New CH3OH laser lines pumped with a fine-tuned high-power CO2-TEA laser

Joule-level pulses from an etalon tuned CO₂-TEA laser with an ～ 4GHz intraline tuning range have been used to pump a large number of new CH₃OH FIR laser lines. FIR wavelength measurements, pump laser offsets which produced FIR laser lines and pump laser offsets at which CH₃OH absorption lines were observed are reported. Identifications are proposed for most of the absorption lines, and an attempt to identify the FIR laser lines is described.     

New CW FIR laser lines obtained in ammonia pumped by a CO2 laser,using the Stark tuning method

We report fifty seven CW FIR emissions observed in NH₃, by resonant pumping with a CO₂ laser. Exact coincidences between IR absorption lines of the gas and emission lines of the CO₂ laser have been carried out by Stark tuning. IR frequency shifts, up to 30 GHz, have allowed the pumping of forty three NH₃ transitions. These FIR emissions correspond to thirty one different wavelengths in the 50–400 μm range; eighteen ones of them are new emitted wavelengths by pumping with the CO₂ laser.     

Investigation of superconductivity effects in single-phase and multiphase Bi2Sr2CaCu2O8 single-crystals at 2-MM wavelengths

Experimental investigations of superconductivity effects in single-phase and multiphase Bi₂Sr₂CaCu₂O₈ single-crystals have been carried out at 142 GHz frequency by means of the standing wave profile method [1]. Josephson harmonic generation has been observed to be responsible for the appearence of additional peaks on the standing wave profile of the open dielectric resonator loaded with a properly orientated multiphase high-T_c superconductor specimen. This leads to the conclusion that most of the Josephson junctions in multiphase crystals are located in certain crystallographic planes. The investigations of temperature dependencies showed that sharp resonant peaks of conductivity observed earlier [2] at 60 GHz could also be observed at 142 GHz.     

Characteristics of a far-infrared molecular laser optically pumped by a high-power CO2 laser

A molecular far-infrared (FIR) laser optically pumped by a high-power CO₂ laser, which is a powerful source for testing detectors and mixers and for FIR spectroscopy, is constructed and the performance is examined through experiments. At frequencies between 580GHz and 4.25THz, FIR output power is more than 20～30m W by pumping power of 35～81W. Amplitude stability of ±3% is obtained at 100m W output at 2.52THz for over 30 minutes when the FIR tube is cooled at 5°C by a chiller. As an application to testing mixers, FIR laser lines up to 4.25 THz are detected by Schottky barrier diodes (SBD). Further, using a SBD, performance of absolute frequency stability at 693GHz of HCOOH oscillation is measured by harmonic mixing with a 115.5GHz millimeter wave from a phase-locked Gunn oscillator. The resultant center-frequency stability is 100kHz per 10 minutes.     

Assignments of fir laser emissions from CH3OH optically pumped by an intra-cavity etalon tuned TEA-CO2 laser

The author reports that TEA-CO₂ with an intra-cavity etalon is a useful pumping source which can deliver widely tunable beam (tunable range ～1 GHz) with accurate oscillation frequencies and with high power compared to a tunable wave guide laser. The source is applied to the excitations of CH₃OH and the FIR emissions from it are well assigned for there absorption transitions and FIR emissions. This proves that the source display not only usefulness for development of new FIR emissions but also for molecular spectroscopy.     

New CH2F2 FIR laser lines pumped by a tunable WG CO2 laser

8 new large offset FIR laser lines of CH₂F₂ have been discovered by pumping with a high tunability waveguide CW CO₂ laser. Optoacoustic measurements of CH₂F₂ have also been performed and the pump offsets of the new and of previously known lines have been measured and checked. Some assignments are proposed and a few assignments found in literature are checked     

Generation of sum-frequency sideband using 964 GHz HCN laser and 70 GHz klystron radiation

Continuosly tunable submillimeter radiation above 1 THz has been generated by sum-frequency mixing of HCN laser radiation (second strongest transition at 964.3 GHz) with that of klystron (70 GHz) in the Schottky barrier diode used as the non-linear element. Generated radiation was sufficiently strong to allow the high resolution frequency measurement of 9_9,1 ← 8_8,0 transition in³²S¹⁶O.     

