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组合型填料与焦炭填料塔中餐厅污水氧传递研究 总被引:1,自引:0,他引:1
本文分别以焦炭和自行开发的新型组合填料为塔内构件,对清水和餐厅污水中的氧传递特征进行了分析和实验研究,纯氧和空气供氧实验结果证实氧传递过程为液膜控制;通过实验测定了清水和餐厅污水在组合型填料和焦碳填料塔中曝气过程溶解氧的变化规律,从实验结果回归得到了上述填料塔内清水与餐厅污水氧转移系数计算关联式,计算值与实测值吻合较好;最后,对相同操作条件下焦炭与组合型填料在清水与餐厅污水中的氧转移系数进行了比较。 相似文献
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《Diamond and Related Materials》2006,15(10):1525-1534
The phonon dynamics of wurtzite aluminum nitride contaminated by oxygen were investigated by employing the Raman back scattering, the Fourier Transform Infrared (FT-IR) reflectivity and absorption, and the Brillouin scattering techniques on unseeded polycrystalline samples of AlN built of single crystallites 1–5 mm in size. The six Raman active zone center optic modes were observed and identified. Throughout the oxygen contamination range (∼1, ∼2, and ∼6 at.%) of three samples investigated, the widths of the principal Raman modes were found to decrease with increasing the oxygen content in the single crystal. This behavior is interpreted as a change in the nature of the oxygen defect when the oxygen concentration exceeds 1 at.%. The FT-IR reflectivity spectrum exhibits two-mode behavior at low oxygen concentration, one-mode behavior tends to be dominant when the oxygen concentration increases, and only one-mode behavior can be observed at high oxygen concentration. These changes in the reststrahlen band with oxygen concentration support the hypothesis of a transition in the oxygen accommodation defect as the concentration of oxygen increases. The oxygen effects on the AlN optical parameters were investigated by calculating these optical parameters from the reflectivity data of single crystallites differing in their oxygen concentration. The FT-IR absorption measurements showed several absorption bands in the multiple-phonon region. A tentative interpretation is proposed in which these bands are considered to be due to oxygen impurity absorption and to a combination of several phonon branches at the Brillouin-zone boundaries. The absorption spectrum in the one-phonon region allowed us to obtain a reliable data on the phonon density of states function in bulk AlN. Lastly, three different configurations were used in Brillouin scattering measurements to achieve a complete determination of the elastic stiffness constants of AlN. 相似文献
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The diffusion coefficients of oxygen in single crystals of nickel ferrite with Fe/Ni=3.4 were determined as a function of oxygen stoichiometry between 1140° and 1340°C. The diffusion kinetics were followed by measuring the rate of exchange of 18 O between the gas and solid slabs of ferrite, and the oxygen stoichiometry was established by controlling total pressure of oxygen in the gas phase. At higher oxygen contents, the diffusion coefficient is independent of stoichiometry and is given by D =10-2.3 exp cm2 /s. At low oxygen contents the diffusion rate depends strongly on oxygen stoichiometry and is smaller. In polycrystalline ferrite the diffusion at 1197°C is 40 times faster than in single crystals but shows the same dependence on oxygen stoichiometry. Probable diffusion mechanisms are discussed. 相似文献
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Atomic-scale structures and dynamic behaviors of CeO2(1 1 1) surfaces were imaged by noncontact atomic force microscopy (NC-AFM) and scanning tunneling microscopy (STM). Hexagonally arranged oxygen atoms, oxygen point vacancies, multiple oxygen vacancies, and hydrogen adatoms at the surfaces were visualized by atom-resolved NC-AFM observations. Multiple defects were stabilized by displacement of the surrounding oxygen atoms around the multiple defects, which gave enhanced brightness in the NC-AFM image due to a geometric reason. Multiple defects without reconstruction of the surrounding oxygen atoms were reactive and were healed by exposure to O2 gas and methanol at RT. Successive NC-AFM and STM measurements of slightly reduced CeO2(1 1 1) surfaces revealed that hopping of surface oxygen atoms faced to the metastable multiple defects was thermally activated even at room temperature (RT) and more promoted at higher temperatures. Heterogeneous feature of the reactivity of surface oxygen atoms with methanol was imaged by successive NC-AFM observations. These observations gave a new insight for understanding the surface structures and behavior of CeO2−x with the facile oxygen reservoir and oxidation–reduction properties related to the unique catalysis. 相似文献
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发酵过程中合理且充分供氧是提高L-赖氨酸发酵产量的主要途径之一,实际生产中溶氧控制策略又往往难以进行具体化操作,尤其是发酵中后期的溶氧水平直接决定了发酵生产的水平.通过5 L发酵罐实验分析中后期溶氧水平对赖氨酸发酵的影响,研究了不同溶氧水平条件下的发酵规律.实验数据表明,赖氨酸发酵中后期溶氧水平控制在60%~80%内,可以明显提高发酵的终点酸、转化率、酸固比和单罐总酸等生产指标,与正常控制水平(40%~60%)相比,依次分别提高了7.30%、3.08%、0.92%、5.48%. 相似文献
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《Ceramics International》2022,48(11):15073-15081
