Reduction of emissions with propane addition to a diesel engine

Recent studies on dual-fuel combustion in compression-ignition (CI) engines, also known as diesel engines, fall into two categories. In the first category are studies focused on the addition of small amounts of gaseous fuel to CI engines. In these studies, gaseous fuel is regarded as a secondary fuel and diesel fuel is regarded as the main fuel for combustion. The objectives of these studies typically involve reducing particulate matter (PM) emissions by using gaseous fuel as a partial substitution for diesel fuel. However, the addition of gaseous fuel raises the combustion temperature, which increases emissions of nitrogen oxides (NO_x). In the second category are studies focused on reactivity-controlled compression-ignition (RCCI) combustion. RCCI combustion can be implemented by early diesel injection with a large amount of low-reactivity fuel such as gasoline or gaseous fuel. Although RCCI combustion promises lower NO_x and PM emissions and higher thermal efficiency than conventional diesel combustion, it requires a higher intake pressure (usually more than 1.7 bars) to maintain a lean fuel mixture. Therefore, in this study, practical applications of dual-fuel combustion with a low air-fuel ratio (AFR), which implies a low intake pressure, were systemically evaluated using propane in a diesel engine. The characteristics of dualfuel combustion for high and low AFRs were first evaluated. The proportion of propane used for four different operating conditions was then increased to decrease emissions and to identify the optimal condition for dual-fuel combustion. Although the four operating conditions differ, the AFR was maintained at 20 (? approximately equal to 0.72) and the 50% mass fraction burned (MFB 50) was also fixed. The results show that dual-fuel combustion can reduce NO_x and PM emissions in comparison to conventional diesel combustion.     

Operating strategy for gasoline/diesel dual-fuel premixed compression ignition in a light-duty diesel engine

Environmental problems have become a major issue for diesel engine development. Although emission aftertreatment systems such as DPFs (diesel particulate filters), LNTs (lean NOx traps) and SCR (selective catalytic reduction) have been used in diesel vehicles, the manufacturing cost increase caused by this equipment can be hard to be control. Thus, it is better for engine emissions to be reduced by improving the combustion system. A dual-fuel combustion concept is a recommended method to improve a combustion system and effectively reduce emissions. Low reactivity fuel including gasoline and natural gas, which was supplied to the intake port by the FPI (port fuel injector), improved the premixed air-fuel mixture conditions before ignition. Additionally, a small amount of high reactivity fuel, in this case diesel, was injected into the cylinder directly as an ignition source. This dual-fuel combustion promises lower levels of NOx (nitrogen oxide) and PM (particulate matter) emissions due to the elimination of local rich regions in the cylinder. However, it is challenging to control the dual-fuel combustion because the combustion stability and efficiency deteriorate due to the lack of ignition source and reactivity. Thus, it is important to establish an appropriate dual-fuel operating strategy to achieve stable, high efficiency and low emission operation. As a result of this research, a detailed operating method of dual-fuel PCI (premixed compression ignition) was introduced in detail at a low speed and low load condition by using a single cylinder diesel engine. Engine operating parameters including the gasoline ratio, a diesel injection strategy consisting of multiple injectors and timing, the EGR (exhaust gas recirculation) rate and the intake pressure were controlled to satisfy the low ISNOx (indicated specific NOx) and PM emissions levels (0.21 g/kWh and 0.1 FSN, 0.040 g/kWh, respectively) as per the EURO-6 regulation without any after-treatment systems. The results emphasized that a well-constructed dual-fuel PCI operating strategy showed low NOx and PM emissions and high GIE (gross indicated fuel conversion efficiency) with excellent combustion stability.     

