INFERRING HYDROLOGICAL PROCESSES IN A TEMPERATE BASIN USING ISOTOPIC AND GEOCHEMICAL HYDROGRAPH SEPARATION: A RE-EVALUATION

Simultaneous monitoring of conservative and non-conservative tracers in streamflow offers a valuable means of obtaining information on the age and flow paths of water reaching the basin outlet. Previous studies of stormflow generation in a small forested basin on the Canadian Shield used isotopic (IHS) and geochemical hydrograph separations (GHS) to infer that some event water during snowmelt reaches the stream via subsurface pathways, and that surface water runoff is generated by direct precipitation on to saturated areas (DPSA) in the stream valley. These hypotheses were tested for rainfall inputs using simultaneous IHS (¹⁸O) and GHS (dissolved silica) of basin stormflow, supplemented by hydrochemical and hydrometric data from throughflow troughs installed on basin slopes. Comparison of pre-event and subsurface water hydrographs did not provide conclusive evidence for subsurface movement of event water to the stream, owing to the appreciable uncertainty associated with the hydrograph separations. However, IHSs of runoff at the soil–bedrock interface on basin slopes indicated that event water comprised 25–50% of total runoff from areas with deep soil cover, and that these contributions supplied event water flux from the basin in excess of that attributable to DPSA. The surface water component of stormflow estimated from the GHS was also largely the result of DPSA. GHS assumes that dissolved silica is rapidly and uniformly taken up by water infiltrating the soil and that water moving via surface pathways retains the low dissolved silica level of rainfall; however, neither assumption was supported by the hillslope results. Instead, results suggest that the observed depression of silica levels in basin stormflow previously attributed to dilution by DPSA was partly a function of transport of dilute event water to the channel via preferential pathways. Implications of these results for the general use of simultaneous IHS and GHS to infer hydrological processes are discussed. © 1997 by John Wiley & Sons, Ltd.     

Sources and sinks of nutrients in a New Zealand hill pasture catchment I. Stormflow generation

The processes of stormflow generation were studied in a hill pasture catchment near Hamilton, New Zealand. Although rainfall was relatively evenly distributed throughout the year, stormflow was highly seasonal and over 65 per cent occurred during the winter. Three main processes contributing to stormflow were identified which could be related to soil type and physiographic position. On gleyed soils derived from rhyolitic colluvium, saturation overland flow was the dominant process. Hydrographs from ‘Whipkey’ throughflow troughs also indicated that there was a subsurface response (saturated wedge) from this soil type. On steeper convex slopes, more permeable soils were derived from weathered greywacke. The presence of ephemeral springs on the hillslopes and direct observation during storm events indicated that storm runoff was generated as return flow from this soil. It was noted that nitrate concentrations from subsurface sources were 5–10 times higher than surface runoff. This difference in concentration was utilized in a chemical mixing equation which partitioned stormflow sources. This was compared with the stormflow predicted from rain falling on to saturated areas. There was good agreement between the two models for winter-spring events with respect to the volumes of surface runoff predicted, however the saturated areas model underestimated total stormflow. The results of the study are briefly discussed in terms of the potential for water quality management.     

HYDROCHEMICAL DECIPHERING OF STREAMFLOW GENERATION IN SEMI-ARID EAST AFRICA

There is a critical lack of knowledge regarding the dynamics of streamflow generation in the semi-arid tropics, particularly in Africa. In this project runoff mechanisms in forested and non-forested degraded catchments in northern Tanzania were studied using combined hydrometrical and hydrochemical methods. Following the hydrochemical identification of several flowpaths contributing to runoff, hydrograph separation by an end-member model based on K and Ca was undertaken. Results from the forested catchment indicate that stormflow was dominated by event water (about 75%), via overland flow and throughflow. The proportion of pre-event water (groundwater) displaced into the stream by a suggested riparian groundwater ridge mechanism varied, depending on the rainfall characteristics. In the non-forested, degraded catchment, nearly all stormflow was event water, and groundwater discharge was unaffected by rainfall. It is suggested that macropore flow is pivotal to the transmission of rainfall to runoff via throughflow, particularly in semi-arid tropical areas.     

