The effect of allanite inclusions on U–Pb step-leaching ages and Sm–Nd isotope systematics of garnet from the Ogcheon metamorphic belt,South Korea

The Ogcheon metamorphic belt consists primarily of metasedimentary and metavolcanic rocks that have experienced polyphase tectonometamorphism since the Neoproterozoic. Peak metamorphism reaching up to lower-amphibolite facies produced ubiquitous garnet porphyroblasts in pelitic and mafic schists. To determine the timing of their formation, step-leaching experiments were undertaken for five garnet fractions separated from pelitic and quartz-hornblende-garnet schists. The U–Pb ages from three samples are identical within 2σ errors, ranging from 291 ± 41 Ma to 276 ± 29 Ma. The quasi-linearity of leachates in ²³⁸U–²⁰⁶Pb and ²⁰⁸Pb–²⁰⁶Pb diagrams suggests that U and Pb are released from a single mineral phase and that minor chemical fractionation between U and Pb may have occurred during the leaching experiment. Deviations of residues and bulk garnet fractions from the linear trend are attributed to partial dissolution of refractory inclusions of detrital zircon. Th/U ratios of leachates are in the range of 3.4–12, much higher than those of pure garnet, and suggest the contribution of allanite. Negative relationships in the Sm–Nd isochron diagram and similar ¹⁴⁷Sm/¹⁴⁴Nd ratios between whole rock and garnet corroborate the influence of light rare earth element (LREE)-rich allanite on the Sm–Nd isotopic system. Simple mass-balance calculations indicate that only a trace amount (0.35 modal%) of allanite inclusions should govern the U–Th–Pb systematics of garnet. Petrographic evidence together with the consistency in U–Pb ages suggests that allanite is a product of prograde metamorphism. Thus, peak metamorphism responsible for the growth of allanite-bearing garnet porphyroblasts in the Ogcheon metamorphic belt is best estimated to be Early Permian.     

Direct dating of mid‐crustal shear zones with synkinematic allanite: new in situ U‐Th‐Pb geochronological approaches applied to the Mont Blanc massif

Dating the timing of motion on crustal shear zones is of tremendous importance for understanding the assembly of orogenic terranes. This objective is achieved in this paper by combining petrological and structural observations with novel developments in in situ U‐Th‐Pb geochronology of allanite. A greenschist facies shear zone within the Mont Blanc Massif is documented. Allanite is synkinematic and belongs to the mylonitic assemblage. LA‐ICP‐MS U‐Th‐Pb isotope analyses of allanite reveal high contents and highly radiogenic isotopic compositions of the common‐Pb component. The use of measured Pb‐isotope compositions of associated minerals (feldspars and chlorite) is critical for accurate common‐Pb correction, and provides a powerful mechanism for linking allanite growth to the metamorphic assemblage. A mean ²⁰⁸Pb/²³²Th age of 29.44 ± 0.95 Ma is accordingly taken for synkinematic allanite crystallisation under greenschist facies conditions. This age reflects the timing of the Mont Blanc underthrusting below the Penninic Front and highlights the potential of directly dating deformation with allanite.     

Phase equilibria modelling and LASS monazite petrochronology: P–T–t constraints on the evolution of the Priest River core complex,northern Idaho

Phase equilibria modelling, laser‐ablation split‐stream (LASS)‐ICP‐MS petrochronology and garnet trace‐element geochemistry are integrated to constrain the P–T–t history of the footwall of the Priest River metamorphic core complex, northern Idaho. Metapelitic, migmatitic gneisses of the Hauser Lake Gneiss contain the peak assemblage garnet + sillimanite + biotite ± muscovite + plagioclase + K‐feldspar ± rutile ± ilmenite + quartz. Interpreted P–T paths predict maximum pressures and peak metamorphic temperatures of ~9.6–10.3 kbar and ~785–790 °C. Monazite and xenotime ²⁰⁸Pb/²³²Th dates from porphyroblast inclusions indicate that metamorphism occurred at c. 74–54 Ma. Dates from HREE‐depleted monazite formed during prograde growth constrain peak metamorphism at c. 64 Ma near the centre of the complex, while dates from HREE‐enriched monazite constrain the timing of garnet breakdown during near‐isothermal decompression at c. 60–57 Ma. Near‐isothermal decompression to ~5.0–4.4 kbar was followed by cooling and further decompression. The youngest, HREE‐enriched monazite records leucosome crystallization at mid‐crustal levels c. 54–44 Ma. The northernmost sample records regional metamorphism during the emplacement of the Selkirk igneous complex (c. 94–81 Ma), Cretaceous–Tertiary metamorphism and limited Eocene exhumation. Similarities between the Priest River complex and other complexes of the northern North American Cordillera suggest shared regional metamorphic and exhumation histories; however, in contrast to complexes to the north, the Priest River contains less partial melt and no evidence for diapiric exhumation. Improved constraints on metamorphism, deformation, anatexis and exhumation provide greater insight into the initiation and evolution of metamorphic core complexes in the northern Cordillera, and in similar tectonic settings elsewhere.     

