claimed for other similar polygeneration systems in the recent literature.     

A flexible model integration approach for evaluating tradeoffs between CO2 emissions and cost in solid oxide fuel cell‐based building energy systems

A simulation framework for flexible evaluation of various distributed building energy systems based on the integration of component device simulation models is presented. Device technology models were constructed for a solid oxide fuel cell (SOFC), a gas turbine, a double pipe heat exchanger, and a compressor. A scheme is proposed for defining model interfaces in order to improve the flexibility and accessibility of the models. Based on that scheme, interfaces are defined for each device model. The component device models are integrated to construct system models of (1) a hybrid system combining an SOFC and a gas turbine (SOFC/GT system) and (2) a stand‐alone SOFC system. The integrated model of the SOFC/GT system is then used to carry out a multi‐objective optimization in order to study the tradeoffs between cost and CO₂ emissions of the SOFC system operation for a given electricity demand. Through these analyses, the optimal configuration of the SOFC/GT system and the optimal operation conditions of the SOFC system for the given electricity demand were explored. Copyright © 2005 John Wiley & Sons, Ltd.     

Dynamics and control of a thermally self-sustaining energy storage system using integrated solid oxide cells for an islanded building

A solid oxide cell-based energy system is proposed for a solar-powered stand-alone building. The system is comprised of a 5 kW_el solid oxide fuel cell (SOFC), a 9.5 kW_el solid oxide electrolysis cell (SOEC), and the required balance of plant. The SOFC supplies: 1- building demand in the absence of sufficient solar power, 2- heat for SOEC in endothermic and standby modes. Thermal integration of SOFC and SOEC is implemented through a network of heat exchangers, combined with set of control algorithms. Two control strategies were implemented to actuate the SOFC in response to endothermic heat demands of SOEC by manipulating: 1- electric power, 2- fuel utilization. The results of dynamic simulation of system for two scenarios (sunny day and cloudy day) showed successful compliance of temperature constraints with both methods. Manipulation of fuel utilization, however, resulted in better system performance in terms of efficiency and H₂ balance.     

Operational optimisation of a complex trigeneration system connected to a district heating and cooling network

The combined production of electricity, heat and cold by polygeneration systems ensures maximum utilization of resources by reducing emissions and energy losses during distribution. Polygeneration systems are highly integrated systems characterized by the simultaneously production of different services (electricity, heating, cooling) by means of several technologies using fossil and renewable fuels that operates together to obtain a higher efficiency than that of an equivalent conventional system. The high number of distribution technologies available to produce electricity, heating and cooling and the different levels of integration make it difficult to select of the optimal configuration. Moreover, the high variability in the energy demand renders difficult the selection of the optimal operational strategy. Optimization methodologies are usually applied for the selection of the optimal configuration and operation of energy supply systems. This paper presents a scenario analysis using optimization models to perform an economic, energetic and environmental assessment of a new polygeneration system in Cerdanyola del Vallès (Spain) in the framework of the Polycity project of the European Concerto Program. This polygeneration system comprise high-efficiency natural gas cogeneration engines with thermal cooling facilities and it will provide electricity, heating and cooling for a new area in growth known as Alba park including a Synchrotron Light Facility and a Science and Technological park through a district heating and cooling network of four tubes. The results of the scenario analysis show that the polygeneration plant is an efficient way to reduce the primary energy consumption and CO₂ emissions (up to 24%).     

Study on zero CO2 emission atmospheric pressure SOFC hybrid power system integrated with OTM

In order to further reduce the energy consumption of CO₂ capture from the traditional SOFC hybrid power system, based on the principle of energy cascade utilization and system integration, a zero CO₂ emission atmospheric pressure solid oxide fuel cell (SOFC) hybrid power system integrated with oxygen ion transport membrane (OTM) is proposed. The oxygen is produced by the OTM for the oxy‐fuel combustion afterburner of SOFC. With the Aspen‐plus software, the models of the overall SOFC hybrid power systems with or without CO₂ capture are developed. The thermal performance of new system is investigated and compared with other systems. The effects of the fuel utilization factor of SOFC and the pressure ratio between two sides of OTM membrane on the overall system performance are analyzed and optimized. The research results show that the efficiency of the zero CO₂ emission atmospheric pressure SOFC hybrid power system integrated with OTM is around 58.36%, only 2.48% lower than that of the system without CO₂ capture (60.84%) but 0.96% higher than that of the zero CO₂ emission atmospheric pressure SOFC hybrid system integrated with the cryogenic air separation unit. Copyright © 2014 John Wiley & Sons, Ltd.     