An isotopic and geochemical study of snowmelt runoff in a small arctic watershed

‘Old’ water contributions to snowmelt runoff in a stream can be defined as water which was stored in the catchment prior to the start of the runoff event in question. We used mass balance techniques for natural oxygen-18 and several chemical parameters (electrical conductivity, Ca and Mg) to estimate the magnitude and timing of ‘old’ water contributions to snowmelt runoff in the Apex River watershed during the 1983 field season. The Apex River catchment is located in the southern part of Baffin Island, Northwest Territories, Canada. The watershed has an area of 60 km², it is in the zone of continuous permafrost, and the geology is dominantly Precambrian gneiss with sporadic, thin, glacial overburden. The isotopic data indicate that for the snowmelt season of 1983 (third highest peak discharge of 11 years of record), approximately 50 per cent of the peak stream discharge consisted of ‘old’ water. Our data also suggest that about 60 per cent of the entire 1983 hydrograph was ‘old’ water. The chemical parameters give old water contributions which are at least 10 per cent less than the isotopically-derived estimate, but they are consistent with the isotopic estimate during peak flow.     

Seasonal changes in runoff generation in a small forested mountain catchment

This study aimed to investigate the seasonal variability of runoff generation processes, the sources of stream water, and the controls on the contribution of event water to streamflow for a small forested catchment in the Italian pre‐Alps. Hydrometric, isotopic, and electrical conductivity data collected between August 2012 and August 2013 revealed a marked seasonal variability in runoff responses. Noticeable differences in runoff coefficients and hydrological dynamics between summer and fall/spring rainfall events were related to antecedent moisture conditions and event size. Two‐component and three‐component hydrograph separation and end‐member mixing analysis showed an increase in event water contributions to streamflow with event size and average rainfall intensity. Event water fractions were larger during dry conditions in the summer, suggesting that stormflow generation in the summer consisted predominantly of direct channel precipitation and some saturated overland flow from the riparian zone. On the contrary, groundwater and hillslope soil water contributions dominated the streamflow response during wet conditions in fall. Seasonal differences were also noted between event water fractions computed based on isotopic and electrical conductivity data, likely because of the dilution effect during the wetter months. Copyright © 2014 John Wiley & Sons, Ltd.     

Precipitation induced stream flow: An event based chemical and isotopic study of a small stream in the Great Plains region of the USA

A small stream in the Great Plains of USA was sampled to understand the streamflow components following intense precipitation and the influence of water storage structures in the drainage basin. Precipitation, stream, ponds, ground-water and soil moisture were sampled for determination of isotopic (D, ¹⁸O) and chemical (Cl, SO₄) composition before and after two intense rain events. Following the first storm event, flow at the downstream locations was generated primarily through shallow subsurface flow and runoff whereas in the headwaters region – where a pond is located in the stream channel – shallow ground-water and pond outflow contributed to the flow. The distinct isotopic signatures of precipitation and the evaporated pond water allowed separation of the event water from the other sources that contributed to the flow. Similarly, variations in the Cl and SO₄ concentrations helped identify the relative contributions of ground-water and soil moisture to the streamflow. The relationship between deuterium excess and Cl or SO₄ content reveals that the early contributions from a rain event to streamflow depend upon the antecedent climatic conditions and the position along the stream channel within the watershed. The design of this study, in which data from several locations within a watershed were collected, shows that in small streams changes in relative contributions from ground water and soil moisture complicate hydrograph separation, with surface-water bodies providing additional complexity. It also demonstrates the usefulness of combined chemical and isotopic methods in hydrologic investigations, especially the utility of the deuterium excess parameter in quantifying the relative contributions of various source components to the stream flow.     

Analysis of storm run-off sources using oxygen-18 in a headwater swamp

A combination of hydrometric data and observations of natural isotope (oxygen-18) variations in saturation overland flow and stream discharge were used to investigate the sources of storm run-off in a headwater swamp located in a permanent groundwater discharge zone near Toronto, Canada. The results of a two-component hydrograph separation indicated that pre-event water formed 80–90% of the stream hydrograph volume for six of the seven storms analyzed in June–November 1990. However, the instantaneous event water contribution showed considerable variability, ranging from maximum values of 20–25% for four moderate intensity storms to 63% for a high intensity thunderstorm with a return period of two years. The relative contribution of event and pre-event water to storm run-off from saturated areas and small streamlets within the swamp was similar to the main outlet stream. The dominance of pre-event water during storms could be accounted for by the mixing of a small volume of event water with a large pool of pre-event water on the surface of permanently saturated areas within the swamp. Occasional storms of high intensity or long duration produced a greater shift towards an event water signature in the saturated areas and a larger event water contribution to the outlet stream hydrograph.     

