Compressive strength,modulus of elasticity,and water permeability of inorganic polymer concrete

Inorganic polymer concretes (IPCs) were produced from rice husk–bark ash (RHBA) combined with fly ash (FA) as a cementitious raw material. Six different mixtures were used to study the properties of IPC. Since RHBA is rich in silica material, varying the ratio of FA to RHBA results in differing SiO₂/Al₂O₃ ratios. To keep the SiO₂/Al₂O₃ ratio constant, the ratio of FA to RHBA was fixed at 80:20 by weight. High concentration sodium hydroxide solution and sodium silicate solution were used as a liquid component of the concrete mixture. The mixing and curing of these inorganic polymer concretes were performed under ambient conditions. Compressive strength, modulus of elasticity, and water permeability of the IPCs were investigated at specified intervals up to 90 days. The results showed that the compressive strength, modulus of elasticity, and water permeability of IPCs depend on the mix proportions, especially the solution to ash (S/A) ratio and the paste to aggregate (P/Agg) ratio. Moreover, the results showed that the water permeability and the elastic modulus of IPCs were significantly related to their compressive strength.     

High rate electrochemical performances of nanosized ZnO and carbon co-coated LiFePO4 cathode

The high rate electrochemical performances of ZnO and carbon co-coated LiFePO₄ have been studied by X-ray diffraction, high-resolution transmission electron microscope, electrochemical impedance spectroscopy, cyclic voltammetry and galvanostatic measurements. The carbon coated LiFePO₄ material was prepared by a freeze-drying method, and the diffusion coefficient and exchange current of these materials were calculated from their electrochemical impedance spectroscopy. The electrode delivered a reversible capacity of about 90% of the theoretical capacity when cycled between 2.5 and 4.2 V and showed stable cycle performance at high charge/discharge rates. This study showed that the co-coating process and freeze-drying method can effectively improve the electrochemical performances of LiFePO₄ materials.     

Microstructure and mechanical performance of metal-composite hybrid joints produced by FricRiveting

The mechanical performance and microstructure of friction riveted metallic-insert joints made of polyether ether ketone composite reinforced with 30% short carbon fibers and titanium grade 3 was studied. The metallic-insert joints reached a maximal pull-out tensile force of 10.6 kN, which corresponds to 100% of the titanium base material strength. It was shown the pull-out force increased as the rivet tip widened. Frictional heat during the process was mainly generated by the friction between the tip of the rivet and the composite substrate in the friction zone. Microstructural analyses of the metallic part of the joint revealed the presence of different microstructural zones: a friction zone, and two thermomechanically affected zones 1 and 2. Based on the composite morphology, the composite part of the joint was categorized into three different zones: the stir zone, a thermomechanically affected zone and a heat-affected zone. A study of the material flow showed that the flow of the composite was strongly affected by the rotation and axial movement of the rivet.     

Electronic behavior of calcined material obtained from a gallium-N-phenylene-N hybrid copolymer

Calcination of a gallium-N-phenylene-N hybrid copolymer under an argon atmosphere gave nano-sized gallium nitride-carbon cluster composite material. ESR spectral examinations of the calcined materials reveals the possibility of an electron transfer in the process of gallium nitride → carbon clusters with an oxidation site at gallium nitride particles and a reduction site at carbon clusters. The calcined material was found to reduce methylene blue under visible light irradiation.     

Mechanical,thermal and morphological characterization of cellulose fiber-reinforced phenolic foams

In this work, the compressive mechanical properties, thermal stability and morphology of cellulose fiber-reinforced phenolic foams were studied. The cellulose fiber-reinforced phenolic foam showed the greatest compressive mechanical properties by incorporating 2 wt.% of the reinforcement. The compressive modulus and strength of 2 wt.% cellulose fiber-reinforced phenolic foam were increased by 21% and 18%, respectively, relative to the unreinforced material. The addition of the cellulose fibers to the phenolic foam slightly decreased the thermal stability of the material. The study on the morphology of the cellulose-reinforced phenolic foams via Scanning electron microscopy (SEM) indicated a strong bonding between the fibers and phenolic matrix. In addition, the incorporation of the cellulose fibers into the foam resulted in a decreased cell size and increased cell density of the material. The incorporation of 2 wt.% of cellulose fibers into the phenolic foam led to obtain the material with the best features.     

