2A12铝合金电化学腐蚀行为研究

采取正交试验方法,利用极化曲线和电化学阻抗谱(EIS)等电化学方法研究了2A12铝合金在不同溶液浓度、pH值以及温度的NaCl溶液中的腐蚀行为。试验结果表明,溶液浓度、pH值以及温度对2A12铝合金在NaCl溶液中耐腐蚀行为的影响依次为：pH值、温度、溶液浓度。2A12铝合金的耐腐蚀性能随着NaCl溶液浓度的增加而变差;NaCl溶液温度越高,腐蚀电流密度Icorr越大,合金耐腐蚀性能下降;溶液中性条件下,合金耐腐蚀性能最强,碱性条件下耐腐蚀性能最差;酸性条件下腐蚀电流密度Icorr随pH值的降低而增大,合金耐腐蚀性能减弱。     

Cl-含量对2A12铝合金腐蚀行为的影响

通过干湿周浸实验、扫描电镜观察和x射线衍射分析研究了2A12铝合金在NaCl的质量分数不同的NaCl溶液中的腐蚀行为与规律.实验结果表明,2A12铝合金在五种NaCl不同含量的NaCl溶液中周浸480 h后,腐蚀动力学均服从幂指数关系,腐蚀形态为明显的局部腐蚀,主要包括点蚀和晶间腐蚀.在NaCl的质量分数为5%的NaCl溶液中,点蚀深度达到极大值.各实验条件下,腐蚀产物组成基本一致,主要含有AlO(OH),AlCl3和Al2O3等.     

阳极氧化时间对2A12铝合金剥落腐蚀性能的影响

利用扫描电镜(SEM)、能谱仪(EDS)以及膜厚测量等分析测试方法研究了不同阳极氧化时间对2A12铝合金抗剥落腐蚀性能的影响。结果表明：随着阳极氧化时间延长,氧化膜厚度逐渐增加,其抗剥落腐蚀性能越好。当阳极氧化时间从30 min延长至60 min时,氧化膜厚度从2.43 μm增大到4.72 μm,膜厚标准差从0.75减少至0.52。但是当阳极氧化时间超过60 min后,氧化膜厚度增长趋势缓慢,膜厚标准差逐渐趋于一水平值。宏观、微观形貌综合分析结果表明,当阳极氧化时间为60 min时,2A12铝合金的耐腐蚀性能最好。     

LY12装甲铝合金焊接残余应力研究

采用钻孔-电测法对LY12铝合金垂直于焊缝方向的焊接残余应力及其分布规律、产生的原因进行了分析,探讨了残余应力的消除措施.研究表明：板厚为6mm的LY12铝合金的焊接残余应力呈双向应力状态;垂直于焊缝方向的残余应力,在焊缝上的应力较大,沿远离焊缝方向逐渐减小,纵向残余应力σx比横向残余应力σy大得多.热处理后的结头强度为236.5 MPa,比未处理的强度提高58.7%.     

铝合金应力腐蚀裂纹内氯离子浓度的分布

研究了ＬＣ４铝合金在３．５％和０．０３５％ＮａＣｌ水溶液中，应力腐蚀裂纹内氯离子浓度的分布。结果表明：裂纹内氯离子浓度升高，外部环境中氯离子浓度对裂纹内氯离子浓度影响较小；在极化状态下，裂纹内氯离子浓度与极化电位的关系，同裂纹内铝离子浓度及ＰＨ值与极化电位的关系有着相对应的规律。     

热处理对705铝合金板应力腐蚀性能的影响

采用了多种热处理工艺对７０５铝合金板应力腐蚀性能进行了研究,结果表明,原供货态的７０５铝合金板短横向抗应力腐蚀性能较低采用新的热处理工艺可在强度与原供货态相当的情况下,显著地提高７０５铝合金板的抗应力腐蚀性能。     

极化电位对5083铝合金型材应力腐蚀行为的影响

采用慢应变速率拉伸（SSRT）测试法及扫描电镜（SEM）、能谱仪（EDS）分析手段,研究了不同极化电位对5083铝合金型材应力腐蚀断裂（SCC）行为的影响.结果表明：5083铝合金型材在阴极极化下应力腐蚀指数（Issrt）数值最小,应力腐蚀敏感性最弱,断口为准解理形貌,并伴随有少量韧窝;在阳极极化下Issrt数值最大,应力腐蚀敏感性最强,断口表面分布大量横向裂纹,边缘有明显腐蚀痕迹,微观形貌呈解理状并分布大量穿晶、沿晶裂纹,属于典型脆性断裂特征.5083铝合金型材SCC属于阳极溶解型.     

