Cob biomass supply for combined heat and power and biofuel in the north central USA

Corn (Zea mays L.) cobs are being evaluated as a potential bioenergy feedstock for combined heat and power generation (CHP) and conversion into a biofuel. The objective of this study was to determine corn cob availability in north central United States (Minnesota, North Dakota, and South Dakota) using existing corn grain ethanol plants as a proxy for possible future co-located cellulosic ethanol plants. Cob production estimates averaged 6.04 Tg and 8.87 Tg using a 40 km radius area and 80 km radius area, respectively, from existing corn grain ethanol plants. The use of CHP from cobs reduces overall GHG emissions by 60%–65% from existing dry mill ethanol plants. An integrated biorefinery further reduces corn grain ethanol GHG emissions with estimated ranges from 13.9 g CO₂ equiv MJ⁻¹ to 17.4 g CO₂ equiv MJ⁻¹. Significant radius area overlap (53% overlap for 40 km radius and 86% overlap for 80 km radius) exists for cob availability between current corn grain ethanol plants in this region suggesting possible cob supply constraints for a mature biofuel industry. A multi-feedstock approach will likely be required to meet multiple end user renewable energy requirements for the north central United States. Economic and feedstock logistics models need to account for possible supply constraints under a mature biofuel industry.     

Growth of microalgae using CO2 enriched air for biodiesel production in supercritical CO2

The optimum conditions for lipids productivity and CO₂ fixation of two freshwater strains, namely Chlorella sp. and Pseudochlorococcum sp. and a marine strain; namely Nannochlorpsis sp. have been determined in this work. The species were grown autotrophically under aeration with different CO₂ concentrations, ranging from 0.04 to 2% (v/v). The growth was tested in nitrogen sufficient and deficient media at different salinities (0.49–680 mM) and temperatures of 27 and 31 °C. The optimum CO₂ enrichment was found to be 1% (v/v) in both media. Nitrogen starvation resulted in an increase in lipid contents, but at lower growth rate, which resulted in a lower overall lipid productivity. The experimental data were used to determine the kinetic parameters of Haldane model. The Chlorella sp. grew well at salinity levels of up to 460 mM. The highest CO₂ biofixation rate was observed when Chlorella sp. was grown at 27 °C in seawater (230 mM NaCl).Lipids were extracted from harvested marine strain, Nannochlorpsis sp., and enzymatically transesterified to produce biodiesel in supercritical CO₂ (SC–CO₂) medium. It was found that the conversion of biodiesel produced from microalgae lipids was 35% higher than that achieved using lamb fat in a similar system.     

Supercritical water gasification of timothy grass as an energy crop in the presence of alkali carbonate and hydroxide catalysts

This study is focused on identifying the candidature of timothy grass as an energy crop for hydrogen-rich syngas production through supercritical water gasification. Timothy grass was gasified in supercritical water to investigate the impacts of temperature (450–650 °C), biomass-to-water ratio (1:4 and 1:8) and reaction time (15–45 min) in the pressure range of 23–25 MPa. The impacts of carbonate catalysts (e.g., Na₂CO₃ and K₂CO₃) and hydroxide catalysts (e.g., NaOH and KOH) at variable mass fractions (1–3%) were examined to maximize hydrogen yields. In the non-catalytic gasification of timothy grass, highest hydrogen (5.15 mol kg⁻¹) and total gas yields (17.2 mol kg⁻¹) with greater carbon gasification efficiency (33%) and lower heating value (2.21 MJ m⁻³) of the gas products were obtained at 650 °C with 1:8 biomass-to-water ratio for 45 min. However, KOH at 3% mass fraction maximized hydrogen and total gas yields up to 8.91 and 30.6 mol kg⁻¹, respectively. Nevertheless, NaOH demonstrated highest carbon gasification efficiency (61.3%) and enhanced lower heating value of the gas products (4.68 MJ m⁻³). Timothy grass biochars were characterized through Fourier transform infrared spectroscopy, Raman spectroscopy and scanning electron microscopy to understand the behavior of the feedstock to rising temperature and reaction time. The overall findings suggest that timothy grass is a promising feedstock for hydrogen production via supercritical water gasification.     

