High-speed metal-semiconductor-metal photodiodes with Er-doped GaAs

Very high-speed MSM photodiodes have been fabricated on Er-doped GaAs over a doping range of 10¹⁸-10²⁰ cm^-3 . The impulse response (characterized by photoconductive sampling) of these diodes, with finger widths/spacings of 2 μm, has been found to be tunable over a range of about 3 ps-22 ps. Electro-optic sampling was used to characterize MSM diodes with finger widths/spacings of 0.5 μm and 1 μm on a sample with [Er]=10¹⁹ cm^-3, resulting in 3-dB bandwidths of 160 GHz and 140 GHz, respectively, corresponding to pulse widths of 2.7 ps and 3.3 ps. Correlation measurements were also done on the GaAs:Er samples, using an all-electronic Sampling Optical Temporal Analyzer (SOTA) structure     

Molecular beam epitaxy growth of TmP/GaAs and transistor action inGaP/TmP/GaAs heterostructures

The growth of thulium phosphide (TmP) by molecular beam epitaxy (MBE) on GaAs substrate is reported. Good epilayer quality was demonstrated through X-ray diffraction (XRD), atomic force microscopy (AFM) and transmission electron microscopy (TEM) analysis. The closely lattice matched TmP layer was n-type with an electron concentration of 1.6×10²¹ cm^-3 and a room temperature mobility of 4.8 cm²V^-1s^-1. The Schottky barrier height determined from 1/capacitance² (1/C²) versus voltage (V) measurements is about 0.81 eV which agrees well with the value obtained through the current-voltage (I-V) measurements. In this work, we also report transistor action in a GaP/TmP/GaAs structure, for which chemical bonding techniques were employed. From I-V measurements, a common base current gain α≈0.55 at V_CB=0 was obtained at room temperature     

Properties of ion-implanted junctions in mercury—cadmium—telluride

The formation of n-p junctions by ion-implantation in Hg0.71Cd0.29Te is shown to be a result of implantation damage. n-p photodiodes have been made by implantation of Ar, B, Al, and P in a p-type substrate with acceptor concentration of 4 × 10¹⁶cm^-3. The implanted n-type layer is characterized by sheet electron concentration of 10¹⁴to 10¹⁵cm^-2and electron mobility higher than 10³cm². V^-1. s^-1, for ion doses in the range 10¹³-5 × 10¹⁴cm^-2. The photodiodes have a spectral cutoff of 5.2 µm, quantum efficiency higher than 80 percent, and differential resistance by area product above 2000 Ω . cm²at 77 K. The temperature dependence of the differential resistance is discussed. The junction capacitance dependence on reverse voltage fits a linearly graded junction model. Reverse current characteristics at 77 K have been investigated using gate-controlled diodes. The results suggest that reverse breakdown is dominated by interband tunneling in field-induced junctions at the surface, for both polarities of surface potential.     

Intersubband lifetimes in Si/SiGe quantum wells

In the present work we report the first measurement of intersubband lifetimes in Si/Si_1−xGe_x quantum well samples. We have determined T₁ by a time resolved pump and probe experiment using the far infrared picosecond free electron laser source FELIX at Rijnhuizen, the Netherlands. In a sample with a well width of 50 Å and a sheet density of 2.1 × 10¹² cm⁻² we find a lifetime of 30 ps while 20 ps is observed for a density of 1.1 × 10¹² cm⁻² and a well width of 75 Å. We discuss acoustic phonon, as well as optical phonon intersubband scattering as possible limiting processes for the observed lifetimes in Si/SiGe and GaAs/AlGaAs quantum wells.     

A high resolution frequency multiplier for clock signal generation

This paper presents a high resolution frequency multiplier (FMUL) with the ability to multiply frequency with a programmable high multiplication factor, in the order of 10²-10⁴ and of the form N/M. It was designed for chip-sets that use a real time clock (32768 Hz) for power-save operation, and an additional high-frequency oscillator, in the range of 40-60 MHz, for regular operation. Using the FMUL spares the need for the additional high-frequency oscillator. The FMUL's frequency resolution is 100 ppm, and its jitter is less than 200 ps. The circuit is designed to work with 25 V supply voltage. It is implemented in a standard 0.8 pm N-well CMOS process, and its area is 0.48 mm²     

Hot-electron InGaAs/InP heterostructure bipolar transistors withfT of 110 GHz

A hot-electron InGaAs/InP heterostructure bipolar transistor (HBT) is discussed. A unity-current-gain cutoff frequency of 110 GHz and a maximum frequency of oscillation of 58 GHz are realized in transistors with 3.2×3.2-μm² emitter size. Nonequilibrium electron transport, with an average electron velocity approaching 4×10⁷ cm/s through the thin (650 Å) heavily doped (p=5×10¹⁹ cm^-3) InGaAs base and 3000-Å-wide collector space-charge region, results in a transit delay of 0.5 ps corresponding to an intrinsic cutoff frequency of 318 GHz     

