IC6合金真空电弧镀沉积HY3防护涂层研究

采用真空电弧镀沉积技术，使用Ａ１０００专用装置在ＩＣ６合金上制备了ＨＹ３防护涂层，进行了性能试验。结果表明，ＩＣ６合金施加ＨＹ３涂层后，大大提高了合金抗周期氧化和抗燃气热腐蚀能力。涂层厚度３０μｍ，对ＩＣ６合金的高温持久性能没有影响，对叶片实验的热疲劳性能无不良影响。     

钇对硅对Ni3Al基IC6合金组织和性能的影响

利用电子探针研究了不同含量Ｙ和Ｓｉ对定向凝固Ｎｉ３Ａｌ基合金ＩＣ６微观组织的影响,测定了合金的１１００℃抗氧化性能,１１００℃／８０ＭＰａ持久性能,１１００℃热疲劳性能以及各种温度下的瞬时性能。结果表明,加适量Ｙ有利于提高ＩＣ６合金的高温抗氧化性能,持久性能和热疲劳性能,Ｓｉ也有利于提高ＩＣ６合金的高温抗氧化性能。而对持久性能和热疲劳性能不利,Ｙ和Ｓｉ对ＩＣ６合金的瞬时性能均无明显影响。     

渗铝涂层对Ni3Al—Mo基合金高温氧化的防护作用及机理

采用高活度渗铝工艺在ＩＣ－６（Ｎｉ３Ａｌ－Ｍｏ基）合金表面获得内扩散型渗铝涂层，在氩气环境下对渗铝涂层进行扩散处理。利用光学显微镜、ＳＥＭ、ＥＰＭＡ、ＸＲＤ分析研究了涂层的成分及组织结构，测定表明，涂层中的钼以Ｍｏ３Ａｌ沉淀相的形式存在。等温氧化及循环氧化实验表明，渗铝涂层的抗高温氧化性能明显优于ＩＣ－６合金；保护性的Ａｌ２Ｏ３氧化膜阻止了钼的氧化物的形成，避免了ＩＣ－６合金在循环氧化中出现的Ｎｉ     

溅射NiCrAlY涂层对IC6合金性能的影响

研究了溅射Ｎｉ－４０Ｃｒ－１０Ａｌ－０．５Ｙ涂层对Ｎｉ３Ａｌ基金属间化合物ＩＣ６合金性能的影响。结果表明ＮｉＣｒＡｌＹ涂层可以大大提高ＩＣ６合金在１０００－１１００℃下的抗氧化性能和９００℃纯Ｎａ２ＳＯ４中的抗热腐蚀性能，同时涂层还可使合金的力学性能及冷热疲劳性能得到改善。     

渗铝涂层对Ni_3Al－Mo基合金高温氧化的防护作用及机理

采用高活度渗铝工艺在ＩＣ－６（Ｎｉ３Ａｌ－Ｍｏ基）合金表面获得内扩散型渗铝涂层，在氮气环境下对渗铝涂层进行扩散处理．利用光学显微镜、ＳＥＭ、ＥＰＭＡ、ＸＲＤ分析研究了涂层的成分及组织结构，测定表明，涂层中的钼以Ｍｏ３Ａｌ沉淀相的形式存在．等温氧化及循环氧化实验表明，渗铝涂层的抗高温氧化性能明显优于ＩＣ－６合金；保护性的Ａｌ２Ｏ３氧化膜阻止了钼的氧化物的形成，避免了ＩＣ－６合金在循环氧化中出现的ＮｉＭｏＯ４相的多晶型转变，显著改变了合金的抗循环氧化能力；涂层经１０００℃、３００ｈ等温氧化及１０００℃、１００ｈ循环氧化后，未出现β－ＮｉＡｌ相的分解，可认为涂层具有较强的保护作用。     