Application of adaptive neuro-fuzzy inference system techniques and artificial neural networks to predict solid oxide fuel cell performance in residential microgeneration installation

This study applies adaptive neuro-fuzzy inference system (ANFIS) techniques and artificial neural network (ANN) to predict solid oxide fuel cell (SOFC) performance while supplying both heat and power to a residence. A microgeneration 5 kW_el SOFC system was installed at the Canadian Centre for Housing Technology (CCHT), integrated with existing mechanical systems and connected in parallel to the grid. SOFC performance data were collected during the winter heating season and used for training of both ANN and ANFIS models. The ANN model was built on back propagation algorithm as for ANFIS model a combination of least squares method and back propagation gradient decent method were developed and applied. Both models were trained with experimental data and used to predict selective SOFC performance parameters such as fuel cell stack current, stack voltage, etc.     

The financial viability of an SOFC cogeneration system in single-family dwellings

In the near future, fuel cell-based residential micro-CHP systems will compete with traditional methods of energy supply. A micro-CHP system may be considered viable if its incremental capital cost compared to its competitors equals to cumulated savings during a given period of time. A simplified model is developed in this study to estimate the operation of a residential solid oxide fuel cell (SOFC) system. A comparative assessment of the SOFC system vis-à-vis heating systems based on gas, oil and electricity is conducted using the simplified model for a single-family house located in Ottawa and Vancouver. The energy consumption of the house is estimated using the HOT2000 building simulation program. A financial analysis is carried out to evaluate the sensitivity of the maximum allowable capital cost with respect to system sizing, acceptable payback period, energy price and the electricity buyback strategy of an energy utility. Based on the financial analysis, small (1–2 kW_e) SOFC systems seem to be feasible in the considered case. The present study shows also that an SOFC system is especially an alternative to heating systems based on oil and electrical furnaces.     

Polygeneration and efficient use of natural resources

The consumption of natural resources has been increasing continuously during recent decades, due to the growing demand caused by both the economic and the demographic rise of global population. Environmental overloads that endanger the survival of our civilization and the sustainability of current life support systems are caused by the increased consumption of natural resources—particularly water and energy—which are essential for life and for the socio-economic development of societies. While not yet well utilized, process integration and polygeneration are promising tools which reach the double objective of increasing the efficiency of natural resources, and also minimizing the environmental impact. This paper discusses the concepts of polygeneration and energy integration and various examples of polygeneration systems: (i) sugar and energy production in a sugarcane factory; (ii) district heating and cooling with natural gas cogeneration engines and (iii) combined production of water and energy. It is clearly evident that polygeneration systems which include appropriate process integration significantly increase the efficient use of natural resources.     

Fuzzy neural control of a hybrid fuel cell/battery distributed power generation system

An innovative control strategy is proposed of hybrid distributed generation (HDG) systems, including solid oxide fuel cell (SOFC) as the main energy source and battery energy storage as the auxiliary power source. The overall configuration of the HDG system is given, and dynamic models for the SOFC power plant, battery bank and its power electronic interfacing are briefly described, and controller design methodologies for the power conditioning units and fuel cell to control the power flow from the hybrid power plant to the utility grid are presented. To distribute the power between power sources, the fuzzy switching controller has been developed. Then, a Lyapunov based-neuro fuzzy algorithm is presented for designing the controllers of fuel cell power plant, DC/DC and DC/AC converters; to regulate the input fuel flow and meet a desirable output power demand. Simulation results are given to show the overall system performance including load-following and power management of the system.     

