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我国生物柴油的研究现状分析 总被引:2,自引:0,他引:2
在总结生物柴油的原料、生产方法和研究动态的基础上,比较了几种常见植物油与矿物柴油的理化特性和各种生物柴油的生产方法的优缺点及生物柴油专利申请情况与柴油价格的关系,提出:(1)几种植物油的理化特性与柴油的相比存在一定差异,而植物油之间差异不大,它们用于生产生物柴油的研究方法可以相互借鉴;(2)生物柴油的研究形势与0#柴油的价格密切相关,就各种方法看,酯交换反应法是最受关注的方法;(3)生产生物柴油的方法各有优缺点,但酯交换反应法由于其适应性强、反应条件要求不高等,是目前最经济最有优势的方法,但此法仍需改进。 相似文献
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文章概述了近年来国内外制备生物柴油技术,重点介绍了酸碱、生物酶及超临界工艺方法的研究进展,指出了影响我国生物柴油工业化发展的制约因素,提出了降低生物柴油生产成本的解决对策。 相似文献
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欧洲生物柴油燃料及其原料的最新动向 总被引:1,自引:0,他引:1
《应用化工》2015,(8):1515-1519
在温室气体排放量逐年增多、大气污染越来越严重的今天,生物柴油作为真正的绿色柴油倍受全球关注。从能源安全、降低温室气体排放量等方面考虑,欧洲乃至全球正在加快生物柴油燃料的使用进程。介绍了欧洲生物柴油的生产情况、各种生物柴油的性质及制造方法,同时介绍了欧洲生产生物柴油所用的原料,最后提出了几点建议。 相似文献
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国内外生物柴油研究生产现状及发展趋势 总被引:103,自引:0,他引:103
可替代柴油的生物柴油在国内外研究及生产的现状和发展趋势,指出了生物柴油的优势及生物柴油制备、应用中存在的问题,分析了发展生物柴油产业对我国石油安全、国民经济建设、农业产业结构调整和环境保护的作用,并展望了该产业的发展前景。 相似文献
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Biodiesel, a promising alternative diesel fuel, is produced by transesterification of vegetable oils or animal fats with methanol.
One of the main problems in the industrial application of the transesterification process is how to determine the conversion
of oils to methyl esters. In this work, a quick analytical method was developed for monitoring the transesterification reaction
of soybean oil with methanol. The conversion of oils to methyl esters could be determined by applying a simple linear correlation
with hydroxyl content of the transesterified mixture or refractive index of the product. The results were in agreement with
the values measured by 1H NMR spectroscopy. Compared with existing chromatographic and other methods, this method for monitoring the transesterification
of vegetable oils with methanol is simple, rapid, and inexpensive and is especially suitable for process control purposes. 相似文献
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D. Samios F. PedrottiA. Nicolau Q.B. ReiznauttD.D. Martini F.M. Dalcin 《Fuel Processing Technology》2009
This study introduces a two consecutive steps basic–acid transesterification process, (denominated Transesterification Double Step Process — TDSP) for biodiesel production from vegetable oils. The process involves homogeneous consecutive basic–acid catalysis steps and is characterized by formation of well-defined phases, easy separation procedures, high reaction velocity and high conversion efficiency. The proposed TDSP is different in relation to other traditional two-step procedures which normally include acid esterification followed by basic transesterification, or enzymatic or even supercritical transesterification conditions. The biodiesel (fatty acid methyl esters) was analyzed by standard biodiesel techniques in addition to 1H-NMR, indicating high quality and purity biodiesel products. The transesterification of sunflower and linseed oils resulted in oil conversions higher than 97% corresponding to yields of 85%. A probable reaction mechanism responsible for the process is presented. 相似文献
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A. Yaron B. Turzynski C. Shmulinzon A. Letan 《European Journal of Lipid Science and Technology》1973,75(9):533-536
Margarine oils have been prepared by transesterification of blends of hardened and liquid soybean oils or by blending of transesterified hardened oils with liquid soybean oil. The dilatometric characteristics of those oils and their nutritional values (as characterized by the L/S ratio of linoleic acid to total saturated acids) have been compared with the same parameters of margarine oils from local and foreign table margarines. It was concluded that margarine oils of suitable melting characteristics and of an average nutritional value (L/S ratio of about 0.70) can be prepared from blends of soybean oils alone, using transesterification process. 相似文献
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Rafael Guzatto Diego Defferrari Quelen Bülow Reiznautt Ígor Renz Cadore Dimitrios Samios 《Fuel》2012,92(1):197-203
