非制冷红外探测器用高TCR氧化钒薄膜制备研究

主要介绍了红外探测器的分类、发展,及基于氧化钒薄膜的热探测器的优势;采用直流对靶磁控溅射法制备氧化钒薄膜,通过设计正交实验,获得了氧化钒薄膜的最佳制备参数,分析了各个制备参数对氧化钒薄膜成分以及TCR的影响,研究了硅衬底上氧化钒薄膜电阻温度系数与电阻之间的关系.     

非致冷红外探测器用氧化钒多晶薄膜的制备

采用离子束溅射镀膜和氧化工艺在Si(110)和石英衬底上制备了用于非致冷红外探测器阵列热敏材料的混合相氧化钒多晶薄膜．扫描电子显微镜(SEM)照片显示：薄膜表面呈针状晶粒状,而且薄膜表面光滑、致密,均匀性好．测试结果表明：氧化钒薄膜的方块电阻和电阻温度系数(TCR)在20℃分别为50KΩ和-0.021K^-1。     

微测辐射热计用氧化钒薄膜制备及特性

热敏薄膜电阻制备是非致冷微测辐射热计红外焦平面的一项关键技术。对目前在非致冷微测辐射热计研制中得到成功应用的氧化钒薄膜的特性、制备及表征技术进行综述。氧化钒存在多种物相和结构 (VOx:0 相似文献   

氧化钒热敏薄膜的制备及其性质的研究

报道一种制备氧化钒热敏薄膜的新方法。采用离子束溅射V2O5粉末靶淀积和氮氢混合气体热处理相结合的薄膜技术,可制备热敏性能较好的低价氧化钒薄膜VOx(x＜2.5)。对不同温度退火后氧化钒薄膜在10－100℃范围内测定了薄层电阻随温度的变化,得到的电阻温度系数（TCR）值为（－1～－4）％K^-1。研究结果表明通过这种方法可在较低温度下制备氧化钒薄膜,这种薄膜具有较低的电阻率和较高的TCR值,可作为非致冷红外微测辐射热计的热敏材料。     

氧化钒热敏薄膜的制备及其性质的研究

报道一种制备氧化钒热敏薄膜的新方法.采用离子束溅射V2O5粉末靶淀积和氮氢混合气体热处理相结合的薄膜技术,可制备热敏性能较好的低价氧化钒薄膜VOx(x＜2.5).对不同温度退火后氧化钒薄膜在10～100℃范围内测定了薄层电阻随温度的变化,得到的电阻温度系数(TCR)值为(-1～-4)%K-1.研究结果表明通过这种方法可在较低温度下制备氧化钒薄膜,这种薄膜具有较低的电阻率和较高的TCR值,可作为非致冷红外微测辐射热计的热敏材料.     

测辐射热计用氧化薄膜与采用氧化薄膜的红外探测器 美国专利US7250604（2007年7月31日授权）

本发明提供一种供高灵敏度测辐射热计型非致冷红外探测器用的氧化薄膜。该氧化薄膜是一种非晶氧化钒钨（v-w-Ox）,即一种掺钨的氧化钒,其电阻较低,为5kΩ至200kΩ,可变电阻温度系数（TCR）在-1．5％／℃与-4．1％／℃之间。它是在300℃左右的温度下通过改变钨的含量和氧化时间使钒-钨金属膜氧化的方法获得的。     

微测热辐射计氧化钒薄膜工艺研究

用射频磁控反应溅射在石英玻璃和硅片上沉积氧化钒薄膜 .利用X射线衍射 ,X射线光电子谱 ,原子力显微镜 ,分光光度计和电阻测量手段对沉积薄膜结构、形貌和性能进行了测试 .结果表明 ,沉积薄膜的电阻温度系数大于 1.8% /℃ ,方块电阻为 2 2± 5kΩ/□ .     

