SiC晶须增强6061Al基复合材料的热机械疲劳性能 Ⅱ.疲劳寿命与损伤机制

研究了本积分数为１５％和２８％ＳｉＣＷ／６０６１Ａｌ基复合材料的同相和反相热机械疲劳寿命和损伤机制．结果表明：在小应变范围时,同相比反相疲劳寿命长,而在大应变时,同相疲劳寿命接近（对于２８％ＳｉＣＷ）、甚至短于（对于１５％ＳｉＣＷ）反相热机械疲劳寿命;１５％ＳＩＣＷ／６０１６Ａｌ基复合材料的反相热机械疲劳寿命高于２８％ＳｉＣＷ／６０１６Ａｌ基复合材料的寿命．两种材料的同相热机械疲劳寿命曲线存在交叉点,寿命高低取决于应变水平;同相和反相热机械疲劳的损仿均为空洞在ＳｉＣ晶须周围基体中形核、长大和连接．     

定向凝固NiAl—28Cr—5.5Mo-0.5Hf合金中Ni_2AlHf相和Ni_(16)Hf_6Si_7相的研究

少量的Ｈｆ（０．５％）加入到定向凝固的ＮｉＡｌ－Ｃｒ（Ｍｏ）合金中,会产生Ｈｅｕｓｌｅｒ相Ｎｉ２ＡｌＨｆ,该相呈网状分布在ＮｉＡｌ／Ｃｒ（Ｍｏ）相界面区域．Ｎｉ２ＡｌＨｆ与ＮｉＡｌ之间不存在固定的晶体学取向关系,但有时也发现二者存在立方－立方取向关系：［１１１］ＮｉＡｌ［１１１］Ｈ,（１０１）ＮｉＡｌ／／（２０２）Ｈ,并通过高分辨电子显微照片分析了二者界面的精细结构由于定向凝固过程中,Ｓｉ元素进入到合金中,所以在此合金中发现了Ｇ－相Ｎｉ１６Ｈｆ６Ｓｉ７．细小弥散的Ｎｉ１６Ｈｆ６Ｓｉ７相呈立方体形状,与Ｎｉ２ＡｌＨｆ相相伴分布在ＮｉＡｌ／Ｃｒ（Ｍｏ）相界面附近同时讨论ＴＮｉＡｌ／Ｎｉ２ＡｌＨｆ及ＮｉＡｌ／Ｎｉ１６Ｈｆ６Ｓｉ７的界面能量,Ｎｉ１６Ｈｆ６Ｓｉ７相在ＮｉＡｌ中析出的惯习面和Ｎｉ２ＡｌＨｆ相及Ｎｉ１６Ｈｆ６Ｓｉ７相分布形态的成因     

晶须增强Al－8．5Fe－1．3V－1．7Si复合材料及晶须增强效果的评价

采用粉末冶金法在较高的温度下制备了ＳｉＣ，Ｓｉ_３Ｎ_４和Ａｌ_（１８）Ｂ_４Ｏ_（３３）晶须增强Ａｌ－８．５Ｆｅ－１．３Ｖ－１．７Ｓｉ耐热铝合金复合材料，山于采用不含Ｍｇ的基体避免了Ａｌ_（１８）Ｂ_４Ｏ_（３３）晶须界面上出现界面反应和Ｓｉ_３Ｎ_４，ＳｉＣ晶须界面上出现的界面生成物，所以所有晶须界面都是清洁的．加入晶须可以明显提高材料的强度和模量，三种晶须的增强效果依次为ＳｉＣ，Ｓｉ_３Ｎ_４和Ａｌ_（１８）Ｂ_４Ｏ_（３３）．这类复合材料的强度随温度的升高呈线性下降，其使用温度可比ＳｉＣ_ｗ／２０２４Ａｌ复合材料提高５０－１００℃     