Thermo-mechanical performance of an ablative/ceramic composite hybrid thermal protection structure for re-entry applications

Hybrid thermal protection systems for aerospace applications based on ablative material (ASTERM™) and ceramic matrix composite (SICARBON™) have been investigated. The ablative material and the ceramic matrix composite were joined using graphite and zirconia–zirconium silicate based commercial high temperature adhesives. The thermo-mechanical performance of the structures was assessed from room temperature up to 900 °C. In all the joints there is a decrease of shear strength with the increase of temperature. Analysis of the fractured surfaces showed that above 150 °C the predominant mode of fracture is cohesive failure in the bonding layer. The joints fabricated with the zirconia–zirconium silicate based adhesive present the best performance and they have the potential to be used as hybrid thermal protection systems for aerospace applications in the temperature range 700–900 °C.     

Effect of welding speed on microstructural and mechanical properties of friction stir welded Inconel 600

In order to evaluate the properties of a friction stir welded Ni base alloy, Inconel 600 (single phase type) was selected. Sound friction stir welds without weld defect were obtained at 150 and 200 mm/min in welding speed, however, a groove like defect occurred at 250 mm/min. The electron back scattered diffraction (EBSD) method was used to analyze the grain boundary character distribution. As a result, dynamic recrystallization was observed at all conditions, and the grain refinement was achieved in the stir zone, and it was gradually accelerated from 19 μm in average grain size of the base material to 3.4 μm in the stir zone with increasing the welding speed. It also has an effect on the mechanical properties so that friction stir welded zone showed 20% higher microhardness and 10% higher tensile strength than those of base material.     

Contact resistance simulations and measurements of MgB2–MgB2 lap joints

Resistive joints are found in many systems using superconductors. Joints are used to connect the superconductor to a normal conducting current terminal or to connect two superconductors, for example in pancake type windings. Knowing the resistance between the contacts is important in studying the heat balance of a superconducting system. We performed several experiments with MgB₂–MgB₂ lap joints to determine the relation between the contact resistance and solder joint length. Also, the effect of the outer sheath material on the contact resistance was studied. To support the experiments, a computational model using Finite Element Method was created. The measured and computed results showed adequate correlation. In the experiments, the soldered joint length was varied from 3 to 20 mm resulting in contact areas between 2.5 and 16.6 mm². The results indicated that the outer sheath material has significant effect on the contact resistance. For a Monel sheathed conductor the measured contact resistances varied between 4 and 16 μΩ and if a copper sheath was used, the resistances were an order of magnitude smaller.     

Mechanical and thermal behavior of non-crimp glass fiber reinforced layered clay/epoxy nanocomposites

Mechanical and thermal properties of non-crimp glass fiber reinforced clay/epoxy nanocomposites were investigated. Clay/epoxy nanocomposite systems were prepared to use as the matrix material for composite laminates. X-ray diffraction results obtained from natural and modified clays indicated that intergallery spacing of the layered clay increases with surface treatment. Tensile tests indicated that clay loading has minor effect on the tensile properties. Flexural properties of laminates were improved by clay addition due to the improved interface between glass fibers and epoxy. Differential scanning calorimetry (DSC) results showed that the modified clay particles affected the glass transition temperatures (T_g) of the nanocomposites. Incorporation of surface treated clay particles increased the dynamic mechanical properties of nanocomposite laminates. It was found that the flame resistance of composites was improved significantly by clay addition into the epoxy matrix.     

Nonlinear shear properties of spruce softwood: Numerical analyses of experimental results