In this study, the transesterification double step process (TDSP) was modified to enable the usage of ethanol as a transesterification agent in the production of biodiesel from vegetable and waste oils. The TDSP comprises a two-step transesterification procedure, which is initiated by a homogeneous basic catalysis step and followed by an acidic catalysis step. To optimize the transesterification parameters, different reaction mixtures and conditions were tested. Compared with methanol transesterification, larger ethanol and catalyst amounts as well as higher reaction times and temperatures were required. However, the results were consistent with those usually reported for ethanol transesterification. The obtained biodiesels (i.e., fatty acid ethyl esters (FAEEs)) were analyzed by standard physico-chemical techniques in addition to 1H NMR, 13C NMR and FTIR spectroscopies, indicating high quality and purity biodiesel products. The obtained conversions were evaluated by 1H NMR spectroscopy. For the optimized process, the triglyceride conversion to biodiesel was ?97% for all oils used. The overall process yields are considerably high when compared to the single basic catalysis yields. 相似文献
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生物柴油是一类清洁的可再生液体燃料,精炼植物油与甲醇酯交换是制备生物柴油的重要反应。针对目前难以准确获得酯交换反应体系的多组分相平衡组成等方面存在的问题,研究了间歇反应和连续逆流分离甘油等不同反应方式下大豆油与甲醇酯交换反应体系的多组分相平衡行为,并以三油酸甘油酯与甲醇酯交换为模型反应,采用UNIFAC和Modified UNIFAC模型进行了模拟计算。结果表明,在常压、60oC反应条件下,在总组成偏离甲醇-甲酯二元组成的区域,UNIFAC和Modified UNIFAC模型准确计算了生物柴油酯交换反应体系的三元和四元相平衡组成。在甘油含量大于2.2%(质量)或转化率小于90%(质量)的酯交换反应中,计算值与实验值的平均偏差约为2%。酯交换反应相平衡的实验值和模型计算值表明,采用连续逆流方式分离甘油可以提高酯相中的甲醇含量,有利于传质和酯交换反应。这些结果为生物柴油工艺过程模拟、设备优化以及新技术开发提供了理论参考。 相似文献
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Two-step chemoenzymatic synthesis of urethane oils has been studied. Initially, the partial esters were prepared by lipase-catalyzed
transesterification of soybean and linseed oils with n-butanol. Partial esters were further reacted with different diisocyanates
to obtain urethane oils. The composition of the partial esters was varied with reaction time in the transesterification step.
Among all the lipases, the lipozyme was found to be the most suitable lipase for the transesterification reaction, yielding
80–85%. All of the urethane oils were of low molecular weights irrespective of the type of oil used in their preparation.
Urethane oils, based on MDI, exhibited the best scratch resistance. All of the urethane oils showed good acid and alkali resistance
and excellent solvent resistance. These oils also satisfactorily passed the impact resistance and the flexibility tests.
Department of Chemistry, Vidyanagari, Mumbai-400 098, India. 相似文献
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Biodiesel production from high FFA rubber seed oil 总被引:7,自引:0,他引:7
Currently, most of the biodiesel is produced from the refined/edible type oils using methanol and an alkaline catalyst. However, large amount of non-edible type oils and fats are available. The difficulty with alkaline-esterification of these oils is that they often contain large amounts of free fatty acids (FFA). These free fatty acids quickly react with the alkaline catalyst to produce soaps that inhibit the separation of the ester and glycerin. A two-step transesterification process is developed to convert the high FFA oils to its mono-esters. The first step, acid catalyzed esterification reduces the FFA content of the oil to less than 2%. The second step, alkaline catalyzed transesterification process converts the products of the first step to its mono-esters and glycerol. The major factors affect the conversion efficiency of the process such as molar ratio, amount of catalyst, reaction temperature and reaction duration is analyzed. The two-step esterification procedure converts rubber seed oil to its methyl esters. The viscosity of biodiesel oil is nearer to that of diesel and the calorific value is about 14% less than that of diesel. The important properties of biodiesel such as specific gravity, flash point, cloud point and pour point are found out and compared with that of diesel. This study supports the production of biodiesel from unrefined rubber seed oil as a viable alternative to the diesel fuel. 相似文献
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An ever increasing demand of fuels has been a challenge for today’s scientific workers. The fossil fuel resources are dwindling day by day. Biodiesel seems to be a solution for future. Biodiesel is an environmentally viable fuel. Out of the four ways viz. direct use and blending, micro-emulsions, thermal cracking and transesterification, most commonly used method is transesterification of vegetable oils, fats, waste oils, etc. Latest aspects of development of biodiesel have been discussed in this work. Yield of biodiesel is affected by molar ratio, moisture and water content, reaction temperature, stirring, specific gravity, etc. Biodegradability, kinetics involved in the process of biodiesel production, and its stability have been critically reviewed. Emissions and performance of biodiesel has also been reported. 相似文献