The application of electrical conductivity as a tracer for hydrograph separation in urban catchments

Two‐component hydrograph separation was performed on 19 low‐to‐moderate intensity rainfall events in a 4·1‐km² urban watershed to infer the relative and absolute contribution of surface runoff (e.g. new water) to stormflow generation between 2001 and 2003. The electrical conductivity (EC) of water was used as a continuous and inexpensive tracer, with order of magnitude differences in precipitation (12–46 µS/cm) and pre‐event streamwater EC values (520–1297 µS/cm). While new water accounted for most of the increased discharge during storms (61–117%), the contribution of new water to total discharge during events was typically lower (18–78%) and negatively correlated with antecedent stream discharge (r² = 0·55, p < 0·01). The amount of new water was positively correlated with total rainfall (r² = 0·77), but hydrograph separation results suggest that less than half (9–46%) of the total rainfall on impervious surfaces is rapidly routed to the stream channel as new water. Comparison of hydrograph separation results using non‐conservative tracers (EC and Si) and a conservative isotopic tracer (δD) for two events showed similar results and highlighted the potential application of EC as an inexpensive, high frequency tracer for hydrograph separation studies in urban catchments. The use of a simple tracer‐based approach may help hydrologists and watershed managers to better understand impervious surface runoff, stormflow generation and non‐point‐source pollutant loading to urban streams. Copyright © 2007 John Wiley & Sons, Ltd.     

Stream temperature,specific conductance and runoff process in mountain watersheds

Stream temperature ranged from 3 to 4°C at an experimental site during snowmelt on Hokkaido Island, Japan, which provided direct evidence of major contributions of subsurface water to stream water. In contrast, stream temperatures during rainstorms in summer decreased gradually after stream flow peaked, attaining a nearly constant temperature ranging from 9 to 11°C. During storm flow recession, stream temperatures during summer or snowmelt were similar to the soil temperature at 1·8 m below the land surface, suggesting that subsurface water contributions to stream flow are derived from this depth. The hygrographs during two rainstorms, August 1987 and September 1989, were separated using temperature. The stream temperature was assumed to depend on the mixing of surface flow, having a temperature ranging from that of rainfall to that of shallow (50 cm deep) soil water, and subsurface flow, having the temperature of the soil at 1·8 m below the land surface. Subsurface flow was estimated to contribute 85–90% of the total stream flow during each rainstorm. A two‐component hydrograph separation was also evaluated using specific conductance. Runoff contributions from the two sources for the temperature and specific conductance analysis were similar. Analysis of the temperature and conductance–discharge hysteresis loop, and of individual flow components for storm hygrographs, provide a general picture of the runoff process in the experimental basin. Copyright © 1999 John Wiley & Sons, Ltd.     

Runoff generation in zero-order precambrian shield catchments: The stormflow response of a heterogeneous landscape

Hydrometric and isotopic (oxygen-18) observations were used to delineate the runoff processes operating in several headwater catchments on the Precambrian Shield of Canada. The catchments comprise patches of conifer forest situated on thin soils among areas of lichen-covered granitic bedrock. Horton overland flow occurred from the lichen-bedrock areas in all precipitation events that exceeded 4–6 mm. Runoff from the forest stands occurred mainly as subsurface stormflow, but in some instances saturation overland flow was observed. The occurrence of saturation overland flow was controlled by the topography of the bedrock beneath the forest soils. The area contributing runoff and the pathway by which water was conveyed to the catchment outflow switched from the open lichen-bedrock areas producing overland flow on the rising limb of the storm hydrograph to the forest stands contributing subsurface stormflow on the recession limb of the hydrograph. The areal extent and position of the landscape units in the basin were important to the rate and magnitude of stormflow production. Runoff was generated from the catchments only during and immediately after snowmelt and/or rainfall events. The catchments were dry and/or frozen for about 70% of the year.     