High-temperature solid oxide fuel cell — technical status

The high-temperature Solid Oxide electrolyte Fuel Cell (SOFC) represents the basic building block for power generation in a variety of applications ranging from total energy systems for residences, industrial cogeneration systems, and utility central station power production. The cell operates at approx. 1000 °C, using a variety of fuels. Yttria-stabilised zirconia is the solid electrolyte that conducts oxygen ions from the cathode to the fuel electrode where the fuel is oxidised to release electrons (current) to an external load.This paper describes the operating principle of the SOFC and relates its component composition in the thin layer concept. Performance and life test data to 5000 h will be presented. Sulphur tolerance prediction data and actual tolerance test data are also presented. In addition, test results will include the effect of various fuels, e.g., CO and/or H₂ (as derived from coal gas), on the performance of the SOFC cell. The status of the present technology is also described. Finally, the usefulness of the SOFC generator, studied as part of a cogeneration system is discussed.     

Combined hydrogen,heat and electricity generation via biogas reforming: Energy and economic assessments

Polygeneration systems, designed for providing multiple energy services like hydrogen, heat and electricity, represent a possible solution for the transition to sustainable low-carbon energy systems, thanks to a substantial increase in the overall efficiency. A further step to reach zero-carbon energy systems can be done by using renewables as primary sources.In this study a biogas-based polygeneration system for the combined hydrogen, heat and electricity production is designed and analyzed from energy and economic points of view.The system consists of four sections: a biogas processing unit consisting in an autothermal reactor and a water gas shift reactor, an SOFC power unit, a hydrogen separation unit and a hydrogen compression/storage unit. The syngas generated in the autothermal reforming reactor is split in two fluxes: the first one is sent to the SOFC power unit for generating electricity and heat, the second one is sent to the water gas shift reactor to increase the hydrogen content. The hydrogen rich gas exiting the shifter, purified in the hydrogen separation unit (hydrogen quality is equal to 99.995%), is then compressed up to 820 bars and stored.The system behavior and the energy performances have been investigated by using the numerical simulation based on thermo-electrochemical models. Four operating conditions, related to different SOFC loads (from 30% to 100%), have been analyzed. The evaluated overall efficiencies range from 68.5% to 72.3% and the energy saving, calculated with respect to the separate production of hydrogen, heat and electricity, ranges from about 8% to 26%.The economic assessment, carried out by estimating the total capital investment and the plant profitability, has been performed by analyzing different management strategies (Base Load, Peaker, Ancillary Service and Mobility) and accounting for different technological development levels and market scenarios. Results show that the hydrogen production is the main contributor to the system economic sustainability thanks to the highest prices of hydrogen with respect to the electricity ones.     

Modelling the UK residential energy sector under long-term decarbonisation scenarios: Comparison between energy systems and sectoral modelling approaches

The UK government has set a groundbreaking target of a 60% reduction in carbon dioxide (CO₂) emissions by 2050. Scenario and modelling assessment of this stringent target consistently finds that all sectors need to contribute to emissions reductions. The UK residential sector accounts for around 30% of the total final energy use and more than one-quarter of CO₂ emissions. This paper focuses on modelling of the residential sector in a system wide energy–economy models (UK MARKAL) and key UK sectoral housing stock models. The UK residential energy demand and CO₂ emission from the both approaches are compared. In an energy system with 60% economy-wide CO₂ reductions, the residential sector plays a commensurate role. Energy systems analysis finds this reduction is primarily driven by energy systems interactions notably decarbonisation of the power sector combined with increased appliance efficiency. The stock models find alternate decarbonisation pathways based on assumptions related to the future building stock and behavioural changes. The paper concludes with a discussion on the assumptions and drivers of emission reductions in different models of the residential energy sector.     

Energy,water and food security through a waste-driven polygeneration system for sustainable dairy production

