Influence of class F fly ash on the abrasion–erosion resistance of high-strength concrete

This study investigates the abrasion–erosion resistance of high-strength concrete (HSC) mixtures in which cement was partially replaced by four kinds of replacements (15%, 20%, 25% and 30%) of class F fly ash. The mixtures containing ordinary Portland cement were designed to have 28 days compressive strength of approximately 40–80 MPa. Specimens were subjected to abrasion–erosion testing in accordance with ASTM C1138. Experimental results show that the abrasion–erosion resistances of fly ash concrete mixtures were improved by increasing compressive strength and decreasing the ratio of water-to-cementitious materials. The abrasion–erosion resistance of concrete with cement replacement up to 15% was comparable to that of control concrete without fly ash. Beyond 15% cement replacement, fly ash concrete showed lower resistance to abrasion–erosion compared to non-fly ash concrete. Equations were established based on effective compressive strengths and effective water-to-cementitious materials ratios, which were modified by cement replacement and developed to predict the 28- and 91-day abrasion–erosion resistance of concretes with compressive strengths ranging from approximately 30–100 MPa. The calculation results are compared favorably with the experimental results.     

Influence of fly ash on strength and sorption characteristics of cold-bonded fly ash aggregate concrete

Cold-bonded fly ash aggregate concrete with fly ash as part of binder or fine aggregate facilitates high volume utilization of fly ash in concrete with minimum energy consumption. This paper investigates the influence of fly ash on strength and sorption behaviour of cold-bonded fly ash aggregate concrete due to partial replacement of cement and also as replacement material for sand. While cement replacement must be restricted based on the compressive strength requirement at desired age, replacement of sand with fly ash appears to be advantageous from early days onwards with higher enhancement in strength and higher utilization of fly ash in mixes of lower cement content. Microstructure of concrete was examined under BSEI mode. Replacement of sand with fly ash is effective in reducing water absorption and sorptivity attributable to the densification of both matrix and matrix–aggregate interfacial bond. Cold-bonded fly ash aggregate concrete with a cement content of 250 kg/m³, results in compressive strength of about 45 MPa, with a total inclusion of around 0.6 m³ of fly ash in unit volume of concrete.     

Effect of elevated temperature on physico-mechanical properties of blended cement concrete

Pozzolanas are readily available for use in concrete in the local markets for strength and/or durability enhancement. Although safety and security against disasters are not new, they still presuming a challenge. For instance, the fire resistive properties of concrete are of prime interest.Through this work, the effect of different kinds of pozzolana on the fire resistive properties of concrete was studied. Four types of pozzolana were incorporated into the concrete mixtures, i.e. metakaolin (MK), silica fume (SF), fly ash (FA), and ground granulated blast furnace slag (GGBS). Each of the employed pozzolana was used in two ratios: 10% and 20%, either in the form of cement replacement or as an addition without affecting the cement content. A total of 17 mixes were cast.For all mixtures, compressive strength is evaluated after 28 days of water curing. The mixtures’ compressive strengths were also evaluated after exposure to elevated temperatures: 200 °C, 400 °C, 600 °C, and 800 °C. The residual compressive strengths after heat exposure are evaluated. The formed cementitious phases after incorporation of pozzolana and the heat-induced transformations are investigated via the X-ray diffraction technique (XRD).Test results demonstrate the impact of each type of the employed pozzolana on the heat resistive properties of concrete in addition to their influence on the strength development of the investigated mixes. Therefore, a decision could be made regarding optimizing the benefits specific to each type of pozzolana and their employment method.     

Effect of fly ash addition on the mechanical properties of tile adhesive

Statistical relationship between various strengths of tile adhesives in which cement or sand was partially replaced with fly ash was studied. A low-lime fly ash was used in five different replacement levels from 5% to 30% by weight of either cement or sand. The tensile adhesion, flexural and compressive strengths of adhesives were determined at 2, 7 and 28 days. In small substitution levels, sand replacement increased the tensile adhesion strength. No strong relationship was found between tensile adhesion strength and flexural or compressive strength of the specimens in which the fly ash was used as sand replacement (r < 0.659). Strong relationship was observed between the same properties when fly ash was used as cement replacement (r > 0.896). Flexural and compressive strength values showed quite strong relationship (r > 0.949). This may be due to the fact that both of these strength values were obtained on the same specimens.     