Interactions between groundwater and surface water in a virginia coastal plain watershed. 1. Hydrological flowpaths

A field study of surface water and groundwater interactions during baseflow and stormflow conditions was performed at the Reedy Creek watershed in the Virginia Coastal Plain. Three estimates of the average saturated hydraulic conductivity (K_s) of the unconfined aquifer were in reasonable agreement (ranging from 0.0033 to 0.010 cm/s), indicating that baseflow in the creek is entirely from the drainage of shallow groundwater from the relatively thin (1–6 m thick) unconfined aquifer. This relatively permeable surficial aquifer was found to be underlain by dark, olive grey, clay-silt and diatomaceous Miocene deposits of low permeability known as the Calvert Formation, which is believed to function as a confining bed in the area. A chemical hydrograph separation technique was used to resolve the contributions of [old] (pre-event) and [new] (event) water to stormflow. Results from a major rainstorm indicated that old water dominated the stormflow response of the watershed, although the new water contribution approached 40% at the hydrograph peak. Stormflow at Reedy Creek appears to result from saturation overland flow from variable source areas which include the stream channels and a significant part of the riparian wetland area. This response appears to be attributable to the transient dynamics of the shallow groundwater flow system and to the formation of localized groundwater mounds which raise the water-table to the wetland surface.     

Characterizing the climatic water balance dynamics and different runoff components in a poorly gauged tropical forested catchment,Nicaragua

ABSTRACT

The water balance dynamics and runoff components of a tropical forested catchment (46?km²) on the southwestern Pacific coast of Nicaragua were studied combining hydrometry, geological characterization and hydrochemical and isotopic tracers (three-component hydrograph separation). The climatic water balance was estimated for 2010/11, 2011/12 and 2012/13 with net values of 811?mm year^-1, 782?mm year^-1 and –447?mm year^-1, respectively. Runoff components were studied at different spatial and temporal scales, demonstrating that different sources and temporal contributions are controlled by dominant landscape elements and antecedent rainfall. In forested sub-catchments, permeable soils, stratigraphy and steep slopes favour subsurface stormflow generation contributing 50% and 53% to total discharge. At catchment scale, landscape elements such as smooth slopes, wide valleys, deeper soils and water table allow groundwater recharge during rainfall events. Groundwater dominates the hydrograph (50% of total discharge) under dry prior conditions. However, low soil infiltration capacity generates a larger surface runoff component (42%) under wet prior conditions which dominates total discharge. Our results show that forested areas are important to reduce surface runoff and thus soil degradation, which is relevant for the design of water management plans.

Editor D. Koutsoyiannis Associate editor D. Gerten     

Subsurface storm flow formation at different hillslopes and implications for the ‘old water paradox’

Although many studies over the past several decades have documented the importance of subsurface stormflow (SSF) in hillslopes, its formation is still not well understood. Therefore, we studied SSF formation in the vadose soil zone at four different hillslopes during controlled sprinkling experiments and natural rainfall events. Event and pre‐event water fractions were determined using artificially traced sprinkling water and ²²²Rn as natural tracer. SSF formation and the fraction of pre‐event water varied substantially at different hillslopes. Both intensity of SSF and fraction of pre‐event water depended on whether SSF in preferential flow paths was fed directly from precipitation or was fed indirectly from saturated parts of the soil. Soil water was rapidly mobilized from saturated patches in the soil matrix and was subsequently released into larger pores, where it mixed with event water. Substantial amounts of pre‐event water, therefore, were contained in fast flow components like subsurface storm flow and also in overland flow. This finding has consequences for commonly used hydrograph separation methods and might explain part of the ‘old water paradox’. Copyright © 2007 John Wiley & Sons, Ltd.     