Disturbance versus preservation of U–Th–Pb ages in monazite during fluid–rock interaction: textural, chemical and isotopic in situ study in microgranites (Velay Dome, France)

Monazite is extensively used to date crustal processes and is usually considered to be resistant to diffusive Pb loss. Nevertheless, fluid-assisted recrystallisation is known to be capable of resetting the monazite chronometer. This study focuses on chemical and isotopic disturbances in monazite grains from two microgranite intrusions in the French Central Massif (Charron and Montasset). Petrologic data and oxygen isotopes suggest that both intrusions have interacted with alkali-bearing hydrothermal-magmatic fluids. In the Charron intrusion, regardless of their textural location, monazite grains are sub-euhedral and cover a large domain of compositions. U–Pb chronometers yield a lower intercept age of 297 ± 4 Ma. An inherited component at 320 Ma is responsible for the scattering of the U–Th–Pb ages. The Montasset intrusion was later affected by an additional F-rich crustal fluid with crystallisation of Ca-REE-fluorocarbonates, fluorite, calcite and chloritisation. Pristine monazite is chemically homogeneous and displays ²⁰⁸Pb/²³²Th and ²⁰⁶Pb/²³⁸U concordant ages at 307 ± 2 Ma. By contrast, groundmass monazite shows dissolution-recrystallisation features associated with apatite and thorite precipitation (Th-silicate) and strong chemical reequilibration. ²⁰⁸Pb/²³²Th ages are disturbed and range between 270 and 690 Ma showing that the Th/Pb ratio is highly fractionated during the interaction with fluids. Apparent U–Pb ages are older due to common Pb incorporation yielding a lower intercept age at 312 ± 10 Ma, the age of the pristine monazite. These results show that F-rich fluids are responsible for Th mobility and incorporation of excess Pb, which thus strongly disturbed the U–Th–Pb chronometers in the monazite.     

Tectonometamorphic evolution of an intracontinental orogeny inferred from P–T–t–d paths of the metapelites from the Rehamna massif (Morocco)

New petrographic and microstructural observations, mineral equilibria modelling and U/Pb (monazite) geochronological studies were carried out to investigate the relationships between deformation and metamorphism across the Rehamna massif (Moroccan Variscan belt). In this area, typical Barrovian (muscovite to staurolite) zones developed in Cambrian to Carboniferous metasedimentary rocks that are distributed around a dome‐like structure. First assemblages are characterized by the presence of locally preserved andalusite, followed by prograde evolution culminating at 6 kbar and 620 °C in the structurally deepest staurolite zone rocks. This Barrovian sequence was subsequently uplifted to supracrustal levels, heterogeneously reworked at greenschist facies conditions, which was followed locally by static growth of andalusite, indicating heating to 2.5–4 kbar and 530–570 °C. The ²⁰⁶Pb/²³⁸U monazite age of 298.3 ± 4.1 Ma is interpreted as minimum age of peak metamorphic conditions, whereas the ages of 275.8 ± 1.7 Ma and 277.0 ± 1.1 Ma date decompression and heating at low pressure, in agreement with previous dating of Permian granitoids intruding the Rehamna massif. The prograde metamorphism occurred during thickening and associated horizontal flow in the deeper crust (S1 horizontal schistosity). The horizontally disposed metamorphic zones were subsequently uplifted by a regional scale antiform during ongoing N–S compression. The re‐heating of the massif follows late massive E–W shortening, refolding and retrograde shearing of all previous fabrics coevally with regionally important intrusions of Permian granitoids. We argue that metamorphic evolution of the Rehamna massif occurred several hundred kilometres from the convergent plate boundaries in the interior of continental Gondwanan plate. The tectonometamorphic history of the Rehamna massif is put into Palaeozoic plate tectonic perspective and Late Carboniferous reactivation of (Devonian)–Early Carboniferous basins formed during stretching of the north Gondwana margin and formation of the Palaeotethys Ocean. The inherited heat budget of these magma‐rich basins plays a role in the preferential location of this intracontinental orogen. It is shown that rapid transition from lithospheric stretching to compression is characterized by specific HT type of Barrovian metamorphism, which markedly differs from similar Barrovian sequences along Palaeozoic plate boundaries reported from Variscan Europe.     

Influence of dissolution/reprecipitation reactions on metamorphic greenschist to amphibolite facies mica 40Ar/39Ar ages in the Longmen Shan (eastern Tibet)

Linking ages to metamorphic stages in rocks that have experienced low‐ to medium‐grade metamorphism can be particularly tricky due to the rarity of index minerals and the preservation of mineral or compositional relicts. The timing of metamorphism and the Mesozoic exhumation of the metasedimentary units and crystalline basement that form the internal part of the Longmen Shan (eastern Tibet, Sichuan, China), are, for these reasons, still largely unconstrained, but crucial for understanding the regional tectonic evolution of eastern Tibet. In situ core‐rim ⁴⁰Ar/³⁹Ar biotite and U–Th/Pb allanite data show that amphibolite facies conditions (~10–11 kbar, 530°C to 6–7 kbar, 580°C) were reached at 210–180 Ma and that biotite records crystallization, rather than cooling, ages. These conditions are mainly recorded in the metasedimentary cover. The ⁴⁰Ar/³⁹Ar ages obtained from matrix muscovite that partially re‐equilibrated during the post peak‐P metamorphic history comprise a mixture of ages between that of early prograde muscovite relicts and the timing of late muscovite recrystallization at c. 140–120 Ma. This event marks a previously poorly documented greenschist facies metamorphic overprint. This latest stage is also recorded in the crystalline basement, and defines the timing of the greenschist overprint (7 ± 1 kbar, 370 ± 35°C). Numerical models of Ar diffusion show that the difference between ⁴⁰Ar/³⁹Ar biotite and muscovite ages cannot be explained by a slow and protracted cooling in an open system. The model and petrological results rather suggest that biotite and muscovite experienced different Ar retention and resetting histories. The Ar record in mica of the studied low‐ to medium‐grade rocks seems to be mainly controlled by dissolution–reprecipitation processes rather than by diffusive loss, and by different microstructural positions in the sample. Together, our data show that the metasedimentary cover was thickened and cooled independently from the basement prior to c. 140 Ma (with a relatively fast cooling at 4.5 ± 0.5°C/Ma between 185 and 140 Ma). Since the Lower Cretaceous, the metasedimentary cover and the crystalline basement experienced a coherent history during which both were partially exhumed. The Mesozoic history of the Eastern border of the Tibetan plateau is therefore complex and polyphase, and the basement was actively involved at least since the Early Cretaceous, changing our perspective on the contribution of the Cenozoic geology.     