Determination of material parameters from experimental tests often rely on simplifying assumptions like the existence of uniform stress and strain fields within the considered part of the test specimen. However, more detailed analyses usually show that the stress and strain fields differ from the assumed (nominal) uniform distributions. In order to utilize the potential of numerical analyses of wooden structures by the FEM method, the nominal material parameters measured directly from tests need to be re-evaluated in order to make them more useful for FEM models and to make FEM models more reliable.Experimental data from shear testing of clear wood from Norway spruce was analysed numerically with a bilinear material law in shear. The inherent material parameters were fitted to the experimental behaviour by means of optimization methods in conjunction with FEM analyses. The study included six Arcan test configurations comprising the three orthotropic material planes of wood, and covered the whole loading range until failure. Compared to numerical results, it was found that stiffness values measured were too high, and that downward adjustments in the range of 5–30% were required. Linear limit stresses between 40% and 60% of the nominal shear strengths were found, whilst the tangent moduli ranged between 30% and 70% of the linear elastic shear moduli. The rolling shear plane RT showed most nonlinearity and the LT plane least. Analyses with modified bilinear parameters showed good correspondence with experimental findings. The parameters were found to be relatively well adapted by Weibull distributions.     

Improved mechanical properties of an epoxy glass–fiber composite reinforced with surface organomodified nanoclays

An organomodified surface nanoclay reinforced epoxy glass-fiber composite is evaluated for properties of mechanical strength, stiffness, ductility and fatigue life, and compared with the pristine or epoxy glass-fiber composite material not reinforced with nanoclays. The results from monotonic tensile tests of the nanoclay reinforced composite material at 60 °C in air showed an average 11.7% improvement in the ultimate tensile strength, 10.6% improvement in tensile modulus, and 10.5% improvement in tensile ductility vs. these mechanical properties obtained for the pristine material. From tension–tension fatigue tests at a stress-ratio = +0.9 and at 60 °C in air, the nanoclay reinforced composite had a 7.9% greater fatigue strength and a fatigue life over a decade longer or 1000% greater than the pristine composite when extrapolated to 10⁹ cycles or a simulated 10-year cyclic life. Electron microscopy and Raman spectroscopy of the fracture and failure modes of the test specimens were used to support the results and conclusions. This nanocomposite could be used as a new and improved material for repair or rehabilitation of external surface wall corrosion or physical damage on piping and vessels found in petrochemical process plants and facilities to extend their operational life.     

Design and analysis of sandwiched fullerene-graphene composites using molecular dynamics simulations

Computational design of a novel carbon based hybrid material that is composed of fullerene units covalently sandwiched between parallel graphene sheets is presented. In this regard, atomistic models for the proposed novel material structure are generated via a systematic approach by employing different fullerene types (i.e. C₁₈₀, C₃₂₀, C₅₄₀ and C₇₂₀) as sandwich cores. Then, thermodynamic stability of the atomistic structures is checked by monitoring free energy profiles and junctional bond configurations which are obtained through classical molecular dynamics (MD) simulations. Thermodynamic feasibility of all atomistic specimens with different fullerene types is suggested by the energy profiles, because total configuration energies for all systems are minimized and remained stable over a long period of time. Furthermore, mechanical behavior of the nano-sandwiched material system is investigated by performing compression tests via MD simulations and basic deformation mechanisms underlying the compressive response are determined. By detailed examination, it is shown that proposed nano-sandwiched material can be identified as quasi-foam material due to comparable energy absorbing characteristics. Furthermore, regarding the effect of fullerene size on the compressive response, it is found that for a given stress level, specimens with larger fullerenes exhibit higher energy absorbing capacity.     

Characterisation and photocatalytic activity of structure-controlled spherical granules of an anatase/hydroxyapatite composite

Materials that can purify the environments are desirable. Anatase (TiO₂) has received attention because it is stable and can decompose organic substances because of its photocatalytic activity. To make use of anatase effectively, we deposited nano-sized anatase particles on porous hydroxyapatite (HA) ceramics composed of rod-shaped particles. Spherical porous HA granules composed of rod-shaped HA particles were prepared using a hydrothermal process. The granules were soaked in a solution containing a water-soluble titanium complex and then hydrothermally treated. Nano-sized anatase particles were deposited on each rod-shaped HA particle. The anatase/HA granules composed of rod-shaped HA particles showed higher photocatalytic activity than those composed of globular HA particles. The granules are expected to be useful as an environment-purifying material with high manageability and photocatalytic activity.     