定向凝固Ni_3Al－Mo基合金高温氧化研究SCIEI

利用热天平连续称重，研究了Ｎｉ３Ａｌ－Ｍｏ基合金（ＩＣ－６）在１２７３，１３７３Ｋ的空气中恒温３００ｈ的氧化行为．用ＥＰＭＡ及ＸＲＤ分析了氧化层的结构和成分，；ＩＣ－６合金的氧化层中包括ＮｉＡｌ２Ｏ４，ＮｉＭｏＯ４，ＭｏＯ２相．氧向内扩散及ＭｏＯ２氧化形成挥发性ＭｏＯ３同时影响着ＩＣ－６合金的氧化进程，氧化反应方程式可表示为：理论方程与实验数据吻合较好．ＭｏＯ３在１２７３、１３７３Ｋ的挥发速率常数分别为３．２７×１０－５和２．５５×１０－４ｍｇ／ｃｍ２·ｓ．     

定向凝固Ni_3Al－Mo基合金高温氧化研究

利用热天平连续称重，研究了Ｎｉ３Ａｌ－Ｍｏ基合金（ＩＣ－６）在１２７３，１３７３Ｋ的空气中恒温３００ｈ的氧化行为．用ＥＰＭＡ及ＸＲＤ分析了氧化层的结构和成分，；ＩＣ－６合金的氧化层中包括ＮｉＡｌ２Ｏ４，ＮｉＭｏＯ４，ＭｏＯ２相．氧向内扩散及ＭｏＯ２氧化形成挥发性ＭｏＯ３同时影响着ＩＣ－６合金的氧化进程，氧化反应方程式可表示为：理论方程与实验数据吻合较好．ＭｏＯ３在１２７３、１３７３Ｋ的挥发速率常数分别为３．２７×１０－５和２．５５×１０－４ｍｇ／ｃｍ２·ｓ．     

黄铜合金轴承瓦的补焊方法

黄铜合金轴承瓦的补焊方法范绍林王子明山西太原十三冶十公司（０３０００８）各种机械设备上的黄铜合金轴承瓦在长期运转中易磨损，用氧乙炔焰补焊，机加工方法进行修复能收到较好的效果，其工艺方法如下。１焊前准备１．１焊接材料选择焊接性及耐磨性良好的丝２２１黄铜...     

定向铸造Ni_3Al基合金IC6的中温蠕变行为

本文测定了ＩＣ６合金在９９３－１０７３Ｋ，７７４一８７４ＭＰａ下的蠕变曲线，利用ＴＥＭ技术观察了蠕变各阶段试样的微观组织，发现不同面上的层错交互作用形成的面角位错控制中温蠕变速率。     

定向铸造Ni3Al基合金的IC6的中温蠕变行为

本文测定了ＩＣ６合金在９９３－１０７３Ｋ，７７４－８７４ＭＰａ下的蠕变曲线，利用ＴＥＭ技术观察了蠕变各阶段试样的微观组织，发现不同面上的层错交互作用形成的面角位错控制中温蠕变速率。     

Repair of NiCrAlYSi overlay coating on Ni3Al base alloy IC6

The effect of repair of NiCrAlYSi coating after long time use on the coherence of coating to substrate and mechanical properties of Ni₃Al base alloy IC6 has been studied. The alloy with NiCrAlYSi coating was stressed under the condition of 900 °C/100 MPa for 200 h to simulate the service condition of IC6 turbine vanes. The results showed that the coherence of base alloy/original coating, original coating/first repair coating, first repair coating/second repair coating or base alloy/second repair coating was firm. The interfaces between them had no cracks and porosity, for either partly or entirely repaired coatings. However, there were more Mo rich particles in the affected zone compared with original coating. Compared with IC6 alloy aged at 900 °C for 200 h, the yield strength at ambient temperature of IC6 alloy with first repair coating was almost equivalent, while the elongation decreased slightly; its stress rupture life under 1100 °C/90 MPa condition was about 100 h. For secondary coating repair, the room temperature tensile properties of base alloy had no obvious change, while stress rupture lives decreased, but still were rather long, compared to the alloy with first repair coating. Therefore, NiCrAlYSi coating repair is feasible to prolong the service lives of IC6 turbine vanes.     

