The boiling liquid expanding vapour explosion (BLEVE): mechanism, consequence assessment, management

Among the most devastating of accidents likely in chemical process industry is the boiling liquid expanding vapour explosion (BLEVE). It is accompanied by highly destructive blast waves and missiles. In most situations there is also a fireball or a toxic gas cloud. The damaging effect of BLEVEs is reflected in the fact that the 80-odd major BLEVEs that have occurred between 1940 and 2005 have claimed over a 1000 lives and have injured over 10,000 persons besides harming property worth billions of dollars. Release of toxic chemicals like chlorine and phosgene from BLEVEs have damaged large chunks of areas surrounding the BLEVE site. This paper presents an overview of the mechanism, the causes, the consequences, and the preventive strategies associated with BLEVEs.     

BLEVE prevention using vent devices

The main features of accidents involving BLEVEs (boiling liquid expanding vapour explosions) occurring in fires are analysed. Simple mathematical models describing liquid or vapour discharge through the perforation of vessels by superheated liquids and liquid behaviour in a vessel heated by fire are formulated. These models are verified on the basis of experimental data available in the literature. An analysis of the well known accident at Alma-Ata in 1989 is presented. This accident involved the BLEVE of a railway tank engulfed by fire, with the resulting formation of a fireball. It is shown that this accident could have been prevented by means of a vent device (safety valve or breaking diaphrgm) with cross-sectional area greater than 77 cm² and operational pressure below 1.6 MPa. The use of such vent devices could prevent the occurrence of BLEVEs when tanks containing superheated liquids or liquefied gases are subjected to thermal loading from fires.     

液化石油气泄漏的危险性分析及其事故后果评价方法

液化石油气（LPG）在其运输和存储过程中存在着各种与火灾和爆炸相关的危险性。由于LPG的泄漏可能导致包括闪火，不可控蒸气云爆炸，沸腾液体膨胀蒸汽爆炸等一系列灾害的发生，针对上述的各种灾害的具体发生条件及其危险性进行了分析；在事故后果评价中采用量化风险分析，提出了沸腾液体膨胀蒸汽爆炸和不可控蒸气云爆炸对周围人员可能造成伤害的评价方法。     

Metallurgical failure analysis of a propane tank boiling liquid expanding vapor explosion (BLEVE)

A severe fire and explosion occurred at a propane storage yard in Truth or Consequences, N.M., when a truck ran into the pumping and plumbing system beneath a large propane tank. The storage tank emptied when the liquid-phase excess flow valve tore out of the tank. The ensuing fire engulfed several propane delivery trucks, causing one of them to explode. A series of elevated-temperature stress-rupture tears developed along the top of a 9800 L (2600 gal) truck-mounted tank as it was heated by the fire. Unstable fracture then occurred suddenly along the length of the tank and around both end caps, along the girth welds connecting the end caps to the center portion of the tank. The remaining contents of the tank were suddenly released, aerosolized, and combusted, creating a powerful boiling liquid expanding vapor explosion (BLEVE). Based on metallography of the tank pieces, the approximate tank temperature at the onset of the BLEVE was determined. Metallurgical analysis of the ruptured tank also permitted several hypotheses regarding BLEVE mechanisms to be evaluated. Suggestions are made for additional work that could provide improved predictive capabilities regarding BLEVEs and for methods to decrease the susceptibility of propane tanks to BLEVEs.     

Incident analysis of Bucheon LPG filling station pool fire and BLEVE

An LPG filling station incident in Korea has been studied. The direct cause of the incident was concluded to be faulty joining of the couplings of the hoses during the butane unloading process from a tank lorry into an underground storage tank. The faulty connection of a hose to the tank lorry resulted in a massive leak of gas followed by catastrophic explosions. The leaking source was verified by calculating the amount of released LPG and by analyzing captured photos recorded by the television news service. Two BLEVEs were also studied.     