Eclogite origin and timings in the North Qinling terrane,and their bearing on the amalgamation of the South and North China Blocks

The amalgamation of South (SCB) and North China Blocks (NCB) along the Qinling‐Dabie orogenic belt involved several stages of high pressure (HP)‐ultra high pressure (UHP) metamorphism. The new discovery of UHP metamorphic rocks in the North Qinling (NQ) terrane can provide valuable information on this process. However, no precise age for the UHP metamorphism in the NQ terrane has been documented yet, and thus hinders deciphering of the evolution of the whole Qinling‐Dabie‐Sulu orogenic belt. This article reports an integrated study of U–Pb age, trace element, mineral inclusion and Hf isotope composition of zircon from an eclogite, a quartz vein and a schist in the NQ terrane. The zircon cores in the eclogite are characterized by oscillatory zoning or weak zoning, high Th/U and ¹⁷⁶Lu/¹⁷⁷Hf ratios, pronounced Eu anomalies and steep heavy rare earth element (HREE) patterns. The zircon cores yield an age of 796 ± 13 Ma, which is taken as the protolith formation age of the eclogite, and implies that the NQ terrane may belong to the SCB before it collided with the NCB. The ?_Hf(t) values vary from ?11.3 to 3.2 and corresponding two‐stage Hf model ages are 2402 to 1495 Ma, suggesting the protolith was derived from an enriched mantle. In contrast, the metamorphic zircon rims show no zoning or weak zoning, very low Th/U and ¹⁷⁶Lu/¹⁷⁷Hf ratios, insignificant Eu anomalies and flat HREE patterns. They contain inclusions of garnet, omphacite and phengite, suggesting that the metamorphic zircon formed under eclogite facies metamorphic conditions, and their weighted mean ²⁰⁶Pb/²³⁸U age of 485.9 ± 3.8 Ma was interpreted to date the timing of the eclogite facies metamorphism. Zircon in the quartz vein is characterized by perfect euhedral habit, some oscillatory zoning, low Th/U ratios and variable HREE contents. It yields a weighted mean U–Pb age of 480.5 ± 2.5 Ma, which registers the age of fluid activity during exhumation. Zircon in the schist is mostly detrital and U–Pb age peaks at c. 1950 to 1850, 1800 to 1600, 1560 to 1460 and 1400 to 1260 Ma with an oldest grain of 2517 Ma, also suggesting that the NQ terrane may have an affinity to the SCB. Accordingly, the amalgamation between the SCB and the NCB is a multistage process that spans c. 300 Myr, which includes: the formation of the Erlangping intra‐oceanic arc zone onto the NCB before c. 490 Ma, the c. 485 Ma crustal subduction and UHP metamorphism of the NQ terrane, the c. 430 Ma arc‐continent collision and granulite facies metamorphism, the 420 to 400 Ma extension and rifting in relation to the opening of the Palaeo‐Tethyan ocean, the c. 310 Ma HP eclogite facies metamorphism of oceanic crust and associated continental basement, and the final 250 to 220 Ma continental subduction and HP–UHP metamorphism.     

Recurrent rare earth element mineralization in the northwestern Okcheon Metamorphic Belt,Korea: SHRIMP U–Th–Pb geochronology,Nd isotope geochemistry,and tectonic implications

Rare earth element (REE) mineralization is hosted within Neoproterozoic alkaline metaigneous rocks in the northwestern part of the Okcheon Metamorphic Belt (OMB), a polymetamorphosed fold-and-thrust belt transecting the Paleoproterozoic Gyeonggi and Yeongnam Massifs in the southern Korean Peninsula. The principal carrier phase of REEs is allanite. Allanite grains can be subdivided into several types based on the texture and mineral assemblage including quartz, K-feldspar, biotite, britholite, apatite, fergusonite, andradite, magnetite, zircon, titanite and fluorite. Electron microprobe analysis of allanite clearly distinguishes sample-to-sample variations in total REEs, Ca, Al, Fe and Y but the textural varieties from each rock sample do not show marked differences in those elements. Sensitive high-resolution ion microprobe dating of allanite and zircon reveals a complex history of multistage mineralization. Allanite grains from REE ores yielded Late Ordovician (444.6 ± 8.0 Ma), Permian to Triassic (ca. 300–220 Ma) and Early Jurassic (199–183 Ma) ²⁰⁸Pb/²³²Th ages. These multiple age components often coexist in single grains showing slight differences in backscattered electron brightness. The Ordovician components have distinctly higher Th/U than the younger domains in the same rock sample. The cores and rims of zircon from a syenite hosting REE ore bodies yielded Neoproterozoic (858.2 ± 6.3 Ma) and Early Jurassic (ca. 190 Ma) ²⁰⁶Pb/²³⁸U ages, respectively. The Early Jurassic ages (194–187 Ma) also obtained from zircon grains from granites taken from dykes occurring close to the ores and a drill core indicate the correspondence between granitic magmatism and REE mineralization. The Neoproterozoic zircon inheritance (weighted mean = 853.9 ± 3.8 Ma) in these granites is in sharp contrast to the dominant Paleoproterozoic inherited zircon from the widespread earliest Middle Jurassic granites enclosing the mineralized zone. The geotectonic significance of the Late Ordovician event recorded in the allanite, as well as in detrital zircon from the OMB, is still unclear but its temporal coincidence with intraplate volcanism and arc-related igneous activity, respectively, reported from the southwestern edge of the adjacent Taebaeksan Basin and the southwestern Gyeonggi Massif is noteworthy. The following Permian–Triassic and Early Jurassic mineralization events are probably linked to the continental suturing between the North and South China blocks and subsequent post-orogenic magmatism, and arc magmatism resulting from the paleo-Pacific plate subduction, respectively. Sub-grain Sm–Nd isotopic analyses of allanite by laser ablation multiple collector ICPMS yielded initial ε_Nd values plotting along the Nd isotopic evolution path of the Neoproterozoic metaigneous rocks, indicating that REEs originating from the host rock have been recycled during multistage mineralization events. The profound differences in inherited zircon ages and Nd isotopic compositions between the Early and Middle Jurassic granites may reflect the presence of a major thrust-bounded crustal structure beneath the OMB.     

