Statistical analysis of groundwater chemistry of the Tarim River lower reaches,Northwest China

This study applied a comprehensive quantitative approach including statistical, principal component and gray relation analyses to assess the groundwater chemistry based on monitored data from 840 samples collected from the lower reaches of Tarim River from 2000 to 2009. The main findings were: (1) there were six types of groundwater chemistry in the lower reaches of Tarim River where Cl·SO₄–Na·Mg was the dominant type accounting for 73.57% in all samples. There were linear relationships among chemical parameters, where TDS had significant multiple correlations with Na⁺, K⁺, Mg²⁺, Ca²⁺ and Cl⁻, respectively. (2) Three principal components (PC1, PC2 and PC3) were extracted. They included comprehensive measurements for salinization, alkalinity and pH, respectively. Most parameters showed decreasing trends during the period of 2000–2009, as well as the scores on PC1, because the concentrations of various chemical substances were diluted due to the uplift of the groundwater table in the lower reaches and the implementation of the ecological water delivery project in 2000. (3) HCO₃ ⁻ was the most sensitive chemical parameter affected by the groundwater table followed by TA, Mg²⁺, TH, SO₄²⁻, K⁺, TDS and TS. PC2 was the most sensitive principal component to the change of the groundwater table followed by PC1 and PC3.     

生态输水影响下地下水化学特征的时空变化分析

对塔里木河下游自2000年以来的4次生态输水的地下水位变化与地下水监测井的水化学资料比较分析,结果表明:地下水化学特征随4次生态输水,在时间与空间上发生明显变化.沿输水河道方向(纵向),下游上段的监测断面的地下水化学特征受输水的影响明显早于下游下段的水化学特征,且变化幅度也较大.沿垂直河道的方向(横向),距输水河道不同距离处的地下水化学特征先后呈现相似的变化规律,即:在受输水影响的初期,地下水化学成分中的主要离子含量和矿化度都明显上升,随着生态输水的继续进行而逐步下降.同时,地下水化学的变化特征反映出生态输水的影响范围在逐渐扩大,4次输水后地下水的响应范围在距离输水 000 m左右态输水虽然对地下水中盐分浓度起到了暂时冲淡和区域盐分再分配作用,但要使下游水质真正好转只有采取一系列工程和管理措施.     

The influence of water conveyances on restoration of vegetation to the lower reaches of Tarim River

Because of long-term stream-flow cut off in the lower reaches of Tarim River, environmental degradation has become the most severe and widespread environmental problem in Tarim River basin. Nine ecological water conveyances to the lower reaches of Tarim River made ecological environment change a lot. 3S technology was used to monitor dynamic change of ecology. However, remote sensing area index cannot analyze ecological restoration degree of Tarim River precisely because the time of each water conveyance is short, the change of vegetation area is not obvious, and there exists visual interpretation error. In this paper, remote monitoring datum of high temporal resolution and high spatial resolution were used to research the relationships between normalized difference vegetation index (NDVI) and the groundwater depth, between NDVI and the surface vegetation coverage, and between the groundwater depth and the surface vegetation coverage. The growth and restoration of the vegetation in different periods were evaluated by investigative analysis of the change trend of NDVI. The conception of relative restoration degree was proposed and the response of vegetation restoration to the water conveyance was evaluated. The evaluation result suggests that: first, the response of vegetation to the water conveyance concentrates within 1,000 m of both riversides, and the range of influence becomes smaller along the lower reaches of Tarim River. Second, influenced by the groundwater recharge, the vegetation coverage shows decreasing trend with the increase of off-river distance. Third, the vegetation coverage shows decreasing trend along the watercourse influenced by the water consumption. Finally, in spatial, original scattered meadow of low coverage transforms to high coverage gradually in research region. Vegetation response to the water conveyance expands to both sides with the watercourse being the axis, and expanding scale increases continuously.     