Consequence analysis in LPG installation using an integrated computer package

This paper presents the prototype of the computer code, Atlantide, developed to assess the consequences associated with accidental events that can occur in a LPG storage plant. The characteristic of Atlantide is to be simple enough but at the same time adequate to cope with consequence analysis as required by Italian legislation in fulfilling the Seveso Directive. The application of Atlantide is appropriate for LPG storage/transferring installations. The models and correlations implemented in the code are relevant to flashing liquid releases, heavy gas dispersion and other typical phenomena such as BLEVE/Fireball. The computer code allows, on the basis of the operating/design characteristics, the study of the relevant accidental events from the evaluation of the release rate (liquid, gaseous and two-phase) in the unit involved, to the analysis of the subsequent evaporation and dispersion, up to the assessment of the final phenomena of fire and explosion. This is done taking as reference simplified Event Trees which describe the evolution of accidental scenarios, taking into account the most likely meteorological conditions, the different release situations and other features typical of a LPG installation. The limited input data required and the automatic linking between the single models, that are activated in a defined sequence, depending on the accidental event selected, minimize both the time required for the risk analysis and the possibility of errors. Models and equations implemented in Atlantide have been selected from public literature or in-house developed software and tailored with the aim to be easy to use and fast to run but, nevertheless, able to provide realistic simulation of the accidental event as well as reliable results, in terms of physical effects and hazardous areas. The results have been compared with those of other internationally recognized codes and with the criteria adopted by Italian authorities to verify the Safety Reports for LPG installations. A brief of the theoretical basis of each model implemented in Atlantide and an example of application are included in the paper.     

Uncertainty quantification in the health consequences of the boiling liquid expanding vapour explosion phenomenon.

A methodology for estimating the risk owing to the phenomenon of boiling liquid expanding vapour explosion (BLEVE) in the presence of uncertainties both in the model and in the parameters of the models is presented. BLEVE takes place when a tank containing liquefied petroleum gas (LPG) is exposed to fire and fails catastrophically. Two models have been used in the estimation of the intensity of thermal radiation from the resulting fireball, namely the solid-flame model assuming an emission power independent of the combustion mass and the point-source model that estimates the emissive power as a function of the combustion mass. Three measures of the BLEVE consequences, the intensity of thermal radiation, the dose of thermal radiation and the probability of loss of life as a result of the exposure to the thermal radiation and as a function of the distance from the center of the tank have been considered. Uncertainties in the exact values of the parameters of the models have been quantified and the resulting uncertainties in the three consequence measures have been assessed. A sensitivity analysis on the relative contribution of the uncertainty in each of the input variables to the uncertainties of the consequence measures has been performed. One conclusion is that the uncertainties in the probability of loss of life are mainly due to the uncertainties in the model of the physical phenomenon rather than to the uncertainties of the dose-response model.     

Potential for BLEVE associated with marine LNG vessel fires

Recent LNG marine shipping hazard studies have discounted BLEVE hazards associated with LNG vessels. This exclusion of a potential major hazard event has been queried, particularly since a recent LNG truck BLEVE-like event in Spain. This paper reviews the physical factors associated with the Spanish LNG truck event and accepts that this had features of a classical BLEVE event and that there is no inherent property of LNG excluding BLEVE-like events, although US LNG trucks would be safer due to design features. Marine LNG vessels have differently designed tanks and it is demonstrated that the combination of physical barriers makes direct thermal input to the LNG inner tank more limited than hypothesized by some, but if it occurs these tanks cannot rise to a pressure sufficient to cause a large flash of liquid and consequent BLEVE event of a scale hypothesized in the literature.     

Using liquid superheating energy for a quick estimation of overpressure in BLEVEs and similar explosions

A method is proposed for the quick estimation of the peak overpressure caused by a Boiling Liquid Expanding Vapor Explosion (BLEVE) or a similar explosion. The method is based on the use of the "superheating energy" (SE), which is the difference between the specific enthalpy of the liquid at the temperature just before the explosion and the specific enthalpy of the liquid at its saturation temperature, at atmospheric pressure. The analysis performed with a set of reference substances showed that in a BLEVE or in similar explosions, the energy converted into overpressure will range between 3.5 and 14% of SE. The comparison of the values thus obtained with experimental data from the literature shows a fairly good agreement.     