Optically pumped submillimeter laser lines from CH2F2 and CD2Cl2 using a12C18O2 CW laser

Thirty-nine new submillimetre laser lines in CH₂F₂ and twelve in CD₂Cl₂ have been obtained in a Fabry-Perot FIR resonator by optically pumping with a CW¹²C¹⁸O₂ laser. The wavelength range obtained for CH₂F₂ is 126μm to 1091μm and for CD₂Cl₂ 212μm to 774μm. The wavelength measurements are accurate to within 5.10^?3. The relative polarisations of the pump laser and the FIR laser output were also determined. Tentative assignments of the IR and FIR transitions were made using existing microwave data.     

A tunable waveguide CO2 laser using Fabry-Perot modulator and fox-smith type mode selector

A tunable waveguide CO₂ laser was constructed and tested. Efficient output was obtained over expanded tuning range making use of the coupling modulation through the F-P modulator. A fox-smith type mode selector was used to obtain the tuning range wider than the longitudinal mode spacing. A continuous tuning range of 2.2GHz was experimentally obtained.     

An injection-locked single-mode tea CO2 laser for SMM laser pumping

A D₂O laser has been developed for collective Thomson scattering measurements of ion temperature in high temperature plasmas. A pulse duration and a spectral width of a high power D₂O laser has been successfully controlled for this purpose, by using a TEA CO₂ laser injection-locked by an etalon-tuned TEA CO₂ laser as a pump source.     

Assignment of laser lines in optically pumped submillimeter lasers: HDCO, D2CO

Respectively, three and eight laser lines have been precisely measured and assigned in asymmetric-top molecules HDCO and D2CO. Frequency calculations of rotational transitions use parameters obtained from microwave studies. For frequency calculations of rovibrational transitions, vibrational energies derived from infrared band analysis have been also taken into account. The assignment is confirmed by infrared radio frequency double resonance experiments inside the submillimeter laser cavity.     

Optically pumped submillimeter laser lines from CD2Cl2 using a large tunability CW CO2 laser

Twenty-five new laser lines have been obtained in the wavelength region from 155 to 830 µm by optically pumping the CD₂Cl₂ (deuterated dichloromethane) molecule with a CW CO₂ laser having a tunability range of 300 MHz. The wavelength, polarization relative to that of CO₂ pumping radiation, and offset relative to the CO₂ center frequency were determined for all of the new lines and some other already known laser emissions. For all of them we give also the relative intensity and the optimum pressure of operation.     

Mini-optically pumped NH3 cavity laser wide band emission at 67.2 µm

The spectral characteristics of mini-optically pumped NH₃ cavity laser emission at 67.2µm was studied. It was found that the spectrum of 67.2µm emission was duality. With low power CO₂-9R(30) pumping condition (lp<1MW/cm²), the spectrum appeared to be two wide FIR laser lines (～4.6GHz for each line), which were the result of competition of multi-Raman processes. With high power pumping condition (lp>2MW/cm²), the spectrum extended to be a very wide band (～14GHz), which was the result of the combination of the competition and interaction enhancement of Raman processes. The wide band spectral characteristics of 67.2 µm would be significant to the tuning of NH₃ OPFIRL.     

Ultra-Low Loss Microwave Dielectric Ceramic Li<Subscript>2</Subscript>Mg<Subscript>2</Subscript>TiO<Subscript>5</Subscript> and Low-Temperature Firing Via B<Subscript>2</Subscript>O<Subscript>3</Subscript> Addition

Li₂Mg₂TiO₅, a rock-salt structured ceramic fabricated by a solid-state sintering technique, was characterized at the microwave frequency band. As a result, a microwave dielectric permittivity (ε_r) of 13.4, a quality factor of 95,000 GHz (at 11.3 GHz), and a temperature coefficient of resonance frequency (τ_f) of ? 32.5 ppm/°C have been obtained at 1320°C. Li₂Mg₂TiO₅ ceramics have low permittivity, a broad processing temperature region, and a low loss, making them potential applications in millimeter-wave devices. Furthermore, B₂O₃ addition efficiently lowered the sintering temperature of Li₂Mg₂TiO₅ to 900°C, which opens up their possible applications in low-temperature co-fired ceramics (LTCC) technology.     

Partly tunable mid-infrared NH3 laser

Using a continously tunable pulsed 20-atmosphere CO₂ laser as a pump source, we generated pulses of mid-infrared radiation, partly tunable in frequency intervals in the range between 200 and 900 cm^?1 via stimulated Raman scattering in gaseous ammonia. As a Raman cell we used a multiple pass cell. We observed for¹⁴NH₃ and¹⁵NH₃ laser lines at 52 different frequencies with 39 lines observed for the first time. Tuning ranges up to 150 GHz and peak powers of several MW were achieved. The quantum efficiency reached 40 %.     

