蔗糖脂肪酸酯的开发应用及市场前景

介绍了蔗糖脂肪酸酯的性质、用途以及国内外生产、消费和市场概况,对蔗糖脂肪酸酯和蔗糖多酯的几种合成方法进行了综述。     

脂肪酸甲酯磺酸钠的生产应用与市场

本文综述了以天然油脂生产脂肪酸甲酯的工艺，介绍了其性质和加工产品的特性、用途，分析了国内市场的需求。     

脂肪酸甲酯磺酸钠的生产应用与市场

本文综述了以天然油脂生产脂肪酸甲酯的工艺,介绍了其性质和加工产品的特性、用途,分析了国内市场的需求。     

当前我国发展皂用合成脂肪酸应当采取什么技术路线

世界上发展合成脂肪酸工业有二种类型,一种是食用油产量较多的国家,如美国人均年产量约为55公斤,主要发展生产天然油脂中少有或没有的合成脂肪酸工业,例如生产＜C11的脂肪酸用以制造合成润滑油等。另一种类型是食用油产量较少的国家,如苏联和我国,要求工业用脂肪酸尽量不从天然油脂中提取,用合成的＞C12脂肪酸来代替食用油用于工业用途。我国肥皂工业消耗的脂肪酸约占工业用油的80%左右,因此发展合成脂肪酸的出发点是多生产皂用合成脂肪酸,以节约肥皂工业中食用油的用量。     

脂肪酸酯的技术与市场发展动向

论述了脂肪酸一元醇酯,多元醇酯的特性、合成及用途,并介绍了由脂肪酸酯开发“绿色”表面活性剂的最新技术动向。     

羊毛脂及其衍生物的应用

1.前言羊毛脂在药品和化妆品方面有许多用途。它的组分是由各种的高级醇与高级脂肪酸生成的天然酯的混合物。本文从化学方面对羊毛脂的酯、脂肪酸和醇的组成,羊毛脂的化学和物理性质,羊毛脂的精制以及它在医药品、化妆品方面的应用等,加以说明。     

蔗糖脂肪酸酯的制备及用途

介绍了蔗糖脂肪酸酯的制备方法，生产现状及用途     

我国脂肪酸的生产和应用

简要介绍脂肪酸的分类、原料来源、生产工艺、品种以及用途。并对我国脂肪酸的生产现状进行了分析。重点介绍了脂肪酸在我国橡胶工业中、塑料助剂等领域的应用,脂肪酸甲酯作为表面活性剂在不同领域的广泛应用,最后还简述了癸二酸和改性醇酸树脂应用。     

蔗糖脂肪酸酯的制备及用途

介绍了蔗糖脂肪酸酯的制备方法，生产现状及用途。     

金属皂

普通肥皂,即脂肪酸的钠盐或钾盐,是大家很熟识的;但是对于脂肪酸和其他金属所化合的金属皂,则比较生疏。本文拟介绍几种金属皂的制法、性质和用途。锂皂是用适量的醋酸锂加入脂肪酸的乙醇溶液中制成。锂皂稍溶于甲醇中,在水和乙醇中的溶解度都很低,在其他有机溶剂中的溶解度也很小。脂肪酸和碱土金属化合的金属皂,可以用这几种金属的氧化物或氢氧化合物和甘油醇用普通的皂化方法做成。例如有的肥皂厂就先用石灰乳     

Back to the future: Fatty acids,the green genie to design smart soft materials

Fatty acids are widely used in industries for various applications as soaps or in their crystalline form. Fatty acid soaps are used as surface-active agent to stabilize foams and emulsions, for detergency, and surface wetting. Fatty acid molecules in organic solvents are used as low-molecular-mass organic gelators. Currently, there is a renewed interest in using fatty acids in industrial applications instead of petrochemical surfactants since fatty acid soaps are green surfactants. Fatty acids exhibit also many advantages, including the design of responsive soft-materials. Fatty acid soaps are natural pH and thermoresponsive surfactants, which can lead to responsive foams and emulsions. In their crystalline form, fatty acid crystals in both aqueous and non-aqueous solvents stabilize liquid foams. These crystals are also efficient in the production of liquid marbles. Fatty acids are solvosurfactants with the ability to form microemulsions and capillary suspensions. In this review, we illustrate how fatty acid molecules can be used in the manufacture of multiresponsive soft-materials ranging from aqueous and non-aqueous foams, emulsions, nanoemulsions, microemulsions, liquid marbles and capillary suspensions.     

