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1.
Nitrogen (N) cycling and respiration rates were measured in sediment columns packed with southeastern United States continental shelf sands, with high permeability (4.66×10−11 m2) and low organic carbon (0.05%) and nitrogen (0.008%). To simulate porewater advection, natural shelf seawater was pumped through columns of different lengths to achieve fluid residence times of approximately 3, 6, and 12 h. Experiments were conducted seasonally at in situ temperature. Fluid flow was uniform in nearly all columns, with minimal dead zones and channeling. Significant respiration (O2 consumption and ∑CO2 production) occurred in all columns, with highest respiration rates in summer. Most (78–100%) remineralized N was released as N2 in the majority of cases, including columns with oxic porewater throughout, with only a small fraction released as NO3 from some oxic columns. A rate of 0.84–4.83×1010 mol N yr−1, equivalent to 1.06–6.09×10−6 mmol N cm−2 h−1, was calculated for benthic N2 production in the South Atlantic Bight, which can account for a large fraction of new N inputs to this shelf region. Metal and sulfate reduction occurred in long residence time columns with anoxic outflow in summer and fall, when respiration rates were highest. Because permeable sediments dominate continental shelves, N2 production in high permeability coastal sediments may play an important role in the global N cycle.  相似文献   

2.
Marine sediment may contain both settled phytoplankton and benthic microalgae (BMA). In river-dominated, shallow continental shelf systems, spatial, and temporal heterogeneity in sediment type and water-column characteristics (e.g., turbidity and primary productivity) may promote spatial variation in the relative contribution of these two sources to the sediment organic matter pool available to benthic consumers. Here we use photosynthetic pigment analysis and microscopic examination of sediment microalgae to investigate how the biomass, composition, and degradation state of sediment-associated microalgae vary along the Louisiana (USA) inner shelf, a region strongly influenced by the Mississippi River. Three sandy shoals and surrounding muddy sediments with depths ranging from 4 to 20 m were sampled in April, August, and October 2007. Pigment composition suggested that sediment microalgae were primarily diatoms at all locations. We found no significant differences in sediment chlorophyll a concentrations (8–77 mg m−2) at the shoal and off-shoal stations. Epipelic pennate diatoms (considered indicative of BMA) made up a significantly greater proportion of sediment diatoms at sandy (50–98%) compared to more silty off-shoal stations (16–56%). The percentage of centric diatoms (indicators of settled phytoplankton) in the sediment was highest in August. Sediment total pheopigment concentrations on sandy stations (<20 mg m−2) were significantly lower than concentrations at nearby muddy stations (>40 mg m−2), suggesting differences in sediment microalgal degradation state. These observations suggest that BMA predominate in shallow sandy sediments and that phytodetritus predominates at muddy stations. Our results also suggest that the relative proportion of phytodetritus in the benthos was highest where phytoplankton biomass in the overlying water was greatest, independent of sediment type. The high biomass of BMA found on shoals suggests that benthic primary production on sandy sediments represents a potentially significant local source of sediment microalgal carbon that may be utilized by benthic consumers in continental shelf food webs.  相似文献   

3.
Simulations of both currents and waves were performed throughout the year 2001 to assess the relative contribution of each to their overall erosive potential on the Gulf of Lions shelf. Statistical analysis of bottom shear stress (BSS) was compared to sediment grain-size distribution on the bottom. The hydrodynamic features of the bottom layer coincide with the distribution of surficial sediments, and three areas with different hydro-sedimentary characteristics were revealed. (i) The sandy inner shelf (<30 m) area is a high-energy-wave dominated area but may be subjected to intense current-induced BSS during on-shore winds along the coast and during continental winds mainly in the up-welling cells. (ii) The middle shelf (30–100 m) is a low-energy environment characterised by deposition of cohesive sediments, where the wave effect decreases with depth and current-induced BSS cannot reach the critical value for erosion of fine-grained sediments. (iii) The outer shelf, which has a higher bottom sand fraction than the middle shelf, may be affected by strong south-westward currents generated by on-shore winds, which can have an erosive effect on the fine-grained sediments.  相似文献   