晶须定向分布SiCw/6A02复合材料的压缩变形行为

通过考察晶须呈定向排列的SiCw/6A02复合材料压缩变形期间的晶须取向和长度的变化，研究了复合材料变形期间的应力应变行为。结果表明，变形期间晶须的转动和折断导致的加工软化和基体合金的加工硬化，共同决定复合材料的压缩应力—应变行为。     

SiCp增强Al基复合材料在应变过程中显微组织的损伤

采用恒定应变速率拉伸试验研究了币喷射成型制成的１５ＳｉＣｐ／Ａｌ－１６１８复合材料在４３８和４９３Ｋ下的应变行为。对不同应变速率下ＳｉＣｐ／Ａｌ－２６１８的应力－应变曲线的分析表明，颗粒复合材料表现出一个临界应变速率的行为，对不同应变条件下ＳｉＣｐ损务数量的定量统计分析表明。     

NiAl－TiC内生复合材料的高温拉伸行为

研究了ＨＰＥＳ法制备的ＮｉＡｌ－ＴｉＣ内生复合材料的高温拉伸行为及ＮｉＡｌ／ＴｉＣ的界面特点．结果表明，内生ＴｉＣ颗粒可大幅度提高ＮｉＡｌ的高温拉伸强度．在ＮｉＡｌ与ＴｉＣ之间存在着一种相互交错的界面，它对提高复合材料的高温拉伸强度具有重要贡献．     

SiCW／Y—TZP／Al2O3复合陶瓷的显微结构及其力学性能

研究了ＳｉＣＷ／Ｙ－ＴＺＰ／Ａｌ２Ｏ３系复合陶瓷的显微结构及其力学性能，通过透射电镜拉伸试样中的裂纹扩展形态与组织变化，分析了晶须与ＺｒＯ２相变增韧机制。结果表明，陶瓷体内各相结合致密，分布较为均匀，其室温强度和断裂韧度分别为１１００ＭＰａ和１１．９ＭＰａ．ｍ＾１／２，晶须拔出，裂纹偏转及ＺｒＯ２ｔ－ｍ相变是该复合材料的主要增韧机制。ＳｉＣ晶须和Ｙ－ＴＺＰ的共同作用，对复合材料强度和断裂韧性的提高     

Al_2O_3／TiB_2和Al_2O_3／TiB_2／SiC_W陶瓷复合材料在

研究了热压烧结工艺制备的Ａｌ２Ｏ３／ＴｉＢ２和Ａｌ２Ｏ３／ＴｉＢ２／ＳｉＣＷ陶瓷复合材料在１３００℃的氧化行为用ＸＲＤ、ＳＥＭ、ＴＥＭ／ＥＤＳＡ分析了材料氧化后的相组成及显微结构．结果表明：两种材料在１３００℃空气中氧化３０ｈ内的氧化增重符合抛物线规律，ＳｉＣ晶须的加入可明显改善Ａｌ２Ｏ３／ＴｉＢ２材料的高温抗氧化性．     

晶须增强Al—8.5Fe—1.3V—1.7Si复合材料及晶须增强效果的评价

采用粉末冶金法在较高的温度下制备了Ｓｉｃ，Ｓｉ３Ｎ４和Ａｌ１８Ｂ４Ｏ３３晶须增强Ａｌ－８．５Ｆｅ－１．３Ｖ－１．７Ｓｉ耐热铝合金复合材料，由于采用不含Ｍｇ的基体避免了Ａｌ１８Ｂ４Ｏ３３晶须界面上出现界面反应和Ｓｉ３Ｎ４，ＳｉＣ晶须界面上出现的办生成，所以所有晶须界面都是清洁的。加入晶须可以明显提高材料的强度和模量，三种晶贩增强效果依次为ＳｉＣ，Ｓｉ３Ｎ４和Ａｌ１８Ｂ４Ｏ３３。这类复合材料的强度随温     