Assessing sustainable forest biomass potential and bioenergy implications for the northern Lake States region,USA

Forestlands in the United States have tremendous potential for providing feedstocks necessary to meet emerging renewable energy standards. The Lake States region is one area recognized for its high potential of supplying forest-derived biomass; however, the long-term availability of roundwood harvests and associated residues from this region has not been fully explored. Better distribution and temporal availability estimates are needed to formulate emerging state policies regarding renewable energy development. We used a novel predictive methodology to quantify sustainable biomass availability and likely harvest levels over a 100-year period in the Lake States region. USDA Forest Inventory and Analysis estimates of timberland were combined with published growth and yield models, and historic harvest data using the Forest Age Class Change Simulator (FACCS) to generate availability estimates. Monte-Carlo simulation was used to develop probability distributions of biomass harvests and to incorporate the uncertainty of future harvest levels. Our results indicate that 11.27–15.71 Mt y⁻¹ dry roundwood could be sustainably harvested from the Lake States. Assuming 65% collection rate, 1.87–2.62 Mt y⁻¹ residue could be removed, which if substituted for coal would generate 2.12–2.99 GW h of electricity on equivalent energy basis while reducing GHG (CO₂e) emission by 1.91–2.69 Mt annually. In addition to promoting energy security and reducing GHG emissions, forest residues for energy may create additional revenues and employment opportunities in a region historically dependent on forest-based industries.     

Combined ethanol and methane production from switchgrass (Panicum virgatum L.) impregnated with lime prior to steam explosion

Pretreatments are crucial to achieve efficient conversion of lignocellulosic biomass to soluble sugars. In this light, switchgrass was subjected to 13 pretreatments including steam explosion alone (195 °C for 5, 10 and 15 min) and after impregnation with the following catalysts: Ca(OH)₂ at low (0.4%) and high (0.7%) concentration; Ca(OH)₂ at high concentration and higher temperature (205 °C for 5, 10 and 15 min); H₂SO₄ (0.2% at 195 °C for 10 min) as reference acid catalyst before steam explosion. Enzymatic hydrolysis was carried out to assess pretreatment efficiency in both solid and liquid fraction. Thereafter, in selected pretreatments the solid fraction was subjected to simultaneous saccharification and fermentation (SSF), while the liquid fraction underwent anaerobic digestion (AD). Lignin removal was lowest (12%) and highest (35%) with steam alone and 0.7% lime, respectively. In general, higher cellulose degradation and lower hemicellulose hydrolysis were observed in this study compared to others, depending on lower biomass hydration during steam explosion. Mild lime addition (0.4% at 195 °C) enhanced ethanol in SSF (+28% than steam alone), while H₂SO₄ boosted methane in AD (+110%). However, methane represented a lesser component in combined energy yield (ethanol, methane and energy content of residual solid). Mild lime addition was also shown less aggressive and secured more residual solid after SSF, resulting in higher energy yield per unit raw biomass. Decreased water consumption, avoidance of toxic compounds in downstream effluents, and post process recovery of Ca(OH)₂ as CaCO₃ represent further advantages of pretreatments involving mild lime addition before steam explosion.     