Study of the effects on exhaust emissions in direct injection diesel engines: Effects of fuel injection system,distillation properties and cetane number

The effect of injection nozzle, diesel fuel density (volatility) and cetane number on diesel exhaust emissions were investigated. Decreasing injection nozzle hole diameter decreases PM emission. However, a small nozzle hole increases NO_x emission and decreases the effect of fuel on PM emission. Decreasing fuel density is effective for reduction of NO_x emission. But the effect is smaller than that of nozzle hole diameter and injection pressure. Furthermore injection timing retardation decreases the effect of fuel density on NO_x emission.     

Effect of direct in-cylinder CO2 injection on HCCI combustion and emission characteristics

Fuel injection during negative valve overlap period was used to realize diesel homogeneous charge compression ignition (HCCI) combustion. In order to control the combustion, CO₂ in-cylinder injection was used to simulate external EGR. Effects of CO₂ injection parameters (injection timing, quantity, pressure) on HCCI combustion and emission characteristics were investigated. Experimental results revealed that CO₂ in-cylinder injection can control the start of combustion and effectively reduce NO_x emission. Either advancing CO₂ injection timing or increasing CO₂ injection quantity can reduce peak cylinder pressure and mean gas temperature, delay the starts of low temperature reaction (LTR) and high temperature reaction (HTR), and lower pressure rise rate; NO_x emission was reduced, while smoke, HC, and CO emissions increased. Since the combustion phase was improved, the indicated thermal efficiency was also improved. Injection pressure determines the amount of disturbance introduced into the cylinder. Generally, with the same injection quantity, higher injection pressure results in higher momentum flux and total momentum. Larger momentum flux and momentum has a stronger disturbance to air-fuel mixture, resulting in a more homogeneous mixture; therefore, larger injection pressure leads to lower NO_x and smoke emissions.     

掺烧比对P50/甲醇双燃料发动机燃烧与排放的影响

燃料富氧重整和双燃料燃烧模式是改善燃烧过程和降低颗粒物排放的重要方法.在一台四缸增压中冷的高压共轨柴油机上,采用进气道喷射甲醇、缸内喷射P50(50％体积比例柴油与50％体积比例PODE)的双燃料模式,研究掺混比对P50/甲醇双燃料发动机燃烧与排放特性的影响.研究结果表明:相比于纯柴油模式,P50及P50/甲醇双燃料燃...     

Cooling effect of methanol on an n-heptane HCCI engine using a dual fuel system

Homogeneous charge compression ignition (HCCI) engines have the potential to raise the efficiency of reciprocating engines during partial load operation. However, the performance of the HCCI engine at high loads is restricted by severe knocking, which can be observed by the excessive pressure rise rate. This is due to the rapid combustion process occurring inside the cylinder, which does not follow the flame propagation that is seen in conventional engines. In this study, a low compression ratio of 9.5:1 for a gasoline engine was converted to operate in HCCI mode with the goal being to expand the stable operating region at high loads. Initially, pure n-heptane was used as the fuel at equivalence ratios of 0.30 to 0.58 with elevated intake charge temperatures of 180 and 90 °C, respectively. The n-heptane HCCI engine could reach a maximum performance at an indicated mean effective pressure (IMEP) of 0.38 MPa, which was larger than the performance found in the literature. To reach an even higher performance, a dual-fuel system was exploited. Methanol, as an anti-detonant additive, was introduced into the intake stream with various amounts of n-heptane at fixed equivalence ratios in the range of 0.42 to 0.52. It was found that the methanol addition cooled the mixture down prior to combustion and resulted in an increased coefficient of variation (COV). In order to maintain stable combustion and keep the pressure rise rate below the limit, the intake charge temperature should be increased. Introduction of 90% and 95% (vol/vol) hydrous methanol showed a similar trend but a lower thermal conversion efficiency and IMEP value. Therefore, a dual fuel HCCI engine could maintain a high thermal conversion efficiency across a wide load and enhance a 5% larger load compared to a pure n-heptane-fuelled HCCI engine. The hydrocarbon (HC) and carbon monoxide (CO) emissions were lower than 800 ppm and 0.10%, respectively. They were less at higher loads. The nitrogen oxides (NO _x ) emissions were below 12 ppm and were found to increase sharply at higher loads to a maximum of 23 ppm.     