Age constraints on the evolution of the Austroalpine basement to the south of the Tauern Window

The Austroalpine basement to the south of the Tauern Window once was part of the northern margin of Gondwana. It includes the “Altkristallin” and the phyllitic Thurntaler Complex. In the Altkristallin (AMU, MPU), suites of arc-related metamafic sequences occur together with calc-alkaline metagranite. SHRIMP U–Pb dating of zircon from calc-alkaline metagranite associated with an eclogitic amphibolite give an age of 470 ± 3 Ma interpreted as the age of protolith emplacement. In the Thurntaler Complex, metaporphyroids occur together with tholeiitic as well as alkaline within-plate basalt-type metabasite. The metaryholites of this association give a crystallization SHRIMP age of 477 ± 4 Ma, which suggests contemporaneity of arc-related and extensional settings in the Austroalpine basement units. The age data demonstrate widespread magmatic activity associated with the Early-Ordovician amalgamation at the end of the 550–470 Ma subduction–accretion–collision cycle. The Pb–Pb and U–Pb systematics of step-wise leached staurolite and kyanite from the peak-metamorphic assemblage of the Altkristallin indicate that (1) step-wise leaching of staurolite and kyanite yields the age of inclusions rather than the host; (2) zircon inclusions in staurolite suggest an Ordovician or older age for the precursor of the staurolite-schists; (3) the weighted average of the ²⁰⁶Pb/²³⁸U data of the various leaching steps yields a Variscan age for the inclusions (ilmenite, biotite, and andesine). Since these inclusions are part of the metamorphic mineral assemblage, this age provides a minimum estimate for staurolite growth, i.e., metamorphism. Thus, the Pb–Pb and U–Pb systematics of staurolite provide evidence for a Variscan metamorphism of the Austroalpine basement, e.g., MPU, AMU and Thurntaler Complex, to the south of the Tauern Window.     

Protracted garnet growth in high‐P eclogite: constraints from multiple geochronology and P–T pseudosection

Understanding convergent margin processes requires determination of the onset and the termination of subduction, the duration of subduction‐zone metamorphism, and the subduction zone polarity. Garnet growth and intracrystalline zonation can be used to constrain the timing, duration and kinetics of tectonometamorphic processes. An eclogite from the Huwan shear zone in the Hong'an orogen was investigated with combined pseudosection analysis and multiple geochronologies. The pseudosection analysis illustrates that garnet growth is continuous and along an early near‐isothermal trajectory followed by a near‐isobaric heating path from 1.9 GPa/500 °C to 2.4 GPa/575 °C and subsequent near‐isothermal decompression. ⁴⁰Ar/³⁹Ar dating of an amphibole inclusion in garnet from the eclogite yielded an age of 310 ± 5 Ma, which is consistent with a U–Pb age of 305 ± 3 Ma for the metamorphic zircon within uncertainty. Garnet core and rim material produced Lu–Hf ages of 296.9 ± 3.8 and 256.9 ± 3.9 Ma respectively; the latter is consistent with its Sm–Nd age of 254.3 ± 4.6 Ma for the same aliquots. Similarly, limited zircon U–Pb ages of c. 257 Ma were obtained in zircon rims with garnet inclusions. These ages were interpreted to bracket the period of garnet growth and the difference of up to c. 40 Ma is best explained by protracted garnet growth. We propose that the rocks represent detachment of part of the downgoing slab and remained free of significant compression/decompression or heating/cooling close to the subduction channel, most likely underplating the mantle wedge, for a long time. These rocks were incorporated into the following subduction channel due to the successive entry of the buoyant materials, and exhumed at some time later than c. 254 Ma. The increasing observations of protracted garnet growth and long‐lived subduction in various orogens worldwide demand more sophisticated geodynamic models.     