Energy recovery from grass of urban roadside verges by anaerobic digestion and combustion after pre-processing

Grass from urban roadside verges is a potential, though widely unused, resource for bioenergy recovery. Two possible bioenergy recovery techniques were tested, i.e. i) direct anaerobic digestion of the whole parent material and ii) the “integrated generation of solid fuel and biogas from biomass” (IFBB) procedure, which divides biomass into a press fluid and a press cake by mashing and mechanical dewatering. Biomass yield, chemical composition and canopy height of biomass, contribution of functional groups, fermentation characteristics of silage and press fluids, as well as characteristics of the produced solid fuel was investigated, applying a 4-cut management for anaerobic digestion, a 2-cut management for IFBB and an 8 times mulching as a reference. Mean annual biomass yield (2013 and 2014) was 3.24, 3.33 and 5.68 t dry matter ha⁻¹ for the mulching, 4-cut management and 2-cut management, respectively. Yields were higher in 2014 due to more favourable weather conditions. Fibre concentration was higher in material of the 2-cut management than in the 4-cut management, however, methane yield of the corresponding silages was the same. Highest methane yield was gained from press fluids with 292 l_N kg⁻¹ volatile solids. The press cake had a lower heating value of 16 MJ kg⁻¹ dry matter and a K₂O/CaO index of 0.51–0.88. Gross energy output was 26.4 GJ ha⁻¹ for anaerobic digestion and 84.4 GJ ha⁻¹ for IFBB. Thus, an altered roadside verge management with reduced cutting frequency might allow a significant energy recovery and improved ecosystem services, i.e. increased biodiversity.     

Resource and revenue potential of California residential load participation in ancillary services

Increasing penetrations of intermittent renewable energy resources will require additional power system services. California recently adopted an energy storage mandate to support its renewable portfolio standard, which requires 33% of delivered energy from renewables by 2020. The objective of this paper is to estimate the amount of energy storage that could be provided by residential thermostatically controlled loads, such as refrigerators and air conditioners, and the amount of revenue that could be earned by loads participating in ancillary services markets. We model load aggregations as virtual energy storage, and use simple dynamical system models and publicly available data to generate our resource and revenue estimates. We find that the resource potential is large: 10–40 GW/8–12 GWh, which is significantly more than that required by the mandate. We also find that regulation and spinning/non-spinning reserve revenues vary significantly depending upon type of load and, for heat pumps and air conditioners, climate zone. For example, mean regulation revenues for refrigerators are $11/year, for electric water heaters are $24/year, for air conditioners are $0-32/year, and for heat pumps are $22–56/year. Both consumer choices, such as appliance settings, and policy, such as the design of ancillary service compensation and appliance standards, could increase revenue potentials.     

Optimization of mechanical pre-treatment of Laminariaceae spp. biomass-derived biogas

Macroalgae have not met their full potential to date as biomass for the production of energy. One reason is the high cost associated with the pretreatment which breaks the biomass's crystalline structure and better exposes the fermentable sugars to anaerobes. In the attempt to overcome this technological barrier, the performance of a Hollander beater mechanical pretreatment is assessed in this paper. This pretreatment has been applied to a batch of Laminariaceae biomass and inoculated with sludge from a wastewater treatment plant. The derived biogas and methane yields were used as the responses of a complex system in order to identify the optimal system input variables by using the response surface methodology (RSM). The system's inputs considered are the mechanical pretreatment time (5–15 min range), the machine's chopping gap (76–836 μm) and the mesophilic to thermophilic range of temperatures (30–50 °C). The mechanical pretreatment was carried out with the purpose of enhancing the biodegradability of the macroalgal feedstock by increasing the specific surface area available during the anaerobic co-digestion. The pretreatment effects on the two considered responses are estimated, discussed and optimized using the tools provided by the statistical software Design-Expert v.8. The best biogas yield of treated macroalgae was found at 50 °C after 10 min of treatment, providing 52% extra biogas and 53% extra methane yield when compared to untreated samples at the same temperature conditions. The highest biogas rate achieved by treating the biomass was 685 cc gTS⁻¹, which is 430 cc gTS⁻¹ in terms of CH₄ yield.     