Exhaust emissions and its control methods in compression ignition engines: A review

Extensive usage of automobiles has certain disadvantages and one of them is its negative effect on environment. Carbon dioxide (CO₂), carbon monoxide (CO), hydrocarbons (HC), oxides of nitrogen (NO_x), sulphur dioxide (SO₂) and particulate matter (PM) come out as harmful products during incomplete combustion from internal combustion (IC) engines. As these substances affect human health, regulatory bodies impose increasingly stringent restrictions on the level of emissions coming out from IC engines. This trend suggests the urgent need for the investigation of all aspects relevant to emissions. It is required to modify existing engine technologies and to develop a better after-treatment system to achieve the upcoming emission norms. Diesel engines are generally preferred over gasoline engines due to their undisputed benefit of fuel economy and higher torque output. However, diesel engines produce higher emissions, particularly NO_x and PM. Aftertreatment systems are costly and occupy more space, hence, in-cylinder solutions are preferred in reducing emissions. Exhaust gas recirculation (EGR) technology has been utilized previously to reduce NO_x. Though it is quite successful for small engines, problem persists with large bore engines and with high rate of EGR. EGR helps in reducing NO_x, but increases particulate emissions and fuel consumption. Many in-cylinder solutions such as lower compression ratios, modified injection characteristics, improved air intake system etc. are required along with EGR to accomplish the future emission norms. Modern combustion techniques such as low temperature combustion (LTC), homogeneous charge compression ignition (HCCI), premixed charge compression ignition (PCCI) etc. would be helpful for reducing the exhaust emissions and improving the engine performance. However, controlling of autoignition timing and achieving wider operating range are the major challenges with these techniques. A comprehensive review of diesel engine performance and emission characteristics is given in this paper.     

Numerical analysis of the effect of inhomogeneous pre-mixture on the pressure rise rate in an HCCI engine using multi-zone chemical kinetics

The HCCI (Homogeneous Charge Compression Ignition) engine is an internal combustion engine under development, which is capable of providing both high diesel-like efficiency and very low NO_x and particulate emissions. However, several technical issues must be resolved before the HCCI engine is ready for widespread application. One issue is that its operating range is limited by an excessive pressure rise rate which is caused by the excessive heat release from its selfaccelerated combustion reaction and the resulting engine knock in high-load conditions. The purpose of this study was to evaluate the potential of thermal and fuel stratification for reducing the pressure rise rate in HCCI engines. The NO_x and CO concentrations in the exhaust gas were also evaluated to confirm combustion completeness and NO_x emissions. The computational work was conducted using a multi-zone code with detailed chemical kinetics, including the effects of thermal and fuel stratification on the onset of ignition and the rate of combustion. The engine was fueled with dimethyl ether (DME) which has a unique two-stage heat release, and methane which has a one-stage heat release.     

Computational study on the effects of volume ratio of DOC/DPF and catalyst loading on the PM and NOx emission control for heavy-duty diesel engines

The use of a diesel particulate filter (DPF) in a diesel aftertreatment system has proven to be an effective and efficient method for removing particulate matter (PM) in order to meet more stringent emission regulations without hurting engine performance. One of the favorable PM regeneration technologies is the NO₂-assisted regeneration method due to the capability of continuous regeneration of PM under a much lower temperature than that of thermal regeneration. In the present study, the thermal behavior of the monolith during regeneration and the conversion efficiency of NO₂ from NO with an integrated exhaust system of a diesel oxidation catalyst (DOC) and DPF have been predicted by one-channel numerical simulation. The simulation results of the DOC, DPF, and integrated DOC-DPF models are compared with experimental data to verify the accuracy of the present model for the integrated DOC and DPF modeling. The effects of catalyst loading inside the DOC and the volume ratio between the DOC and DPF on the pressure drop, the conversion efficiency, and the oxidation rate of PM, have been numerically investigated. The results indicate that the case of the volume ratio of ‘DOC/DPF=1.5’ within the same diameter of both monoliths produced close to the maximum conversion efficiency and oxidation rate of PM. Under the engine operating condition of 175 kW at 2200 rpm, 100% load with a displacement of 8.1, approximately 55 g/ft³ of catalyst (Pt) loading inside the DOC with the active Pt surface of 5.3 m²/g_pt was enough to maximize the conversion efficiency and oxidation rate of PM.     