High-performance AlGaAs/GaAs SDHTs and ring oscillators grown byMBE on Si substrates

High-performance AlGaAs/GaAs selectively doped heterojunction transistors (SDHTs) and 19-stage oscillators fabricated on silicon substrates are discussed. Epitaxial layers of AlGaAs/GaAs were grown by MBE on Si substrates. The mobility of two-dimensional electron gas (2DEG) in the SDHTs was as high as 53000 cm²/V-s at 77 K for a sheet charge density of 10×1¹² cm^-2. For 1-μm-gate-length devices, maximum transconductances of 220 and 364 mS/mm were measured at 300 and 77 K, respectively, for the SDHTs. A minimum propagation delay time of 27 ps/stage at room temperature was obtained for a 19-stage direct-coupled FET logic ring oscillator with a power dissipation of 1.1 mW/stage. The propagation delay time was reduced to 17.6 ps/stage at 77 K. From microwave S-parameter measurements at 300 K, current gain and power gain cutoff frequencies of 15 and 22 GHz, respectively, were measured. These results are comparable to those obtained for SDHT technology on GaAs substrates     

Turn-on process in 4H-SiC thyristors

Detailed turn-on measurements of 4H-Silicon Carbide (SiC) npnp thyristors are presented for a wide range of operating conditions. Comparisons with similarly-rated silicon and Gallium Arsenide thyristors show a superior rise time and pulsed turn-on performance of SiC thyristors. Rise time for a 400 V blocking voltage, 4 V forward drop (2.8×10³ A/cm²) SiC thyristor has been found to be of the order of 3-5 ns. Pulsed turn on measurements show a residual voltage of only 50 V when a current density of 10⁵ A/cm² (35 A) was achieved in 20 ns     

Electrical characteristics of 4.5 kV implanted anode 4H-SiC p-i-njunction rectifiers

4500 V 4H-SiC p-i-n junction rectifiers with low on-state voltage drop (3.3-4.2 V), low reverse leakage current (3×10^-6 A/cm²), and fast switching (30-70 ns) have been fabricated and characterized. Forward current-voltage measurements indicate a minimum ideality factor of 1.2 which confirms a recombination process involving multiple energy levels. Reverse leakage current exhibits a square root dependence on voltage below the punchthrough voltage where leakage currents of less than 3×10^-6 A/cm² are measured. Reverse recovery measurements are presented which indicate the presence of recombination at the junction perimeter where a surface recombination velocity of 2-8×10⁵ cm/s is found. These measurements also indicate drift layer bulk carrier lifetimes ranging from 74 ns at room temperature to 580 ns at 250°C     

Erase/write cycle tests of n-MOSFETs with Si-implantedgate-SiO2

To discuss the applicability of a MOSFET with Si-implanted gate-SiO₂ of 50 nm thickness to a non volatile random access memory (NVRAM) operating more than 3.3×10¹⁵ erase/write (E/W) cycles, E/W-cycle tests were performed up to 10¹¹ cycles by measuring the hysteresis curve observed in a source follower MOSFET in which a sine-wave voltage of 100 kHz was supplied to the gate. Degradations in the threshold-voltage window of 15 V and gain factor were scarcely observed in a MOSFET with Si-implantation at 50 keV/1×10¹⁶ cm^-2 at a gate voltage of ±40 V. Those degradations observed in a MOSFET with 25 keV/3×10¹⁶ cm^-2 were improved by lowering the gate voltage from ±40 V to ±30 V in sacrificing the smaller threshold-voltage window from 20 to 8.5 V     

Ion-dosage-dependent room-temperature hysteresis in MOS structureswith thin oxides

Two sets of metal-oxide-silicon (MOS) structures with oxide thicknesses of 115 and 350 Å, respectively, were exposed to 16-keV Si ion beams after dry oxidation. Small-signal capacitance-voltage measurements at room temperature revealed a hysteresis effect in the ion exposed samples, whose magnitude and direction depended on the ion dosage. No hysteresis could be detected in the control (unimplanted) samples. Mobile charge species in the oxide dominated the hysteresis effect for dosages below 10¹³/cm². Around this dosage, electron trapping/detrapping at the Si-SiO₂ interface began to take place. From the rate of the parallel voltage shifts of the C-V characteristics with respect to time, electron trapping and the mobile oxide charge transfer from the silicon/oxide to the aluminum/oxide interface were found to be faster than electron detrapping and the mobile oxide charge transfer form the oxide/Al to the Si-SiO₂ interface. With increasing dosage, the magnitude of the hysteresis came down and reversed its sign as the dosage approached 10¹³/cm². Experimental results suggest immobilization of the mobile oxide charge by lattice disorder induced by the energetic ions, and generation of oxide electron traps in the vicinity of the silicon/oxide interface after the lattice damage becomes heavy     