Net N2O and CH4 soil fluxes of annual and perennial bioenergy crops in two central German regions

The area used for bioenergy feedstock production is increasing because substitution of fossil fuels by bioenergy is promoted as an option to reduce greenhouse gas (GHG) emissions. However, agriculture itself contributes to rising atmospheric nitrous oxide (N₂O) and methane (CH₄) concentrations. In this study we tested whether the net exchanges of N₂O and CH₄ between soil and atmosphere differ between annual fertilized and perennial unfertilized bioenergy crops. We measured N₂O and CH₄ soil fluxes from poplar short rotation coppice (SRC), perennial grass-clover and annual bioenergy crops (silage maize, oilseed rape, winter wheat) in two central German regions for two years. In the second year after establishment, the N₂O emissions were significantly lower in SRC (<0.1 kg N₂O–N ha⁻¹ yr⁻¹) than grassland (0.8 kg N₂O–N ha⁻¹ yr⁻¹) and the annual crop (winter wheat; 1.5 kg N₂O–N ha⁻¹ yr⁻¹) at one regional site (Reiffenhausen). However, a different trend was observed in the first year when contents of mineral nitrogen were still higher in SRC due to former cropland use. At the other regional site (Gierstädt), N₂O emissions were generally low (<0.5 kg N₂O–N ha⁻¹ yr⁻¹) and no crop-type effects were detected. Net uptake of atmospheric CH₄ varied between 0.4 and 1.2 kg CH₄–C ha⁻¹ yr⁻¹ with no consistent crop-type effect. The N₂O emissions related to gross energy in the harvested biomass ranged from 0.07 to 6.22 kg CO₂ equ GJ⁻¹. In both regions, Gierstädt (low N₂O emissions) and more distinct Reiffenhausen (medium N₂O emissions), this energy yield-related N₂O emission was the lowest for SRC.     

GIS-based assessment of sustainable crop residue potentials in European regions

In this paper a novel model based on a geographic information system (GIS) is presented for the assessment of sustainable crop residue potentials. The approach is applied to analyse the amount and the spatial distribution (1 km × 1 km grid cells) of cereal straw, root crop and oil plant residues for five European regions, considering spatially differentiated environmental sustainability issues, i.e. organic carbon content in topsoil, soil erodibility, and protected areas. The maximum sustainable residue potential varies strongly between the regions and residue types. In the scenarios Basis and Restrict, it accounts for 45–59% and 24–48% of the theoretical potential respectively without considering competing uses. Among the crop residues, cereal straw shows the highest energy potential in all regions under investigation. In terms of wet mass it accounts for 3.7 Mio. t_wet/a in North Rhine-Westphalia, 1.6 Mio. t_wet/a in Île-the-France, 1.2 Mio. t_wet/a in Wallonia, 0.9 Mio. t_wet/a in West Midlands, and 0.3 Mio. t_wet/a in South Netherlands (scenario Basis). Our survey shows that spatially differentiated potential estimations and the inclusion of crop residues other than cereal straw are urgently needed to improve the present rough estimations for crop residues which can be used in a sustainable way. The rather high spatial resolution of our analyses particularly allows for the support of regional stakeholders and prospective investors when it comes to questions of regional availability of biomass resources, transport distances to biomass conversion plants, and identification of suitable plant sites and sizes, respectively.     

An oil palm-based biorefinery concept for cellulosic ethanol and phytochemicals production: Sustainability evaluation using exergetic life cycle assessment

In this study, thermo-environmental sustainability of an oil palm-based biorefinery concept for the co-production of cellulosic ethanol and phytochemicals from oil palm fronds (OPFs) was evaluated based on exergetic life cycle assessment (ExLCA). For the production of 1 tonne bioethanol, the exergy content of oil palm seeds was upgraded from 236 MJ to 77,999 MJ during the farming process for OPFs production. Again, the high exergy content of the OPFs was degraded by about 62.02% and 98.36% when they were converted into cellulosic ethanol and phenolic compounds respectively. With a total exergy destruction of about 958,606 MJ (internal) and 120,491 MJ (external or exergy of wastes), the biorefinery recorded an overall exergy efficiency and thermodynamic sustainability index (TSI) of about 59.05% and 2.44 per tonne of OPFs' bioethanol respectively. Due to the use of fossil fuels, pesticides, fertilizers and other toxic chemicals during the production, the global warming potential (GWP = 2265.69 kg CO₂ eq.), acidification potential (AP = 355.34 kg SO₂ eq.) and human toxicity potential (HTP = 142.79 kg DCB eq.) were the most significant environmental impact categories for a tonne of bioethanol produced in the biorefinery. The simultaneous saccharification and fermentation (SSF) unit emerged as the most exergetically efficient (89.66%), thermodynamically sustainable (TSI = 9.67) and environmentally friendly (6.59% of total GWP) production system.     