4.
Development of guidelines for ammonia in estuarine and marine water systems   总被引:1,自引:0,他引:1  
The water quality guideline trigger value for ammonia in estuarine and marine waters has been revised with the addition of 38 new results to the data set of 21 used in earlier guideline derivations. Using species sensitivity distributions, a new trigger value of 460 μg total NH3-N/L was derived for slightly to moderately disturbed systems (95% protection concentration, PC95), with a value of 160 μg total NH3-N/L applying to waters of high conservation value (PC99). For sediment pore waters, a guideline trigger value of 3.9 mg total NH3-N/L, derived from the 80th percentile of background data from Sydney Harbour, is recommended. This value is likely to be exceeded in degraded sediments subject to dredging; however, ocean disposal of such sediments results in rapid decreases in porewater ammonia and a guideline trigger value for dissolved ammonia during disposal of dredged sediments of 1550 μg total NH3-N/L is proposed.  相似文献   

5.
Tagus intertidal microphytobenthos (MPB) assemblages were characterized over a wide range of sediment type and tidal height and the possible effects of these variables on MPB spatial distribution and photo-adaptation mechanisms were investigated. Two transects with six different sediment type and different tidal height sites were sampled once every two months from 2002 to 2004. Upper shore and sandy sites showed higher chlorophyll a (chl a) content, with sandy sediments showing a biomass peak in late winter–early spring, and muddy sites showing no obvious seasonal pattern. Stepwise multiple linear regressions showed that only SiO2, tidal height and sediment particle size <63 μm were significant variables (p<0.05), explaining 50% of MPB biomass spatial–temporal variability. However, when data were separated by transect, only tidal height remained significant at both transects. Sandier sediments exhibited higher zeaxanthin/chl a and lower fucoxanthin/chl a ratios characteristic of a mixed cyanobacteria/diatom assemblages, showing an alternate seasonality with cyanobacteria increasing in summer and diatoms dominating in spring. Diatom biofilms showed contrasting features depending on the sediment type. Epipsammic diatoms were small with an average length of around 10 μm, while epipelic diatoms showed a wider size range with size distribution peaks at 10–15 μm, 25–35 μm and >60 μm. Epipelic biofilms showed evidence of being low light-acclimated (high fucoxanthin/chl a) and of photo-regulating by vertical migration movements (presence of endogenous vertical rhythms and lower diatoxanthin/diadinoxanthin). Epipsammic biofilms showed higher diatoxanthin/diadinoxanthin ratios and no vertical migration rhythms. Thus, the two diatom biofilm types had distinct strategies to photo-regulate: epipelic diatoms using vertical migration to position themselves at the sediment depth of optimum light conditions, and epipsammic diatoms using the xanthophyll cycle to photo-regulate. Further studies comparing epipsammic and epipelic assemblages are necessary to better understand MPB photo-regulation mechanisms.  相似文献   

6.
The Adriatic Sea general circulation model coupled to a third generation wave model SWAN and a sediment transport model was implemented in the Adriatic Sea to study the dynamics of the sediment transport and resuspension in the northern Adriatic Sea (NAS) during the Bora event in January 2001. The bottom boundary layer (BBL) was resolved by the coupled model with high vertical resolution, and the mechanism of the wave–current interaction in the BBL was also represented in the model. The study found that, during the Bora event of 13–17 January 2001, large waves with significant wave height 2 m and period of 5 s were generated by strong winds in the northwestern shelf of the Adriatic where the direction of wave propagation was orthogonal to the current. The combined motion of the wave and current in the BBL increased the bottom stress over the western Adriatic shelf, resulting in stronger sediment resuspension there. Combining stronger bottom resuspension and strong upward vertical flux of resuspended sediments due to turbulent mixing, the model predicted that sediment concentration near the Po River was much higher than that predicted by the model run without wave forcing. The study also shows that wave–current interaction in the BBL reduced the western Adriatic Coastal Currents (WACCs) in the shallower north. It is concluded that wave forcing significantly changed the sediment distributions and increased the total horizontal fluxes over the western shelf. These results signified wave effect on sediment flux and distribution in the NAS, and suggested that waves cannot be neglected in the study of dynamics of sediment transport and resuspension in the shallow coastal seas. By including the tidal forcing in the coupled model, we also examined the effect of tides on the sediment transport dynamics in the NAS.  相似文献   