Effect of W/C ratio on covering depth of fly ash concrete in marine environment

This investigation studied the effect of W/C ratio on covering depth required against the corrosion of embedded steel of fly ash concrete in marine environment up to 4-year exposure. Fly ash was used to partially replace Portland cement type I at 0%, 15%, 25%, 35%, and 50% by weight of cementitious material. Water to cementitious material ratios (W/C) of fly ash concretes were varied at 0.45, 0.55, and 0.65. The 200-mm concrete cube specimens were cast and steel bars with 12-mm diameter and 50 mm in length were inserted in the concrete with the covering depth of 10, 20, 50, and 75 mm. The specimens were cured in water for 28 days, and then placed to the tidal zone of marine environment in the Gulf of Thailand. Subsequently, the concrete specimens were tested for the compressive strength, chloride penetration profile and corrosion of embedded steel bar after being exposed to tidal zone for 2, 3, and 4 years. The results showed that the concrete mixed with Portland cement type I exhibited higher rate of the chloride penetration than the fly ash concrete. The chloride penetration of fly ash concrete was comparatively low and decreased with the increasing of fly ash content. The increase of fly ash replacement and the decrease of W/C ratio could reduce the covering depth required for the initial corrosion of the steel bar. Interestingly, fly ash concretes with 35% and 50% cement replacement and having W/C ratio of 0.65 provided better corrosion resistance at 4-year exposure than the control concrete with W/C ratio of 0.45. In addition, the covering depth of concrete with compressive strength of 30 MPa (W/C ratio of 0.65) could be reduced from 50 to 30 mm by the addition of fly ash up to 50%.     

Assessment of the effects of rice husk ash particle size on strength,water permeability and workability of binary blended concrete

This study develops the compressive strength, water permeability and workability of concrete by partial replacement of cement with agro-waste rice husk ash. Two types of rice husk ash with average particle size of 5 micron (ultra fine particles) and 95 micron and with four different contents of 5%, 10%, 15% and 20% by weight were used. Replacement of cement up to maximum of 15% and 20% respectively by 95 and 5 μm rice husk ash, produces concrete with improved strength. However, the ultimate strength of concrete was gained at 10% of cement replacement by ultra fine rice husk ash particles. Also the percentage, velocity and coefficient of water absorption significantly decreased with 10% cement replacement by ultra fine rice husk ash. Moreover, the workability of fresh concrete was remarkably improved by increasing the content of rice husk ash especially in the case of coarser size. It is concluded that partial replacement of cement with rice husk ash improves the compressive strength and workability of concrete and decreases its water permeability. In addition, decreasing rice husk ash average particle size provides a positive effect on the compressive strength and water permeability of hardened concrete but indicates adverse effect on the workability of fresh concrete.     

A study of the workability and compressive strength characteristics of corn cob ash blended cement concrete

The study investigated the workability and compressive strength characteristics of corn cob ash (CCA) blended cement concrete. Nine classes of CCA-blended cements were employed with the CCA content ranging from 0% to 25%. The 0% CCA replacement involved the use of normal ordinary Portland cement and it served as the control. The mix proportions of cement:sand:granite used were 1:1½:3, 1:2:4 and 1:3:6 with 0.5, 0.6 and 0.7 water-to-cement ratios, respectively. The concrete cubes were tested at the curing ages of 3, 7, 28, 60, 120, and 180 days. Slump and compacting factor tests were carried out to check the effect of CCA on the workability of concrete. The results showed that the concrete slump and compacting factor decreased as the CCA content increased indicating that concrete becomes less workable (stiff) as the CCA percentage increases. The compressive strength of CCA-blended cement concrete was lower than the control at early ages, but improves significantly, and outperforms the control at later ages (120 days and above). The optimum compressive strength of 57.10 N/mm², 40.30 N/mm² and 28.07 N/mm² for 1:11/2:3, 1:2:4 and 1:3:6 mix proportions, respectively at 180 days were obtained at 8% CCA replacement level. It was concluded that only up to 8% CCA substitution is adequate where the blended cement is to be used for structural concrete.     