Knock in dual-fuel diesel combustion with an E85 ethanol/gasoline blend by multi-dimensional simulation

In this paper, knocking combustion in dual-fuel diesel engine is modeled and investigated using the CFD code coupled with detailed chemical kinetics. The ethanol/gasoline blend E85 is used as the primary fuel in a dual-fuel combustion concept based on a light-duty diesel engine equipped with a common-rail injection system. The E85 blend is injected and well mixed with intake air in the intake manifold and is ignited by the direct injection diesel fuel. A 46-species, 187-reaction Multicomponent mechanism is adopted to model the auto-ignition process of the E85/air/diesel mixture ahead of the flame front. Based on the model validation, knocking combustion under boost and full load operating condition for 0 %, 20 %, 50 %, as well as 70 % E85 substitute energy is simulated. The effects of E85 substitute rate and two stage injection strategies on knock intensity, power output, as well as location of the auto-ignition initiation is clearly reproduced by the model. The calculation result shows that, for a high E85 rate of 50 % and 70 % with single injection strategies, the most serious knock and the origin of auto-ignition always occurs far away from where the flame of diesel spray is first generated, at the center of combustion chamber, due to higher pressure wave, relatively richer E85 mixture and longer distances of flame propagation. The two stage injection strategies with a small amount of diesel pilot injection ahead of the main injection primarily influence the ignition behavior of the directly injected fuel, leads to a lower pressure rise rate and a reduced propagation distance, both of which contribute to the attenuation of knock intensity for a higher E85 rate.     

Experimental study on the characteristics of nano-particle emissions from a heavy-duty diesel engine using a urea-SCR system

Particulate matter in diesel engine exhaust, particularly nano-particles, can cause serious human health problems including diseases such as lung cancer. Because diesel nano-particle issues are of global concern, regulations on particulate matter emissions specify that not only the weight of particulate matter emitted but also the concentration of nanoparticles must be controlled. This study aimed to determine the effects on nano-particle and PM emissions from a diesel engine when applying a urea-SCR system for NO_x reduction. We found that PM weight increases by approximately 90% when urea is injected in ND-13 mode over the emission without urea injection. Additionally, PM weight increases as the NH₃/NO_x mole ratio is increased at 250 °C. In SEM scans of the collected PM, spherical particles were observed during urea injection, with sizes of approximately 200 nm to 1 μm. This study was designed to determine the conditions under which nano-particles and PM are formed in a urea-SCR system and to relate these conditions to particle size and shape via a quantitative analysis in ND-13 mode.     

基于喷射正时的柴油机燃烧和排放研究

基于集成电控单体泵柴油机,讨论了喷射正时对柴油机燃烧及排放特性的影响规律。喷射正时对滞燃期和速燃期有显著的影响,从而影响放热规律、缸内压力和燃烧温度,进而对NOx和PM排放特性有显著的影响。在中大负荷下,随着喷射正时的滞后,放热率曲线相对于上止点的相位滞后,缸内最高燃烧温度下降,NOx排放下降,PM排放升高。在中小负荷下,随着喷射正时的进一步滞后,NOx和PM的排放同时下降。     

Real-time empirical NO<Subscript>x</Subscript> model based on In-cylinder pressure measurements for light-duty diesel engines