Physiological acclimation strategies of riparian plants to environment change in the delta of the Tarim River,China

The occurrence and development of riparian forests, which were mainly dominated by mesophytes species related closely with surface water. Since there was no water discharged to the lower reaches of Tarim River in the past three decade years, the riparian forests degrade severely. The groundwater table, the saline content of the groundwater, as well as the content of free proline, soluble sugars, plant endogenous hormones (abscisic acid (ABA), and cytokinins (CTK)) of the leaves and relative rates of sap flow of the Populus euphratica Oliv. (arbor species), Tamarix ramosissima Ldb. (bush species), and Apocynum venetum L. (herb species) were monitored and analyzed at the lower reaches of the Tarim River in the study area where five positions on a transect were fixed at 100 m intervals along a sampling direction from riverbank to the sand dunes before and after water release. The physiological responses and acclimation strategies of three species to variations in water and salinity stress were discussed. It was found that A. venetum population recovered to groundwater table ranging from −1.73 to −3.56 m, and when exposed to saline content of the groundwater ranging from 36.59 to 93.48 m mol/L; P. euphratica appeared to be more sensitive to the elevation of groundwater table than the A. venetum and T. ramosissima at groundwater table ranging from −5.08 to −5.80 m, and when exposed to saline content of the groundwater ranging from 42.17 to 49.55 m mol/L. T. ramosissima tended to be the best candidate species for reclamation in this hyper-arid area because it responded to groundwater table ranging from −1.73 to −7.05 m, and when exposed to saline content of the groundwater ranging from 36.59 to 93.48 m mol/L. These results explained the distribution patterns of desert vegetation in the lower reaches of the Tarim River. Understanding the relationships among ecological factors variables, physiological response and acclimation strategies of plant individuals could provide guidance to sustainable management, reclamation and development of this and similar regions.     

The influence of 10 years of water conveyances on groundwater and juvenile Populus euphratica of the lower Tarim River

The changes in the depth of groundwater were studied from the period before water conveyance through 2010, and the TDS of groundwater was analyzed in the lower reaches of the Tarim River during the period 2001–2010. Besides, the numbers of juvenile P. euphratica were investigated in the lower reaches of the Tarim River during the period 2001–2010. The findings indicate that: (1) the hydrological environment of the lower reaches has slowly deteriorated again; and (2) few juvenile P. euphratica were observed along the channel. These results show that the positive influence of the ecological water conveyance project on the ecosystem of the lower Tarim River should be beneficial in the long term; however, the long-term stability of the ecosystem cannot be achieved by the current water diversion scheme.     

Desert riparian vegetation and groundwater in the lower reaches of the Tarim River basin

The Green Corridor in the lower reaches of Tarim River in northwestern China has an extreme hot and dry climate. Vegetation here, consisting of arbor, shrub and grass, relies on groundwater exceedingly. However, the increasing anthropogenic activities of large-scale agricultural reclamation and unreasonable water utilization in the upper and middle reaches caused the 321-km riverway in the lower reaches to dry up completely in 1972 and resulted in the sharp decline of groundwater, followed by the ruin of desert riparian vegetation on a large scale. The Green Corridor is on the verge of shrinking. Water has a key role in maintaining ecological balance and socioeconomic development. This paper, focused on the relationship between vegetation and groundwater, discusses (1) the change of groundwater table caused by the ecological water delivery carried out in the lower reaches of Tarim River; (2) the appropriate groundwater depth meeting the vegetation’s survival; (3) the minimum ecological flux and ecological water requirement for the growth of natural vegetation. It was shown that (1) based on the analysis of the monitoring data from the groundwater level of ten times water delivery, such an extensive artificial watering takes positive effect on raising the groundwater level along the two sides of the river; (2) a groundwater table depth of 2–4 m is probably the appropriate ecological water table level for the lower reaches of the Tarim River, and 6 m is the threshold for the local vegetation; (3) at the lower Tarim River, 1.157 × 10⁸ m³ of water flow is needed for itself. The longer the duration of water releases, the greater would be the groundwater rise and the larger the range of vegetation influenced. It was found that the duration and volume of water delivery was closely related to restoration of vegetation in the lower reaches of the Tarim River. The goal of this paper is to offer scientific evidences for water delivery in the rigorous areas to maintain an ecological balance.     

