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1.
Measurements were taken in new US residences to assess the extent to which ventilation and source control can mitigate formaldehyde exposure. Increasing ventilation consistently lowered indoor formaldehyde concentrations. However, at a reference air exchange rate of 0.35 h?1, increasing ventilation was up to 60% less effective than would be predicted if the emission rate were constant. This is consistent with formaldehyde emission rates decreasing as air concentrations increase, as observed in chamber studies. In contrast, measurements suggest acetaldehyde emission was independent of ventilation rate. To evaluate the effectiveness of source control, formaldehyde concentrations were measured in Leadership in Energy and Environmental Design (LEED)‐certified/Indoor airPLUS homes constructed with materials certified to have low emission rates of volatile organic compounds (VOC). At a reference air exchange rate of 0.35 h?1, and adjusting for home age, temperature and relative humidity, formaldehyde concentrations in homes built with low‐VOC materials were 42% lower on average than in reference new homes with conventional building materials. Without adjustment, concentrations were 27% lower in the low‐VOC homes. The mean and standard deviation of formaldehyde concentration was 33 μg/m3 and 22 μg/m3 for low‐VOC homes and 45 μg/m3 and 30 μg/m3 for conventional.  相似文献   

2.
In buildings which were built within the last 15 to 20 years, or which have been retrofitted, and which do notfeature a mechanical ventilation system, air changes between 0.01 h?1 and 0.5 h?1 were measured while windows were closed. In the bedrooms of such buildings, when doors and windows were closed, CO2 concentrations of up to 4300 ppm were measured whereby the 1500 ppm limit was often exceeded. Simulation calculations and diverse measurements using different door positions with simultaneously closed windows have shown that with the door open more than 10 cm, and a minimal air exchange in the whole of an apartment of 0.1 h?1, a CO2 concentration of I500 ppm was not or was only insignifiantly exceeded even after 10 hours. Investigations in a dwelling fined with a mechanical ventilation system have shown that air quality and the indoor climate parameters were in an optimal range.  相似文献   

3.
S. Shi  Y. Bian  L. Zhang  C. Chen 《Indoor air》2017,27(6):1190-1200
Recently, many nanofiber films have been developed for air filtration applications. These films exhibit high PM2.5 (particles with aerodynamic diameters less than 2.5 μm) removal efficiency and relatively low air resistance. Thus, coating window screens with nanofiber films may be able to mitigate residential exposure to PM2.5 of outdoor origin. This study developed a method for assessing the performance of nanofiber window screens in reducing residential exposure to PM2.5 of outdoor origin in Beijing. The results show that the use of selected nanofiber window screens all the time throughout the year can reduce the mean value of the annual average indoor PM2.5 of outdoor origin by 64%‐66% for Beijing residences. However, the mean value of annual harmonic average air exchange rate when the windows are open was also reduced from 2.34 h?1 to 0.27‐0.35 h?1, which is far below the national standard. If the nanofiber window screens were used only when the outdoor PM2.5 pollution was severe, the screens had less of an impact on residential natural ventilation, but the national standard still could not be met. Hence, more efforts are needed to further reduce the air resistance of nanofiber window screens in order to ensure proper residential ventilation.  相似文献   

4.
Volatile organic compounds (VOC) in office buildings originate from multiple sources, such as outdoor air, building materials., occupants, office supplies, and office equipment. Many of the VOC found in office buildings are also present in environmental tobacco smoke (ETS), e.g., benzene, toluene, formaldehyde. Measurements made to date in office buildings have been interpreted by some to imply that the contributions of ETS to VOC exposures in office buildings are small. We have made a first order estimate of the contributions of ETS to VOC concentrations based on the VOC content of ETS and a time-dependent mass-balance model. Four different ventilation-infiltration scenarios were modelled for a typical office building. The results indicate that ETS can contribute significantly to total indoor levels of VOC in office buildings, even under moderate ventilation conditions. Ranges of concentrations for three of the four modelled scenarios substantially overlapped measured ranges of the compounds in office buildings. Average daytime concentrations of benzene from ETS, for example, for three of the four modelled scenarios, ranged from 2.7 to 6.2 μg m?3, compared to reported measurements of 1.4 to 8.1 μg m?3 for four office buildings. Under a “worst reasonable” case scenario, the average modelled ETS-contributed concentration of benzene was 33.9 μg m?3 for a 40-hour work week.  相似文献   