Effect of coating repair on microstructure and mechanical properties of Ni3Al based alloy IC6

1　ＩＮＴＲＯＤＵＣＴＩＯＮＮｉ3ＡｌｂａｓｅｄａｌｌｏｙＩＣ6,ｗｈｉｃｈｉｓａｄｉｒｅｃｔｉｏｎａｌｌｙｓｏｌｉｄｉｆｉｅｄｈｉｇｈｔｅｍｐｅｒａｔｕｒｅｓｔｒｕｃｔｕｒａｌｍａｔｅｒｉａｌ,ｈａｓｂｅｅｎｒｅｃｅｎｔｌｙｄｅｖｅｌｏｐｅｄｂｙＢｅｉｊｉｎ     

Effect of high temperature aging on microstructure and mechanical properties of a directionally solidified Ni3Al base alloy IC6A

1　ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅｄｉｒｅｃｔｉｏｎａｌｌｙｓｏｌｉｄｉｆｉｅｄＮｉ3ＡｌｂａｓｅａｌｌｏｙＩＣ6ＡｗｉｔｈｔｈｅｃｈｅｍｉｃａｌｃｏｍｐｏｓｉｔｉｏｎｏｆＮｉ (7.5～8.5 )Ａｌ (13.0～ 15 .0 )Ｍｏ (0 .0 2～ 0 .1)Ｂ (0 .0 0 5～0 .0 5 )Ｙ (ｍａｓｓｆｒａｃｔｉｏｎ ,% )ｈａｓｂｅｅｎｒｅｃｅｎｔｌｙｄｅｖｅｌ ｏｐｅｄｂａｓｅｄｏｎａｌｌｏｙＩＣ6ａｓａｈｉｇｈ ｔｅｍｐｅｒａｔｕｒｅｓｔｒｕｃ ｔｕｒａｌｍａｔｅｒｉａｌｕｓｅｄｆｏｒａｄｖａｎｃｅｄｊｅｔ ｅｎｇｉｎｅｖａｎｅｓｏｐ ｅｒ…     

DIFFUSION PHENOMENA AND MICROSTRUCTURE STABILITY OF Ni－Cr－Al－Y－Si COATING ON THENi_3Al BASED ALLOY SUBSTRATE

ＤＩＦＦＵＳＩＯＮＰＨＥＮＯＭＥＮＡＡＮＤＭＩＣＲＯＳＴＲＵＣＴＵＲＥＳＴＡＢＩＬＩＴＹＯＦＮｉ－Ｃｒ－Ａｌ－Ｙ－ＳｉＣＯＡＴＩＮＧＯＮＴＨＥＮｉ_３ＡｌＢＡＳＥＤＡＬＬＯＹＳＵＢＳＴＲＡＴＥＺ．Ｐ．Ｘｉｎｇ;Ｙ．Ｆ．Ｈａｎ;Ｙ．Ｌ．ＪｉａｎｄＭ．Ｇ?..     

Effect of yttrium on microstructure and properties of Ni3Al base alloy IC6

The effect of yttrium on the microstructure of alloy IC6 was examined by scanning electron microscopy (SEM), the energy dispersive spectrum (EDS) technique of electron probe micro-analyzer (EPMA) and transmission electron microscopy (TEM). The results show that the microstructure of alloy IC6 with addition of 0.04–0.12 wt% yttrium has no obvious difference compared with that of the alloy without yttrium, and that Ni₃Y and Mo_1.24Ni_0.76 precipitate in the interdendritic area surrounded by large size γ′ phase in the alloy with addition of 0.20–0.30 wt% yttrium. The effect of yttrium on high temperature static and cyclic oxidation resistance, stress rupture properties and thermal fatigue resistance was also investigated in this study.     

Towards Friction Stir Remanufacturing of High-Strength Aluminum Components

Volumetric defects in high-strength aluminum alloy components were repaired via friction stir remanufacturing (FSR). Various consumable pins made of AA7075-T6 were designed. Top diameters of the consumable pins affected material flow, which ensured that the materials at the repairing interface were forged to metallurgical bonding. Conical angles determined load transfer besides material flow, which affected the fracture of the pins before the dwelling stage. Sound repaired components were achieved when the conical angle of the consumable pin was 1° larger than that of the volumetric defect. The ultimate tensile strength and elongation of the repaired components reached 445.9 MPa and 9.6%, respectively. The design criteria of the consumable pin in the FSR was established, which provided valuable references to repair volumetric defects in high-strength aluminum components.     