Can slurry biogas systems be cost effective without subsidy in Mexico?

Biogas from pig slurry in Mexico has potential to produce 21 PJ per year, equivalent to 3.5% of natural gas consumption in 2013. In this paper, three different scenarios are analysed: mono-digestion of pig slurry in a finisher farm (scenario 1); co-digestion of pig slurry and elephant grass in a finisher farm in situ (scenario 2) and co-digestion of pig slurry and elephant grass in centralised biogas plants (scenario 3). The digesters proposed are anaerobic high density polyurethane (HDPE) covered lagoons. HDPE centralised plants can have capital costs 5 times cheaper than European biogas plants. The economics of utilisation of biogas for electricity generation and as biomethane (a natural gas substitute) were investigated. Economic evaluations for on-site slurry digestion (Scenario 1) and on-site co-digestion of elephant grass and pig slurry (Scenario 2) showed potential for profitability with tariffs less than $US 0.12/kWh_e. For centralised systems (Scenario 3) tariffs of $US 0.161/kWh_e to $US 0.195/kWh_e are required. Slurry transportation, energy use and harvest and ensiling account for 65% of the operational costs in centralised plants (Scenario 3). Biomethane production could compete with natural gas if a subsidy of 4.5 c/L diesel (1 m³ of biomethane) equivalent was available.     

Improving methane production from wheat straw by digestate liquor recirculation in continuous stirred tank processes

Wheat straw is an abundant, cheap substrate that can be used for methane production. However, the nutrient content in straw is inadequate for methane fermentation. In this study, recycling digestate liquor was implemented in single-stage continuous stirred tank processes for enrichment of the nutrient content of straw with the aim of improving the methane production. The VS-based organic loading rate was set at 2 g/(L d) and the solid retention time at 40 days. When wheat straw alone was used as the substrate, the methane yields achieved with digestate liquor recycling was on average 240 ml CH₄/g VS giving a 21% improvement over the processes without recycling. However, over time, the processes suffered from declining methane yields and poor stability evidenced by low pH. To maintain process stability, wheat straw was co-digested with sewage sludge or supplemented with macronutrients (nitrogen and phosphorous). As a result, the processes with digestate liquor recycling could be operated stably, achieving methane yields ranging from 288 to 296 ml CH₄/g VS. Besides, the processes could not be operated sturdily with supplementation of macronutrients without digestate liquor recycling. The highest methane yield (296 ± 16 ml CH₄/g VS) was achieved by co-digestion with sewage sludge plus recycling of digestate liquor after filtration (retention of nutrients and microorganisms). This was comparable to the maximum expected methane yield of 293 ± 13 ml CH₄/g VS achieved in batch test. The present study therefore demonstrated that digestate liquor recycling could lead to a decreased dilution of vital nutrients from the reactors thereby rendering high process performance and stability.     