Effects of post-mercury-control fly ash on fresh and hardened concrete properties

Activated carbon injection is the most mature technology for mercury capture from coal burning power plants; however, this technology increases the carbon content and mercury concentration in the fly ash. This, in turn, may reduce the suitability of fly ash for use in concrete and call into question the safety of using fly ash derived from this process. The focus of this paper is to investigate the reuse potential of post-mercury-control fly ash in concrete by examining the influence of three fly ashes derived from the activated carbon injection on the air content, compressive strength, permeability, and resistance to freezing and thawing of concrete mixtures. Laboratory testing confirmed the influence of the carbon on the air content of the concrete. However there was no difficulty in entraining air in activated carbon injection fly ash concretes within the recommended dosage range of the air-entraining admixture. All air-entrained fly ash concretes exhibited excellent characteristics in compressive strength (?32.0 MPa, 4641 psi at 28 days), resistance to chloride-ion penetration (moderate to low at 28 days of age) and freeze–thaw (?90 average durability factor after 300 cycles). The possible leaching of toxic elements including mercury from one fly ash sample used in this study was also evaluated using the US Environmental Protection Agency’s Toxicity Characteristic Leaching Procedure. The test results indicated that the leaching of toxic elements was much lower than the contamination level.     

Influence of soaking and polymerization conditions on the properties of polymer concrete

An experimental investigation was conducted to study the effect of soaking time and polymerization temperature on the mechanical and physical properties of polymer-impregnated concrete. Soaking time was controlled in 4, 8, 12, 16, 20 and 24 h, polymerization temperature was set at 70, 80 and 90 °C for 0.5, 1, 2, 4, 6, 12 and 24 h in impregnation process, respectively. Cylindrical concrete specimens with water/cement ratios of 0.45 and 0.65 were impregnated with methyl methacrylate (MMA) and benzoyl peroxide (BPO) mixtures. The polymer loading increases as immersion time increases until 12 h. Based on compressive strength and surface absorption, optimum polymerization temperature is 70 °C for Mix A (high cement content) and 80 °C for Mix B (low cement content). Polymer impregnation not only increases concrete strength and resistivity but also greatly decreases surface absorption comparing with normal concrete. SEM and MIP observations indicate that the micro-pores and meso-pores of PIC specimens are filled with PMMA and the total pore volume and maximum pore size are reduced significantly.     

Effect of Granulated Blast Furnace Slag and fly ash addition on the strength properties of lightweight mortars containing waste PET aggregates

In this work, the effect of Granulated Blast Furnace Slag (GBFS) and fly ash (FA) addition on the strength properties of lightweight mortars containing waste Poly-ethylene Terephthalate (PET) bottle aggregates was investigated. Investigation was carried out on three groups of mortar specimens. One made with only Normal Portland cement (NPC) as binder, second made with NPC and GBFS together and, third made with NPC and FA together. The industrial wastes mentioned above were used as the replacement of cement on mass basis at the replacement ratio of 50%. The size of shredded PET granules used as aggregate for the preparation of mortar mixtures were between 0 and 4 mm. The waste lightweight PET aggregate (WPLA)–binder ratio (WPLA/b) was 0.60; the water–binder (w/b) ratios were determined as 0.45 and 0.50. The dry unit weight, compressive and flexural–tensile strengths, carbonation depths and drying shrinkage values were measured and presented. The results have shown that modifying GBFS had positive effects on the compressive strength and drying shrinkage values (after 90 days) of the WPLA mortars. However, FA substitution decreased compressive and flexural–tensile strengths and increased carbonation depths. Nevertheless a visible reduction occurred on the drying shrinkage values of FA modifying specimens more than cement specimens and GBFS modified specimens. The test results indicated that, GBFS has a potential of using as the replacement of cement on the WPLA mortars by taking into consideration the characteristics. But using FA as a binder at the replacement ratio of 50% did not improve the overall strength properties. Although it was thought that, using FA as binder at the replacement ratio of 50% for the aim of production WPLA concrete which has a specific strength, would provide advantages of economical and ecological aspects.     

Modeling mechanical performance of lightweight concrete containing silica fume exposed to high temperature using genetic programming

In this study, the mechanical performance of lightweight concrete exposed to high temperature has been modeled using genetic programming. The mixes incorporating 0%, 10%, 20% and 30% silica fumes were prepared. Two different cement contents (400 and 500 kg/m³) were used in this study. After being heated to temperatures of 20 °C, 200 °C, 400 °C and 800 °C, respectively, the compressive and splitting tensile strength of lightweight concrete was tested. Empirical genetic programming based equations for compressive and splitting tensile strength were obtained in terms of temperature (T), cement content (C), silica fume content (SF), pumice aggregate content (A), water/cement ratio (W/C) and super plasticizer content (SP). Proposed genetic programming based equations are observed to be quite accurate as compared to experimental results.     