7N01铝合金脉冲MIG焊与直流CMT焊多次补焊试验

高速列车用7N01铝合金有较大热裂纹倾向,而补焊时该问题更突出.分别采用脉冲MIG焊和低热输入直流CMT焊对4 mm厚7N01铝合金对接接头进行1次、2次、3次补焊,分析了补焊焊接接头的宏观成形、微观组织和硬度.结果表明,脉冲MIG补焊时下塌量和熔宽均大于直流CMT补焊,脉冲MIG补焊焊道与先焊焊缝微观组织界面明显,先焊焊缝晶粒粗大且晶界发生重熔,熔合区变宽,而直流CMT补焊焊道界面不明显,焊缝微观组织晶粒细小,熔合区无明显变化;脉冲MIG焊3次补焊后软化现象较直流CMT补焊严重.采用直流CMT焊进行7N01铝合金补焊,可有效降低热裂纹倾向并缓解接头性能下降.     

EFFECT OF SILICON ON THE MICROSTRUCTURE AND MECHANICAL PROPERTIES OF YTTRIUM MODIFIED Ni_3Al BASE ALLOY IC6

1.IntroductionAdirectionallysolidifiedNi3AIbasealloyIC6hasbeenrecentlydevelopedinBIAMasahigh-temperaturestructuralmaterialusedforadvancedjet--enginebladesandvanesoperatinginthetemperaturerangeof1000mll50oC[1].Thealloynotonlyhashighyieldstrengthandfairlygoodductilityfromroomtemperatureto1100"C,butalsohashighcreepresistanceinthetemperaturerangeof760--1100"C.Itsoxidationresistancehasbeensubstantiallyimprovedbytheadditionofproperamountsofsiliconandyttrium[2--4].Siliconmaybeusedasrefiningaddit…     

热过程对IC21单晶合金组织和力学性能的影响

利用光学显微镜和扫描电镜对IC21单晶合金的铸态、热处理后和不同热过程后的组织进行了观察,检测了铸态、热处理态和不同热过程后合金的高温拉伸和持久性能,研究了热处理和热过程对IC21合金组织演变和力学性能的影响。结果表明,IC21合金的铸态组织呈树枝晶状,由γ′相、γ相以及枝晶间的粗大γ′相和NiMo相组成,枝晶干上γ′相尺寸比枝晶间的γ′相尺寸大。1315 ℃/6 h/充氩冷却+两次时效热处理后合金未实现完全固溶,枝晶干上部分铸态γ′相在固溶时未完全溶解,枝晶间仍存在粗大γ′相,持久性能与铸态相比有明显提升。热过程后,γ′相明显长大,立方度略有降低,枝晶间和枝晶干的γ′相尺寸差距减小,并且有针状相析出。合金的持久寿命与热处理态相比,稍有降低,抗拉强度有所提高。     

喷射沉积Ni3Al-Mo合金的位错结构分析和断裂特性

利用多功能雾化沉积装置,制备了Ni3Al-Mo高温合金.拉伸性能测试表明:喷射沉积Ni3Al-Mo合金的屈服强度有明显的"R"特性,即喷射沉积合金的屈服强度随着温度的增加而增加,在760 ℃时达到最大值;随着温度的继续增加,屈服强度会逐渐降低.利用TEM对位错结构分析,阐明了合金屈服强度与微观结构之间的关系.研究结果表明,试验合金所具有的屈服强度随温度的变化规律主要是由不同温度下γ′及γ相内的位错缠结状况、位错对的形态及数量和六面体滑移系的开动程度决定的.裂纹的TEM分析表明,随着变形应力的增加,裂纹在晶界部位产生,然后迅速扩展,而且在不同的晶面内存在一些不同的滑移带.喷射沉积合金在室温、中温及高温下裂纹严格沿八面体滑移系(111)面开裂.