共查询到19条相似文献,搜索用时 171 毫秒
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镁合金脉冲阳极氧化工艺 总被引:6,自引:0,他引:6
采用正交实验对镁合金在碱性环保型溶液的脉冲阳极氧化工艺进行了研究,分析了周期、占空比、电流密度、溶液温度、氧化时间等工艺参数对氧化膜层性能的影响,得出了最佳工艺为周期10 m s、占空比0.05、电流密度100 mA/cm2、温度40℃。采用扫描电镜、能谱、X射线衍射、电化学等多种测试方法对氧化膜层的性能、组分、形貌、结构以及耐腐蚀性能进行了研究。结果表明,该工艺能在镁合金表面形成灰白色的氧化膜层,膜层光滑致密,与基体结合牢固。氧化膜微观为均匀多孔结构,孔径也小于直流成膜,氧化膜主要由MgO和MgA l2O4组成,膜层耐腐蚀和结合力优于传统的直流工艺制备的膜层。 相似文献
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在正交试验基础上,利用MATLAB软件建立BP神经网络膜层耐蚀性能预测模型,通过网络模型对样本实验数据的学习,确定最佳网络结构,对钛合金微弧氧化膜耐蚀性能进行预测,并对微弧氧化工艺参数进行了优化。分析确定BP神经网络结构为4-7-1三层结构,该网络结构能够较好地掌握输入参数(电流密度、脉冲频率、占空比和氧化时间)与输出数据间(膜层腐蚀电位)的内在规律,网络的平均训练误差与平均预测误差分别为0.101%和0.596%,BP网络优化后,所得最佳参数Ja为15A/dm2、脉冲频率600Hz、占空比10%、氧化t为12min。 相似文献
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采用双脉冲电源,研究了电源参数对Ni/α-AI2O3纳米复合镀层耐蚀性的影响,得到最佳的脉冲参数为:正向脉冲频率1000Hz,正向脉冲占空比0.4,正向工作时间5ms,正向平均电流密度1.1A/dm^2,反向脉冲频率l000Hz,反向脉冲占空比0.4,反向工作时间1ms,反向平均电流密度0.44A/dm^2。 相似文献
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电流密度对AZ31B镁合金阳极氧化及膜层性能的影响 总被引:2,自引:1,他引:1
采用KOH-Na2SiO3-Na2B4O7-Na2CO3环保型电解液体系,研究了电流密度对AZ 31B铁合金阳极氧化过程、氧化膜微观形貌、膜层厚度、氧化膜耐蚀性等的影响.结果表明:在恒电流阳极氧化过程中,根据电压-时间曲线,阳极氧化过程可分为电压快速升高阶段、电压缓慢升高阶段、电压相对稳定阶段.随着电流密度的增大,电压-时间曲线的斜率增大,电压明显增大,点火时间缩短,但对击穿电压影响不大;随着电流密度的增加,膜层致密性、厚度、耐蚀性都呈先增大后减小的趋势.当电流密度为1.5 A/dm2时,阳极氧化膜的致密性和耐蚀性最好. 相似文献
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阳极氧化是提高铝镁合金表面硬度的一种有效方法。在AC7A铝合金表面制备硬质阳极氧化膜,研究了阳极氧化时间、电流密度、工作液温度以及阳极氧化溶液中硫酸浓度等工艺参数对氧化膜显微硬度及耐蚀性的影响,并对工艺参数进行了优化。结果表明,优化后的工艺参数θ为-6℃,氧化t为50 min,Ja为1~6 A/dm~2,240 g/L硫酸,硬质阳极氧化膜硬度可达480 HV,有效强化了轮胎模具花纹块配合表面的硬度,提高了其使用寿命,可以达到工件硬质阳极氧化膜硬度的要求,且氧化膜颜色深而均匀。最佳工艺参数下制备的氧化膜在240 h盐雾试验中,耐中性盐雾腐蚀性能明显提高。 相似文献
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Sealing effects of anodic oxide films formed on Mg-Al alloys 总被引:1,自引:0,他引:1
Mg alloys were anodized in alkaline NaOH solutions with various additives as a non-chromate method. Specimen AZ91 was anodized
at a potential that produced a strong surface dissolution reaction and generated a large amount of Mg(OH)2. The effect of sealing after anodizing was investigated, focusing on the effects of sealing time, temperature and solution
conditions. The current density decreased with increasing A1(OH)3 concentration in 1 M NaOH solution during anodizing; sparking occurred at potentials above 80 V. The best corrosion resistance
with anodizing in 1 M NaOH solution occurred at a potential of 4 V, which caused the strongest active dissolution reaction.
The sealing effect improved with increasing time and temperature, and corrosion resistance was proportional to the relative
ratio of Mg(OH)2. If the oxygen thickness observed by EDX equaled the film thickness, the film formed at 4 V in 1 M NaOH was 10–15 Μm thickness.
The optimum corrosion resistance in sealing at various solutions after anodizing was 1M-NaOH solution. 相似文献
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采用恒流氧化模式对二元共晶Al-Si合金进行微弧氧化(MAO)处理。在碱性电解液体系中,以Na2SiO3和C6H12N4(六次甲基四胺)质量浓度、电流密度、脉冲频率和占空比为优化对象,以膜层的耐腐蚀性能、生长速率及成膜的单位能耗同时作为评价指标,通过正交试验得到以下最优成膜工艺:电解液由12 g/L Na2SiO3、2 g/L NaOH和5 g/LC6H12N4组成,正、负向电流密度分别为10 A/dm2和4 A/dm2,脉冲频率400 Hz、占空比25%,单个周期的正负脉冲数之比为1。该工艺显著降低了Si相对共晶铝硅合金上MAO的不利影响。 相似文献
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Anodic coatings formed on magnesium alloys by plasma anodization process are mainly used as protective coatings against corrosion. The effects of KOH concentration, anodization time and current density on properties of anodic layers formed on AZ91D magnesium alloy were investigated to obtain coatings with improved corrosion behaviour. The coatings were characterized by scanning electron microscopy (SEM), electron dispersion X-ray spectroscopy (EDX), X-ray diffraction (XRD) and micro-Raman spectroscopy. The film is porous and cracked, mainly composed of magnesium oxide (MgO), but contains all the elements present in the electrolyte and alloy. The corrosion behaviour of anodized Mg alloy was examined by using stationary and dynamic electrochemical techniques in corrosive water. The best corrosion resistance measured by electrochemical methods is obtained in the more concentrated electrolyte 3 M KOH + 0.5 M KF + 0.25 M Na3PO4·12 H2O, with a long anodization time and a low current density. A double electrochemical effects of the anodized layer on the magnesium corrosion is observed: a large inhibition of the cathodic process and a stabilization of a large passivation plateau. 相似文献
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镁合金AZ61碱性阳极氧化工艺研究 总被引:1,自引:0,他引:1
文章用正交试验对镁合金AZ61的碱性阳极氧化工艺进行了优化研究,对优化条件下得到的氧化膜进行了耐蚀性能和物相分析。封孔氧化膜的主要成分是Mg(OH)2、MgSiO3、Mg0.36Al2.44O4,能够在镁合金表面形成致密膜,膜厚可达30μm,且实行封孔阻塞了腐蚀介质到达基体的通路,从而能保证氧化膜具有较强的防腐蚀性。 相似文献