5.
Abstract To investigate the effect of ventilation on indoor radon (222Rn), simultaneous measurements of radon concentrations and air change rates were made in 117 Danish naturally ventilated slab-on-grade houses built during the period 1984–1989. Radon measurements (based on CR-39 alpha-track detectors) and air change rate measurements (based on the perfluorocarbon tracer technique; PFT) were in the ranges 12–620 Bq m?3 and 0.16?0.96 h?1, respectively. Estimates of radon entry rates on the basis of such time-averaged results are presented and the associated uncertainty is discussed. It was found that differences in radon concentrations from one house to another are primarily caused by differences in radon entry rates whereas differences in air change rates are much less important (accounting for only 80,0% of the house-to-house variation). In spite of the large house-to-house variability of radon entry rates it was demonstrated, however, that natural ventilation does have a significant effect on the indoor radon concentration. Most importantly, it was found that the group of houses with an air change rate above the required level of 0.5 h?1 on average had an indoor radon concentration that was only 50% (0.5±0.1) of that of the group of houses with air change rates below 0.5 h?1. The reducing effect of increased natural ventilation on the indoor radon concentration was found to be due mainly to dilution of indoor air. No effect could be seen regarding reduced radon entry rates.  相似文献   

6.
This study measured air exchange rates, indoor concentrations of aldehydes and volatile organic compounds (VOCs), and radioactivity levels at 19 temporary houses in different temporary housing estate constructed in Minamisoma City following the Great East Japan Earthquake. The 19 surveyed houses represented all of the companies assigned to construct temporary houses in that Minamisoma City. Data were collected shortly after construction and before occupation, from August 2011 to January 2012. Mean air exchange rates in the temporary houses were 0.28/h, with no variation according to housing types and construction date. Mean indoor concentrations of formaldehyde, acetaldehyde, toluene, ethylbenzene, m/p‐xylene, o‐xylene, styrene, p‐dichlorobenzene, tetradecane, and total VOCs (TVOCs) were 29.2, 72.7, 14.6, 6.35, 3.05, 1.81, 7.29, 14.3, 8.32, and 901 μg/m3, respectively. The levels of acetaldehyde and TVOCs exceeded the indoor guideline (48 μg/m3) and interim target (400 μg/m3) in more than half of the 31 rooms tested. In addition to guideline chemicals, terpenes (α‐pinene and d‐limonene) and acetic esters (butyl acetate and ethyl acetate) were often detected in these houses. The indoor radiation levels measured by a Geiger–Müller tube (Mean: 0.22 μSv/h) were lower than those recorded outdoors (Mean: 0.42 μSv/h), although the shielding effect of the houses was less than for other types of buildings.  相似文献   

7.
Indoor surfaces may be adsorptive sinks with the potential to change Indoor Air Quality. To estimate this effect, the sorption parameters of formaldehyde and toluene were assessed on five floorings by an experimental method using solid-phase microextraction in an airtight emission cell. Adsorption rate constants ranged from 0.003 to 0.075 m·h−1, desorption rate constants from 0.019 to 0.51 h−1, and the partition coefficient from 0.005 to 3.9 m, and these parameters vary greatly from one volatile organic compound/material couple to another indicating contrasted sorption behaviors. A rubber was identified as a sink of formaldehyde characterized by a very low desorption constant close to 0. For these sorbent floorings identified, the adsorption rates of formaldehyde are from 2 to 4 times higher than those of toluene. Two models were used to evaluate the sink effects of floorings on indoor pollutant concentrations in one room from different realistic conditions. The scenarios tested came to the conclusion that the formaldehyde sorption on one rubber (identified as a sink) has a maximum contribution from 15% to 21% for the conditions of low air exchange rate. For other floorings, the sorption has a minor contribution less than or equal to 5%, regardless of the air exchange rate.  相似文献   