磁控溅射法制备氧化钒薄膜的研究

主要介绍了红外探测器的分类、发展,及基于氧化钒薄膜的热探测器的优势;采用直流磁控溅射法在相对较低温度220℃下制备出电阻温度系数(TCR)为-1.9%/℃的VOx薄膜.通过XRD、AFM、红外透过测试方法对薄膜的形貌、组分及其红外吸收性能进行分析,结果表明该VOx薄膜非常适合用作非制冷红外探测器热敏材料.与传统的工艺相比,由于该薄膜淀积过程无需高温退火,在后期的红外焦平面制作过程中,可以较好地保护红外焦平面阵列的CMOS电路.     

氧化钒热致变色薄膜的研究进展

介绍了氧化钒热致变色薄膜的研究进展，对其制备、特性、理论研究和应用技术作了简要的介绍和分析。     

氧化钒薄膜电阻PSPICE模型及特性分析

在分析了热敏电阻红外探测器工作原理的基础上,利用PSPICE的多项式受控源和现有器件,建立了氧化钒热敏电阻的等效子电路模型,进而推导出氧化钒热敏薄膜红外探测器的PSPICE等效模型.对子电路等效模型进行了PSPICE模拟,模拟结果与理论推导公式相一致.并利用模拟结果分析了薄膜电阻率与温度系数之间的关系.该模型也可用于其他类型的热敏薄膜探测器,具有一定的通用性.     

Properties of pulsed laser deposited vanadium oxide thin film thermistor

Vanadium oxide thin film has been deposited on glass substrate at room temperature using pulsed laser deposition with the laser fluence of 1.4 J/cm² under high vacuum. X-ray photoelectron spectroscopy analysis shows that the film is oxygen deficient compared to the stoichiometric V₂O₅. X-ray diffraction study reveals the amorphous nature of the film. Atomic force microscopy ensures the particulate free film with smooth surface topography. From the temperature-dependent resistance measurements, thermistor parameters such as temperature coefficient of resistance (α) and thermistor constant (B) were determined as 28000 ppm K⁻¹ and 2623 K, respectively.     

基于二氧化钒薄膜的太赫兹开关器件

二氧化钒(VO2)作为一种优质的光电功能材料一直备受人们的关注,在信息存储、光调制器、太阳能电池、光电探测器等方面有着重要应用。采用磁控溅射及原位退火氧化的"两步法"制备了VO2薄膜,并对其进行晶态、形貌表征。设计并搭建VO2薄膜热致相变实验系统,研究了VO2薄膜在变温条件下对2.52 THz辐射的开关特性。结果表明,VO2薄膜样品为多晶态,具有明显的太赫兹调制效果,可以实现对2.52 THz波的调制,并可作为太赫兹开关/调制器件的功能材料。     

Solution-processed vanadium oxide thin film as the hole extraction layer for efficient hysteresis-free perovskite hybrid solar cells

In this study, we report a simple way to fabricate VO_x thin film from pure-water solution, as the hole extraction layer (HEL) for perovskite hybrid solar cells (pero-HSCs). Furthermore, an aminopropanoic acid (APPA) interfacial layer is used to modify VO_x thin film for reducing the charge carrier recombination rate. As a result, the pero-HSCs with the VO_x/APPA HEL exhibits better device performance than that of the pero-HSCs with the VO_x HEL and the pero-HSCs with poly(3,4-ethylenedioxythiophene):poly-(styrenesulfonate) HEL. Moreover, the pero-HSCs with the VO_x/APPA HEL exhibits hysteresis-free characteristics. All these results indicate that we report a simple approach to realize high performance of perovskite hybrid solar cells.     