7.
Observations of sediment dispersal from the Santa Clara River of southern California during two moderately sized river discharge events suggest that river sediment rapidly formed a negatively buoyant (hyperpycnal) bottom plume along the seabed within hours of peak discharge. An array of acoustic and optical sensors were placed at three stations 1 km from the Santa Clara River mouth in 10-m water depth during January–February 2004. These combined observations suggest that fluid mud concentrations of suspended sediment (>10 g/l) and across-shore gravity currents (∼5 cm/s) were observed in the lower 20–40 cm of the water column 4–6 h after discharge events. Gravity currents were wave dominated, rather than auto-suspending, and appeared to consist of silt-to-clay sized sediment from the river. Sediment mass balances suggest that 25–50% of the discharged river sediment was transported by these hyperpycnal currents. Sediment settling purely by flocs (∼1 mm/s) cannot explain the formation of the observed hyperpycnal plumes, therefore we suggest that some enhanced sediment settling from mixing, convective instabilities, or diverging plumes occurred that would explain the formation of the gravity currents. These combined results provide field evidence that high suspended-sediment concentrations from rivers (>1 g/l) may rapidly form hyperpycnal sediment gravity currents immediately offshore of river mouths, and these pathways can explain a significant portion of the river-margin sediment budget. The fate of this sediment will be strongly influenced by bathymetry, whereas the fate of the remaining sediment will be much more influenced by ocean currents.  相似文献   

8.
Forty-three sediment samples were collected from the beaches of Miri City, Sarawak, Malaysia to identify the enrichment of partially leached trace metals (PLTMs) from six different tourist beaches. The samples were analyzed for PLTMs Fe, Mn, Cr, Co, Cu, Ni, Pb, Sr and Zn. The concentration pattern suggest that the southern side of the study area is enriched with Fe (1821–6097 μg g−1), Mn (11.57–90.22 μg g−1), Cr (51.50–311 μg g−1), Ni (18–51 μg g−1), Pb (8.81–84.05 μg g−1), Sr (25.95–140.49 μg g−1) and Zn (12.46–35.04 μg g−1). Compared to the eco-toxicological values, Cr > Effects range low (ERL), Lowest effect level (LEL), Severe effect level (SEL); Cu > Unpolluted sediments, ERL, LEL; Pb > Unpolluted sediments and Ni > ERL and LEL. Comparative results with other regions indicate that Co, Cr, Cu, Ni and Zn are higher, indicating an external input rather than natural process.  相似文献   

9.
A field experiment was conducted to investigate how water-based drill cuttings and sediment type influence colonization of soft bottom communities. Bottom frames with trays containing defaunated sediments were placed at the seabed for 6 months to study colonization of macrofauna. Two different sediments (coarse and fine) were used, and 6 or 24 mm layer of water-based drill cuttings were added on top of these sediments. Some of the sediments were controls with no additions. In the end of the experiment, the oxygen availability in sediment porewater and macrofaunal abundance were reduced in treatments with 24 mm drill cuttings compared to controls. Tube-building annelids were particularly sensitive to drill cuttings. However, these responses were only minor, and notably, the drill cuttings initiated a weaker faunal response than sediment type and site of the bottom frame. Sediments capped with water-based drill cuttings thus showed a rapid colonization of macrofaunal communities.  相似文献   

10.
Biodiversity, abundance and taxonomic composition of shallow-water zoobenthos were studied in the W?oc?awek Dam Reservoir (the lower Vistula River, central Poland). The following habitats located near the shore were studied: (1) sandy bottom in the flooded part of the reservoir; (2) sandy bottom close to the main riverine flow in the reservoir and (3) organic-rich bottom covered by a thick layer of plant remnants in a shallow, isolated cove. In each habitat we investigated two sites (ca. 0.5 and 1 m depth). Also examined was the bottom of a phytolittoral site (sandy bottom, with elodeids and nympheids, 1 m depth), located in the flooded zone. In general, the bottom fauna was highly diverse and abundant in these habitats. The highest biodiversity (38 taxa, Shannon-Wiener index=4.3) was found on the bottom rich in organic matter. However, the zoobenthos abundance in this habitat was comparatively low, probably due to periodical oxygen deficiencies. The highest density of bottom fauna (>30,000 individuals per m2), accompanied by its high biodiversity, occurred at the phytolittoral site. The benthic community of the organic-rich sediments was the most distinct, with many taxa occurring exclusively in this area. The composition of the bottom fauna, from the two sandy habitats and phytolittoral, also differed from one another. The differences in taxonomic composition between the shallower and deeper sites were less pronounced. Lower densities at the shallower sandy sites and a very high variability of taxonomic composition among particular samples from these sites indicated lower stability of their environmental conditions. These were certainly due to water level fluctuations and/or destructive wave action. On the other hand, no such differences were found between the sites of various depths from the organic-rich sediments, showing that this substratum provided better protection against adverse hydrodynamical factors.  相似文献   