8.
A representative sample of over 2,000 UK dwellings was monitored for a year using thermoluminescent and etchable plastic dosemeters to measure gamma-ray dose rates and radon concentrations. The survey was carried out by post. Each householder completed a questionnaire on the type of dwelling and its characteristics. These data will be used in the assessment of the factors affecting indoor exposure. The mean gamma-ray dose rates were 0.062 and 0.057 μGy h?1 in air and the mean radon concentrations were 25 and 18 Bq m?3 for living areas and bedrooms respectively. Other results of the preliminary data analysis are given.More detailed surveys were conducted in areas where the local geology indicated that elevated exposures to natural radiation might occur. Over 800 dwellings were visited and measurements made of several parameters. The mean gamma-ray dose rates varied from 0.05 to 0.10 μGy h?1 in air. The mean radon concentrations varied from 14 Bq m?3 to 520 Bq m?3. Other findings related to equilibrium factors and regional differences are discussed.  相似文献   

9.
Abstract Five classrooms, air-conditioned or naturally ventilated, at five different schools were chosen for comparison of indoor and outdoor air quality. Temperature, relative humidity (RH), carbon dioxide (CO2), sulphur dioxide (SO2), nitric oxide (NO), nitrogen dioxide (NO2), particulate matter with diameter less than 10 mm (PM10), formaldehyde (HCHO), and total bacteria counts were monitored at indoor and outdoor locations simultaneously. Respirable particulate matter was found to be the worst among parameters measured in this study. The indoor and outdoor average PM10 concentrations exceeded the Hong Kong standards, and the maximum indoor PM10 level was even at 472 μ;g/m3. Air cleaners could be used in classrooms to reduce the high PM10 concentration. Indoor CO2 concentrations often exceeded 1,000 μl/l indicating inadequate ventilation. Lowering the occupancy and increasing breaks between classes could alleviate the high CO2 concentrations. Though the maximum indoor CO2 level reached 5,900 μl/l during class at one of the sites, CO2 concentrations were still at levels that pose no health threats.  相似文献   

10.
The formaldehyde emission rates from building and furniture materials in 24 student rooms were measured using a passive sampling method parallel to a monitoring of indoor and outdoor concentrations. This passive tool represents an interesting alternative to standard dynamic methods as it is easier to implement for field investigation. Although the indoor formaldehyde concentrations (21.3 μg m−3 on average) are at a medium level, consistent with earlier published results, the recorded emission rates are globally low (from 1 to 15 μg m−2 h−1) except for the high emission of beds identified in one building (87.3 μg m−2 h−1 on average). Data analysis revealed that the emissions released from furniture and building materials are the main contributions to the indoor formaldehyde concentrations with 45 and 43% on average. The high formaldehyde levels in rooms are mainly explained by the rise of formaldehyde emissions from indoor materials with temperature although the buildings and the furniture were older than 7 years. Basing on the data of emission rates, outdoor concentrations and air exchange rates, a one compartment mass balance model was used to calculate indoor concentrations. A good agreement was found between the predictions of the model and the measured indoor concentrations. This methodology could lead to the definition of arrangements for the efficient reduction of indoor formaldehyde levels.  相似文献   

11.
《Building and Environment》2005,40(11):1566-1571
Based on an averaging technique, a methodology has been established to estimate an effective radon emanation factor M for residential premises. The model shows that the new term M and the ventilation rate are the essential parameters in estimating the level of indoor radon. M includes two components: the radon emanation rates of internal surface materials and the ratio of surface areas of applicable materials to premises volume. The value of M can be determined from on-site measurements. Different ventilation modes of a sampled residential unit during daytime and nighttime, with air conditioner on, window-open, and window-closed were included in site measurements. Each ventilation mode was measured twice during daytime and twice at night. During the investigation, air exchange rate, and indoor and outdoor radon levels were monitored simultaneously. The results of measurements were then used to verify the model. The value of M was found to be 31.7 Bq m−3 h−1. The model is valid if the air exchange rate is larger than 0.2 h−1.  相似文献   

