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液相沉淀法制备纳米硫化锌的研究 总被引:2,自引:0,他引:2
介绍了利用液相沉淀法制备纳米硫化锌的方法。其过程是以硫酸锌和硫化铵为原料,加入表面活性剂1631,经过沉淀、过滤、洗涤、干燥,最后得到产品。对其进行比表面积、孔容积和透射电镜(TEM)测定,结果表明:制备的硫化锌晶粒尺寸在5—30nm,并最终确定了最佳的原料配比,即硫酸锌与硫化铵物质的量比为1:(1-0.8)。 相似文献
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一、概述立德粉的制取是由硫酸锌和硫化钡的水溶液进行复分解反应,生成硫化锌和硫酸钡的共沉淀物,再加工处理得到标准立德粉颜料。因此,硫酸锌和立德粉的制取都要首先制备纯净的疏酸锌水溶液。一般常用冶炼氧化锌、氢氧化锌或其他易溶于酸的含锌物质作原料。这些物质溶于硫酸即得粗制硫酸锌溶液,其中含有铁、镉、镍、铜等重金属离子杂质,必须仔细地加以除去。首先要除去铁。这就必须将亚铁Fe~(+2)氧化成Fe~(+3),才 相似文献
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通过液相沉淀法制备出无定形硫化锌粉末,硫化锌粉末经高温热处理后制得纳米硫化锌粉状晶体。具体过程为:将硫化钠溶液缓慢加入酸性的氯化锌溶液中,沉淀、洗涤、干燥后,研磨至200目以上,并在H_2气氛保护下于400℃温度焙烧,制得20~30nm粒径的硫化锌晶体。 相似文献
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均匀沉淀法制备不同粒径的纳米硫化锌 总被引:2,自引:0,他引:2
以硫代硫酸钠为硫源,采用均匀沉淀法研究了不同粒径纳米硫化锌的制备,讨论了反应温度、加热方式、反应物的浓度及物质的量比对其粒径的影响。研究结果表明:通过控制制备工艺条件,采用均匀沉淀法可以制备出平均粒径为4~24 nm、立方晶型的球形纳米硫化锌;制备工艺条件对纳米硫化锌的平均粒径有显著影响;加热方式对硫化锌的平均粒径影响较大,微波加热比水浴加热制备的硫化锌粒径小;此外,纳米硫化锌的粒径随着反应温度的增加、反应物浓度的增加、醋酸锌和硫代硫酸钠物质的量比的减小而减小。 相似文献
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由于纳米硫化锌的功能和用途不同,需要制备出不同粒径的球形纳米硫化锌。以乙酸锌为锌源,硫代硫酸钠为沉淀剂,采用均匀沉淀法研究了制备工艺对纳米硫化锌粒径的影响。 相似文献
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针对硫酸锌生产中出现的压滤困难、锌粉用量大、双氧水用量大及排放严重超标、回收率大大降低等问题,进行了一些有建设性地探讨,指出其根源很可能是氧化锌产品中人为地加入了硫化锌矿石粉。 相似文献
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超重力法制备纳米材料的研究现状 总被引:3,自引:0,他引:3
纳米材料的合成与制备技术已成为全球的研究热点。介绍了一种独创性的纳米材料合成方法即超重力法。论述了超重力法的理论依据,并介绍了目前根据该法合成碳酸钙、氢氧化铝、硫化锌、氧化锌、硫酸钡、钛酸钙等纳米粉体材料的制备方法和工艺流程。 相似文献
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Martijn F.M. Bijmans Pieter-Jan van Helvoort Cees J.N. Buisman Piet N.L. Lens 《Separation and Purification Technology》2009,69(3):243-248
Dissolved zinc is present in natural waters and process streams generated by the mining and metallurgical industry. These streams usually have a low pH. By using sulfate reducing bacteria, sulfide can be produced that precipitates with zinc as zinc sulfide (sphalerite), which can be easily separated from the wastewater and even reused as zinc concentrate. In this study, a sulfate reducing gas-lift bioreactor was operated at pH 5.5 using hydrogen as electron donor for sulfate reduction. We demonstrate effective zinc removal (7.2 mmol L−1 d−1) with low zinc effluent concentrations (0.65–8.8 μM) in a system combining sulfide generation by sulfate reducing bacteria (7.2–10.6 mmol SO42− L−1 d−1) at low pH (5.5) with the bio-precipitation of crystalline sphalerite. To investigate the effect of the sulfide excess on the settling properties of the sphalerite precipitates, the sulfide excess concentration was varied about two orders of magnitude (0.008–2.2 mM). The results show that crystalline sphalerite was formed in all cases, but larger particles with better settling properties were formed at lower sulfide concentrations. 相似文献
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The inhibition efficiencies of zinc chromate, barium metaborate, calcium silicate, amino carboxylate, calcium barium phosphosilicate, aluminum triphosphate and a modified zinc phosphate on the corrosion of steel and zinc were determined by polarization experiments on pigment extracts. Zinc phosphate and zinc chromate were the best and were studied further to determine the effect of pH and chloride concentration on their inhibition of steel. Zinc chromate is adversely affected by high concentration of chloride