11.
We examined spatial variations in benthic remineralisation (measured as sediment oxygen consumption (SOC)) and sediment properties on the northeastern New Zealand continental shelf and slope to assess the importance of benthic mineralisation in this ecosystem and to provide data for more complete global carbon budgets. SOC measured in dark incubations conducted in early summer ranged from 128 μmol m−2 h−1 at the deepest (360 m) to 1222 μmol m−2 h−1 at the shallowest (4.2 m) site and decreased significantly with water depth (p<0.001, r2=0.78, SOC=1222.8−456.3×log10[water depth], n=14 sites). These rates were in the range found on continental shelves elsewhere (64–1750 μmol m−2 h−1, n=30 studies) and had a very similar distribution with water depth. SOC was also measured in light incubations at seven sites (4.2–35 m water depth) to examine the effects of microphytobenthos and accounted for 42–106% of rates measured in the dark. Measurements of near-bed light intensities suggested that microphytobenthos production was not solely regulated by light intensity but evidently influenced by other factors. A two-dimensional PCA ordination of surface sediment properties accounted for 83.3% of the total variance in the data and divided the study area into three clusters that corresponded well to its spatial division into the shallow (<30 m) Firth of Thames, the Hauraki Gulf (30–50 m) and the northern shelf-slope region. In the Firth of Thames sediments were very fine-grained with low CaCO3 and high total organic matter and pigment content, and low C:N ratios. The northern shelf-slope sediments showed the opposite trends to the Firth of Thames and those in the Hauraki Gulf had mostly intermediate values. Dark SOC was significantly correlated with sediment organic matter, carbon, nitrogen, pigments and silt/clay content (p<0.05, r=0.55–0.85) but a multiple linear regression revealed that water depth was the only significant predictor. Calculations suggest that approximately 13%, 10% and 34% of primary production is remineralised in the sediments of the northern shelf-slope region, Hauraki Gulf and Firth of Thames, respectively, indicating a strong benthic–pelagic coupling on the northeastern New Zealand continental shelf that was particularly pronounced in the Firth of Thames due to its shallow depth and significant terrestrial and riverine inputs.  相似文献   

12.
13.
The paper analyses the concentrations of total phosphorus and its forms in sediments from the Gulf of Gdańsk on the basis of studies conducted at 25 sampling sites in 2001–05. The phosphorus speciation analysis was performed by sequential extraction. The extensive spatial variability of Ptot concentrations and speciation was found to be dependent on the physicochemical properties of the sediments, the oxygen conditions in the water and sediments, and the depth of the water column above the sediment surface. In the coastal zone, the sedimentation of riverine suspended matter and the sorption and chemisorption processes exert a considerable influence on P speciation. Over 70% of variation of total phosphorus concentration in sediments in the Gulf of Gdańsk could be explained by changes of proportion of fine fraction of sediments (grain size <0.0625 mm). Maximum Ptot concentrations were recorded in clays and silts in the deep water, stratified part of the Gulf of Gdańsk. In the coastal zone, where sandy sediments are dominant, phosphorus concentrations were much lower; this was due to the considerable dynamics of the bottom water and intensive sea floor transport. Ptot concentrations in the Gulf of Gdańsk sediments ranged from 1.75 to 957.17 μmol g−1 d.w. Of all the forms of phosphorus, the highest concentrations were found for organic phosphorus (Org-P). Of its inorganic forms, the highest concentrations were of phosphorus bound to clay minerals and aluminium oxides (NaOH-P), the lowest ones were of loosely bound phosphorus (NaCl-P). On the basis of determinations of total phosphorus concentrations in sediments of a given type and the available data on the seabed areas covered by particular sediment types in the Gulf of Gdańsk, the mass of total phosphorus in the surficial sediment layer (0–2 cm) was estimated at ca. 15.6×103 tonnes.  相似文献   