Preparation,Infrared Emissivity,and Dielectric and Microwave Absorption Properties of Fe-Doped ZnO Powder

Fe-doped ZnO powders have been synthesized by the coprecipitation method using zinc nitrate [Zn(NO₃)₂·6H₂O] as starting material, urea [CO(NH₂)₂] as precipitator, and ferric nitrate [Fe(NO₃)₃·9H₂O] as doping source. The microstructure of the prepared powders has been characterized by x-ray diffraction and scanning electron microscopy. Results show that, when the molar ratio of Fe to (Zn + Fe) was less than 0.09, the prepared powder was ZnO(Fe) solid solution, and the ZnFe₂O₄ impurity phase appeared when the Fe doping content was further increased. The electric permittivity in the frequency range of 8.2 GHz to 12.4 GHz and the average infrared emissivity in the wavelength range of 8 μm to 14 μm have been determined for the prepared powders. The average infrared emissivity decreased with increasing Fe doping content. The real (ε′) and imaginary part (ε″) of the permittivity of the prepared powders showed opposite trends. When the molar ratio of Fe to (Zn + Fe) was 0.03, the prepared Fe-doped ZnO powder demonstrated the best microwave absorption in the frequency range of 8.2 GHz to 12.4 GHz.     

Gas breakdown with nanosecond CO2 laser radiation

The thresholds for CO₂ laser induced breakdown and their variation with pulse width have been measured at various pressures for Ar, N₂ and an 8/1/1 laser mixture of He/CO₂/N₂ using 3–40 ns duration pulses. These measurements indicate that excited state production plays a dominant role in determining the threshold for nanosecond duration pulses. This has been confirmed by the good agreement obtained between the measured and theoretical thresholds.     

Precision Tunable Infrared Source at 10 μM: CO2-Laser/Microwave-Sideband System with an Evenson CO2 Laser and a Cheo Waveguide Modulator

A CO₂-laser/microwave-sideband tunable infrared source system has been newly built at the University of New Brunswick (UNB) in Canada. The system employs a high-resolution CO₂ laser of Evenson design that lases on a wide range of lines including hot and sequence band lines as well as high-J lines of the regular 9.6 and 10.6 μm bands. The frequency of the CO₂ laser is stabilized to the Lamb dip in the 4.3 μm fluorescence signal in an external CO₂ cell. Microwave (MW) sidebands are generated in a Cheo-type infrared waveguide modulator driven by a synthesized sweeper and a traveling wave tube (TWT) amplifier. The MW sidebands appear on either side of the CO₂ laser line, and are individually separated from the carrier by a tunable Fabry-Perot etalon. The sidebands currently have a typical power of about 1.4 mW and a continuous frequency tuning range of 22 GHz (from ± to ±18 GHz) when 5 W laser power and 15 W microwave power are delivered to the modulator. Details are given on the source construction and measured performance characteristics. Features of the source and its planned applications are discussed.     

GaAs-based metal-oxide semiconductor field-effect transistors with Al2O3 gate dielectrics grown by atomic layer deposition

We demonstrate GaAs-based, metal-oxide-semiconductor field-effect transistors (MOSFETs) with excellent performance using an Al₂O₃ gate dielectric, deposited by atomic layer deposition (ALD). This achievement is very significant because Al₂O₃ possesses highly desirable physical and electrical properties as a gate dielectric. These MOSFET devices exhibit extremely low gate-leakage current, high transconductance, and high dielectric breakdown strength. A short-circuit, current-gain, cutoff frequency (f_T) of 14 GHz and a maximum oscillation frequency (f_max) of 25.2 GHz have been achieved from a 0.65-μm gate-length device. The interface trap density (D_it) of Al₂O₃/GaAs is evaluated by the hysteresis of drain-source current, I_ds, versus gate-source bias, V_gs, and the frequency dispersion of transconductance, g_m.     

混合型TEA CO2激光器

本文给出了一种获得单纵模脉冲激光的装置。该激光器由TEA CO2和CWCO2激光器组成,采用内注入,结构简单易注入成功。本实验得到了预期的结果,并提出了进一步改进的方法。