Structural and impedance properties of KBa2V5O15 ceramics

The polycrystalline sample of KBa₂V₅O₁₅ ceramics was prepared by a mixed oxide method at low temperature (i.e., at 560 °C). The formation of the compound was confirmed using an X-ray diffraction technique at room temperature. Scanning electron micrograph of the material showed uniform grain distribution on the surface of the sample. Detailed studies of dielectric properties of the compound as a function of temperature at different frequencies suggest that the compound has a dielectric anomaly of ferroelectric to paraelectric type at 323 °C, and exhibits diffuse phase transition. Electrical properties of the material were analyzed using a complex impedance technique. The Nyquists plot showed the presence of both grain (>10³ Hz) and the grain boundary (<10³ Hz) effects in the material. Studies of electrical conductivity over a wide temperature range suggest that the compound exhibits the negative temperature coefficient of resistance behavior. The ac conductivity spectrum was found to obey Jonscher's universal power law.     

Curing kinetics and mechanical properties of a composite hydrogel for the replacement of the nucleuspulposus

A polymer material system has been developed to propose an injectable, UV and insitu curable hydrogel with properties similar to the native nucleuspulposus of intervertebral disc. Neat hydrogels based on Tween® 20 trimethacrylates (T3) and N-vinyl-2-pyrrolidone (NVP) and composite hydrogels of same composition reinforced by nano-fibrillated cellulose were synthesized with different T3 concentrations and their curing kinetics was investigated by photorheology using UV light. The T3 concentration has an influence on the time of curing and final shear stiffness of the material. NFC does not alter the time of curing but increases the final mechanical performance of the hydrogels for a same chemical composition. Hydrogel samples, neat and composite, were then tested in unconfined compression at different hydration stages and in confined compression and their elastic modulus was determined. The amount of fluid present in the network is mostly responsible for the mechanical properties and NFC fibres proved to be an efficient reinforcement. The elastic modulus ranged from 0.02 to 8 MPa. Biocompatibility studies showed that cells are confluent at 90% and do not show any morphology change when in contact with the hydrogel. The present hydrogel can therefore be considered for NP replacement.     

Mechanical performance of innovative GFRP-bamboo-wood sandwich beams: Experimental and modelling investigation

Innovative GFRP-bamboo-wood sandwich beams were developed and investigated experimentally and by modeling. The effects of the thickness of the GFRP and bamboo layers on the overall structural performance in bending were clarified. It was shown that an increase of thickness of the bamboo and GFRP layers could significantly increase the flexural stiffness and ultimate load of the sandwich beams. ANSYS was used to parametrically analyze the material efficiency and to obtain optimal solutions for the thickness of the GFRP, wood, and bamboo layers. The total depth of 60 mm and the thickness of 6 mm for bamboo and of 4.5 mm for GFRP presented the best material efficiency in terms of stiffness enhancement. A simplified model based on Timoshenko beam theory was proposed to predict the load-deflection behavior of the sandwich beams, where the section transformation method was used to calculate the stress distribution along the depth of the sandwich beams. The calculated results showed good correlation with the experimental and numerical results. Design optimization in terms of self-weight and cost of the proposed sandwich beam was conducted using MATLAB and ANSYS, and the optimized thicknes was obtained with minimized self-weight, cost, and acceptable mechanical performance.     

Fabrication of thermoplastic polyester elastomer/layered zinc hydroxide nitrate nanocomposites with enhanced thermal,mechanical and combustion properties

The objective of this study is to explore the potential of layered zinc hydroxide nitrate modified with sodium benzoate as nanoparticle in thermoplastic polyester elastomer (TPEE). The organically modified zinc hydroxide nitrate was compounded with TPEE using solution blending method. The nanocomposite structure was characterized by means of X-ray diffraction and transmission electron microscopy. The results showed that the nanoparticle was homogenously dispersed in TPEE matrix, and partially exfoliated structure was formed. The thermal behavior, mechanical and thermal combustion properties of the novel nanocomposite were studied respectively through differential scanning calorimeter (DSC), dynamic mechanical analysis (DMA) and microscale combustion calorimeter (MCC). For the nanocomposite containing 7 wt% nanoparticle, the crystallization temperature evaluated by DSC was increased by 10 °C. The storage modulus at −95 °C measured by DMA was improved by around 26%. The heat release capacity (an indicator of a material fire hazard) from MCC testing was reduced by about 56% (compared to the results of neat TPEE).     