Upgraded biofuel from residue biomass by Thermo-Catalytic Reforming and hydrodeoxygenation

Research is focused on the utilisation of waste or residue biomass for bioenergy conversion. A promising conversion technology for the production of liquid biofuels from residue biomass is a process called Thermo-Catalytic Reforming (TCR^®​) which is a combination of prior thermal treatment of the biomass at mild temperatures (intermediate pyrolysis) followed by a second catalytic treatment step at elevated temperatures (reforming). This article focuses on the conversion of TCR^® liquids from digestate as a feedstock for subsequent hydrocarbon production. The generated bio-oil showed a lower heating value of 34.0 MJ kg⁻¹ with an oxygen content of 7.0% and a water content of 2.2%. The bio-oil was hydrodeoxygenated using an industrial NiMo–Al₂O₃ catalyst at temperatures of 503 K–643 K and a pressure of 14 MPa. The hydrodeoxygenated bio-oil reached a lower heating value of 42.3 MJ kg⁻¹ with an oxygen content below 0.8 mg kg⁻¹ and water content of 30 ppm. Product yields and catalyst life give confidence that upgrading of the TCR^®​ bio-oil offers a suitable option to meet the high standards of common fuels.     

Ni/Ru–Mn/Al2O3 catalysts for steam reforming of toluene as model biomass tar

The catalytic steam reforming of the major biomass tar component, toluene, was studied over two commercial Ni-based catalysts and two prepared Ru–Mn-promoted Ni-base catalysts, in the temperatures range 673–1073 K. Generally, the conversion of toluene and the H₂ content in the product gas increased with temperature. A H₂-rich gas was generated by the steam reforming of toluene, and the CO and CO₂ contents in the product gas were reduced by the reverse Boudouard reaction. A naphtha-reforming catalyst (46-5Q) exhibited better performance in the steam reforming of toluene at temperatures over 873 K than a methane-reforming catalyst (Reformax 330). Ni/Ru–Mn/Al₂O₃ catalysts showed high toluene reforming performance at temperatures over 873 K. The results indicate that the observed high stability and coking resistance may be attributed to the promotional effects of Mn on the Ni/Ru–Mn/Al₂O₃ catalyst.     

Effect of doping pretreated corn stover conditions on yield of bioethanol in immobilized cell systems

The surface characteristics of immobilized yeast before and after adding CO₂-laser pretreated corn stover (LPCS) substrates were investigated using bioethanol production. Response surface methodology (RSM), based on the Box–Behnken design (BBD) for experiments, was used to optimize the doping condition. An optimum experimental condition was obtained at pH 4.5, 2.08% yeast concentration, and 0.20% LPCS substrates. Under this condition, doping LPCS increased the yield of bioethanol from 53% to 84%, which matched the predicted value. After doping LPCS, the results of inverted microscope (IM) and atomic force microscopy (AFM) illustrated that the immobilized gel beads changed from rod-like in shape with a smooth surface to a larger rod-like ultrastructure with a rougher surface. The yield was relatively stable within 28 d, with a downward trend subsequently appearing.     

Biosynthesis of β-caryophyllene,a novel terpene-based high-density biofuel precursor,using engineered Escherichia coli

β-caryophyllene is a common sesquiterpene compound currently being studied as a promising precursor for the production of high-density fuels. Acute demand for high-density fuels has provided the impetus to pursue biosynthetic methods to produce β-caryophyllene from reproducible sources. In this study, we produced β-caryophyllene by assembling a biosynthetic pathway in an engineered Escherichia coli strain of which phosphoglucose isomerase gene has been deleted. The 1- deoxy-d-xylulose 5-phosphate (DXP) or heterologous mevalonate (MVA) pathways were employed. Meanwhile, geranyl diphosphate synthase, glucose-6-phosphate dehydrogenase and β-caryophyllene synthase genes were co-overexpressed in the above strain. The final genetically modified strain, YJM59, produced 220 ± 6 mg/L of β-caryophyllene in flask culture. We also evaluated the use of fed-batch fermentation for the production of β-caryophyllene. After induction for 60 h, the YJM59 strain produced β-caryophyllene at a concentration of 1520 mg/L. The volumetric production fermented in the aerobic fed-batch was 0.34 mg/(L·h·OD₆₀₀) and the conversion efficiency of glucose to β-caryophyllene (gram to gram) was 1.69%. Our results are the first successful attempt to produce β-caryophyllene using E. coli BL21(DE3), and provide a new strategy that is green and sustainable for the production of β-caryophyllene.     