Enhanced catalytic activity of nanoscale platinum islands loaded onto SnO<Subscript>2</Subscript> thin film for sensitive LPG gas sensors

In the present study, different catalysts (∼ 10 nm thick) including metals, noble metals and metal oxides, were loaded in dotted island form over SnO₂ thin film for LPG gas detection. A comparison of various catalysts indicated that the presence of platinum dotted islands over SnO₂ thin film deposited by r.f. sputtering exhibited enhanced response characteristics with a high sensitivity, ∼ 742, at an operating temperature of ∼ 280°C. Different characterization techniques have been employed such as atomic force microscopy, X-ray diffraction and UV-vis spectroscopy, to study the surface morphology, grain size and optical properties of the deposited thin films. The results suggest the possibility of utilizing the sensor element with the present novel method of catalyst dispersal for the efficient detection of LPG.     

Experimental and analytical investigation of thermal coating effectiveness for 3m(3) LPG tanks engulfed by fire

Two large-scale diesel pool fire engulfment tests were carried out on LPG tanks protected with intumescing materials to test the effectiveness of thermal coatings in the prevention of hot BLEVE accidental scenarios in the road and rail transport of LPG. A specific test protocol was defined to enhance reproducibility of experimental tests. The geometrical characteristics of the test tanks were selected in order to obtain shell stresses similar to those present in full-size road tankers complying to ADR standards. In order to better understand the stress distribution on the vessel and to identify underlying complicating phenomena, a finite element model was also developed to better analyze the experimental data. A non-homogeneous and time-dependent effectiveness of the fire protection given by the intumescing coating was evidenced both by finite element simulations and by the analysis of the coating after the tests. The results of the fire tests pointed out that the coating assured an effective protection of the tanks, consistently increasing the expected time to failure. The data obtained suggest that the introduction of fire protection coatings may be a viable route to improve the safety of the LPG distribution chain.     

Does a country’s scientific ‘productivity’ depend critically on the number of country journals indexed?

In this paper, we examine the question whether it is meaningful to talk about the scientific productivity of nations based on indexes like the Science Citation Index or Scopus, when the journal set covered by them keeps changing with time. We hypothesize from the illustrative case of India’s declining productivity in the 1980s which correlated with a fall in its journals indexed, that an apparent increase/decrease in productivity for any country, based on observed change in its share of papers could, in fact, be an effect resulting from the inclusion of more/less journals from the country. To verify our hypothesis we have used SCIMAGO data. We found that for a set of 90 countries, the share of journals regressed on the share of papers gave a linear relationship that explained 80% of the variance. However, we also show that in the case of China’s unusual rise in world scientific productivity (to second rank crossing several other countries), there is yet another factor that needs to be taken into account. We define a new indicator—the JOURNAL PACKING DENSITY (JPD) or average number of papers in journals from a given country. We show that the packing density of Chinese journals has steadily increased over the last few years. Currently, Chinese journals have the highest ‘packing density’ in the world, almost twice the world average which is about 100 papers per journal per annum. The deviation of the JPD from the world average is another indicator which will affect so called ‘national productivities’ in addition to the number of national journals indexed. We conclude that in the context of a five fold increase in the number of journals indexed over 20 years, the simplistic notion of ‘scientific productivity’ as equivalent to papers indexed needs to be re-examined.     