12.
Particle mass and number concentrations were measured in a mechanically ventilated classroom as part of a study of ventilation strategies for energy conservation. The ventilation system was operated either continuously, intermittently, or shut down during nights while it was on during workdays. It appears that the nighttime ventilation scheme is not important for indoor particle concentrations the following day if fans are operated to give five air exchanges in advance of the workday. The highest concentrations of PM10 were found during and after workdays and were due to human activity in the classroom. The average workday PM10 concentration was 14 μg/m3, well below the WHO guideline values. The number concentration of particles with diameter <0.750 μm was typically between 0.5 × 103 and 3.5 × 103 particle/cm3. These concentrations were largely independent of the occupants. Transient formation of small particles was observed when ventilation was shut down. Then remaining ozone reacted with terpenes emitted by indoor sources and gave up to 8 × 103 particle/cm3 before formation stopped due to lack of ozone. The intermittent ventilation regime was found least favorable for the indoor air quality in the classroom.  相似文献   

13.
Little information is available about air quality in early childhood education (ECE) facilities. We collected single‐day air samples in 2010–2011 from 40 ECE facilities serving children ≤6 years old in California and applied new methods to evaluate cancer risk in young children. Formaldehyde and acetaldehyde were detected in 100% of samples. The median (max) indoor formaldehyde and acetaldehyde levels (μg/m3) were 17.8 (48.8) and 7.5 (23.3), respectively, and were comparable to other California schools and homes. Formaldehyde and acetaldehyde concentrations were inversely associated with air exchange rates (Pearson r = ?0.54 and ?0.63, respectively; P < 0.001). The buildings and furnishings were generally >5 years old, suggesting other indoor sources. Formaldehyde levels exceeded California 8‐h and chronic Reference Exposure Levels (both 9 μg/m3) for non‐cancer effects in 87.5% of facilities. Acetaldehyde levels exceeded the U.S. EPA Reference Concentration in 30% of facilities. If reflective of long‐term averages, estimated exposures would exceed age‐adjusted ‘safe harbor levels’ based on California's Proposition 65 guidelines (10?5 lifetime cancer risk). Additional research is needed to identify sources of formaldehyde and acetaldehyde and strategies to reduce indoor air levels. The impact of recent California and proposed U.S. EPA regulations to reduce formaldehyde levels in future construction should be assessed.  相似文献   

14.
In indoor environments with high levels of air pollution, it is desirable to remove major sources of emissions to improve air quality. In order to identify the emission sources that contribute most to the concentrations of indoor air pollutants, we used passive flux samplers (PFSs) to measure emission rates of carbonyl compounds and volatile organic compounds (VOCs) from many of the building materials and furnishings present in a room in a reinforced concrete building in Tokyo, Japan. The emission flux of formaldehyde from a desk was high (125 μg/m2/h), whereas fluxes from a door and flooring were low (21.5 and 16.5 μg/m2/h, respectively). The emission fluxes of toluene from the ceiling and the carpet were high (80.0 and 72.3 μg/m2/h, respectively), whereas that from the flooring was low (9.09 μg/m2/h). The indoor and outdoor concentrations of formaldehyde were 61.5 and 8.64 μg/m3, respectively, and those of toluene were 43.2 and 17.5 μg/m3, respectively. The air exchange rate of the room as measured by the perfluorocarbon tracer (PFT) method was 1.84/h. Taking into consideration the area of the emission sources, the carpet, ceiling, and walls were identified as the principal emission sources, contributing 24%, 20%, and 22% of the formaldehyde, respectively, and 22%, 27%, and 14% of the toluene, respectively, assuming that the emission rate from every major emission sources could be measured. In contrast, the door, the flooring, and the desk contributed little to the indoor levels of formaldehyde (1.0%, 0.54%, and 4.1%, respectively) and toluene (2.2%, 0.31%, and 0.85%, respectively).  相似文献   