Ensuring secure and sustainable food production amidst growing demand requires developing high-yield sustainable food production systems, noting that conventional food production systems are large consumers of energy and water resources. Moreover, they induce substantial environmental impacts. In this context, this study considers dairy food production systems, and proposes a dairy waste driven polygeneration system that can increase the milk yield of the dairy food production system whilst reducing its environmental impact. The system utilises dairy manure, very low concentration methane, wastewater, and harsh environmental conditions in an integrated manner to fulfil the dairy farms' vital needs, including air-conditioning, electricity, and freshwater. In addition, the system also provides a solution concerning social perception related to wastewater reuse for potable purposes in the form of an integrated electrolyser and fuel-cell cycle. Unique to this study is the harnessing of the energy of the methane, which is in very low concentrations in the barns, and benefitting from the harsh environmental conditions in an integrated manner. Comprehensive thermodynamic investigations revealed that the system generates 2.17 MW of Electricity, 1152 m³ of freshwater daily, 6970 tons of cooling capacity, and 1.6 kg/day of H₂. Besides, on a daily basis, the system consumes 864 tons of manure, recycles 732.5 m³ of wastewater, and utilises 87.62 tons of methane (resulting in savings of ～711,750 tons of CO₂ eq. annually). The calculated energy and exergy efficiencies of the polygeneration system are 50% and 4%, respectively. Moreover, in the design of polygeneration systems, the importance of the proper definition of the thermodynamic system's boundaries and the effects of technology choice for the same purpose is illustrated. Furthermore, the parametric investigations revealed that the system performs stable with variations in the inputs and ambient conditions. Also, unlike other systems, the system's performance improves in harsher environmental conditions. This study also illustrates that the food production systems can be developed for decentralised operations with near zero-waste outputs and near-zero emissions.     

A comprehensive investigation of a low-energy building in Sweden

In Sweden, the building sector alone accounts for almost 40% of the total energy demand and people spend more than 80% of their time indoors. Reducing energy demand in the buildings is essential to the achievement of a sustainable built environment. At the same time, it is important to not deteriorate people's health, well-being and comfort in buildings. Thus, designing healthy and energy efficient buildings are one of the most challenging tasks for building scientists. A low-energy building that uses less than half of the purchased energy of a comparable typical Swedish building has been investigated from different viewpoints in an attempt to represent the building at different system levels. First, the ventilation performance in different rooms using the tracer gas method is reported. Second, results from simulations and in situ measurements are used to analyse the building's power demand and energy performance. The household's behaviour and their impact on energy usage as well as acceptance are reported. Finally, the CO₂ emissions with regard to the energy usage are analysed on the basis of different supply energy forms from surrounding energy systems, for example a Swedish and European electricity mix, or district heating as a substitute for electrical heating.     

Integration of wind turbine with heliostat based CSP/CPVT system for hydrogen production and polygeneration: A thermodynamic comparison

In this study, two wind-solar-based polygeneration systems namely CES-1 and CES-2 are developed, modeled, and analyzed thermodynamically. CES-1 hybridizes a heliostat based CSP system with wind turbines while CES-2 integrates heliostat-based CPVT with wind turbines. This study aims to compare the production and thermodynamics performance of two heliostat based concentrated solar power technologies when hybridized with wind turbines. The systems have been modeled to produce, freshwater, hot water, electricity, hydrogen, and cooling with different cycles/subsystems. While the overall objective of the study is to model two polygeneration systems with improved energy and exergy performances, the performances of two solar technologies are compared. The wind turbine system integrated with the comprehensive energy systems will produce 1.14 MW of electricity and it has 72.2% energy and exergy efficiency. Also, based on the same solar energy input, the performance of the heliostat integrated CPVT system (CES-2) is found to be better than that of the CSP based system (CES-1). The polygeneration thermal and exergy efficiencies for the two systems respectively are 48.08% and 31.67% for CES-1; 59.7% and 43.91% for CES-2. Also, the electric power produced by CES-2 is 280 kW higher in comparison to CES-1.     

CO2-emissions reduction potential and costs of a decentralized energy system for providing electricity,cooling and heating in an office-building in Tokyo

Decentralized energy systems are thought to have great potential for supplying electricity, cooling, and heating to buildings. A decentralized system combining a solid oxide fuel cell (SOFC) with an absorption chiller-heater (ACH) is proposed. The CO₂-emissions and costs of using different configurations of this SOFC-based system to provide an office building in Tokyo with electricity, cooling and heating are calculated by using an SOFC-model and an absorption-chiller model together with data for cooling and heating loads measured at an office building in downtown Tokyo. The results are compared with the CO₂-emissions and costs of a conventional system that obtains the base electricity requirements as well as electricity for an electric chiller–heater system from the central power grid. The fully decentralized SOFC-based energy system could result in a potential CO₂ reduction of over 30% at an estimated cost increase of about 70% compared to the conventional system.     