天然橡胶中脂肪酸的分析与研究

天然橡胶和复合橡胶在许可证管理和关税税率方面存在较大的差异,使海关对复合橡胶的进口监管面临着较大风险。本方法紧贴海关监管要求,利用气相色谱和溶解法对天然橡胶中的各种脂肪酸进行分析和测定,通过对比天然橡胶加入工业硬脂酸后制成的复合橡胶中脂肪酸的变化,对添加工业硬脂酸的复合橡胶进行定性分析。     

N-酰基甘氨酸类表面活性剂的合成

以天然脂肪酸和甘氨酸为主要原料,脂肪酸先与氯化亚砜反应制得酰氯,酰氯再与甘氨酸进行缩合反应,合成N-酰基甘氨酸,最后成盐。缩合反应条件为:脂肪酰氯与甘氨酸物质的量比为1.0∶2.0,25℃下反应2.5h,反应体系pH值控制在9～10,以丙酮与水的混合溶液(体积比为1∶1)作为溶剂,产物的收率均在85%以上,并对N-酰基甘氨酸结构进行了1HNMR表征。     

油脂化学工业中酶与微生物开发利用的新进展

评述了油脂化学工业中酶、微生物开发应用的新进展。介绍了脂肪酶的分解，脂肪酸、脂肪醇的微生物转化和利用微生物生产不饱和脂肪酸及油脂等过程。指出生物工艺学的发展前景。     

Differently sized native milk fat globules separated by microfiltration: fatty acid composition of the milk fat globule membrane and triglyceride core

The aim of this study was to characterize the fatty acid composition of the core and membrane of differently sized milk fat globules separated by microfiltration, which can now be used to manufacture dairy products. Native milk fat globules of various mean diameters, ranging from d₄₃ = 2.3 µm to 8.0 µm, were obtained using microfiltration of raw whole milk. After milk fat globule washing, the milk fat globule membrane (MFGM) and the triglyceride core (TC) were separated by manual churning. After total lipid extraction from each fraction, their fatty acid composition was characterized using methyl ester analysis by gas chromatography. Regardless of season, no significant differences were observed in the fatty acid composition of the MFGM phospholipids. Conversely, significant differences were found in the fatty acid composition of TC; particularly, small fat globule TC contained more medium‐chain fatty acids and less stearic acid than large fat globule TC. These results show that the previously observed differences in total fatty acid composition among differently sized milk fat globules are due to their triglyceride composition and MFGM amount rather than to the composition of the MFGM.     

Single-Cell Oils as a Source of Omega-3 Fatty Acids: An Overview of Recent Advances

Omega-3 fatty acids, namely docosahexaenoic acid and eicosapentaenoic acid, have been linked to several beneficial health effects (i.e. mitigation effects of hypertension, stroke, diabetes, osteoporosis, depression, schizophrenia, asthma, macular degeneration, rheumatoid arthritis, etc.). The main source of omega-3 fatty acids is fish oil; lately however, fish oil market prices have increased significantly. This has prompted a significant amount of research on the use of single-cell oils as a source of omega-3 fatty acids. Some of the microbes reported to produce edible oil that contains omega-3 fatty acids are from the genus Schizochytrium, Thraustochytrium and Ulkenia. An advantage of a single cell oil is that it usually contains a significant amount of natural antioxidants (i.e. carotenoids and tocopherols), which can protect omega-3 fatty acids from oxidation, hence making this oil less prone to oxidation than oils derived from plants and marine animals. Production yields of single cell oils and of omega-3 fatty acids vary with the microbe used, with the fermentative growing conditions, and extractive procedures employed to recover the oil. This paper presents an overview of recent advances, reported within the last 10 years, in the production of single cell oils rich in omega-3 fatty acids.     

单体酸混合物成分的GC-MS分析

研究了生产二聚酸时得到的副产品单体酸的化学组成的GC MS分析方法,样品首先用质量浓度为140g/L KOH M eOH进行甲酯化,然后用GC MS进行分析和鉴定,共鉴定出棕榈酸、肉豆蔻酸、10甲基月桂酸、12甲基十四烷酸、十八烯酸等13种物质,总脂肪酸的质量分数占76.71%,其中饱和酸占66.36%,不饱和酸占10.35%,其中直链酸占饱和脂肪酸的41.02%,支链酸即异构酸占饱和脂肪酸的58.98%。     

环氧脂肪酸钙/锌的直接合成法及其对PVC热稳定作用的研究

以一种简使的方法制备了环氧基保留完好的高纯度环氧脂肪酸钙／锌，研究发现环氧脂肪酸钙／锌对聚氯乙烯（PVC）的热稳定作用类似于硬脂酸钙／锌，但其热稳定效能明显优于后者，且具有较好的初期着色性。可用于无毒制品，具有良好的社会效益和经济效益。     

乌桕梓油脂肪酸组成分析

乌柏是我国四大木本油料之一,种子含油量高,乌桕梓油是由种仁榨取所得的液体油脂,是轻工业、食品和国防等行业的重要油源。乌桕梓油甲酯化后,利用100 m×0.25 mm的GC毛细管柱,气相色谱法测定乌桕梓油的脂肪酸组成。测定结果表明：乌桕梓油中饱和脂肪酸占10.68%,以棕榈酸含量最高,占7.52%。不饱和脂肪酸占89.13%,单不饱和脂肪酸占18.63%,以油酸含量最高,占14.55%;多不饱和脂肪酸占70.50%;其中含量最高的为人体所必需的脂肪酸亚油酸和α-亚麻酸,分别占30.77%和39.30%。还含有相当数量天然植物中少有的奇数碳原子脂肪酸十一烷酸,占0.29%。其中月桂烯酸（占3.19%）和十一烷酸未见报道。     

油脂水解生产脂肪酸工艺选择

文章阐述了以天然油脂为原料生产脂肪酸的发展前景,分析了影响油脂水解的因素,详细介绍了工业上常用的三种油脂水解的生产工艺,并对最先进的生产工艺做出选择。