The influence of preferential flow on hillslope hydrology in a semi‐arid watershed (in the Spanish Dehesas)

Preferential flow is known to influence hillslope hydrology in many areas around the world. Most research on preferential flow has been performed in temperate regions. Preferential infiltration has also been found in semi‐arid regions, but its impact on the hydrology of these regions is poorly known. The aim of this study is to describe and quantify the influence of preferential flow on the hillslope hydrology from small scale (infiltration) to large scale (subsurface stormflow) in a semi‐arid Dehesa landscape. Precipitation, soil moisture content, piezometric water level and discharge data were used to analyse the hydrological functioning of a catchment in Spain. Variability of soil moisture content during the transition from dry to wet season (September to November) within horizontal soil layers leads to the conclusion that there is preferential infiltration into the soils. When the rainfall intensity is high, a water level rapidly builds up in the piezometer pipes in the area, sometimes even reaching soil surface. This water level also drops back to bedrock within a few hours (under dry catchment conditions) to days (under wet catchment conditions). As the soil matrix is not necessarily wet while this water layer is built up, it is thought to be a transient water table in large connected pores which drain partly to the matrix, partly fill up bedrock irregularities and partly drain through subsurface flow to the channels. When the soil matrix becomes wetter the loss of water from macropores to the matrix and bedrock decreases and subsurface stormflow increases. It may be concluded that the hillslope hydrological system consists of a fine matrix domain and a macropore domain, which have their own flow characteristics but which also interact, depending on the soil matrix and macropore moisture contents. The macropore flow can result in subsurface flow, ranging from 13% contribution to total discharge for a large event of high intensity rainfall or high discharge to 80% of total discharge for a small event with low intensity rainfall or low discharge. During large events the fraction of subsurface stormflow in the discharge is suppressed by the large amount of surface runoff. Copyright © 2008 John Wiley & Sons, Ltd.     

Analysis of geomorphologic and hydrological characteristics in watershed saturated areas using topographic‐index threshold and geomorphology‐based runoff model

The objective of this paper is to investigate the variation of geomorphology and runoff characteristics in saturated areas under different partial contributing area (PCA) conditions. Geomorphologic information and hydrologic records from two mid‐size watersheds in northern Taiwan were selected for analysis. The PCA ratio in the watershed during a storm was assumed equal to the ratio of the surface‐flow volume to the direct runoff volume from measured hydrologic data. The extents of PCA regions were then determined by using a topographic‐index threshold. Consequently, the geomorphologic factors in saturated and unsaturated areas could be calculated using a digital elevation model, and these factors could then be linked to a geomorphology‐based IUH model for runoff simulation, which can consider both the surface‐ and subsurface‐flow processes in saturated and unsaturated areas, respectively. The results show that geomorphologic characteristics in the saturated areas vary significantly with different PCA ratios especially for higher order streams. A large PCA ratio results in a sharp hydrograph because the quick surface flow dominates the runoff process, whereas the hydrologic response in a low PCA case is dominated by the delayed subsurface flow. Copyright © 2007 John Wiley & Sons, Ltd.     

Sources and sinks of nutrients in a New Zealand hill pasture catchment II. Phosphorus

The management of the riparian zone has been suggested as a technique for controlling the amounts of phosphorus (P) entering watercourses draining pasture catchments. A study was therefore made of P entering a stream from various sources (rainfall, surface and subsurface derived runoff, direct fallout from aerial topdressing), with the object of providing a rational basis for the design of effective riparian management schemes. P entrained in surface runoff could account for virtually all of the P entering the stream during storms. Approximately 20 per cent of the annual P export from the catchment could be accounted for by direct aerial input of P to the stream during autumn fertilizer topdressing. More than 85 per cent of the P was exported from the catchment as particulate P. Stream sediment had higher P sorption capacities, and were enriched with P relative to the soils from which they were derived. There was a pronounced seasonal variation in sediment enrichment which could be predicted (r² = 0.92) by the logarithm of the rainfall since fertilizer topdressing (LNFERT) and flood intensity. The amount of P lost in streamflow during any flood event was predicted (r² = 0.94) by peak flow, seven day antecedent peak flow and LNFERT. Approximately 40 per cent of the 1.3 kg P ha^?1 exported during 1981 occurred in four storms with recurrence intervals of more than three months. From a P budget compiled from nine events it was hypothesized that the stream acted as a net sink for P at baseflow and low-medium intensity floods but was a source of P at higher flood intensities. It was concluded that P losses from hill pasture catchments could be reduced by avoidance of direct application of P fertilizer to the stream channel, and by fencing out stock from seasonally saturated areas during periods of saturation. The ultimate success of the latter technique would depend on whether buffer vegetation could retain accumulated P during extreme storm events.     