14.
Platinum contamination in estuarine and coastal sediments has been evaluated in three cores collected from the Tagus Estuary and Prodelta shelf sediments. Elevated concentrations, up to 25-fold enrichment compared to background values, were found in the upper layers of the estuarine sediments. The degree of Pt enrichment in the estuarine sediments varied depending on the proximity to vehicular traffic sources, with a maximum concentration of 9.5 ng g−1. A considerable decrease of Pt concentrations with depth indicated the absence of significant contamination before the introduction of catalytic converters in automobiles. Platinum distribution in the Tagus Prodelta shelf sediment core showed no surface enrichment; instead a sub-surface maximum at the base of the mixed layer suggested the possibility of post-depositional mobility, thereby blurring the traffic-borne contamination signature in coastal sediments.  相似文献   

15.
Water column profiles and near-bed time series of pressure, current velocity, suspended-particulate matter (SPM) concentration and seawater temperature and salinity were collected during three short cruises carried out in May 2005 in the shoreface and inner shelf area adjacent to Cassino Beach, southern Brazil. The measurements were part of the Cassino Experiment, a project conducted at an open, sandy coastal area known for the occurrence of patches of fairly large amounts of muddy sediments that are sporadically fluidized, transported onshore and eventually stranded on the beach. The study area is close to the Patos Lagoon mouth, being influenced by its water and suspended-sediment discharge. The presence of the Patos Lagoon outflow on the inner shelf was detected in one of the cruises (May 13) through measurements of near-surface salinity: while close to shore salinity was 29.4, a minimum value of 13.8 was measured at ∼10 km from the coast. Four days later, no trace of the plume was detected in the area. Regarding seawater temperature, no large temporal or spatial variability was documented with measured values ranging from 19.3 to 20 °C. Water column currents were prominently to N and NE, except at the outermost station, located ∼42 km from the coast, where NW-directed flows were observed at surface and mid-depth. Maximum near-bed current velocity oscillated between 18 and 42 cm s−1 in the east–west direction and between 14 and 42 cm s−1 in the north–south direction. Near-surface concentration of SPM oscillated between 11 and 99 mg L−1, in general one order of magnitude lower than near-bed values. However, near-bed concentration of SPM showed large spatial variability: the highest value (2200 mg L−1) was yielded by a water sample collected at ∼8 m water depth, at a station located ∼2 km away from the shoreline; two water samples collected 500 m, apart from this station, yielded SPM concentrations of 148 and 205 mg L−1, one order of magnitude lower. Spectral analyses of near-bed current speed and SPM concentration indicate the relevance of oscillations in the low-frequency (<0.05 Hz) range. Detailed sampling of bottom sediment indicated that in May 2005 the mud patch was centered at ∼8.5 m water depth.  相似文献   

16.
Field experiments were carried out to evaluate the effect of Granulated Coal Ash (GCA) on remediation of coastal sediments in terms of removing phosphates and hydrogen sulfide. Phosphate concentrations in the sediment were kept below 0.2 mg/l after the application of GCA, whereas those in the control sites increased up to 1.0 mg/l. The concentration of hydrogen sulfide in the sediment was maintained at almost zero in the experimental sites (GCA application sites) for over one year, whereas it ranged 0.1–2.4 mg S L−1 in control sites. Meanwhile, individual number of benthos increased in the experimental sites by several orders of magnitude compared to the control sites. The major process involved in hydrogen sulfide removal by GCA was thought to be the increase in pH, which suppresses hydrogen sulfide formation. From our findings, we concluded that GCA is an effective material for remediating organically enriched coastal sediment.  相似文献   

17.
Matrix bound phosphine (MBP), a kind of chemically reduced phosphorus, has received limited attention in prevailing modeling of the phosphorus biogeochemical cycle. MBP has been found to occur in marine sediments. MBP in the sediments of the Yellow Sea and its coastal areas was measured by gas chromatography from 2004 to 2007. MBP levels in surface sediments were 0.19–38.24 ng kg−1 in the shelf of the Yellow Sea, 0.34–17.15 ng kg−1 in the Jiaozhou Bay, 2.11–71.79 ng kg−1 in the Sanggou Bay and 0.28–319.32 ng kg−1 in the rivers around the Jiaozhou Bay. High levels of MBP occurred in the northern and middle areas of the Yellow Sea. Obvious seasonal variation of MBP was observed in surface sediments of the Sanggou Bay, with the highest MBP level occurring in summer and the lowest in winter. MBP in surface sediments of the inner Jiaozhou Bay was higher than those in the outer region. MBP levels increased with depth in the top 5–10 cm sediments of the Jiaozhou Bay and on the intertidal flats. Environmental factors such as type of sediments, temperature, organic matter and human activity were found to affect the concentrations and distribution of MBP in marine sediments.  相似文献   