Two successive phases of ultrahigh temperature metamorphism in Rogaland,S. Norway: Evidence from Y‐in‐monazite thermometry

In Rogaland, South Norway, a polycyclic granulite facies metamorphic domain surrounds the late‐Sveconorwegian anorthosite–mangerite–charnockite (AMC) plutonic complex. Integrated petrology, phase equilibria modelling, monazite microchemistry, Y‐in‐monazite thermometry, and monazite U–Th–Pb geochronology in eight samples, distributed across the apparent metamorphic field gradient, imply a sequence of two successive phases of ultrahigh temperature (UHT) metamorphism in the time window between 1,050 and 910 Ma. A first long‐lived metamorphic cycle (M1) between 1,045 ± 8 and 992 ± 11 Ma is recorded by monazite in all samples. This cycle is interpreted to represent prograde clockwise P–T path involving melt production in fertile protoliths and culminating in UHT conditions of ~6 kbar and 920°C. Y‐in‐monazite thermometry, in a residual garnet‐absent sapphirine–orthopyroxene granulite, provides critical evidence for average temperature of 931 and 917°C between 1,029 ± 9 and 1,006 ± 8 Ma. Metamorphism peaked after c. 20 Ma of crustal melting and melt extraction, probably supported by a protracted asthenospheric heat source following lithospheric mantle delamination. Between 990 and 940 Ma, slow conductive cooling to 750–800°C is characterized by monazite reactivity as opposed to silicate metastability. A second incursion (M2) to UHT conditions of ~3.5–5 kbar and 900–950°C, is recorded by Y‐rich monazite at 930 ± 6 Ma in an orthopyroxene–cordierite–hercynite gneiss and by an osumilite gneiss. This M2 metamorphism, typified by osumilite paragenesis, is related to the intrusion of the AMC plutonic complex at 931 ± 2 Ma. Thermal preconditioning of the crust during the first UHT metamorphism may explain the width of the aureole of contact metamorphism c. 75 Ma later, and also the rarity of osumilite‐bearing assemblages in general.     

Petrogenesis of metatexite and diatexite migmatites determined using zircon U–Pb age,trace element and Hf isotope data,Higo metamorphic terrane,central Kyushu,Japan

Metatexite and diatexite migmatites are widely distributed within the upper amphibolite and granulite facies zones of the Higo low‐P/high‐T metamorphic terrane. Here, we report data from an outcrop in the highest grade part of the granulite facies zone, in which diatexite occurs as a 3 m thick layer between 2 m thick layers of stromatic‐structured metatexite within pelitic gneiss. The migmatites and gneiss contain the same peak mineral assemblage of biotite + plagioclase + quartz + garnet + K‐feldspar with retrograde chlorite ± muscovite and some accessory minerals of ilmenite ± rutile ± titanite + apatite + zircon + monazite ± pyrite ± zinc sulphide ± calcite. Calculated metamorphic P–T conditions are 800–900 °C and 9–12 kbar. Zircon in the diatexite forms elongate euhedral crystals with oscillatory zoning, but no core–rim structure. Zircon from the gneiss and metatexite forms euhedral–subhedral grains comprising inherited cores overgrown by thin rims. The overgrowth rims in the metatexite have lower Th/U ratios than zircon in the diatexite and yield a ²⁰⁶Pb/²³⁸U age of 116.0 ± 1.6 Ma, which is older than the 110.1 ± 0.6 Ma ²⁰⁶Pb/²³⁸U age derived from zircon in the diatexite. Zircon from the diatexite has variable REE contents with convex upward patterns and flat normalized HREE, whereas the overgrowth rims in the metatexite and gneiss have steep HREE‐enriched patterns; however, both types have similar positive Ce and negative Eu anomalies. ¹⁷⁶Hf/¹⁷⁷Hf ratios in the overgrowth rims from the metatexite are more variable and generally lower than values from zircon in the diatexite. Based on U–Pb ages, trace element and Hf isotope data, the zircon rims in the metatexite are interpreted to have crystallized from a locally derived melt, following partial dissolution of inherited protolith zircon during anatexis, whereas the zircon in the diatexite is interpreted to have crystallized from a melt that included an externally derived component. By integrating zircon and petrographic data for the migmatites and pelitic gneiss, the metatexite migmatite is interpreted to have formed by in situ partial melting in which the melt did not migrate from the source, whereas the diatexite migmatite included an externally derived juvenile component. The Cretaceous high‐temperature metamorphism of the Higo metamorphic terrane is interpreted to reflect emplacement of mantle‐derived basalts under a volcanic arc along the eastern margin of the Eurasian continent and advection of heat via hybrid silicic melts from the lower crust. Post‐peak crystallization of anatectic melts in a high‐T region at mid‐crustal depths occurred in the interval c. 116–110 Ma, as indicated by the difference in zircon ages from the metatexite and diatexite migmatites.     

Precise U–Pb and Th–Pb age determination of kimberlitic perovskites by secondary ion mass spectrometry