Eco-physiological response of <Emphasis Type="Italic">Populus euphratica</Emphasis> Oliv. to water release of the lower reaches of the Tarim River,China

Eco-physiological and plant performance responses and acclimation of Populus euphratica Oliv. to water release of the lower reaches of Tarim River, China were investigated. Three representative areas and 15 transects were selected along the lower reaches of the Tarim River. The groundwater level and salt content as well as plant performance and the contents of proline, soluble sugar, and plant endogenous hormone (ABA, CTK) in leaves were monitored and analyzed before- and after-water release. The groundwater level was raised in different areas and transects by the water release program. The physiological stress to P. euphratica decreased after the water release. Our results suggested that the groundwater level in the studied region changed from −3.15 to −4.12 m, salt content of the groundwater from 67.15 to 72.65 mM, the proline content from 9.28 to 11.06 mM, the soluble sugar content from 224.71 to 252.16 mM, the ABA content from 3.59 to 5.01 ng/(g FW), and the CK content from 4.01 to 4.56 ng/(g FW)- for the optimum growth and recover of P. euphratica indicated by the plant performance parameters, and the efficiency of water release was the highest.     

The effects of human activities on oasis climate and hydrologic environment in the Aksu River Basin,Xinjiang, China

Under the influence of human activities, the differences in climate changes emerged obviously in the Aksu Oasis. The summer air temperature in Aksu City increased at a rate of 0.20°C·(10 annum)⁻¹, while the air temperature in Aler in summer decreased at a rate of −0.27°C·(10 annum)⁻¹. Human intervention has become the dominant factor in the the changes of water resources in the Aksu Oasis. Compared with the Xidaqiao hydrological station, which is located on the upper reaches of the Aksu River, the runoff ratio at the Aler hydrological station increased in summer and decreased in spring. Though the natural water inflow has increased in the last 50 years, irrigation diversion and water consumption for human activities have increased unceasingly due to the increased reclamation of land and the development of extensive agriculture. The water quality at the Xidaqiao station is in Grade I at different periods, and the water quality at the Aler station of the Tarim River is good because the river did not suffer from human disturbance before the large-scale development of oasis agriculture; but the salinity of river water increased from 0.67 g L⁻¹ in 1960 to 5.27 g L⁻¹ in 2000 at the Aler station after farmland development, reclamation and salt washing in the oasis. The geographic distribution of surface water resources has changed due to human activities and in turn affected groundwater replenishment, bringing about changes to groundwater table and quality.     

Geochemistry of groundwater,Markandeya River Basin,Belgaum district,Karnataka State,India

The Markandeya River Basin stretches geographically from 15o56′ to 16o08′ N latitude and 74o37′ to 74o58′ E longitude, positioned in the midst of Belgaum district, in the northern part of Karnataka. The groundwater quality of 54 pre-monsoon samples in the Markandeya River Basin was evaluated for its suitability for drinking and irrigation purposes by estimating pH, EC, TDS, hardness and alkalinity besides major cations (Na+, K+, Ca2+, Mg2+) and anions (HCO3–, Cl–, SO42–, PO43-, F-, NO3–), boron, SAR, % Na, RSC, RSBC, chlorinity index, SSP, non-carbonate hardness, Potential Salinity, Permeability Index, Kelley’s ratio, Magnesium hazard and Index of Base Exchange. Negative Index of Base Exchange indicates the chloro-alkaline disequilibrium in the study area and the majority of water samples fall in the rock dominance field based on Gibbs’ ratio. Permeability indices of classes I and II suggest suitability of groundwater for irrigation. Based on Cl, SO4, HCO3 concentrations, water samples can be classified as normal chloride (96.3%) and normal sulfate (94.4%) and normal bicarbonate (44.4%) water types.     