This paper proposes a real-time empirical model of NO_x emissions for diesel engines. The proposed model predicts the level of NO_x emissions using an empirical model developed based on the thermal NO formation mechanism, the extended Zeldovich mechanism. Since it is difficult to consider the exact physical NO formation phenomena in real-time applications, the proposed algorithm adapts the key factors of the NO formation mechanism from the extended Zeldovich mechanism: temperature of the burned gas, concentration of the gas species, and combustion duration where NO is generated. These factors are considered in a prediction model as four parameters: exhaust gas recirculation rate (EGR rate), crank angle location of 50 % of mass fraction burned (MFB50), exhaust lambda value, and combustion acceleration. The proposed prediction model is validated with various steady engine experiments that showed a high linear correlation with the NO_x emission measured by a NO_x sensor. Furthermore, it is also validated for transient experiments.     

Evaluation and visualization of stratified ultra-lean combustion characteristics in a spray-guided type gasoline direct-injection engine

To comply with reinforced emission regulations for harmful exhaust gases, including carbon dioxide (CO₂) emitted as a greenhouse gas, improved technologies for reducing CO₂ and fuel consumption are being developed. Stable lean combustion, which has the advantage of improved fuel economy and reduced emission levels, can be achieved using a sprayguided-type direct-injection (DI) combustion system. The system comprises a centrally mounted injector and closely positioned spark plugs, which ensure the combustion reliability of a stratified mixture under ultra-lean conditions. The aim of this study is to investigate the combustion and emission characteristics of a lean-burn gasoline DI engine. At an excess air ratio of 4.0, approximately 23% improvement in fuel economy was achieved through optimal event timing, which was delayed for injection and advanced for ignition, compared to that under stoichiometric conditions, while NO_x and HC emissions increased. The combustion characteristics of a stratified mixture in a spray-guided-type DI system were similar to those in DI diesel engines, resulting in smoke generation and difficulty in three-way catalystutilization. Although a different operating strategy might decrease fuel consumption, it will not be helpful in reducing NO_x and smoke emissions; therefore, alternatives should be pursued to achieve compliance with emission regulations.     

多次喷射对柴油机燃烧与排放影响的试验研究

基于1台高压共轨涡轮增压柴油机,采用不同的预喷正时、预喷油量与后喷正时等,研究了多次喷射对燃烧放热、排放生成与燃油经济性的影响,以实现均质压燃和低温燃烧过程。研究结果表明:随预喷正时提前,缸内峰值压力降低,主燃阶段的滞燃期缩短,NOx和炭烟排放均降低;随预喷油量增加,预喷阶段燃烧的放热率和最大压力升高率增大,NOx和HC排放增大,而PM和CO排放降低;随后喷始点推迟,缸内压力与主放热率峰值差异变小,NOx排放降低,但炭烟排放先增大后逐渐降低。     

NOx emission characteristics in rich–lean combustion of hydrogen

Characteristics of NO_x formation in a gas turbine fuelled with hydrogen were analyzed with both an experimental and a numerical approach. This research experimentally investigated NO_x reduction effect of rich–lean combustion in a coaxial burner. Hydrogen emits no Prompt NO even in rich mixture conditions, and can be more effective to reduce NO_x in the rich–lean combustion system than hydrocarbons. The results show that the rich–lean combustion of hydrogen successfully reduces NO_x emission compared with diffusive combustion. In the rich–lean combustion, hydrogen combustion has lower NO_x emission compared to methane combustion, especially with larger equivalence ratio of richer side mixture. Calculations of NO_x formation in the rich–lean combustion were also done employing the extended Zel’dovich NO formation mechanism.     

Study of diesel spray combustion and ignition using high-pressure fuel injection and a micro-hole nozzle with a rapid compression machine: improvement of combustion using low cetane number fuel

This study aimed to reduce NO_x and soot by creating a more homogeneous lean fuel distribution in a diesel spray using high-pressure fuel injection and a micro-hole nozzle. This injection system shortened the ignition delay, but a homogeneous lean fuel distribution in the diesel spray was not achieved. Using a lower cetane number fuel, the resulting longer ignition delay made a uniform, lean fuel distribution in the diesel spray possible with this injection system. Ignition and combustion were analyzed by the combustion chamber pressure history, and flame temperatures and KL values were analyzed by the two-color method.     