15.
According to the Californian Safe Drinking Water and Toxic Enforcement Act, Proposition 65 (State of California, 1986) the manufacturers and retailers of products (such as furniture and fittings) which emit formaldehyde are obliged to either mark their products with a warning label or provide evidence that their products do not pose a significant cancer risk to the consumer. The significant risk is defined as 1 case of cancer in a population of 100,000 persons within a period of exposure of 70 years (State of California, 1992). In this study, a large-scale climate chamber test of a full set of furniture and fitments was made. The formaldehyde concentration in a test chamber peaked at about 112 μg/m3 within a day after the furniture had been installed. After 8 weeks the concentration leveled out at about 50 μg/m3. Various models were used to predict occupant exposures in homes containing the same furniture and fitments; multi-compartment models identified a short-term compartment with a half-life of between 5.2 and 6.0 h and a relative source strength of between 75% and 30% of the total source strength; a medium-term compartment with a half-life of between 14 and 81 days; and a long-term compartment for which the best estimate of a half-life was 384 days. The accumulated dose of formaldehyde absorbed by an occupant during 70 years of exposure in the hypothetical home was estimated by extrapolation using the same models. The dose was found to be in the range of 0.13 g to 0.16 g. The concentration in the test chamber showing a maximum value of 112 μg/m3 formaldehyde may cause discomfort among hypersensitive persons during the first couple of days. The risk estimates based on the estimated long-term dose indicate that the cancer risks associated with the exposure caused by furniture are in the range of 6.9 to 8.9 × 10?8, based on monkey data, and 5.8 to 7.4 × 10?7, based on rat data. In conclusion, a successful draft protocol was established for tests in relation to Proposition 65 and, with the limitations of this exploratory study, the actual furniture equipment is considered to cause no significant cancer risk to the consumer according to the Proposition.  相似文献   

16.
A particle exposure experiment inside a large climate‐controlled chamber was conducted. Data on spatial and temporal distribution of nanoscale and fine aerosols in the range of mobility diameters 8‐600 nm were collected with high resolution, for sodium chloride, fluorescein sodium, and silica particles. Exposure scenarios studied included constant and intermittent source emissions, different aggregation conditions, high (10 h?1) and low (3.5 h?1) air exchange rates (AERs) corresponding to chamber Reynolds number, respectively, equal to 1 × 105 and 3 × 104. Results are presented and analyzed to highlight the main determinants of exposure and to determine whether the assumptions underlying two‐box models hold under various scenarios. The main determinants of exposure found were the source generation rate and the ventilation rate. The effect of particles nature was indiscernible, and the decrease of airborne total number concentrations attributable to surface deposition was estimated lower than 2% when the source was active. A near‐field/far‐field structure of aerosol concentration was always observed for the AER = 10 h?1 but for AER = 3.5 h?1, a single‐field structure was found. The particle size distribution was always homogeneous in space but a general shift of particle diameter (?8% to +16%) was observed between scenarios in correlation with the AER and with the source position, presumably largely attributable to aggregation.  相似文献   

17.
This paper presents pollutant concentrations and performance data for code-required mechanical ventilation equipment in 23 low-income apartments at 4 properties constructed or renovated 2013-2017. All apartments had natural gas cooking burners. Occupants pledged to not use windows for ventilation during the study but several did. Measured airflows of range hoods and bathroom exhaust fans were lower than product specifications. Only eight apartments operationally met all ventilation code requirements. Pollutants measured over one week in each apartment included time-resolved fine particulate matter (PM2.5), nitrogen dioxide (NO2), formaldehyde and carbon dioxide (CO2) and time-integrated formaldehyde, NO2 and nitrogen oxides (NOX). Compared to a recent study of California houses with code-compliant ventilation, apartments were smaller, had fewer occupants, higher densities, and higher mechanical ventilation rates. Mean PM2.5, formaldehyde, NO2, and CO2 were 7.7 µg/m3, 14.1, 18.8, and 741 ppm in apartments; these are 4% lower, 25% lower, 165% higher, and 18% higher compared to houses with similar cooking frequency. Four apartments had weekly PM2.5 above the California annual outdoor standard of 12 µg/m3 and also discrete days above the World Health Organization 24-hour guideline of 25 µg/m3. Two apartments had weekly NO2 above the California annual outdoor standard of 30 ppb.  相似文献   