Impact of agricultural activity and geologic controls on groundwater quality of the alluvial aquifer of the Guadalquivir River (province of Jaén,Spain): a case study

The alluvial aquifer of the Alto Guadalquivir River is one of the most important shallow aquifers in Jaén, Spain. It is located in the central-eastern part of the province, and its groundwater resources are used mainly for crop irrigation in an agriculture-dominated area. Hydrochemical and water-quality data obtained through a 2-year sampling (2004–2006) and analysis program indicate that nitrate pollution is a serious problem affecting groundwater due to the use of nitrogen (N)-fertilizers in agriculture. During the study, 231 water samples were collected from wells and springs to determine water chemistry and the extent of nitrate pollution. The concentration of nitrate in groundwater ranged from 1.25 to 320.88 mg/l. Considerable seasonal fluctuations in groundwater quality were observed as a consequence of agricultural practices and other factors such as annual rainfall distribution and the Guadalquivir River flow regime. The chemical composition of the water is not only influenced by agricultural practices, but also by interaction with the alluvial sediments. The dissolution of evaporites accounts for part of the Na⁺, K⁺, Cl⁻, SO₄ ²⁻, Mg²⁺, and Ca²⁺, but other processes, such as calcite precipitation and dedolomitization, also contribute to groundwater chemistry.     

生态输水条件下塔里木河下游断面尺度地下水流数值模拟

由于中国西北地区地表水资源有限,地下水则成为重要的备用水资源,而地表水和地下水转化过程及其耦合模拟是水资源开发利用和科学评价的基础,因此,为了准确反映塔里木河下游间歇性生态输水后地下水的动态变化,以塔里木河下游英苏断面为例,基于Boussinesq方程建立了改进的地下水动力学(GH-D2)模型,模拟了塔里木河下游绿色走廊典型断面地下水对全时段(2000-2015年)间歇性生态输水的响应过程。结果表明,尽管Boussinesq方程的GH解能较好地模拟地下水位的瞬态变化,但模拟地下水位多年变化的结果并不理想,而改进的GH-D2模型考虑了间歇性生态输水对地下水位变化的滞后效应,对长时间尺度地下水位变化的模拟具有较好的效果。与GH和GH-D1模型相比,GH-D2模型模拟的地下水位值更接近于观测值,这将对塔里木河下游实施科学合理的生态输水计划以及生态恢复和重建策略提供关键的技术支撑。     

Isotopic and geochemical characteristics of groundwater in the Senegal River delta aquifer: implication of recharge and flow regime

Groundwater and surface water samples were collected to improve understanding of the Senegal River Lower Valley and Delta system, which is prone to salinization. Inorganic ion concentrations and environmental isotopes (¹⁸O, ²H and ³H) in groundwater, river, lake and precipitation were investigated to gain insight into the functioning of the system with regard to recharge sources and process, groundwater renewability, hydraulic interconnection and geochemical evolution. The geochemical characteristics of the system display mainly cation (Ca²⁺ and/or Na⁺) bicarbonated waters, which evolve to chloride water type; this occurs during groundwater flow in the less mineralized part of the aquifer. In contrast, saline intrusion and secondary brines together with halite dissolution are likely to contaminate the groundwater to Na–Cl type. Halite, gypsum and calcite dissolution determine the major ion (Na⁺, Cl⁻, Ca²⁺, Mg²⁺, SO₄ ²⁻ and HCO₃ ⁻) chemistry, but other processes such as evaporation, salt deposition, ion exchange and reverse exchange reactions also control the groundwater chemistry. Both surface water and groundwater in the system show an evaporation effect, but high evaporated signatures in the groundwater may be due to direct evaporation from the ground, infiltration of evaporated water or enriched rainwater in this region. The stable isotopes also reveal two types of groundwater in this system, which geomorphologically are distributed in the sand dunes (depleted isotopes) and in the flood plain (enriched isotopes). Consideration of the ³H content reinforces this grouping and suggests two mechanisms of recharge: contribution of enriched surface water in recharging the flood plain groundwater and, in the sand dunes area where water table is at depth between 8 and 13 m, slow recharge process characterized the submodern to mixed water.     