18.
Side scan sonar records, sediment textural characteristics, and in-situ field observations were used to study gravelly and pebbly dunes and sorted bedforms on the inner shelf of Marettimo Island, along the northwestern Sicilian shelf. The dunes are composed of coarse sands, gravels and pebbles (D50: 2–16 mm), displaying a symmetrical shape with a wavelength in the range of 1–2.5 m and a height of 0.15–0.30 m. The bedforms are distributed in a patchy pattern in a depth range of 10–50 m, and are described for the first time on a Mediterranean inner shelf. Sorted bedforms are linear morphological features developed almost perpendicular to the coast in the eastern sector of the island between 15 and 50 m water depth. Bottom shear stresses required for sediment entrainment and the generation of the shallower dunes can be reached during strong storms (Hs=5–6 m; Tp=9–11 s), which are not common in the Mediterranean Sea. However, wave storm events recorded in the study area during the last 17 years are not able to generate the coarsest and deeper dunes, suggesting that the stirring mechanism for dune formation is associated with severe storms that have a recurrence interval of more than 17 years. The long-term stability of the coarse bedforms is supported by the permanence of sorted bedforms without significant morphological changes for long periods (>13 years). Therefore, it is shown that processes forming coarse bedforms can occur in tideless and moderate-energy settings like those of the Mediterranean continental shelves, although the morphological features are probably less dynamic and remain unaltered for longer periods than on higher-energy shelves.  相似文献   

19.
Georges Bank is one of the world’s most productive marine ecosystems, but the lack of accurate broad-scale sediment maps presently limits habitat assessments and spatial fisheries management. From 1999 to 2009 we surveyed 36,669 km2 of Georges Bank using 2.8 and 0.6 m2 quadrats viewed with live underwater video (video quadrats). The sediment types observed in 61,604 quadrats were used to map and evaluate spatial structure of local surficial sediment coarseness, dominance, heterogeneity, and maximum size characteristics at a 1 km2 spatial resolution. Sand dominated sediment covered 62% of the study area, and there was a logarithmic decline in coverage by larger, coarser and more heterogeneous sediments. Gravel dominated sediments covered 38% of the study area and were more than twice as abundant as previously estimated. A 12,890 km2 swath of gravel dominated seabed stretched from Cape Cod to northeastern Georges Bank consistent with estimates of prehistoric glacial extent. Within the swath there were 14 large gravel outcrops (15–2743 km2) . This work increases the spatial resolution of sediment information available for habitat assessments and spatial fisheries management on Georges Bank by two orders of magnitude. The four sediment characteristics we evaluated support further detailed investigations of the Bank’s benthos, including the influences of surficial sediment characteristics on species and community distributions, and more spatially accurate estimates of seabed roughness. Finally, this work demonstrates the use of video quadrats as an alternative to traditional grab sampling and modern acoustic sampling for continental shelf-scale mapping.  相似文献   

20.
Surface sediments collected from 2001 to 2011 were analyzed for total petroleum hydrocarbons (TPH) and five heavy metals. The sediment concentration ranges of TPH, Zn, Cu, Pb, Cd and Hg were 6.3–535 μg/g, 58–332 μg/g, 7.2–63 μg/g, 4.3–138 μg/g, 0–0.98 μg/g, and 0.10–0.68 μg/g, respectively. These results met the highest marine sediment quality standards in China, indicating that the sediment was fairly clean. However, based on the effects range-median (ERM) quotient method, the calculated values for all of the sampling sites were higher than 0.10, suggesting that there was a potential adverse biological risk in Bohai Bay. According to the calculated results, the biological risk decreased from 2001 to 2007 and increased afterwards. High-risk sites were mainly distributed along the coast. This study suggests that anthropogenic influences might be responsible for the potential risk of adverse biological effects from TPH and heavy metals in Bohai Bay.  相似文献   

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