SiC is a widely used material. Understanding how oxygen content affects the SiC structure and properties is crucial. In this paper, heat treatment was used to prepare SiC powder samples with different oxygen contents, which were doped with AlN and ZrB2 and were densified by pressureless sintering at 2050 °C. The effect of oxygen content on the sintered SiC structure was determined by X-ray diffraction analysis, X-ray photoelectron spectroscopy, scanning electron microscopy, and energy-dispersive spectroscopy. The results indicated that the oxygen content influenced the SiC phase composition, grain boundaries, and densification. Additionally, the interaction between oxygen defects and AlN played an important role in sintering. The nanoindentation, alternating-current impedance, and thermal conductivity of the densified SiC specimens were also evaluated to elucidate the influence of the oxygen content on the densified-SiC functional properties. The results revealed that the oxygen content affected all the measured mechanical, electrical, and thermal properties. Furthermore, surface oxygen impurities suggested that oxygen content had similar critical effects on both the densified SiC structure and properties. 相似文献
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Surface modification of poly(p-phenylene terephthalamide) (PPTA) film by a remote oxygen plasma treatment has been investigated from a viewpoint of comparison with a direct oxygen plasma treatment. We call the modification procedure in a space far away from the oxygen plasma zone “the remote oxygen plasma treatment,” and the modification procedure in a space just in the oxygen plasma zone (a conventional oxygen plasma treatment) “the direct oxygen plasma treatment.” In a space far away from the plasma zone, oxygen radicals rather than electrons and oxygen ions are predominant, and the PPTA film can be modified by the remote oxygen plasma treatment into a hydrophilic surface without heavy degradation of the PPTA film. The PPTA film surfaces modified by the remote oxygen plasma treatment were analyzed with contact angle measurement, scanning microscopy, atomic force microscopy, and X-ray photoelectron spectroscopy. © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 64: 831–840, 1997 相似文献
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An apparatus for measuring ignition temperature and ignition-limiting oxygen index was devised in order to study ignition properties of polymers. Ignition limiting oxygen index, which was suggested by the limiting oxygen index (ASTM D2863-70), was defined as the minimum volume fraction of oxygen required for ignition to occur in a slowly rising gaseous atmosphere. The ignition temperatures and the ignition limiting oxygen indexes of typical polymers were measured by this apparatus. Polymers which produced more ethylene by pyrolysis tend to have lower ignition temperatures. In the case of the same kinds of polymers, plots of ignition temperatures versus ignition limting oxygen indexes gave nearly straight lines (Fig. 3), but the straight line of depolymerization-type polymers differed from that of random degradation-type polymers differed from that of random degradation-type polymers. In most polymers, ignition limiting oxygen indexes were nearly proportional to limiting oxygen indexes, but in the cases of hard poly(vinyl chloride) and soft poly(vinyl chloride), the plots did not follow this relation (Fig. 4). Ignition properties of self-extinguishing polymers were also studied. 相似文献
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Parvin M. Yasaei George C. Yang Charles R. Warner Dan H. Daniels Yuoh Ku 《Journal of the American Oil Chemists' Society》1996,73(9):1177-1181
Singlet oxygen produced by photochemical sensitizers may play an important role in the oxidation of lipids in foods. Therefore,
we studied the singlet oxygen oxidation of lipids and the scavenging ability of antioxidants. Singlet oxygen was generated
using the photosensitizer rose bengal. The oxidation products of lipids and antioxidants were separated by high-performance
liquid chromatography and monitored using post-column chemiluminescence and/or iodometric detection. The competitive reaction
rates of various antioxidants and lipids were studied to elucidate the roles played by antioxidants in the prevention of food
oxidation by singlet oxygen. 相似文献
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The impacts of four different types of tocotrienol homologues on the singlet oxygen oxidation of lard were evaluated by measuring the headspace oxygen content and the peroxide value. Singlet oxygen oxidation of lard was induced by chlorophyll photosensitization. Samples of 0.100, 0.250, and 0.400 M lard in methylene chloride containing chlorophyll and α‐, β‐, γ‐, or δ‐tocotrienol were prepared and stored under light at 3,000 lux for 4 h. All tocotrienol homologues at 1.20 mM significantly prevented the singlet oxygen oxidation of lard. Chlorophyll under light produced singlet oxygen at 1.09 μmol oxygen/mL headspace/h. A steady state kinetic study showed that tocotrienols reduced the singlet oxygen oxidation of lard by quenching the singlet oxygen. Singlet oxygen reacted with lard at 6.50 × 104M?1 s?1. α‐, β‐, γ‐, and δ‐tocotrienol quenched singlet oxygen with the rate of 2.16, 1.99, 2.05, and 0.800 × 107M?1 s?1, respectively. Among them, α‐tocotrienol significantly prevented singlet oxygen oxidation of lard. 相似文献