Electron and hole traps in SiO2 films thermally grown onSi substrates in ultra-dry oxygen

The densities of electron and hole traps in SiO₂ films, thermally grown on Si substrates in ultra-dry oxygen, were compared with those in SiO₂ films grown in pyrogenic steam (wet-oxide films). The results show that ultra-dry-oxide films have an undetectable density of electron traps that is less that 10¹¹/cm² , and little interface-states generation during carrier injection. However, hole traps in ultra-dry-oxide films are high, (2.6±0.1)×10¹²/cm² compared with (1.3±0.2)×10¹²/cm² in wet-oxide films, and these increase by a factor of two with post-oxidation anneal in ultra-dry Ar. The results of electron spin resonance measurements of E' centers in SiO₂ films are consistent with the results of electrical measurements. These suggest that there is a tradeoff correlation between the density of electron traps and hole traps, with respect to the amount of water- or hydrogen-related defects in SiO₂     

High quality SiO2/Si interfaces of poly-crystallinesilicon thin film transistors by annealing in wet atmosphere

A new post-metallization annealing technique was developed to improve the quality of metal-oxide-semiconductor (MOS) devices using SiO ₂ films formed by a parallel-plate remote plasma chemical vapor deposition as gate insulators. The quality of the interface between SiO₂ and crystalline Si was investigated by capacitance-voltage (C-V) measurements. An H₂O vapor annealing at 270°C for 30 min efficiently decreased the interface trap density to 2.0×10¹⁰ cm^-2 eV^-1, and the effective oxide charge density from 1×10 ¹² to 5×10⁹ cm^-2. This annealing process was also applied to the fabrication of Al-gate polycrystalline silicon thin film transistors (poly-Si TFT's) at 270°C. In p-channel poly-Si TFT's, the carrier mobility increased from 60-400 cm² V^-1 s^-1 and the threshold voltage decreased from -5.5 to -1.7 V     

Nitrogen Implantation to Improve Electron Channel Mobility in 4H-SiC MOSFET

Normally off 4H-SiC MOSFET devices have been fabricated on a p-type semiconductor and electrically characterized at different temperatures. A gate oxide obtained by nitrogen ion implantation performed before the thermal oxidation of SiC has been implemented in n-channel MOSFET technology. Two samples with a nitrogen concentration at the SiO₂/SiC interface of 5 X 10¹⁸ and 1.5 X 10¹⁹ cm^-3 and one unimplanted sample have been manufactured. The sample with the highest N concentration at the interface presents the highest channel mobility and the lowest threshold voltage. For increasing temperature, in all the samples, the threshold voltage decreases, and the electron channel mobility increases. The latter case attains a maximum value of about 40 cm²/V ldr s at 200degC for the sample with the highest N concentration. These trends are explained by the reduction of interface electron traps in the upper half of the band gap toward the conduction band edge. These results demonstrate that N implantation can be effectively used to improve the electrical performances of an n-type surface channel 4H-SiC MOSFET.     

High-speed InP/InGaAs heterojunction bipolar transistors

Very-high-performance common-emitter InP/InGaAs single heterojunction bipolar transistors (HBTs) grown by metalorganic molecular beam epitaxy (MOMBE) are reported. They exhibit a maximum oscillation frequency (f_T) of 180 GHz at a current density of 1×10⁵ A/cm². this corresponds to an (R_BC_BC)_eff=f _T/(8πf²_max) delay time of 0.12 ps, which is the smallest value every reported for common-emitter InP/InGaAs HBTs. The devices have 11 μm² total emitter area and exhibit current gain values up to 100 at zero base-collector bias voltage. The breakdown voltage of these devices is high with measured BV_CEO and BV_CEO of 8 and 17 V, respectively     

Saturable absorbers based on impurity and defect centers incrystals

Saturation of near-infrared absorption and transmission dynamics are investigated in tetravalent-chromium-doped Gd₃Sc₂ Ga₃O₁₂, Gd₃Sc₂Al₃ O₁₂, and Mg₂SiO₄ crystals, as well as in reduced SrTiO₃ using 20 ps 1.08 μm laser pulses. An absorption cross section of (5±0.5)×10^-18 cm² in garnets and (2.3±0.3)×10^-18 cm² in forsterite is estimated for the ³A ₂-³T₂ transition of tetrahedral Cr⁴⁺. Q-switched and ultra-short pulses are realized in neodymium lasers using chromium-doped crystals as the saturable absorbers. Saturation of free-carrier absorption with ultra-short relaxation time is observed in SrTiO₃ at 10⁸-10 ¹⁰ W/cm² pump intensities, while at 10¹⁰-10¹¹ W/cm² three-photon interband transitions predominate. The free-carrier absorption cross section is estimated to be (2.7±0.3)×10^-18 cm²     