机械合金化制备NiAl—TiC复合材料的组织和力学性能

研究了反应球磨方法制备的ＮｉＡｌ－ＴｉＣ复合材料的组织和力学性能。结果表明,强化相呈两态分布。１０００℃长期退火对材料的组织和显微硬度影响不大。ＮｉＡｌ－ＴｉＣ复合材料的强度远高于铸态ＮｉＡｌ的强度,也比ＸＤ ＮｉＡｌ－ＴｉＢ２复合材料的强度高。高温热等静压后,该复合材料的室温和高温屈服强度都明显下降。材料的高温强度依赖于应变速率,变形受扩散机制控制。     

Effect of SiC whiskers on the oxidation protective properties of SiC coatings for carbon/carbon composites

In order to effectively employ the unique high temperature mechanical properties of carbon/carbon composite substrates, SiC coatings reinforced by SiC whiskers were prepared by pack cementation method. The effect of SiC whiskers on the oxidation resistance properties of the single-layer coating and double-layer coating was investigated. SiC whiskers in the single-layer SiC coating have little effect on the anti-oxidation property but obviously improve the thermal shock property. The double-layer coating with inner-layer reinforced coating exhibits more perfect anti-oxidation ability than the double-layer coating with SiC inner-layer coating.     

Effect of deformation temperature on the hot compressive behavior of metal matrix composites with misaligned whiskers

A multi-inclusion cell model is used to investigate the effect of deformation temperature and whisker rotation on the hot compressive behavior of metal matrix composites with misaligned whiskers. Numerical results show that deformation temperature influences the work-hardening behavior of the matrix and the rotation behavior of the whiskers. With increasing temperature, the work hardening rate of the matrix decreases, but the whisker rotation angle increases. Both whisker rotation and the increase of deformation temperature can induce reductions in the load supported by whisker and the load transferred from matrix to whisker. Additionally, it is found that during large strain deformation at higher temperatures, the enhancing of deformation temperature can reduce the effect of whisker rotation. Meanwhile, the stress-strain behavior of the composite is rather sensitive to deformation temperature. At a relatively lower temperature （150℃）, the composite exhibits work hardening due to the matrix work hardening, but at relatively higher temperatures （300℃ and above）, the composite shows strain softening due to whisker rotation. It is also found that during hot compression at higher temperatures, the softening rate of the composite decreases with increasing temperature. The predicted stress-strain behavior of the composite is approximately in agreement with the experimental results.     

变形温度对碳化硅颗粒增强铝基复合材料超塑变形的影响

本文总结了变形温度对碳化硅增强铝基复合材料超塑性的影响规律。探讨了碳化硅颗粒对超塑变形的影响。讨论了碳化硅与铝基体之间的界面液相对超塑变形的影响。     

Fabrication and mechanical properties of SiCw/MoSi2–SiC composites by liquid Si infiltration of pyrolyzed rice husk preforms with Mo additions

Dense SiC ceramic matrix composites containing SiC whiskers (SiC_w) and MoSi₂ phase (SiC_w/MoSi₂–SiC) are fabricated by a liquid Si infiltration (LSI) method. Pyrolyzed rice husks (RHs) containing SiC whiskers, particles and amorphous carbon are mixed with different amounts of Mo powder to form preforms for the infiltration. Microstructure and mechanical properties of the composites are studied. Fracture mode of the composites is discussed. Results show that the SiC whiskers and fine particles in the pyrolyzed RHs were preserved in the composites after the LSI process. The amorphous carbon and Mo powder in the preforms reacted with molten Si, forming SiC and MoSi₂ in the composites. The presence of MoSi₂ in the composite increases the elastic modulus but lowers the flexure strength. Content of MoSi₂ of ca. 20 wt.% provides an enhanced fracture toughness of 4.1 MPa m^1/2 for the composite. But too large amount of MoSi₂ caused crack formation in the composite. The compressive residual stress introduced by the formation of MoSi₂ and SiC, and the de-bonding of the fine SiC particles and SiC whiskers from the residual Si phase are considered to favor the fracture toughness of the composites.     