Environmental changes after ecological water conveyance in the lower reaches of Heihe River,northwest China

This paper analyzed the dynamic change of the groundwater level by 6 years’ monitoring in field monitoring and the change of vegetation by the field survey and satellite remote sensing after watering in the lower reaches of Heihe River. The findings indicated: (1) the groundwater level elevation and the plant growth are closely related to the volume and the duration of watering. In general, groundwater level elevates dramatically and plants are growing much more vigorously after watering; (2) Watering incidence on groundwater keeps extending with the watering times increasing; (3) Plants grew rapidly in 100–400 m away from the water channel after watering. Watering incidence on vegetation reached 1,000 m; (4) In terms of the function and structure of ecosystem after watering in the lower reaches of Heihe River, the ecological water conveyance does not still reach the goal of ecological restoration at a large spatial scale at present. In addition, in order to solve fundamentally the problem of ecological environment worsens in the lower reaches of Heihe River, some suggestions and countermeasures are put forward.     

Hydrogeochemical processes in the groundwater environment of Heihe River Basin,northwest China

The Heihe River Basin is a typical arid inland river basin for examining stress on groundwater resources in northwest China. The basin is composed of large volumes of unconsolidated Quaternary sediments of widely differing grain size, and during the past half century, rapid socio-economic development has created an increased demand for groundwater resources. Understanding the hydrogeochemical processes of groundwater and water quality is important for sustainable development and effective management of groundwater resources in the Heihe River basin. To this end, a total of 30 representative groundwater samples were collected from different wells to monitor the water chemistry of various ions and its quality for irrigation. Chemical analysis shows that water presents a large spatial variability of chemical facies (SO₄ ²⁻–HCO₃⁻, SO₄ ²⁻–Cl⁻, and Cl⁻–SO₄ ²⁻) as groundwater flow from recharge area to discharge area. The ionic ratio indicates positive correlation between the flowing pairs of parameters: Cl⁻ and Na⁺(r = 0.95), SO₄ ²⁻ and Na⁺ (r = 0.84), HCO₃ ⁻ and Mg²⁺(r = 0.86), and SO₄ ²⁻ and Ca²⁺ (r = 0.91). Dissolution of minerals, such as halite, gypsum, dolomite, silicate, and Mirabilite (Na₂SO₄·10H₂O) in the sediments results in the Cl⁻, SO₄ ²⁻, HCO₃ ⁻, Na⁺, Ca²⁺ and Mg²⁺ content in the groundwater. Other reactions, such as evaporation, ion exchange, and deposition also influence the water composition. The suitability of the groundwater for irrigation was assessed based on the US Salinity Laboratory salinity classification and the Wilcox diagram. The results show that most of the groundwater samples are suitable for irrigation uses barring a few locations in the dessert region in the northern sub-basin.     

Geochemistry of groundwater,Burdwan District,West Bengal,India

Hydrogeochemical investigations are carried out in the different blocks of Burdwan district, West Bengal, India in order to assess its suitability for drinking as well as irrigation water purpose. Altogether 49 representative groundwater samples are collected from bore wells and the water chemistry of various ions viz. Ca²⁺, Mg²⁺, Na⁺, K⁺, CO₃²⁻, HCO₃⁻, Cl⁻, SO₄²⁻ and NO₃⁻ are carried out. The chemical relationships in Piper and Gibbs diagram suggest that the groundwater mainly belongs to alkali type and Cl⁻ group and are controlled by rock dominance. A comparison of groundwater quality in relation to drinking water quality standards proves that most of the water samples are suitable for drinking water purpose whereas groundwater in some areas of the district has high salinity and high sodium adsorption ratio (SAR), indicating unsuitability for irrigation water and needs adequate drainage.     