Perovskite, a common Th- and U-enriched accessory mineral crystallised from kimberlitic magmas, has long been thought to be an important geochronometer for dating the emplacement of kimberlite. However, it also contains variably high levels of common Pb, which makes it difficult to obtain a precise measurement of radiogenic Pb/U and Pb/Th isotopic compositions using microbeam techniques such as SIMS and LA-ICP-MS. We present calibration protocols for in situ U–Pb and Th–Pb age determination of kimberlitic perovskite using the large double-focusing Cameca IMS 1280. Linear relationships are found between ln(²⁰⁶Pb?⁺/U⁺) and ln(UO₂⁺/U⁺), and between ln(²⁰⁸Pb?⁺/Th⁺) and ln(ThO⁺/Th⁺), based on which the inter-element fractionation in unknown samples during SIMS analyses can be precisely calibrated against a perovskite standard. The well-characterized Ice River perovskite is chosen as the U–Pb and Th–Pb age standard in this study. The ²⁰⁴Pb-correction method was used to estimate the fraction of common Pb, which is consistent with the results obtained using the ²⁰⁷Pb-based correction method for the dated perovskites of Phanerozoic age.A Tazheran perovskite with unusually high U but rather low Th yielded a Concordia U–Pb age of 462.8 ± 2.5 Ma and a Th–Pb age of 462 ± 4 Ma. Two perovskite samples from the Iron Mountain kimberlite have identical Concordia U–Pb ages of 410.8 ± 3.4 Ma and 411.0 ± 2.6 Ma, which are consistent within errors with their corresponding Th–Pb ages of 409.2 ± 7.2 Ma and 412.3 ± 3.3 Ma, respectively. Two perovskite samples from the Wesselton Mine of South Africa yielded indistinguishable ²⁰⁶Pb/²³⁸U ages of 91.5 ± 2.2 Ma and 90.3 ± 2.9 Ma, and Th–Pb ages of 90.5 ± 0.8 Ma and 88.4 ± 1.6 Ma, respectively. Accuracy and precision of 1–2% (95% confidence level) for these measurements have been demonstrated by the consistency of their U–Pb and Th–Pb ages with the recommended U–Pb ages of previous works.     

Metamorphic stages in mountain belts during a Wilson cycle: A case study in the central Sanandaj–Sirjan zone (Zagros Mountains,Iran)

Polymetamorphic units are important constituents of continent–continent collisional orogens, and rift metamorphic assemblages are often overprinted by subsequent metamorphism during subduction and collision. This study reports the metamorphic conditions and evolution of the Dorud–Azna metamorphic units in the central part of the Sanandaj–Sirjan zone (SSZ), Iran. Here, new geothermobarometry results are integrated with ⁴⁰Ar/³⁹Ar mineral and Th–U–Pb monazite and thorite ages to provide new insight of polyphase metamorphism in the two different basement units of the SSZ, the lower Galeh-Doz orthogneiss and higher Amphibolite-Metagabbro units. In the Amphibolite-Metagabbro unit, staurolite micaschist underwent a prograde P–T evolution from 640 ± 20 °C/6.2 ± 0.8 kbar in garnet cores (M1) to 680 ± 20 °C/7.2 ± 1.0 kbar in garnet rims (M2). Three Th–U–Pb monazite ages of 306 ± 5 Ma, 322 ± 28 Ma and 336 ± 39 Ma from the garnet-micaschists testify the Carboniferous age of M1 metamorphism. In the same unit, the metagabbro records P–T conditions of 4.0 ± 0.8 kbar and 580 ± 50 °C in the (magmatic) amphibole core (Late Carboniferous intrusion) to 7.5 ± 0.7 kbar and 700 ± 20 °C in the amphibole rim indicating a prograde P–T path during subsequent burial (M1). New ⁴⁰Ar/³⁹Ar dating of white mica from the staurolite micaschist yielded a staircase pattern ranging from 36 ± 12 Ma to 170 ± 2 Ma. This implies polymetamorphism with a minimum Late Jurassic cooling age through the Ar retention temperature of ca. 425 ± 25 °C after M2 metamorphism and a Paleogene low-grade metamorphic overprint (M3), while ⁴⁰Ar/³⁹Ar white mica dating of garnet micaschist yielded a plateau age of 137.84 ± 0.65 Ma. We therefore interpret the amphibolite-grade metamorphism M2 to have predated 170 Ma and is likely between 180 and 200 Ma. Furthermore, it is overprinted at about 36 Ma under retrogressive low-grade M3 metamorphism (at temperatures of ~350–240 °C) during final shortening and exhumation. In the underlying Galeh-Doz unit, the Panafrican granitic orthogneiss intruded at P–T conditions of 3.2 ± 4 kbar and 700 ± 20 °C, then it was metamorphosed and deformed at 600 ± 50 °C and 2.0 ± 0.8 kbar (metamorphic stage M1) prior to Late Carboniferous intrusion of mafic dikes. ⁴⁰Ar/³⁹Ar dating of amphibole from the Galeh-Doz orthogneiss gave plateau-like steps between 260 and 270 Ma, representing the age of cooling through ca. 500 °C after the M1 metamorphic event. Interestingly, the results of this study demonstrate polyphase metamorphic histories in both the Galeh-Doz orthogneiss and Amphibolite-Metagabbro units at different P–T conditions and final thick-skinned Paleogene emplacement of these units over the underlying low-grade metamorphic June Complex. Our findings suggest that both units are affected by high-T/low-P Late Carboniferous orogenic metamorphism along with the bimodal magmatism, as result of rifting. We propose that the Early Jurassic amphibolite-grade M2 metamorphism of the SSZ is correlated with the initial subduction of the Neotethyan Ocean. Eventually, the investigated units reflect various stages of a Wilson cycle, from rifting to initiation of the subduction in final plate collision.     