Enhanced substrate degradation and methane yield with maleic acid pre-treatments in biomass crops and residues

Organic acids are envisaged as alternative catalysts to strong mineral acids, in pre-treatment of ligno-cellulosic biomass for anaerobic digestion (AD). To evaluate this hypothesis, an untreated control and four pre-treatments (25 °C for 24 h) involving two levels of maleic acid (34.8 and 69.6 kg m⁻³), alone and combined with sulphuric acid (4 kg m⁻³), were studied in three agricultural substrates: Arundo (aka giant reed), Barley straw and B133 fibre sorghum. Methane production was assessed in a batch AD assay (35 °C for 51 days) with 4 g L⁻¹ of volatile solid (VS) load. Fibre composition and structure were investigated through chemical analysis and Fourier transform infrared (FTIR) spectrometry. Arundo and B133 that were the most and least recalcitrant substrate, respectively, staged the highest and lowest increase in methane with high maleic acid: +62% over 218 cm³ g⁻¹ of VS in untreated Arundo; +36% over 284 cm³ g⁻¹ of VS in untreated B133. Barley straw showed an intermediate behaviour (+41% over 269 cm³ g⁻¹ of VS). H₂SO₄ addition to maleic acid did not improve CH₄ output. The large increase in methane yield determined by pre-treatments was reflected in the concurrent decrease of fibre (between 14 and 39% depending on fibrous component). Based on FTIR spectra, bands assigned to hemicellulose and cellulose displayed lower absorbance after pre-treatment, supporting the hypothesis of solubilisation of structural carbohydrates and change in fibre structure. Hence, maleic acid was shown a suitable catalyst to improve biodegradability of ligno-cellulosic biomass, especially in recalcitrant substrates as Arundo.     

Thermodynamic and exergoeconomic analysis of energy recovery system of biogas from a wastewater treatment plant and use in a Stirling engine

The aim of this research it is to show how the biogas biomethanisation from primary and secondary treatment of activated sludge from a wastewater treatment plant (WWTP), can be an alternative renewable energy option from fossil fuels, which offers competitive advantages and points out new horizons for the use of this fuel. This will allow to achieve some important priorities of energy plans in EU countries: to reduce the organic matter deposited in landfills and CO₂ emissions and to find viable solutions to minimize the environmental impact of sewage sludge (SS).This study analyses the biogas combustion and energy recovery processes from a thermodynamic, thermoeconomic and exergetic point of view.The results show that the boiler of the process is the main source of irreversibility and exergy destruction. Moreover, the energy and exergy economic value of exhaust gases from the combustion chamber, are significant and worthwhile to be exploited. For this reason, the present study explores the applicability and suitability of integrating a Stirling engine in such process. The study reveals that it is possible to create a small micro-cogeneration system which leads to sustainable waste management and energy savings in the treatment plant itself.     

Biopower from direct firing of crop and forestry residues in China: A review of developments and investment outlook

This paper reviews developments in the direct-fired biomass power sector and provides an up to date investment outlook by calculating the Net Present Value of new investments, and the appropriate level of Feed-in-Tariff needed to stimulate future investment. An overview is provided of support policies, historical growth in installations, and main market players. A number of data sources is combined to build a database with detailed information of individual biopower projects. This data is used to describe technological and market trends, which are used in a cash flow model to calculate the NPV of a typical project. The NPV for new projects is estimated to be negative, and investment should be expected to stall without proper policy intervention. Increasing fuel prices, local competition over biomass fuel resources, lower than expected operational performance and a downturn in carbon markets have deteriorated the investment outlook. In order to ensure reasonable profitability, the Feed-In-Tariff should be increased, from the current level of 90.9 € MWh⁻¹, to between 97 and 105 € MWh⁻¹. Where possible, government organizations should help organize demand for the supply of heat. Local rural energy bureaus may help organize supply networks for biomass fuels throughout the country, in order to reduce seasonal and local fuel scarcity and price fluctuations.