Component flow processes at four streams in the Catskill Mountains,New York,analysed using episodic concentration/discharge relationships

Plots of solute concentration against discharge have been used to relate stream hydrochemical variations to processes of flow generation, using data collected at four streams in the Catskill Mountains, New York, during the Episodic Response Project of the US Environmental Protection Agency. Results suggest that a two‐component system of shallow and deep saturated subsurface flow, in which the two components respond simultaneously during hydrologic events, may be applicable to the study basins. Using a large natural sea‐salt sodium input as a tracer for precipitation, it is argued that an additional distinction can be made between pre‐event and event water travelling along the shallow subsurface flow path. Pre‐event water is thought to be displaced by infiltrating event water, which becomes dominant on the falling limb of the hydrograph. Where, as appears to be the case for sulfate, a solute equilibrates rapidly within the soil, the pre‐event–event water distinction is unimportant. However, for some solutes there are clear and consistent compositional differences between water from the two sources, evident as a hysteresis loop in concentration–discharge plots. Nitrate and acidity, in particular, appear to be elevated in event water following percolation through the organic horizon. Consequently, the most acidic, high nitrate conditions during an episode generally occur after peak discharge. A simple conceptual model of episode runoff generation is presented on the basis of these results. Copyright © 1999 John Wiley & Sons, Ltd.     

Analysis of runoff pathways and flow contributions using deuterium and stream chemistry

The two-component hydrograph separation method has been used to investigate the sources of storm runoff at Allt a Mharcaidh during storms in October 1987, September 1988, and June 1989. Results show that for the September and October storms, more than 88 per cent of storm runoff was contributed by pre-event water and 54 per cent of the June storm runoff. Instantaneous contributions of pre-event water at the hydrograph peak vary from 91 per cent in September 1988 to 41 per cent in June 1989. Detailed examination of soil and borehole water, however, shows that these subcomponents of pre-event water do not always have similar chemistry and isotope concentrations. Therefore, information from the two-component separation method alone should not be used to infer processes or pathways, although some broad indications can be obtained through the additional use of soil water and groundwater chemistry.     

Base flow separation for soil erosion simulation in a granitic forested headwater catchment using a process-based model,GeoWEPP

Distributed erosion models, which simulate the physical processes of water flow and soil erosion, are effective for predicting soil erosion in forested catchments. Although subsurface flow through multiple pathways is dominant for runoff generation in forested headwater catchments, the process-based erosion model, Geo-spatial interface for Water Erosion Prediction Project(Geo WEPP), does not have an adequate subsurface component for the simulation of hillslope water flow. In the current study, t...     

Physically‐based modelling of double‐peak discharge responses at Slapton Wood catchment

Heavy winter rainfall produces double‐peak hydrographs at the Slapton Wood catchment, Devon, UK. The first peak is saturation‐excess overland flow in the hillslope hollows and the second (i.e. the delayed peak) is subsurface stormflow. The physically‐based spatially‐distributed model SHETRAN is used to try to improve the understanding of the processes that cause the double peaks. A three‐stage (multi‐scale) approach to calibration is used: (1) water balance validation for vertical one‐dimensional flow at arable, grassland and woodland plots; (2) two‐dimensional flow for cross‐sections cutting across the stream valley; and (3) three‐dimensional flow in the full catchment. The main data are for rainfall, stream discharge, evaporation, soil water potential and phreatic surface level. At each scale there was successful comparison with measured responses, using as far as possible parameter values from measurements. There was some calibration but all calibrated values at one scale were used at a larger scale. A large proportion of the subsurface runoff enters the stream from three dry valleys (hillslope hollows), and previous studies have suggested convergence of the water in the three large hollows as being the major mechanism for the production of the delayed peaks. The SHETRAN modelling suggests that the hillslopes that drain directly into the stream are also involved in producing the delayed discharges. The model shows how in the summer most of the catchment is hydraulically disconnected from the stream. In the autumn the catchment eventually ‘wets up’ and shallow subsurface flows are produced, with water deflected laterally along the soil‐bedrock interface producing the delayed peak in the stream hydrograph. Copyright © 2007 John Wiley & Sons, Ltd.