ions, which effect seems to be less pronounced on zinc. A low pH, although increasing the solubility of zinc phosphate, does not increase its efficiency. The pigments were also incorporated into an epoxy-poly(amide) binder, applied to cold-rolled steel and galvanized steel, exposed at a marine exposure station and the degradation monitored by electrochemical impedance spectroscopy. There was a general correlation between the results of pigment extract studies and atmospheric exposure except in the case of phosphate pigments on cold rolled steel. 相似文献
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在含硫污水中加入乙酸锌,通过高速离心法进行预处理,得到硫化锌沉淀,倒出部分上清液,再加入弱碱性水与显色剂反应,最后通过分光度计或比色法测定硫化物的含量。该测定方法简便、易于操作,准确度高。 相似文献
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Barium sulfate is the chief source for the manufacture of barium compounds, which have a wide range of applications in chemical industries. In the preparation of these compounds, the first step is the reaction between barium sulfate and carbon to produce barium sulfide. In the present work, the mechanism of reaction between barium sulfate and carbon is investigated experimentally, covering a wide range of temperatures, times of reaction, and stoichiometric ratios of reactants. The reaction is conducted in air, nitrogen, and vacuum. It is also studied using the reactants in pellet form to determine the effect of compaction pressure on rate of reaction. A model is developed to estimate the kinetic parameters and mechanism of the reaction. An attempt is also made to study the feasibility of conducting the reaction for continuous production of barium sulfide in a moving bed rector using the reactants in pellet form. 相似文献
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《分离科学与技术》2012,47(13-15):1817-1828
Abstract Metal oxides supported on zeolites have been demonstrated to be effective regenerable desulfurization agents for high temperature removal of hydrogen sulfide from fossil fuels. Metals of interest are iron and zinc. Zeolites of particular interest are commercially available zeolites with high hydrothermal stability such as synthetic mordenite and rare earth stabilized faujasite Y. The metals used as desulfurization agents are introduced by cation exchange. Zinc faujasite Y is of particular interest because of the demonstrated ability to reduce the hydrogen sulfide to several PPM concentration range in the desulfurized fuel in the temperature range of 500 to 650 C. 相似文献
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N. A. Ibrahim M. H. Abo-Shosha M. A. Gaffar A. M. Elshafei O. M. Abdel-Fatah 《Polymer-Plastics Technology and Engineering》2013,52(6):719-727
To improve the performance properties of cellulose-containing fabric, ester was cross-linked with polycarboxylic acid in the presence of specific catalysts. Its pendant carboxyl groups were exploited in binding some heavy metals (by reacting with some salts, such as zinc acetate, zinc chloride, zinc sulfate, cupric acetate, cupric chloride, cupric sulfate, and nickel sulfate) capable of imparting their antibacterial activity toward some gram-positive bacteria (viz., B. subtilis, B. mycoides, Sta. aureus) and a gram-negative bacteria (E. coli). Zinc salts impart to the fabric the highest antibacterial activity, followed by cupric acetate. Zinc chloride proved to be the metal salt that yielded the maximum antibacterial activity. 相似文献