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The performance of a stabilized zirconia sensor and electrochemical oxygen pump combination in the isothermal control of oxygen fugacity in a nonflowing atmosphere was studied in a closed furnace system in the temperature range of 800° to 1100°C. Under certain conditions, large differences in oxygen pressure were found between sensors at the same constant temperature in close proximity to each other. This result reflected the existence of a stable steplike oxygen fugacity "front" in the furnace, separating regions which differed by several orders of magnitude in oxygen fugacity. This oxygen pressure profile in the furnace resulted from the steady-state transport of oxygen from oxygen leakage sources to the pump. The existence, magnitude, and position of the oxygen fugacity front were found to depend on the gas-phase composition, the relative locations of the leakage sources and the pump, the oxygen fugacity of the reference electrode, and the magnitude of the oxygen flux in the gas phase. 相似文献
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Hongbo Song Wei Wang Jiachen Sun Xianhui Wang Xianhua Zhang Sai Chen Chunlei Pei Zhi-Jian Zhao 《中国化学工程学报》2023,53(1):409-420
The oxygen distribution and evolution within the oxygen carrier exert significant influence on chemical looping processes. This paper describes the influence of oxygen bulk diffusion within FeVO4 oxygen carrier pellets on the chemical looping oxidative propane dehydrogenation (CL-ODH). During CL-ODH, the oxygen concentration at the pellet surface initially decreased and then maintained stable before the final decrease. At the stage with the stable surface oxygen concentration, the reaction showed a stable C3H6 formation rate and high C3H6 selectivity. Therefore, based on Fick’s second law, the oxygen distribution and evolution in the oxygen carrier at this stage were further analyzed. It was found that main reactions of selective oxidation and over-oxidation were controlled by the oxygen bulk diffusion. C3H8 conversion rate kept decreasing during this stage due to the decrease of the oxygen flux caused by the decline of oxygen gradient within the oxygen carrier, while C3H6 selectivity increased due to the decrease of over-oxidation. In addition, reaction rates could increase with the propane partial pressure due to the increase of the oxygen gradient within the oxygen carrier until the bulk transfer reached its limit at higher propane partial pressure. This study provides fundamental insights for the diffusion-controlled chemical looping reactions. 相似文献
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Diffuse reflectance laser flash photolysis was successfully employed to study the triplet states of dyes adsorbed on or chemically attached to cotton. This technique, together with the detection of singlet oxygen from dyes on cotton, made it possible to investigate the diffusion of oxygen in cotton fibres and the mobility of dyes adsorbed onto cotton. Absorption by the triplet states of aluminium phthalocyanine chloride and eosin and the phosphorescence of singlet oxygen produced by sensitisation with rose bengal was used to monitor oxygen diffusion and dye mobility by measuring differences in triplet lifetimes, singlet oxygen lifetimes and in signal intensities. It was found that swollen cotton allows diffusion of oxygen in the fibres. However, a noticeable effect on the triplet state of adsorbed aluminium phthalocyanine chloride is only observed if oxygen is removed or added by thorough evacuation or oxygenation of the samples over several days. Singlet oxygen was quenched dynamically by adsorbed dyes, which were found to be immobilised on the fibres, demonstrating that oxygen is mobile within the fibres at the molecular level. 相似文献
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Lijing Gou Blaine Opheim Chris N. Coretsopoulos 《Chemical Engineering Communications》2013,200(5):620-627
It is well known that the presence of oxygen in free radical polymerization systems leads to an inhibition period and a lowered ultimate conversion. In this contribution, we report a method for consuming molecular oxygen photochemically before the polymerization takes place, thereby allowing the reaction to proceed in an oxygen-free environment. The method is based on the generation of singlet oxygen by reaction of the ground state oxygen with the excited triplet state of the singlet oxygen generator (a porphyrin, Znttp). The singlet oxygen is then consumed by reaction with a second compound (the singlet oxygen trapper, dimethylanthracene). The possible factors that might affect the efficiency of the singlet oxygen generation/trapping processes were discussed and the effectiveness of a dimethylanthracene/Znttp combination for consumption of oxygen was investigated in two acrylate systems of different viscosity. 相似文献
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研究制作了一种可在线检测发酵过程中气相氧、溶解氧及中间补料、采样的特殊摇瓶,取得了摇瓶规模下的菌体摄氧率、氧传递系数等重要工程参数,并以摇瓶所得摄氧率(OUR)为依据进行发酵放大,通过质谱仪在线检测,验证发酵罐发酵与摇瓶发酵所得数据的异同。 相似文献