Influence of palladium on gas-sensing performance of magnesium ferrite nanoparticles

Commercial ferrites with high densities are mostly used in the electromagnetic devices, which require high temperature synthesis. In this article the gas-sensing characteristics of pure and Pd-doped MgFe₂O₄ powder has been discussed. The synthesis has been carried out by using a simple molten salt method. This method facilitates rapid synthesis at comparatively lower temperature enabling formation of nanostructures, suitable for the gas-sensing application. Various physicochemical techniques have been used for the characterization of samples. X-ray diffraction analysis confirmed the single-phase formation of pure and Pd-doped MgFe₂O₄ having crystallite size 15–20 nm. Pure MgFe₂O₄ showed highest responses towards liquid petroleum gas (LPG) at 350 °C while, on doping with Pd the highest response shifted towards lower operating temperature of ～200 °C. Pure MgFe₂O₄ exhibited some response towards 200 ppm of LPG which markedly increased on doping of palladium (Pd). The probable mechanism is proposed to explain the selective response towards LPG.     

An international comparison of relative contributions to academic productivity

This paper presents a methodology for measuring the improvements in efficiency and adjustments in the scale of R&D (Research & Development) activities. For this purpose, this study decomposes academic productivity growth into components attributable to (1) world academic frontier change, (2) R&D efficiency change, (3) human capital accumulation, and (4) capital accumulation. The world academic frontier at each point in time is constructed using data envelopment analysis (DEA). This study calculates each of the above four components of academic productivity for 27 countries over 1990–2003, and finds that the components which contribute to academic productivity growth vary with the different countries’ characteristics and development stages. Human capital has more weight in terms of the quantity of academic research, and capital accumulation plays a more important role in the citation impact of academic research.     

Investigating Ahuja–Orlin’s large neighbourhood search approach for examination timetabling

Since the 1960s, automated approaches to examination timetabling have been explored and a wide variety of approaches have been investigated and developed. In this paper we build upon a recently presented, sequential solution improvement technique which searches efficiently over a very large set of “adjacent” (neighbourhood) solutions. This solution search methodology, originally developed by Ahuja and Orlin, has been applied successfully in the past to a number of difficult combinatorial optimisation problems. It is based on an improvement graph representation of solution adjacency and identifies improvement moves by finding cycle exchange operations using a modified shortest path label-correcting algorithm. We have drawn upon Ahuja–Orlin’s basic methodology to develop an effective automated exam timetabling technique. We have evaluated our approach against the latest methodologies in the literature on standard benchmark problems. We demonstrate that our approach produces some of the best known results on these problems.     

Effects of fire on small commercial gas cylinders

Current standards on the safety of small portable gas cylinders only define the pressures at temperatures of up to 50 °C and therefore have limited applicability in situations where cylinders are close to fires. Cylinders containing a pressurised liquid butane–propane mixture were heated in a small barbecue. The cylinders underwent a boiling liquid expanding gas explosion (BLEVE) at a liquid temperature of 90–100 °C. Failure was at the rolled seam where gas could escape thus provoking the BLEVE. Previous hydrostatic pressure testing of the cylinders showed that collapse of the spherical cap base occurred at a pressure of 1.8 MPa and that this was followed by failure of the rolled seam at a pressure of 2.0 MPa. These pressures were lower than that required to produce longitudinal cracks in the cylinder wall. Analysis of the pressure created as the temperature is raised by means of the Clausius–Clapeyron equation indicated the temperature for failure of the seam to be about 100 °C. After the BLEVE the cylinder broke into two fragments, an end cap and a tub rocket. The velocity of the tub rocket was estimated to be 65 m s⁻¹, giving a kinetic energy of 309 J. By comparison with the ballistics of rubber bullets it is believed that any injuries will be non-penetrating blunt trauma injuries and be less likely to cause severe injuries than those created by rubber bullets. The range over which the kinetic energy is likely to be capable of creating injuries is estimated to be less than 30 m.     

Effective algorithms for parametrizing linear control systems over Ore algebras

In this paper, we study linear control systems over Ore algebras. Within this mathematical framework, we can simultaneously deal with different classes of linear control systems such as time-varying systems of ordinary differential equations (ODEs), differential time-delay systems, underdetermined systems of partial differential equations (PDEs), multidimensional discrete systems, multidimensional convolutional codes, etc. We give effective algorithms which check whether or not a linear control system over some Ore algebra is controllable, parametrizable, flat or π-free. This paper is dedicated to the memory of our dear friend and colleague Manuel Bronstein. The third author has been financially supported by the Control Training Site grant HPMT-CT-2001-00278 and the Deutsche Forschungsgemeinschaft during his stays at INRIA Sophia Antipolis.     