铝合金应力腐蚀裂纹内的电化学行为

研究了LC4铝合金在3.5%Nacl水溶液中，应力腐蚀裂纹尖端区域与内部其它各样块之间，裂纹尖端区域与外自由表面之间电流随时间的变化，结果表明；活化与纯化是LC4铝合金应力腐蚀裂纹尖端的电化学特征，裂纹尖端反应速度主要取决于裂纹尖端自身微电池的作用。     

Effects of Different Electrolytes on Stress Corrosion Properties of 2A12 Aluminum Alloy

The stress corrosion cracking (SCC) behaviors of 2A12 aluminum alloy after annealing treatment were studied by slow strain rate testing (SSRT),electrochemical polarization measurement,scanning electron microscope (SEM),energy dispersive spectrometer (EDS) and transmission electron microscopy (TEM).Various concentrations of NaCl,H_2SO_(4 ) and HCl aqueous solution were prepared to act as the corrosive solution.The experimental results show that regarding the SCC,2A12 alloy performs best in NaCl solution but worst in HCl solution and intermediately between the above mentioned two cases in H_2SO_4 solution.For the SSRT carried out in room temperature,there is a higher decrease in elongation without large strength loss for the alloy immersed in NaCl solution.With the test conducted in H_2SO_4 solution,there is a higher strength loss and a relatively less loss of elongation compared to the one immersed in NaCl solution.With the test conducted in HCl solution,there is a relativel level loss of strength and elongation compared to either result carried out in NaCl solution or H_2SO_4 solution.     

预腐蚀LY12CZ铝合金疲劳裂纹扩展行为研究

腐蚀疲劳是一种在机械应力和腐蚀介质联合作用下的材料退化行为。这种材料退化对于航空工业是一个严峻的问题。因此利用扫描电镜原位技术对于预腐蚀LY12CZ铝合金进行了实验研究。实验结果表明腐蚀损伤对于铝合金疲劳裂纹扩展行为具有强烈的影响,这种影响可以用腐蚀坑深度来表征。并提出了一种评价铝合金腐蚀疲劳裂纹行为的方法。     

Effect of Stress and Galvanic Factors on the Corrosion Behave of Aluminum Alloy

The interaction between stress and galvanic during the corrosion process of 5050 aluminum alloys was studied and the evolution of mechanics properties was indicated. Electrochemical impedance technique and scanning electron microscopy were used to analyze the surface electrochemical states and the corrosion morphology. At the same time, corrosion kinetics and thermodynamic theory were used to analyze the influencing mechanism of the stress factor and the galvanic factor. The results show that both of galvanic factor and tensile stress factor can increase the corrosion potential of aluminum alloys and result in the corrosion resistance decrease. With decreasing corrosion resistance, the mechanical properties of aluminum alloys decrease. These phenomena are attributed to two reasons: One is that aluminum alloys may under the condition of anodic polarization after coupled with 40 Cr Ni Mo A steel, so the corrosion can be promoted; The other is that with increasing stress, the electrochemical potential of 5050 aluminum alloys decreases and the potential difference between two materials increases, so the corrosion becomes serious. Compared to the stress factor, the galvanic factor is significant.     

5083铝合金在3．5％NaCl溶液中的应力腐蚀行为

通过慢应变速率拉伸(SSRT)测试、扫描电镜分析等研究了5083铝合金在空气和质量分数为3.5%的NaCl溶液中的应力腐蚀开裂(SCC)行为.研究了预变形量、应变速率对5083铝合金SCC行为的影响.结果表明:5083铝合金具有SCC敏感性,在质量分数为3.5%的NaCl溶液中发生SCC,而在空气中不发生SCC;在应变速率为1.0×10-6s-1时,其SCC敏感性比应变速率为0.33×10-5s-1时的敏感性大;同一应变速率下,预变形15%的5083铝合金在质量分数为3.5%的NaCl溶液中的SCC敏感性比预变形10%时的大.     

7475铝合金与TC18钛合金接触腐蚀研究

为了研究7475铝合金接触腐蚀性能,测定了7475铝合金和TC18钛合金组成的电偶对的电偶电流,利用扫描电镜和光学显微镜对腐蚀表面形貌和深度进行分析,研究了7475铝合金和TC18钛合金在使用中接触时产生电偶腐蚀的敏感性.结果表明:7475铝合金不同表面处理状态与TC18接触时,7475铝合金与TC18接触腐蚀严重,电偶腐蚀的敏感性为C级.7475阳极化与TC18阳极化处理后接触腐蚀敏感性降低,电偶腐蚀的敏感性为A级,对7475阳极化后进行涂漆可进一步降低电偶腐蚀电流.