西藏山南列麦始新世花岗岩独居石U-Th-Pb年龄及地质意义

西藏山南隆子县列麦地区始新世花岗岩的成岩时代和背景对喜马拉雅地区同碰撞阶段的构造演化具有重要意义。本文对隆子县列麦乡界归党村的白云母花岗岩开展独居石LA-ICP-MS U-Th-Pb测年,独居石40个测点的~(208)Pb/~(232)Th加权平均年龄为41±0.1Ma(MSWD=1.4),形成于始新世中期。结合区域上的始新世岩浆岩活动和区域变质作用,本文认为在50～45Ma印度下地壳发生中-高压变质和部分熔融;45Ma新特提斯洋洋壳板片断离,软流圈地幔上涌;45～41Ma喜马拉雅发生短暂的拉张环境导致大量的埃达克质岩浆岩侵位和麻粒岩的折返。     

Time‐scale of deformation and intertectonic phases revealed by P–T–D–t relationships in the orogenic middle crust of the Orlica‐Śnieżnik Dome,Polish/Czech Central Sudetes

A section of the orogenic middle crust (Orlica‐?nie?nik Dome, Polish/Czech Central Sudetes) was examined to constrain the duration and significance of deformation (D) and intertectonic (I) phases. In the studied metasedimentary synform, three deformation events produced an initial subhorizontal foliation S1 (D₁), a subsequent subvertical foliation S2 (D₂) and a late subhorizontal axial planar cleavage S3 (D₃). The synform was intruded by pre‐, syn‐ and post‐D₂ granitoid sheets. Crystallization–deformation relationships in mica schist samples document I_1–2 garnet–staurolite growth, syn‐D₂ staurolite breakdown to garnet–biotite–sillimanite/andalusite, I_2–3 cordierite blastesis and late‐D₃ chlorite growth. Garnet porphyroblasts show a linear Mn–Ca decrease from the core to the inner rim, a zone of alternating Ca–Y‐ and P‐rich annuli in the inner rim, and a Ca‐poor outer rim. The Ca–Y‐rich annuli probably reflect the occurrence of the allanite‐to‐monazite transition at conditions of the staurolite isograd, whereas the Ca‐poor outer rim is ascribed to staurolite demise. The reconstructed P–T path, obtained by modelling the stability of parageneses and garnet zoning, documents near‐isobaric heating from ~4 kbar/485 °C to ~4.75 kbar/575 °C during I_1–2. This was followed by a progression to 4–5 kbar/580–625 °C and a subsequent pressure decrease to 3–4 kbar during D₂. Pressure decrease below 3 kbar is ascribed to I_2–3, whereas cooling below ~500 °C occurred during D₃. In the dated mica schist sample, garnet rims show strong Lu enrichment, oscillatory Lu zoning and a slight Ca increase. These features are also related to allanite breakdown coeval with staurolite appearance. As Lu‐rich garnet rims dominate the Lu–Hf budget, the 344 ± 3 Ma isochron age is ascribed to garnet crystallization at staurolite grade, near the end of I_1–2. For the dated sample of amphibole–biotite granitoid sheet, a Pb–Pb single zircon evaporation age of 353 ± 1 Ma is related to the onset of plutonic activity. The results suggest a possible Devonian age for D₁, and a Carboniferous burial‐exhumation cycle in mid‐crustal rocks that is broadly coeval with the exhumation of neighbouring HP rocks during D₂. In the light of published ages, a succession of telescoping stages with time spans decreasing from c. 10 to 2–3 Ma is proposed. The initially long period of tectonic quiescence (I_1–2 phase, c. 10 Ma) inferred in the middle crust contrasts with contemporaneous deformation at deeper levels and points to decoupled P–T–D histories within the orogenic wedge. An elevated gradient of ~30 °C km^?1 and assumed high heating rates of c. 20 °C Ma^?1 are explained by the protracted intrusion of granitoid sheets, with or without deformation, whereas fast vertical movements (2–3 Ma, D₂ phase) in the crust require the activity of deformation phases.     

P–T evolution and episodic zircon growth in barroisite eclogites of the Lanterman Range,northern Victoria Land,Antarctica

Prograde P–T–t paths of eclogites are often ambiguous owing to high variance of mineral assemblages, large uncertainty in isotopic age determinations and/or variable degree of retrograde equilibration. We investigated these issues using the barroisite eclogites from the Lanterman Range, northern Victoria Land, Antarctica, which are relatively uncommon but free of retrogression. These eclogites revealed three stages of prograde metamorphism, defining two distinctive P–T trajectories, M_1–2 and M₃. Inclusion minerals in garnet porphyroblasts suggest that initial prograde assemblages (M₁) consist of garnet+omphacite+barroisite/Mg‐pargasite+epidote+phengite+paragonite+rutile/titanite+quartz, and subsequent M₂ assemblages of garnet+omphacite+barroisite+phengite+rutile±quartz. The inclusion‐rich inner part of garnet porphyroblasts preserves a bell‐shaped Mn profile of the M₁, whereas the inclusion‐poor outer part (M₂) is typified by the outward decrease in Ca/Mg and X_Fe (=Fe²⁺/(Fe²⁺+Mg)) values. A pseudosection modelling employing fractionated bulk‐rock composition suggests that the eclogites have initially evolved from ~15 to 20 kbar and 520–570°C (M₁) to ~22–25 kbar and 630–650°C (M₂). The latter is in accordance with P–T conditions estimated from two independent geothermobarometers: the garnet–clinopyroxene–phengite (~25 ± 3 kbar and 660 ± 100°C) and Zr‐in‐rutile (~650–700°C at 22–27 kbar). The second segment (M_3A–B) of prograde P–T path is recorded in the grossular‐rich overgrowth rim of garnet. Apart from disequilibrium growth of the M_3A garnet, ubiquitous overgrowth of the M_3B garnet permits us to estimate the P–T conditions at ~26 ± 3 kbar and 720 ± 80°C. The cathodoluminescence (CL) imaging of zircon grains separated from a barroisite eclogite revealed three distinct zones with bright rim, dark mantle and moderately dark core. Eclogitic phases such as garnet, omphacite, epidote and rutile are present as fine‐grained inclusions in the mantle and rim of zircon, in contrast to their absence in the core. The sensitive high‐resolution ion microprobe U–Pb dating on metamorphic mantle domains and neoblasts yielded a weighted mean ²⁰⁶Pb/²³⁸U age of 515 ± 4 Ma (tσ), representing the time of the M₂ stage. On the other hand, overgrowth rims as well as bright‐CL neoblasts of zircon were dated at 498 ± 11 Ma (tσ), corresponding to the M₃. Average burial rates estimated from the M₂ and M₃ ages are too low (<2 mm/year) for cold subduction regime (~5–10°C/km), suggesting that an exhumation stage intervened between two prograde segments of P–T path. Thus, the P–T–t evolution of barroisite eclogites is typified by two discrete episodes with an c. 15 Ma gap during the middle Cambrian subduction of the Antarctic Ross Orogeny.     