挤压变形对SiCw/ZK51A镁基复合材料组织和性能的影响

利用透射电镜、扫描电镜和拉伸试验等实验方法,研究了铸态和挤压态ＳｉＣｗ／ＺＫ５１Ａ镁基复合材料的组织与力学性能。结果表明,挤压铸造ＳｉＣｗ／ＺＫ５１Ａ复合材料经等温热挤压后,其力学性能有很大提高。主要原因是：挤压变形能消除铸造缺陷,增强ＳｉＣ晶须与ＺＫ５１Ａ镁合金基体的界面结合,使复合材料中ＳｉＣ晶须发生定向分布,沿挤压方向呈准一维分布特征,晶须的增强承载能力得到充分发挥。     

(WC+SiCw)/Cu-Al2O3复合材料载流摩擦磨损行为

目的 研究相同载流条件下纳米Al2O3颗粒、微米WC颗粒和SiC晶须对(WC+SiCw)/Cu-Al2O3复合材料表面摩擦磨损性能的影响.方法 采用粉末冶金法和内氧化法相结合的方式,制备了(WC+SiCw)/Cu-Al2O3复合材料,并利用HST-100高速载流摩擦试验机进行载流摩擦磨损性能测试.采用透射电镜和扫描电镜...     

DESIGN AND PREPARATION OF SILICON NITRIDE COMPOSITE WITH HIGH FRACTURE TOUGHNESS AND NACRE STRUCTURE

ＤＥＳＩＧＮＡＮＤＰＲＥＰＡＲＡＴＩＯＮＯＦＳＩＬＩＣＯＮＮＩＴＲＩＤＥＣＯＭＰＯＳＩＴＥＷＩＴＨＨＩＧＨＦＲＡＣＴＵＲＥＴＯＵＧＨＮＥＳＳＡＮＤＮＡＣＲＥＳＴＲＵＣＴＵＲＥＹＨｕａｎｇ；Ｈ．ＮＨａｏ；Ｙ．Ｌ．ＣｈｅｎａｎｄＢ．Ｌ．Ｚｈｏｕ（１）Ｄｅ...     

混合炸药爆炸压实制备ZrB2-SiCw超高温陶瓷

为了改善ZrB2-SiC超高温陶瓷材料的韧性，采用黑索今与硝酸铵混合炸药爆炸压实制备了SiC晶须增韧ZrB2基超高温陶瓷，并研究爆炸压实过程中的能量与变形，爆炸压实坯密度与显微组织。结果表明，采用爆炸压实工艺制备了相对密度约95．25％的ZrB2-SiC。陶瓷复合材料。随着混合炸药中黑索今质量的增加，爆轰压力单调增加，爆炸坯密度先增加，后减小，有一个最大值；钢管的外径收缩率、等效应变与爆炸坯密度变化一致；钢管变形能几乎不变，爆炸冲击能与粉末压实能同步增加。由于爆炸冲击波的作用，SiC晶须被折断成碎片；其组织为均匀、碎小的SiC晶须镶嵌于较大的ZrB2颗粒中。     

SiC晶须强化树脂的磨损特性及其在磨削加工中的应用

本文使用SiC晶须(细纤维)与酚醛树脂混合，经特殊工艺处理后制成了几种不同晶须含量、排列方向及粉末添加剂的SiC晶须强化树脂。通过对接触材料(模具钢SKD11，HRC60)所进行的磨损特性试验可知，当SiC晶须强化树脂中晶须的含量增高及排列方向与接触材料的摩擦面相垂直时，其磨损量将小于接触材料的磨损量，这表明SiC晶须材料具有磨料的作用。本文利用这一作用将SiC晶须强化树脂制成杯形砂轮，并应用到模具钢SKD11的磨削加工中，能获得高达6000的磨削比和纳米级的加工表面(Ra1．5nm／Ry16nm)，进一步表明SiC晶须作为磨料是可行的、实用的。