Durability design and performance of self-consolidating lightweight concrete

In terms of the durability, the reduction in cement paste is crucial to both volume stability and long-term performance of concrete. The objective of this paper is to compare the performance of lightweight concrete under different w/cm ratio and different cement paste content. The slump and slump flow spread of fresh self-consolidating lightweight concrete (SCLWC) are designed to be within 230–270 and 550–650 mm, respectively. The test results indicate that the 91-day compressive strength of SCLWC is up to 56 MPa when cement content is 386 kg/m³ and water content is 150 kg/m³. If enough cement paste is used, then the less the paste amount and the denser the packing of aggregate, the higher the strength efficiency of cement and the electric resistance, and the lower the chloride ion penetrability capacity of SCLWC.     

Mix proportion of high-strength,roller-compacted,latex-modified rapid-set concrete for rapid road repair

In this study, we optimized a blend of high-strength, roller-compacted, latex-modified rapid-set concrete (RCLMC) that can be re-opened to traffic after 4 h. To this end, we tested several variables in laboratory experiments, including hardening acceleration agents, cement type, latex addition, and CSA admixture ratios. The target compressive strength was 21 MPa after 4 h. A mixture of Type III cement to CSA admixture at 235:165 kg/m³ (400 kg/m³ total binder) and 23.5 kg/m³ latex (10% of the cement weight) achieved the target compressive strength and was the most economically efficient.     

Reuse of incineration fly ashes and reaction ashes for manufacturing lightweight aggregate

This paper reports the result of the investigation on manufacturing lightweight aggregate by incorporating municipal solid waste (MSW) incineration fly ashes and reaction ashes with reservoir sediments. The investigation was first performed in a laboratory scale to assess the effects of the composition and the firing conditions on the properties of the resulting aggregate. Afterward, a big amount of aggregates was manufactured in a pilot scale using a commercially available rotary kiln. Physical properties of the synthetic aggregates were subsequently assessed. In addition, compressive strength of the concrete made from the manufactured aggregates was experimentally measured. The investigation shows that the analysis results for the MSW incineration fly ashes and reaction ashes are not in the limits of the expandable region of Riley’s ternary diagram due to the low content of SiO₂. Therefore, they can only be used as additives. The proper content for MSW incineration ashes should not exceed 30%, except compositional adjustment using oxide constituents. The particle density of the manufactured aggregates using a commercially available rotary kiln was 0.99 g/cm³, which is significantly lower than normal density aggregate. Moreover, its dry loose bulk density is 593 kg/m³, which meets the requirements of ASTM C 330 with bulk density less than 880 kg/m³ for coarse aggregate. On the other hand, the results of toxicity test meet the Taiwan Environmental Regulatory requirements, which demonstrate that the aggregate thus fabricated is non-hazardous for construction use.     

Strength and drying shrinkage properties of concrete containing furnace bottom ash as fine aggregate

The strength and drying shrinkage of concretes with the natural sand replaced with furnace bottom ash (FBA) at 0%, 30%, 50%, 70% and 100% by mass, were studied at fixed water–cement ratios (W/C) and fixed slump ranges.The results showed that, at fixed water–cement ratios, the compressive strength and the drying shrinkage decreased with the increase of the FBA sand content. However, at fixed workability, the compressive strength was comparable with that of the control concrete, while the drying shrinkage increased with the increase of the FBA sand content beyond 30% replacement level. Nevertheless, 30% of the natural sand can be beneficially replaced with the FBA sand to produce concrete in the compressive strength range from 40 to 60 N/mm² without detrimentally affecting drying shrinkage properties of the concrete.     

Hybrid effect of carbon nanotube and nano-clay on physico-mechanical properties of cement mortar

In this work, several nanomaterials have been used in cementitious matrices: multi wall carbon nanotubes (MWCNTs) and nano-clays. The physico-mechanical behavior of these nanomaterials and ordinary Portland cement (OPC) was studied. The nano-clay used in this investigation was nano-kaolin. The metakaolin was prepared by thermal activation of nano-kaolin clay at 750 °C for 2 h. The organic ammonium chloride was used to aid in the exfoliation of the clay platelets. The blended cement used in this investigation consists of ordinary Portland cement, carbon nanotubes and exfoliated nano metakaolin. The OPC was substituted by 6 wt.% of cement by nano metakaolin (NMK) and the carbon nanotube was added by ratios of 0.005, 0.02, 0.05 and 0.1 wt.% of cement. The blended cement: sand ratio used in this investigation was 1:2 wt.%. The blended cement mortar was prepared using water/binder ratio of 0.5 wt.% of cement. The fresh mortar pastes were first cured at 100% relative humidity for 24 h and then cured in water for 28 days. Compressive strength, phase composition and microstructure of blended cement were investigated. The results showed that, the replacement of OPC by 6 wt.% NMK increases the compressive strength of blended mortar by 18% compared to control mix and the combination of 6 wt.% NMK and 0.02 wt.% CNTs increased the compressive strength by 29% than control.     