Creep response of GFRP–concrete hybrid structures: Application to a footbridge prototype

Glass fibre reinforced polymer (GFRP) pultruded profiles have been increasingly used in civil engineering structural applications in the past few decades owing to their high strength, low weight and corrosion resistance. Nevertheless, the low material moduli, which makes design most often governed by deformability and instability phenomena, the brittle failure mechanisms and the high initial costs, have been delaying their widespread use. Hybrid GFRP–concrete structural solutions have been proposed to overcome the aforementioned limitations, namely the low material moduli. Furthermore, GFRP material creep models suggest that such hybrid structures may reduce the creep deformations when compared to full GFRP structures. In this context, this paper presents experimental and analytical investigations about the creep behaviour of a hybrid GFRP–concrete footbridge comprising two I-shaped GFRP pultruded profiles and a thin deck made of steel fibre reinforced self-compacting concrete (SFRSCC). The experiments comprised flexural creep tests on a 6.0 m long footbridge prototype subjected to a uniformly distributed load for up to 2642 h, during which deflections and axial deformations were monitored. In order to assess the influence of loading and environmental conditions on the creep behaviour of the structural system, the prototype was tested for three different combinations of load levels and seasons. Experimental results showed that (i) GFRP–concrete hybrid structures lead to a considerable decrease of the creep deformations of GFRP structures and that (ii) environmental conditions significantly influence the viscoelastic response of these hybrid structures. The models proposed, based on the creep response of the constituent materials, were able to predict the observed structural response for the different load levels and environmental conditions with very good accuracy. Therefore, they are proposed to predict the long-term response of GFRP–concrete structures instead of empirical models based on short-term experimental data.     

Impedance analysis of MnCoCuO NTC ceramic

Impedance spectroscopy is often used to analyse the electrical properties of ceramic materials having high-resistive grain boundaries, such as ZnO and SrTiO₃. Fewer attempts have been made at using this technique for the analysis of inhomogeneous electronic ceramics consisting of grains with differing composition, such as those occurring in negative temperature coefficient (NTC) thermistors. In this study, we have attempted to adopt ac impedance spectroscopy together with other techniques to analyse an NTC thermistor ceramic material.An Mn, Co and Cu multielements transition metal oxide (MnCoCuO) ceramic was prepared by using homogeneous precipitation employing oxalic acid. This material displayed a typical NTC effect, showing an electrical resistance decrease with temperature when dc electrical measurement was performed. The ac impedance spectroscopy analysis showed that there were two peaks in impedance and conductance versus frequency plot. By using an alternative representation of impedance spectra Z″/f versus Z′, three distinct relaxation frequency ranges were identified. They are believed to originate, respectively, from the electrode, phase 1 (rich-Cu phase) and phase 2 (poor-Cu phase) grains existing in this ceramic. SEM observation and EDX analysis clearly showed existence of two distinct phase grains. The resistance values were derived from phases 1 and 2 grains based on ac impedance data. The sum of the resistance values was in good agreement with that from dc measurement in the temperature range of 30-95 °C. The material constant, B, for the two phases was also calculated, giving 3100 and 3600 K for phases 1 and 2, respectively.     

Some technological properties of wood–styrofoam composite panels

Synthetic resins are widely used in wood based composites manufacturing. Besides their many advantages, most of them contain formaldehyde and a chemical agents that cause environmental problems. Styrofoam known as expanded polystyrene, is used all over the world for various purposes including thermal insulation, packing, coffee cups, fabrication of car parts etc. This study investigated the evaluation possibilities of styrofoam wastes in plywood production as a bonding material. Pine (Pinus pinea) and poplar (Populus deltoides I-77/51) veneers were used to produce wood–styrofoam composite (WSC) and traditional plywood. Urea-formaldehyde adhesive was used as bonding material for traditional plywood panels. Two different types of styrofoam having high density (25 kg/m³) and low density (10 kg/m³) were used as binder in the manufacturing of WSC panels. Bonding and bending strength, modulus of elasticity, density and thermal conductivity of plywood and WSC panels were investigated. Experimental results showed that mechanical properties of panels manufactured with low density styrofoam type were higher than those of panels manufactured with high density styrofoam type. The lowest thermal conductivity among the all panels was found for poplar panels manufactured with high density styrofoam.