Geochemical assessment of groundwater around Macherla-Karempudi area,Guntur district,Andhra Pradesh

Groundwater in Palnad sub-basin is alkaline in nature and Na⁺-Cl⁻-HCO₃⁻ type around Macherla-Karempudi area in Guntur district, Andhra Pradesh. Total dissolved solids (TDS) show strong positive correlation with Cl⁻, Na⁺, Ca²⁺ and Mg²⁺, and positive correlation with SO₄²⁻, K⁺ and HCO₃⁻. Calcareous Narji Formation is the dominant aquifer lithology, and water-rock interaction controls the groundwater chemistry of the area. Chloro-alkaline indices (CAI) are positive at Miriyala, Adigopula, Mutukuru, Macherla and Durgi suggesting replacement of Na⁺ and K⁺ ions from water by Mg⁺⁺ and Ca⁺⁺ ions from country rock through base exchange reactions. Negative CAI values are recorded at Terala, Rayavaram and Nehrunagar, which indicate exchange of Na⁺ and K⁺ from the rock as cation-anion exchange reaction (chloro-alkaline disequilibrium). TDS range from 91 to 7100 ppm (Avg. 835 ppm) and exceed the prescribed limit of drinking water around Mutukuru, Durgi, Rayavaram, Khambampadu and Ammanizamalmadaka areas. Scanty rainfall and insufficient groundwater recharge are the prime factors responsible for high salinity in the area. Fluoride content ranges from <1 to 3.8 ppm and contaminated areas were identified around Macherla (1 sq km; 3.8ppm), Mandadi (1 sq km, 2.1ppm) and Adigopula (2 sq km, <1 to 3.7 ppm). The % Na⁺ content varies from 17 to 85 with the mean value of 57, and eighty (80) samples showed higher %Na⁺ in comparison to the prescribed limit of 60 for irrigation water. Sodium Adsorption Ratio (SAR) and % Na⁺ in relation to total salt concentration indicate that groundwater (51%) mostly falls under doubtful to poor quality for irrigation purpose. Groundwater of Adigopula village is fluoride contaminated and remedial measures are suggested to improve the water quality.     

Surface and groundwater quality characterization of Deoria District,Ganga Plain,India

A water quality investigation was carried out in the Deoria district, Ganga plain, to assess the suitability of surface and groundwaters for domestic, agricultural, and industrial purposes. As much as 50 representative samples from river and groundwater were collected from various stations to monitor the water chemistry of various ions, comprising Ca²⁺, Mg²⁺, Na⁺, K⁺, HCO₃ ⁻, SO₄ ²⁻, NO₃ ⁻, Cl⁻, F⁻, and trace metals, such as Fe, Cu, Mn, Zn, Cd, and Pb. The results showed that electrical conductance (EC), total dissolved solids (TDS), HCO₃ ⁻, Mg²⁺, Na⁺, and total hardness (TH) are above the maximum desirable limit, and apart from Fe and Mn all other trace metals are within the maximum permissible limit for drinking water. The calculated values for sodium absorption ratio (SAR), salinity, residual sodium carbonate (RSC), and permeability index (PI) indicate well to permissible use of water for irrigation. High values of Na%, RSC, and Mg-hazard (MH) at some stations restrict its use for agricultural purpose. Anthropogenic activities affect the spatial variation of water quality. Economic and social developments of the study area is closely associated with the characteristics of the hydrological network.     

Environmental geochemistry and quality assessment of mine water of Jharia coalfield,India