Mechanical and durability properties of concretes containing paper-mill residuals and fly ash

The use of paper-mill residuals in concrete formulations was investigated as an alternative to landfill disposal. The mechanical and durability properties of concrete containing paper-mill residuals collected from a wastewater treatment-plant were evaluated. Class F fly ash was used as a replacement for Portland cement (PC) when incorporated into concrete mixtures containing paper-mill residuals and the resulting products were compared to normal concrete. Compressive, splitting tensile, flexural strength and drying shrinkage tests were carried out to evaluate the mechanical properties for up to 90 days. Rapid chloride-permeability tests and initial surface-absorption tests were carried out at 28 days to determine the durability properties. Concrete containing paper-mill residuals showed improvement in the durability test results when PC was replaced with class F fly ash.     

The effect of activator concentration on the residual strength of alkali-activated fly ash pastes subjected to thermal load

This investigation reports on a comparative study of the residual compressive strength at different temperatures of alkali-activated fly ash (AAFA) pastes chemically activated using sodium silicate with three different concentrations named 20, 30 and 40 (wt.%). The behaviour of different mixtures in conditions of rapid temperature changes was studied. Water quench test was applied to determine thermal shock resistance. The traditional Portland cement pastes were used as a reference. The temperatures ranging from 200 °C to 1000 °C with an increment of 200 °C has been examined. Pore solution pH and compressive strengths before and after exposure to elevated temperatures were determined. The various decomposition phases formed were identified using X-ray diffraction (XRD), thermogravimetric analysis (TGA), differential thermal analysis (DTG) and scanning electron microscopy (SEM). The results indicated that fly ash activated by sodium silicate is more able to resist degradation caused by exposure to elevated temperature than Portland cement system as its relative strengths are superior. In the hardened AAFA pastes, as activator concentration dosage increased as the relative compressive strengths and thermal shock resistance decreased. The AAFA system is able to maintain a sufficient high pH to retain the passive protective layer on the surface of any reinforcing steel present.     

Filler effect and pozzolanic reaction of ground palm oil fuel ash

This research examines the compressive strength of mortar and how the filler effect and pozzolanic reaction of ground palm oil fuel ash (POFA) contribute to this strength. POFA and river sand were ground to three different particle sizes and used to replace Type I Portland cement at 10–40% by weight of binder to cast the mortar. The compressive strengths of ground POFA and ground river sand mortars were determined at various ages between 7 and 90 days. The results showed that the compressive strength of mortar due to the filler effect of ground river sand was nearly constant during the 7–90 day period for a specified replacement rate of cement. However, the compressive strength of mortar due to the filler effect tended to increase slightly with increased cement replacement. The pozzolanic reaction of ground POFA increased with increasing particle fineness of ground POFA, replacement rate of cement, and age of the mortar. The compressive strength contribution from the pozzolanic reaction of ground POFA was much more pronounced than the contribution from the filler effect when the smallest sizes of both materials were considered.     

Effect of rice husk ash on the strength and durability characteristics of concrete

This work investigates the effects of adding residual rice husk ash (RHA) from South Vietnam, generated when burning rice husk pellets in the boiler, to cement. To improve pozzolanic reactivity, RHA was ground for 1 h. The non-ground RHA and ground RHA were used to test strength activity index according to ASTM C311. The properties of the concrete were investigated, including compressive strength, concrete electrical resistivity, and ultrasonic pulse velocity. Results show that the non-ground RHA can be applied as a pozzolanic material. Decreasing the non-ground RHA average particle size provides a positive effect on the compressive strength of mortar. Compressive strength of cylindrical concrete in the 47–66 MPa range was obtained in this study. The results also indicate that up to 20% of ground RHA could be advantageously blended with cement without adversely affecting the strength and durability properties of concrete.