An experimental study on HC290 and a commercial liquefied petroleum gas (LPG) mix as suitable replacements for HCFC22

This paper presents an experimental study on the performance of hydrocarbon refrigerants, namely propane and a liquefied petroleum gas (LPG) mix as suitable replacements for the widely used refrigerant HCFC22 in refrigeration and heat pump applications. A cylinder of commercially available LPG from New Zealand market was obtained for this study. The composition of the specific LPG mix (by mass fraction) was propane (HC290)—98.95%, ethane (HC170)—1.007%, iso-butane (HC600a)—0.0397% and other constituents in small proportions. Experiments were carried out in a laboratory heat pump test facility with maximum condenser capacity of approximately 15 kW. Condensing temperatures were held constant at 35, 45 and 55°C, while evaporating temperatures were varied over a wide range from − 15 to + 15°C. All tests were carried out at constant degree of superheat (about 1 K) and subcooling (about 8 K). All appropriate precautions were observed against any leaks or fire.The analysis revealed that the hydrocarbon refrigerants performed better than HCFC22 but with a small loss of condenser capacity. The mass flow rate and compressor discharge temperature were found to be significantly lower than HCFC22. The performance of the specific LPG mix tested was found to be better than HC290 at higher condensing temperatures but poorer at a lower condensing temperature. No adverse effects were found with the LPG mix despite the presence of little moisture (less than 0.01%) in its composition. The study reveals that LPG of the tested composition (i.e. predominantly a mixture of propane, ethane and iso-butane) can be an excellent refrigerant in heat pump/refrigeration applications.     

A study of the behaviour of a protected vessel containing LPG during pool fire engulfment

Theoretical and experimental investigations of various methods for protection against fires of vessels containing liquefied petroleum gases (LPG) (safety relief valves, intumescent fire retardant coatings, thermal isolation) have been carried out. A simple mathematical model has been proposed, which describes dependences of various parameters on time. These parameters are temperature, pressure and mass of LPG, temperatures of the vessel's walls and thermal protection layer. The case of total fire engulfment of the vessel with LPG was considered. Experiments have been executed, which were aimed on the investigation of the behaviour of vessels with LPG (50 l), equipped with protective devices during total fire engulfment. It was found out that the safety valve prevented an explosion of the vessels without any other protective measures. The presence of the intumescent fire retardant coating caused a significant delay in operation of the safety valve. A rather good agreement between the theoretical and experimental data was obtained. It has been revealed that the considered methods for protection of LPG vessels are promising in regard to prevention of explosions in these vessels at the fire engulfment.     

Tin Pest: Elusive Threat in Lead-Free Soldering?

Tin pest is the result of an allotropic transformation of tin from its β phase to its α phase at temperatures below 13 °C. This transformation is accompanied by a change in density from 7.31 to 5.77 g/cm³. The resulting expansion usually results in degradation of the affected part, as the α phase material is mechanically weak and over time becomes little more than a gray powder. The tin pest effect is cumulative unless the sample in question is exposed to temperatures above 70 °C or so, where some reversion back to white tin has been observed. However, by this point a tin sample’s physical integrity may have been destroyed by the partial β to α transformation. The transformation to α tin is inhibited strongly by soluble alloying elements such as bismuth and antimony at concentrations of about 0.5%, or lead at concentrations of about 5%. Hence, tin pest is generally observed only in quite pure tin. However, nearly pure tin alloys may become common. For example, the advent of the European Union’s RoHS law, which essentially eliminates lead from solder, has spawned lead-free alloys that can be almost pure tin and may be at risk of tin pest. This risk has caused some concern over the long-term stability of emergent, lead-free solders during low temperature service. This overview article is written in light of this concern.