A long mining history and unscientific exploitation of Jharia coalfield caused many environmental problems including water resource depletion and contamination. A geochemical study of mine water in the Jharia coalfield has been undertaken to assess its quality and suitability for domestic, industrial and irrigation uses. For this purpose, 92 mine water samples collected from different mining areas of Jharia coalfield were analysed for pH, electrical conductivity (EC), major cations (Ca²⁺, Mg²⁺, Na⁺, K⁺), anions (F⁻, Cl⁻, HCO₃ ⁻, SO₄ ²⁻, NO₃ ⁻), dissolved silica (H₄SiO₄) and trace metals. The pH of the analysed mine water samples varied from 6.2 to 8.6, indicating mildly acidic to alkaline nature. Concentration of TDS varied from 437 to 1,593 mg L⁻¹ and spatial differences in TDS values reflect the variation in lithology, surface activities and hydrological regime prevailing in the region. SO₄ ²⁻ and HCO₃ ⁻ are dominant in the anion and Mg²⁺ and Ca²⁺ in the cation chemistry of mine water. High concentrations of SO₄ ²⁻ in the mine water of the area are attributed to the oxidative weathering of pyrites. Ca–Mg–SO₄ and Ca–Mg–HCO₃ are the dominant hydrochemical facies. The drinking water quality assessment indicates that number of mine water samples have high TDS, total hardness and SO₄ ²⁻ concentrations and needs treatment before its utilization. Concentrations of some trace metals (Fe, Mn, Ni, Pb) were also found to be above the desirable levels recommended for drinking water. The mine water is good to permissible quality and suitable for irrigation in most cases. However, higher salinity, residual sodium carbonate and Mg-ratio restrict its suitability for irrigation at some sites.     

Evaluation of groundwater quality with emphasis on fluoride concentration in Nalbari district,Assam, Northeast India

This study was carried out to analyze groundwater quality in selected villages of Nalbari district, Assam, India, where groundwater is the main source of drinking water. 40 groundwater samples collected from hand pumps and analyzed for pH, EC, TDS, Ca²⁺, Mg²⁺, Na⁺, K⁺, HCO₃ ⁻, SO₄ ²⁻, Cl⁻ and F⁻. Chemical analysis of the groundwater showed that mean concentration of cations in (mg/L) is in the order Ca²⁺ > Mg²⁺ > Na⁺ > K⁺ while for anions it is HCO₃ ⁻ > Cl⁻ > SO₄ ²⁻ > F⁻. Fluoride concentration was recorded in the range of 0.02–1.56 mg/L. As per the desirable and maximum permissible limits for fluoride in drinking water recommended by WHO and by Bureau of Indian Standards (BIS), which is 1.5 mg/L, the groundwater of about 97% of the samples were found to be suitable for drinking purpose. The suitability of the groundwater for irrigation purpose was investigated by some determining factors such as sodium adsorption ratio, soluble sodium percentage, Kelly’s ratio and electrical conductivity. The value of the sodium absorption ratio and electrical conductivity of the groundwater samples were plotted in the US Salinity laboratory diagram for irrigation water. Most of the groundwater samples fall in the field of C2S1 and C3S1 indicating medium to high salinity and low sodium water, which can be used for irrigation on almost all types of soil with little doubt of exchangeable sodium. The hydrochemical facies shows that the groundwater is Ca-HCO₃ type.     

Hydrochemical and isotopic evidence of recharge,apparent age,and flow direction of groundwater in Mayo Tsanaga River Basin,Cameroon: bearings on contamination

Unplanned exploitation of groundwater constitutes emerging water-related threats to MayoTsanaga River Basin. Shallow groundwater from crystalline and detrital sediment aquifers, together with rain, dams, springs, and rivers were chemically and isotopically investigated to appraise its evolution, recharge source and mechanisms, flow direction, and age which were used to evaluate the groundwater susceptibility to contamination and the basin’s stage of salinization. The groundwater which is Ca–Na–HCO₃ type is a chemically evolved equivalent of surface waters and rain water with Ca–Mg–Cl–SO₄ chemistry. The monsoon rain recharged the groundwater preferentially at an average rate of 74 mm/year, while surface waters recharge upon evaporation. Altitude effect of rain and springs show a similar variation of −0.4‰ for δ¹⁸O/100 m, but the springs which were recharged at 452, 679, and 773 m asl show enrichment of δ¹⁸O through evaporation by 0.8‰ corresponding to 3% of water loss during recharge. The groundwater which shows both local and regional flow regimes gets older towards the basins` margin with coeval enrichment in F⁻ and depletion in NO₃ ⁻. Incidentally, younger groundwaters are susceptible to anthropogenic contamination and older groundwaters are sinks of lithologenic fluoride. The basins salinization is still at an early stage.