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电氨基磺酸盐和硫酸盐电解液电沉积Ni—Co合金的对比研究 总被引:2,自引:1,他引:1
通过大量实验对比了氨基磺酸盐和硫酸盐两种电解液电沉积Ni-Co合金Co含量的影响因素,以及Ni-Co合金沉积层的硬度、内应力与Co含量的关系,结果表明,与硫酸盐民解液相比,从氨基磺酸盐电解液中沉积的Ni-Co合金硬度高,内应力低。 相似文献
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脉冲电镀Ni-Co合金的研究 总被引:6,自引:0,他引:6
研究了脉冲参数对电沉积Ni-Co合金镀层的钴含量与硬度的影响。确定了最佳的脉冲参数。应用X射线和扫描电镜分析了Ni-CO合金镀层的结构和形貌。比较了脉冲电流(PC)和直流电流(DC)电镀Ni-Co合金镀层的各种性能。 相似文献
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电沉积Ni—Co合金及其结构研究 总被引:3,自引:0,他引:3
采用硫酸盐体系电沉积Ni-Co合金,研究了电镀工艺参数对镀层组成及电流效率的影响,测定了镀层结构。实验发现:在Ni-Co合金镀层中,当Co含量低于76wt%时,合金由两种面心立方结构的固溶体组成;Co含量介于76 ̄90wt%之间时,由面心立方和六方密排两种结构的固溶体组成;Co含量超过90wt%时,合金只有一种立方密排结构的固溶体相成。 相似文献
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通过对镀液组成及电镀参数的研究,确定了电沉积Zn-Ni-Co三元合金的工艺条件,获得的三元合金镀层其耐蚀性明显优于Zn-Ni合金镀层,且随钴含量增加耐蚀性增强。 相似文献
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化学镀Co—W—P三元合金的研究 总被引:4,自引:0,他引:4
研究了镀液中各组分及pH值与镀层中钨、磷含量的关系,获得Co73W16P11合金镀支,并通过人工汗液浸泡试验比较了Co-W-P合金镀层与不锈钢、Co-P、Ni-W-P、Ni-P合金镀层的耐蚀性。 相似文献
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研究了共沉积钨对化学镀Ni-P合金结构和性能的影响,研究结果表明,Ni-W-P合金镀层的晶化程度主要由磷含量决定而与钨含量无关;钨的共沉积对镀层硬度影响不大;在相同含量的情况下,Ni-W-P合金镀层的耐蚀性,耐磨性和热稳定性能都优于Ni-P合金。 相似文献
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The role of anion additives in the electrodeposition of nickel-cobalt alloys from sulfamate electrolyte 总被引:1,自引:0,他引:1
Nickel-cobalt alloys have been deposited from sulfamate electrolyte with acetate and citrate-anion additives and evaluated for structure and properties, such as microhardness, tensile strength, internal stress and high-temperature oxidation. XRD data show that at low Co content, the alloys exhibit face-centered cubic (fcc) growth orientations. Above 60% Co, the deposit is completely hexagonal close packed (hcp) with pronounced (100) and (110) lines. It seems likely that the Ni-Co deposits from typical sulfamate electrolyte at pH 5, as well as at current density higher than 5 A/dm2, include metal hydroxides. This is followed by the formation of a more strained structure. The high-temperature oxidation rate of the Ni-Co coating from sulfamate electrolyte at pH 5 is twice that of the alloy deposited from the electrolyte with anion additives. We believe that, citrate complexes of Ni and Co, which are assumed to be involved in alloy deposition, eliminate the incorporation of hydroxides into the deposits and enable low-internal-stress coating. The anion-modified bath offers stability of structure and properties of the alloy over a wide range of acidity and current density. 相似文献
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A 70 m thick Ni layer was electrodeposited from a sulfamate bath containing various amounts of ammonium ions onto a copper plate. The detailed microstructure of the Ni deposits was characterized using a plane-view and cross-sectional transmission electron microscopy (TEM). The textures of the Ni deposits were also determined using conventional X-ray diffraction. Experimental results indicated that ammonium ions suppressed the lateral growth of Ni deposits and favoured out growth, thus leading to the growth of [1 1 0] and [3 1 0] oriented deposits. A structural refinement effect was observed after ammonium ions were added to the sulfamate bath. Ammonium ions also increased the internal stress and hardness of the deposits. A general Hall–Petch relationship was observed for the dependence of deposit hardness on the average grain size of the Ni deposits. The adsorption of atomic hydrogen and the polar NH3 molecule explains the effect of ammonium ions on the electrocrystallization of Ni. 相似文献
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为提高Ni-Co合金镀层的致密性、硬度、耐磨性和耐蚀性等各方面性能,采用电沉积方法在镀层中引入原子态的碳。对Ni-Co-C代铬镀液中可能的碳源进行了筛选,并利用单因素试验对镀液中各组分的含量及工艺条件进行了优化,最终确定了草酸铵-柠檬酸铵体系为Ni-Co-C代铬镀液体系。得到的镀层外观与暗镍类似,结晶较细,平整性和均匀性稍差。优化的Ni-Co-C基础镀液稳定性好,长期放置不结晶、不沉淀;阴极电流效率稳定在45%~48%。 相似文献
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为了顺应RoHS、ELV指令的要求,开发了无铅/镉化学镀镍工艺。从镀层合金成分、中性盐雾实验、硬度、耐磨性、整平性、内应力、微观形貌、镀速、镀液稳定性和含磷量等方面与中磷化学镀镍工艺进行了比较。结果表明,无铅/镉化学镀镍工艺镀液更稳定,所得的镍镀层内应力稍高;硬度、耐蚀性、可焊性、附着力等性能相当;而耐磨性、耐污性、沉积速度和含磷量均高于中磷化学镀镍工艺,尤其是镀层亮度、微观结构和整平效应表现更优。 相似文献
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The paper describes the results of electrochemical investigations of Ni–Co deposition from a sulfamate bath in the presence of boric acid and two additives. The individual deposition of nickel was shown to be partly inhibited by the adsorption of sulfamate ions at low polarization; such inhibition was not observed for cobalt. The introduction of saccharin at 100 ppm, with a wetting agent seems to hinder sulfamate adsorption and Ni deposition departs at less cathodic potentials. The presence of cobalt has no effect on nickel deposition, whereas cobalt deposition is hindered by the presence of nickel in the bath. Galvanostatic deposition was carried out at the surface of a RDE and with a rotating cylinder Hull cell. At low current densities deposits with a Co content of approx. 40% were produced, but this content was shown to decrease with the applied current density. Examination of experimental data showed that cobalt deposition is diffusion-controlled and that Co content decreases with the applied current density relative to the limiting current density. 相似文献
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The electrodeposition of Zn-Co alloy deposits was studied by means of pulse-plating technique. The surface morphologies of Zn-Co alloy deposits were examined using scanning electron microscopy (SEM), and an attendant energy dispersive X-ray analyser (EDA) was used to analyse the composition of Zn-Co alloy deposits. Results obtained showed that the average current density and reverse current density amongst all the variables investigated had very strong effects on the cobalt content in the Zn-Co alloy deposits. It is possible to electrodeposit Zn-Co alloy coatings with a very wide cobalt content range of 10-90 wt.% by modulating pulse parameters. Grain size, surface appearance and internal stress in the deposits were also improved significantly by introducing reverse current. 相似文献