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采用Thermo-calc热力学计算软件,对SKD61钢在400~1600℃存在的平衡相进行了热力学计算,探讨了不同合金元素含量对回火析出相析出行为的影响,在此基础上设计出热处理工艺,并对热处理试样中的析出相经电解腐蚀后进行扫描电镜(SEM)和EDS研究。计算结果表明:SKD61钢中平衡析出相主要为MC、M7C3、M6C和M23C6,试样回火后的稳定析出相为MC和M23C6,合金元素V、C对MC相和M23C6相影响最大。SKD61钢热处理后的结果显示,该模具钢较合适的淬火温度区间为(1040±20)℃,回火温度的确定应以不出现粗大的M23C6碳化物相为宜。 相似文献
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采用力学性能检测、显微组织观察等方法,研究了回火热处理及焊后热处理对12Cr2Mo1V钢组织及力学性能的影响。试验结果表明:在回火及焊后热处理过程中,在晶界上会有析出相M23C6析出。保温时间越长,晶界上M23C6越多;而M23C6在晶界析出是导致12Cr2Mo1V钢力学性能下降的主要原因。 相似文献
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针对时效处理铸造镍基高温合金K52的碳化物,研究了其在强磁场作用下的组织形貌与化学成分变化规律。结果表明:在不同磁场条件下时效处理后,合金中碳化物MC和M23C6的组织形貌与分布基本相同,强磁场的施加对碳化物的组织形貌与分布并未产生显著影响,但经强磁场条件下时效处理后,MC和M23C6中强碳化物形成元素W、Mo、Nb和Ti含量有所增加,而弱碳化物形成元素Cr和非碳化物形成元素Co、和Ni含量显著降低。分析指出强磁场的施加可能提高了强碳化物形成元素与C间的亲和力,增强了其形成碳化物的倾向;同时其可能减弱了弱碳化物形成元素和非碳化物形成元素与C间的亲和力,从而使其在碳化物中存在的倾向也进一步降低。 相似文献
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国产T23钢高温时效时组织和力学性能的研究 总被引:1,自引:0,他引:1
采用光学显微镜、扫描电镜、透射电镜观察和拉伸、冲击试验等方法,研究了国产T23钢在600 ℃时效时的组织变化和力学性能.结果表明,T23钢在600 ℃时效时随着时效时间的延长,T23钢中M23C6型碳化物不断粗化,粒状贝氏体形貌逐渐退化.时效时间较短时,主要是M23C6型碳化物粗化引起T23钢力学性能下降;时效时间较长时,主要是粒状贝氏体形貌的变化导致T23钢力学性能下降,同时,M23C6的球化及其向M6C的转变、亚晶的形成和W、Mo固溶强化的降低加快了T23钢力学性能的下降. 相似文献
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研究Inconel690合金在不同的热处理条件下晶粒大小和晶界析出物.结果表明:当固溶处理温度低于1100℃时,晶粒尺寸变化不大,当温度超过1150℃时,晶粒开始显著长大,建议固溶处理应在1100℃以下.Incone1690合金经固溶处理和特殊热处理(TT处理)后,晶界的主要析出物和沉淀物为Ti(C,N)和M23C6,析出物尺寸随热处理温度的升高而增大,分布的形态主要呈断续和半连续状. 相似文献
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形变热处理(TMT)可以有效改善9%~12%Cr铁素体/马氏体钢的力学性能。为了更好的理解形变热处理对钢材力学性能的影响,尤其是对钢中析出相的影响,本研究利用透射电镜对形变热处理后铁素体/马氏体钢P92中的MX、M23C6和M2X 3种析出相的形成机理进行了着重分析。结果表明,由于富铌/钒的M(C,N)和富铬M23C6碳化物的析出温度高于富铬M2(C,N)碳氮化物的析出温度,且富铬M2X的形核体积自由能的改变量最小,形变热处理过程中富铬M2X相优先在P92钢的基体中析出。 相似文献
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采用高温快速回火方法,对40Cr钢及45、T10钢进行了高于Ac1以上温度的高温回火试验,并与传统回火工艺进行了比较,建立了高温回火时间与传统回火温度的对应关系.试验结果表明用高温快速回火后,其组织和力学性能与传统工艺回火后的基本相同,且所用的回火时间可以大大缩短,并可以避免回火脆性. 相似文献
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通过Gleeble-3800热模拟试验机研究了变形温度850~1200 ℃,应变速率0.1 ~10 s-1条件下Ti微合金化非调质钢的奥氏体动态再结晶行为。分析变形温度、变形速率、碳氮化物的析出行为对奥氏体动态再结晶的影响,计算动态再结晶激活能,获得动态再结晶状态图和热加工图。结果表明,随着Ti含量从0增加为0.042%和0.063%,钢中碳氮化物的析出量分别为0%、0.040%和0.038%,呈现出先增加后减少的趋势,相应的动态再结晶的激活能分别为360.218、394.015和378.247 kJ/mol,0.042%Ti含量的非调质钢激活能最高。通过功率耗散图和塑性失稳图的叠加得到了热加工图,获得了Ti微合金化非调质钢的最佳热加工工艺范围是900~1050 ℃的变形温度,0.1~0.2 s-1的变形速率和1100~1200 ℃变形温度,0.1~4 s-1变形速率。 相似文献
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为研究磁场作用下热处理工艺对超高强度钢组织调控及碳化物种类、形态、尺寸和演变规律的影响,采用OM、SEM、TEM、EBSD和力学性能测试等技术手段研究了磁场作用对含有Nb、V、Ti等微合金元素的25CrMo48V超高强度钢中组织演变与力学性能的影响。试样均在1000 ℃下进行30 min奥氏体化处理,水淬之后在1 T磁场作用下,在200~600 ℃温度范围内回火1 h。结果表明,磁场的施加会抑制马氏体板条合并,促进M23C6和M7C3型碳化物的析出。经外加1 T磁场不同温度回火后,试样的硬度均高于未加磁场的常规回火处理试样,而其强度低于常规回火处理。 相似文献
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M. Mujahid A. K. Lis C. I. Garcia A. J. DeArdo 《Journal of Materials Engineering and Performance》1998,7(2):247-257
The structural steels used in critical construction applications have traditionally been heat-treated low-alloy steels. These
normalized and/or quenched and tempered steels derive strength from their carbon contents. Carbon is a very efficient and
cost-effective element for increasing strength in ferrite-pearlite or tempered martensitic structures, but it is associated
with poor notch toughness. Furthermore, it is well known that both the overall weldability and weldment toughness are inversely
related to the carbon equivalent values, especially at high carbon contents. The stringent control needed for the welding
of these traditional steels is one of the major causes of high fabrication costs.