一种高性能氧化钒热敏薄膜的制备和应用

报道一种制备高性能氧化钒热敏薄膜的方法和其应用。采用反应磁控溅射薄膜沉积技术，通过改变氧化钒热敏薄膜沉积时溅射功率，从而调整钒原子在溅射出来之后接触到基片表面时的沉积速率，同时通过对设备进行改造升级，即在钒溅射腔腔外增加一个控制电源来精确控制溅射电压及氧气分压等参数来精确控制反应过程中电流密度，优化了氧化钒薄膜的制备工艺，制备出方块电阻为500 kΩ/□，电阻温度系数（TCR）为?2.7% K?1的氧化钒薄膜。实验测试结果表明，利用高性能氧化钒热敏薄膜制作的非制冷红外焦平面探测器，其噪声等效温差（NETD）降低30%，噪声降低28%，显著提升了非制冷焦平面探测器的综合性能。     

Compound barriers in thin oxide film diodes

High-frequency reverse bias measurements are made on sandwiched evaporated oxide films of tungsten and molybdenum. The linearity of the capacitance-voltage pilot gives an indication of Schottky-type barrier. The intercept and the n values obtained from the plot are used to calculate the thickness of the space charge region. It is concluded that a compound barrier exists at the interface.     

Development of highly conducting n-type micro-crystalline silicon oxide thin film and its application in high efficiency amorphous silicon solar cell

Wide band gap and highly conducting n-type nano-crystalline silicon film can have multiple roles in thin film solar cell. We prepared phosphorus doped micro-crystalline silicon oxide films (n-μc-SiO:H) of varying crystalline volume fraction (X_c) and applied some of the selected films in device fabrication, so that it plays the roles of n-layer and back reflector in p-i-n type solar cells. It is generally understood that a higher hydrogen dilution is needed to prepare micro-crystalline silicon, but in case of the n-μc-SiO:H an optimized hydrogen dilution was found suitable for higher X_c. Observed X_c of these films mostly decreased with increased plasma power (for pressure<2.0 Torr), increased gas pressure, flow rate of oxygen source gas and flow rates of PH₃>0.08 sccm. In order to determine deposition conditions for optimized opto-electronic and structural characteristics of the n-μc-SiO:H film, the gas flow rates, plasma power, deposition pressure and substrate temperature were varied. In these films, the X_c, dark conductivity (σ_d) and activation energy (E_a) remained within the range of 0–50%, 3.5×10⁻¹⁰ S/cm to 9.1 S/cm and 0.71 eV to 0.02 eV, respectively. Low power (30 W) and optimized flow rates of H₂ (500 sccm), CO₂ (5 sccm), PH₃ (0.08 sccm) showed the best properties of the n-μc-SiO:H layers and an improved performance of a solar cell. The photovoltaic parameters of one of the cells were as follows, open circuit voltage (V_oc), short circuit current density (J_sc), fill-factor (FF), and photovoltaic conversion efficiency (η) were 950 mV, 15 mA/cm², 64.5% and 9.2% respectively.     

Some studies of mixed oxide thin film transistors

The behaviour of mixed oxide TFTs, with Pr₆O₁₁ and Yb₂O₃ in the ratio of 1 : 1 by weight, both in dry air and in the ambient atmosphere is reported. CdS-(Pr₆O₃+Yb₂O₃) and CdSe-(Pr₆O₁₁ + Yb₂O₃) were used as the semiconductor-insulator (S-I) combinations with Al electrodes. The tranconductance, output resistance, amplification factor and gain-bandwidth product of the fabricated TFTs were calculated from the various characteristic curves. In addition, the trap density, critical donor density, mobility and crystallite size were also evaluated     

利用同步测量研究二氧化钒薄膜的电学与光学相变特性

利用射频磁控溅射方法在蓝宝石衬底上制备了氧化钒薄膜,X射线衍射的测量结果表明薄膜的主要成分是多晶二氧化钒.实现了二氧化钒薄膜半导体-金属相变过程的电阻和五个不同波长下薄膜反射率的同步测量.实验结果表明,电学和光学测量都在相变过程中出现回滞曲线,但是二者的表现形式有明显差别.当用光学方法探测时,同一次相变过程中不同区域的反射率曲线几乎完全重合,证明了薄膜样品的均匀性.