Comparison of HC species from diesel combustion modes and characterization of a heat-up doc formulation

This study summarizes engine speed and load effects on HC species emissions from premixed charge compression ignition (PCI) and conventional diesel combustion, and it evaluates diesel oxidation catalyst (DOC) formulations on a gas flow reactor for the purpose of diesel particulate filter regeneration or lean NO_x trap desulfation. HC emissions are sampled simultaneously by a Tedlar bag for light HC species and by a Tenax TA™ adsorption trap for semi-volatile HC species, and they are analyzed by gas chromatography with a flame ionization detector. The bulk temperature and residence time during combustion are key parameters that are important for understanding the effects of speed and load on engine-out HC emissions. The degree of post-flame oxidation is higher in PCI than in conventional combustion, and it is increased for PCI with a higher speed and load, as indicated by a lower fuel alkanes/THC ratio, a higher alkenes/fuel alkanes ratio, and a higher methane/THC ratio. Ethene and n-undecane are two representative HC species, and they are used as a surrogate mixture in the gas flow reactor to simulate PCI and conventional combustion with in-cylinder post fuel injection. Among the three DOC formulations tested, the catalyst with constituent precious metals of platinum and palladium (PtPd) showed the best light-off performance, followed by PtPd with an addition of cerium dioxide (PtPd+CeO₂), and platinum (Pt), regardless of exhaust compositions. Conventional combustion exhaust composition shows a lower light-off temperature than that of PCI, regardless of catalyst formulation.     

Heat exchanger/catalytic system for reducing the exhaust emissions from diesel engines

A system has been researched over the past 3 years for reducing the exhaust pollutants from diesel engines for light commercial vehicles. The system researched achieves Euro 6 standards for reduction of polluting gases (CO, HC, PM, NO). It consists of 4 main sections: 1. A heater and heat exchanger (HE); 2. A CO/HC oxidising catalyst (D°C); 3. Pt catalyst on a diesel particulate filter (DPF); 4. A NO reducing reaction (SCR) within the DPF. The system operates as follows. The exhaust gas contains oxidising gases, namely both O₂ and NO₂. The levels of CO and HC are oxidised by O₂ to CO₂ for temperatures above 200°C. Carbon (PM) is oxidised to CO₂ by NO₂ but requires a temperature above 250°C. The operating exhaust temperature of 300°C is ideal for the removal of NO by using the Pt catalyst and the CO generated within the DPF. The heater is required to be able to raise the exhaust temperature at any time to 300°C in order to optimise the performance of the system, since diesel engine exhaust temperatures vary between 160°C (slow speeds) to 350°C (high speeds). Considerable heat is required (??3 kW) to maintain the exhaust gas for a 2l engine at 300°C for engine idle conditions. Therefore a heat exchanger is required to re-circulate the input heat and thereby reduce the maximum power consumption to a maximum of 500W over the engine full operating test cycle. This energy is supplied by the engine battery and alternator. Experimental results have been obtained for the exhaust from a Kubota diesel engine and the reductions in exhaust emissions of 83% (CO/ HC), 58% (NOx) and 99% (PM) were obtained. The PM was continuously cleaned so that there was no build up of back pressure.     

小缸径增压中冷柴油机燃烧特性及放热规律分析

通过实测小缸径增压中冷柴油机气缸压力,分析其燃烧过程及放热规律。结果表明,负荷增加,放热率增大,燃烧始点提前;采用较小的供油提前角,可降低最大压力升高率和最大燃烧压力;采用增压中冷技术,可降低峰值温度,因而对降低NOx 有利。