Micro‐sampling Lu–Hf geochronology reveals episodic garnet growth and multiple high‐P metamorphic events

We present Lu–Hf dates from multiple growth zones within two large garnet porphyroblasts by a micro‐sampling method. A single eclogite sample, taken from the Huwan shear zone in the Hong'an orogen, was investigated with Lu–Hf geochronology by micro‐sampling and traditional bulk separation methods. The sample contains a few large garnet porphyroblasts up to several centimetres in diameter and a second major population of smaller (0.1–2.0 mm) garnet porphyroblasts, comprised of dark cores and pale rims. Elemental compositions and mineral inclusions in the garnet appear consistent with two garnet generations. Lu–Hf dates (c. 400–264 Ma) were determined from twelve micro‐sawed garnet sections from two large garnet porphyroblasts. These Lu–Hf dates overlap with age peaks defined by 115 SIMS zircon U–Pb analyses from the same eclogite sample. Bulk analyses of smaller garnet separates define a minimum date of c. 306 Ma and a maximum date of c. 252 Ma for the dark cores and pale rims respectively. These Lu–Hf dates were interpreted to bracket the period of garnet growth and the broad interval from c. 400 to 264 Ma is best explained by protracted and episodic garnet growth, which may require that these rocks experienced two subduction cycles that were initiated during the Devonian and terminated in the Triassic.     

Integrated pressure–temperature–time constraints for the Tso Morari dome (Northwest India): implications for the burial and exhumation path of UHP units in the western Himalaya

Northward subduction of the leading edge of the Indian continental margin to depths greater than 100 km during the early Eocene resulted in high‐pressure (HP) quartz‐eclogite to ultrahigh‐pressure (UHP) coesite–eclogite metamorphism at Tso Morari, Ladakh Himalaya, India. Integrated pressure–temperature–time determinations within petrographically well‐constrained settings for zircon‐ and/or monazite‐bearing assemblages in mafic eclogite boudins and host aluminous gneisses at Tso Morari uniquely document segments of both the prograde burial and retrograde exhumation path for HP/UHP units in this portion of the western Himalaya. Poikiloblastic cores and inclusion‐poor rims of compositionally zoned garnet in mafic eclogite were utilized with entrapped inclusions and matrix minerals for thermobarometric calculations and isochemical phase diagram construction, the latter thermodynamic modelling performed with and without the consideration of cation fractionation into garnet during prograde metamorphism. Analysis of the garnet cores document (M1) conditions of 21.5 ± 1.5 kbar and 535 ± 15 °C during early garnet growth and re‐equilibration. Sensitive high resolution ion microprobe (SHRIMP) U–Pb analysis of zircon inclusions in garnet cores yields a maximum age determination of 58.0 ± 2.2 Ma for M1. Peak HP/UHP (M2) conditions are constrained at 25.5–27.5 kbar and 630–645 °C using the assemblage garnet rim–omphacite–rutile–phengite–lawsonite–talc–quartz (coesite), with mineral compositional data and regional considerations consistent with the upper P–T bracket. A SHRIMP U–Pb age determination of 50.8 ± 1.4 Ma for HP/UHP metamorphism is given by M2 zircons analysed in the eclogitic matrix and that are encased in the garnet rim. Two garnet‐bearing assemblages from the Puga gneiss (host to the mafic eclogites) were utilized to constrain the subsequent decompression path. A non‐fractionated isochemical phase diagram for the assemblage phengite–garnet–biotite–plagioclase–quartz–melt documents a restricted (M3) P–T stability field centred on 12.5 ± 0.5 kbar and 690 ± 25 °C. A second non‐fractionated isochemical phase diagram calculated for the lower pressure assemblage garnet–cordierite–sillimanite–biotite–plagioclase–quartz–melt (M4) documents a narrow P–T stability field ranging between 7–8.4 kbar and 705–755 °C, which is consistent with independent multiequilibria P–T determinations. Th–Pb SHRIMP dating of monazite cores surrounded by allanite rims is interpreted to constrain the timing of the M4 equilibration to 45.3 ± 1.1 Ma. Coherently linking metamorphic conditions with petrographically constrained ages at Tso Morari provides an integrated context within which previously published petrological or geochronological results can be evaluated. The new composite path is similar to those published for the Kaghan UHP locality in northern Pakistan, although the calculated 12‐mm a^?1 rate of post‐pressure peak decompression at Tso Morari would appear less extreme.