Economic analysis of coal-based polygeneration system for methanol and power production

Polygeneration system for chemical and power co-production has been regarded as one of promising technologies to use fossil fuel more efficiently and cleanly. In this paper the thermodynamic and economic performances of three types of coal-based polygeneration system were investigated and the influence of energy saving of oxygenation systems on system economic performance was revealed. The primary cost saving ratio (PCS) is presented as a criterion, which represents the cost saving of polygeneration system compared with the single-product systems with the same products outputs, to evaluate economic advantages of polygeneration system. As a result, the system, adopting un-reacted syngas partly recycled to the methanol synthesis reactor and without the shift process, can get the optimal PCS of 11.8%, which results from the trade-off between the installed capital cost saving and the energy saving effects on the cost saving, and represents the optimal coupling relationship among chemical conversion, energy utilization and economic performance. And both of fuel price and the level of equipment capital cost affect on PCS faintly. This paper provides an evaluation method for polygeneration systems based on both technical and economic viewpoints.     

Fuel cell energy generation and recovery cycle analysis for residential application

Today’s concern regarding limited fossil fuel resources and their contribution to environmental pollution have changed the general trend to utilization of high efficiency power generation facilities like fuel cells. According to annual reducing capital cost of these utilities, their entrance to commercial level is completely expected. Hot exhaust gases of Solid Oxide Fuel Cells (SOFC) are potentially applicable in heat recovery systems. In the present research, a SOFC with the capacity of 215 kW has been combined with a recovery cycle for the sake of simultaneous of electric power, cooling load and domestic hot water demand of a hotel with 4600 m² area. This case study has been evaluated by energy and exergy analysis regarding exergy loss and second law efficiency in each component. The effect of fuel and air flow rate and also current density as controlling parameters of fuel cell performance have been studied and visual software for energy-exergy analysis and parametric study has been developed. At the end, an economic study of simultaneous energy generation and recovery cycle in comparison with common residential power and energy systems has been done. General results show that based on fuel lower heating value, the maximum efficiency of 83 percent for simultaneous energy generation and heat recovery cycle can be achieved. This efficiency is related to typical climate condition of July in the afternoon, while all the electrical energy, cooling load and 40 percent of hot water demand could be provided by this cycle. About 49 percent of input exergy can be efficiently recovered for energy requirements of building. Generator in absorption chiller and SOFC are the most destructive components of exergy in this system.     

Development of metal supported solid oxide fuel cells based on powder metallurgical manufacturing route

Abstract

In the past few decades, stationary solid oxide fuel cell (SOFC) systems have been developed that can generate electricity and heat from the energy stored in hydrogen or hydrocarbons with total efficiencies up to 95%. While the mechanical cell support of stationary systems is commonly supplied by thick ceramic cell components (i.e. anode and electrolyte supported concepts), mobile systems demand a more robust design. This is ensured by a strong yet porous metallic substrate which serves as the mechanical backbone of thin film membrane electrode assemblies [metal supported cell (MSC) concept]. Porous PM Fe–Cr oxide dispersion strengthened alloys for use as MSC supports have recently been developed. These materials provide mechanical and chemical long term stability in typical SOFC atmospheres at operation temperatures up to 850°C. The substrates support a multilayer anode–electrolyte–cathode thin film assembly, constituting a high performance MSC repeat unit. These units are the building blocks for MSC stacks with superior properties for mobile applications.     

Suitable operational strategy for power interchange operation using multiple residential SOFC (solid oxide fuel cell) cogeneration systems

A suitable operational strategy for a power interchange operation using multiple residential solid oxide fuel cell (SOFC) cogeneration systems for saving energy is investigated by an optimization approach based on mixed-integer linear programming. In this power interchange operation, electricity generated by residential SOFC cogeneration systems is shared among households in a housing complex without allowing a reverse power flow to a commercial electric power system in order to increase electric load factors of the system. For an SOFC cogeneration system operated continuously with the minimum output, two types of operational strategies for the power interchange operation are adopted: an operation to meet the total demand for electricity in intended households by the electricity output of SOFC cogeneration systems and an operation to meet the demand for hot water in each household by the hot water output of the SOFC cogeneration system. To clarify a theoretical limit of the energy-saving effects of the two strategies, this study numerically analyzes optimal operation patterns for 20 households on three representative days. The results show that the former operational strategy, which takes advantage of the high electricity generating efficiency of the SOFC, is more suitable for saving energy as compared to the latter strategy.