In order to reduce fabrication cost while simultaneously improving the quality of structural steels, a new family of high-strength
low-alloy steels with copper additions (HSLA-100) has been developed. The alloy design philosophy of the new steels includes
a reduction in the carbon content, which improves toughness and weldability. 相似文献
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The influence of heat treating on mechanical properties as well as on the sliding wear behavior of sintered Fe-1.5Mo-0.7C steels was experimentally studied. The microstruc-tures of sintered steels change from upper bainite to martensite, tempered martensite, pearlite and lower bainite depending on the heat treating conditions. Heat treating increases the hardness of sintered steels but high tempering temperature, i.e. 700℃, causes the hardness to be even lower than that of the as-sintered ones. The impact energy of sintered steels increases with increasing tempering temperature and arrives the highest at 700℃, while the steels tempered at 200℃ have the highest transverse rupture strength. Austempering results in fair good overall properties, such as hardness, impact energy, and transverse rupture strength. When the sintered steels were austempered, oil-quenched or tempered below 400℃ after quenched, the wear coefficient becomes considerably lower. Fair high hardness, such as HV30 > 380, and structur 相似文献
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Govindaraj Magudeeswaran Visvalingam Balasubramanian Gankidi Madhusudhan Reddy 《Metals and Materials International》2008,14(4):523-529
Quenched and tempered (Q&T) steels are prone to hydrogen induced cracking after welding. Austenitic stainless steel (ASS)
welding consumables are traditionally used for welding of high hardness, Q&T steels as they have higher solubility for hydrogen
in the austenitic phase. The use of stainless steel consumables for a non stainless steel base metal is not economical. Hence,
in the present work, an attempt was made to explore alternate consumables for welding Q&T steels. Flux cored arc welding process
was used to fabricate the joints using austenitic stainless steel and low hydrogen ferritic steel consumables. The joints
fabricated using low hydrogen ferritic steel consumables exhibited superior fatigue performances than the joints fabricated
using ASS consumables. 相似文献
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The influence of a high magnetic field on carbide precipitation during the tempering of a 2.25 Cr–Mo steel was investigated by means of transmission electron microscopy. As-quenched specimens were tempered at 200, 550 and 700 °C for various times in the absence and presence of a 12 T magnetic field. Experimental results indicate that the applied high magnetic field effectively promotes the precipitation of M23C6 carbides at low temperature (200 °C) and M7C3 and M23C6 carbides at intermediate temperature (550 °C). The increased Fe content in the M23C6 and M7C3 carbide significantly increases the magnetization. The magnetic Gibbs free energy, which influenced the alloy carbide precipitation behavior, was considered to be mainly determined by the intrinsic magnetization energy for M23C6 and M7C3 carbides. With the increase of the tempering temperature (700 °C), there was no pronounced effect of the high magnetic field on the precipitation sequence and the concentration of substitutional solute atoms in paramagnetic carbides. The investigation of alloy carbide precipitation under high magnetic fields could contribute to a better understanding of phase transformation of alloy carbides and to the heat treatment and fabrication of heat-resistant steels. 相似文献
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Steels with elasticity limits between 650 and 680 MPa include thermomechanical steels and quenched and tempered steels. Thermomechanical steels have excellent weldability, but, nevertheless, require fillers with low diffusible H2 levels, and a rigorous control over the welding operations, due to the molten zone. Quenched and tempered steels require almost automatic recourse to preheating, and frequently post-heating, but at moderate temperatures. The heterogeneity of the commercial range of base metals available, and the poverty of the range of filler materials with very high elasticity limits, are crucial problems. The risk of cold cracking in the molten zone is very high and, sadly, less well understood than that of cold cracking in the HAZ. Given that the maintenance of good mechanical characteristics requires limiting the T r 800–500, the weldability range is very narrow. The welding of these steels is not intrinsically complex, but requires considerable rigour. 相似文献
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本文用示波冲击弯曲试验、扫描电镜断口分析和金属薄膜透射电子显微分析,研究了高温回火后34CrNiMo和40CrNiMo钢的缺口敏感性。结果表明:V型缺口试样的裂纹扩展功能较好地反映材料的缺口敏感性。回火温度升高,试验钢的缺口敏感性降低。回火稳定性好的材料缺口敏感性大。 相似文献