Transport of the photoexcited electron-hole plasma in InP

Transport properties of the photoexcited electron-hole plasma in n-type InP have been studied by the spatial-imaged, time-resolved Raman scattering technique with 30μm and 0.1μm spatial resolution for lateral and perpendicular transport, respectively, and on a picosecond time scale. The plasma density ranging from 1 × 10¹⁶ to 2 × 10¹⁷ cm⁻³ was deduced from fitting of the Raman spectra with the plasmon-LO phonon scattering theory which took into account the contributions from free holes. In contrast to the experimental results of Young and Wan who found that ordinary diffusion equation was sufficient to fit their transient plasma density-time profiles in semi-insulating InP, our experimental measurements have shown that perpendicular transport (i.e., expansion into the bulk crystal) of the plasma in n-type InP can be very well described by a modified diffusion equation including the effect of drifting away from the surface based on a hydrodynamic model. The transient plasma density-time profiles were studied at T = 300K and for an initial injected plasma density n 2 × 10¹⁷ cm⁻³. The plasma has been found to expand laterally at a velocity V 5 × 10⁴ cm/sec and perpendicularly into the crystal at a velocity Vp 1.5 × 10⁵ cm/sec.     

C-V Characteristics of GaP MOS diode with anodic oxide film

Gallium phosphide was anodically oxidized in an aqueous H2O2solution and MOS diodes were fabricated by the evaporation of aluminum. The resistivity and electric breakdown strength were higher than 10¹⁴Ω.cm and 6 × 10⁶V/cm, respectively. Almost no frequency dispersion was observed in the C-V curves from 100 Hz to 1 MHz. The C-V curve showed the injection-type hysteresis. From the hysteresis window, the transferred charged carriers were estimated to be about 9 × 10¹¹/cm². By leaving the diode biased at negative voltage or by shining light with energy higher than 1.8 eV, the curve shifted to negative voltage direction. The results indicate that the density of the fast interface states which follow the 100-Hz signal is very low but there exist deep electron traps with activation energy higher than 1.8 eV near the surface in the oxide film and the shallower electron traps which cause the hysteresis in the dark.     

Carrier transport related analysis of high-power AlGaN/GaN HEMTstructures

Shubnikov-de Haas (SdH) oscillation and Hall measurement results were compared with HEMT DC and RF characteristics for two different MOCVD grown AlGaN-GaN HEMT structures on semiinsulating 4H-SiC substrates. A HEMT with a 40-nm, highly doped AlGaN cap layer exhibited an electron mobility of 1500 cm²/V/s and a sheet concentration of 9×10¹² cm at 300 K (7900 cm²/V/s and 8×10¹² cm^-2 at 80 K), but showed a high threshold voltage and high DC output conductance. A 27-nm AlGaN cap with a thinner, lightly doped donor layer yielded similar Hall values, but lower threshold voltage and output conductance and demonstrated a high CW power density of 6.9 W/mm at 10 GHz. The 2DEG of this improved structure had a sheet concentration of n_SdH=7.8×10¹² cm^-2 and a high quantum scattering lifetime of τ_q=1.5×10^-13 s at 4.2 K compared to n_SdH=8.24×10¹² cm^-2 and τ_q=1.72×10^-13 s for the thick AlGaN cap layer structure, Despite the excellent characteristics of the films, the SdH oscillations still indicate a slight parallel conduction and a weak localization of electrons. These results indicate that good channel quality and high sheet carrier density are not the only HEMT attributes required for good transistor performance     

Low-operation voltage of InGaN-GaN light-emitting diodes withSi-doped In0.3Ga0.7N/GaN short-period superlatticetunneling contact layer

InGaN/GaN multiple-quantum-well light-emitting diode (LED) structures including a Si-doped In_0.23Ga_0.77N/GaN short-period superlattice (SPS) tunneling contact were grown by metalorganic vapor phase epitaxy. In_0.23Ga_0.77N/GaN(n⁺)-GaN(p) tunneling junction, the low-resistivity n⁺-In_0.3Ga_0.77 N/GaN SPS instead of high-resistivity p-type GaN as a top contact layer, allows the reverse-biased tunnel junction to form an “ohmic” contact. In this structure, the sheet electron concentration of Si-doped In_0.23Ga_0.77N/GaN SPS is around 1×10¹⁴/cm², leading to an averaged electron concentration of around 1×10²⁰/cm³. This high-conductivity SPS would lead to a low-resistivity ohmic contact (Au/Ni/SPS) of LED. Experimental results indicate that the LEDs can achieve a lower operation voltage of around 2.95 V, i.e., smaller than conventional devices which have an operation voltage of about 3.8 V