18.
This study aimed to better understand and quantify the influence of ventilation strategies on occupant‐related indoor air chemistry. The oxidation of human skin oil constituents was studied in a continuously ventilated climate chamber at two air exchange rates (1 h?1 and 3 h?1) and two initial ozone mixing ratios (30 and 60 ppb). Additional measurements were performed to investigate the effect of intermittent ventilation (“off” followed by “on”). Soiled t‐shirts were used to simulate the presence of occupants. A time‐of‐flight‐chemical ionization mass spectrometer (ToF‐CIMS) in positive mode using protonated water clusters was used to measure the oxygenated reaction products geranyl acetone, 6‐methyl‐5‐hepten‐2‐one (6‐MHO) and 4‐oxopentanal (4‐OPA). The measurement data were used in a series of mass balance models accounting for formation and removal processes. Reactions of ozone with squalene occurring on the surface of the t‐shirts are mass transport limited; ventilation rate has only a small effect on this surface chemistry. Ozone‐squalene reactions on the t‐shirts produced gas‐phase geranyl acetone, which was subsequently removed almost equally by ventilation and further reaction with ozone. About 70% of gas‐phase 6‐MHO was produced in surface reactions on the t‐shirts, the remainder in secondary gas‐phase reactions of ozone with geranyl acetone. 6‐MHO was primarily removed by ventilation, while further reaction with ozone was responsible for about a third of its removal. 4‐OPA was formed primarily on the surfaces of the shirts (~60%); gas‐phase reactions of ozone with geranyl acetone and 6‐MHO accounted for ~30% and ~10%, respectively. 4‐OPA was removed entirely by ventilation. The results from the intermittent ventilation scenarios showed delayed formation of the reaction products and lower product concentrations compared to continuous ventilation.  相似文献   

19.
The interaction between different ventilation strategies, and the adsorption and desorption of volatile organic compounds on material surfaces in small test chambers, is investigated. In test chamber experiments, nylon carpet was exposed to a mixture of toluene and α-pinene at two different dosing rates. The ventilation strategies were chosen to mimic the conditions in real buildings, i.e. with an air exchange rate of 2 h−1 during the working day (8–17) and a rate of 0.67 h−1 during the remainder of the 24 h. The results show that the sorption behavior has to be included when estimating the concentration variations in a room based on source characteristics and ventilation rates. The software application “EnviSim” was used to model the concentrations in a model room based on the experimental conditions. As the ventilation strategy influences the resulting concentrations, it is recommended that the ventilation system be “turned on” a couple of hours before the start of the working day and “turned down” again soon after the occupants have left the building.  相似文献   

20.
Y. Yang  M. S. Waring 《Indoor air》2016,26(6):939-952
Secondary organic aerosol (SOA) owing to reactive organic gas (ROG) ozonolysis can be an important indoor particle source. However, SOA formation owing to ozonolysis of α‐terpineol, which is emitted by consumer product usage and reacts strongly with ozone, has not been systematically quantified. Therefore, we conducted 21 experiments to investigate the SOA formation initiated by α‐terpineol ozonolysis for high (0.84 h?1), moderate (0.61 h?1), and low (0.36 h?1) air exchange rates (AER), which is the frequency with which indoor is replaced by outdoor air. α‐Terpineol concentrations of 6.39 to 226 ppb were combined with high ozone (~25 ppm) to ensure rapid and complete ozonolysis. No reactants were replenished, so SOA peaked quickly and then decreased due to AER and surface losses, and peak SOA ranged from 2.03 to 281 μg/m3 at unit density. SOA mass formation was parameterized with the aerosol mass fraction (AMF), a.k.a. the SOA yield, and AMFs ranged from 0.056 to 0.24. The AMFs strongly and positively correlated with reacted α‐terpineol, whereas they weakly and negatively correlated with higher AERs. One‐product, two‐product, and volatility basis set (VBS) models were fit to the AMF data. Predictive modeling demonstrated that α‐terpineol ozonolysis could meaningfully form SOA in indoor air.  相似文献   

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