Fatigue and fracture of a 316 stainless steel metal matrix composite reinforced with 25% titanium diboride

Fatigue and fracture mechanisms have been studied in a steel-based metal matrix composite (MMC), comprising a 316L austenitic matrix reinforced with 25 wt.% particulate titanium diboride (TiB₂). The fracture toughness was determined in the as-HIPped condition as being slightly below 30 MPa√m. Fatigue crack growth rates have been determined, and corrected for the effects of crack closure. The fracture surfaces have been studied to determine the mechanisms of damage during crack advance, which are determined as matrix fatigue, reinforcement particle fracture, and ductile rupture of the matrix. We show that the occurrence of damage mechanisms during fatigue of the material is linked to K_max, rather than to ΔK. This is rationalised in terms of a semi-cohesive process zone within the monotonic plastic zone ahead of the crack tip.     

Crack closure and fatigue crack growth near threshold of a metastable austenitic stainless steel

In this paper R-ratio effects on fatigue crack growth near threshold region of a metastable austenitic stainless steel (MASS) in two different conditions, i.e. annealed and cold rolled, is investigated. The authors present two approaches to correlate FCGR data for R = 0.1, 0.3, 0.5, 0.7 and K_max = 23 MPa√m using a two-parameters approach (ΔK, K_max and α in Kujawski’s model) and crack closure model (using Elber’s K_op and in Donald’s ACRn2 approaches). The K_op and ACRn2 were experimentally measured on a single edge tension specimens. The K_op measurements were performed using a modified method and based on ASTM standards. While the two driving force approaches correlate data well in the Paris region, they fail to correlate them in the threshold region. However, this correlation can be improved in the threshold region when a different α value from the Paris region is used. The authors indicated that two different mechanisms operate; one in the Paris region and another in the near threshold. Hence, they proposed to combine the two-parameter and crack closure approaches where ΔK is replaced by ΔK_eff (estimated by a new method proposed in this paper), which is shown to correlate the FCGR data for different stress ratios for annealed steel. The correlation for cold rolled condition shows improvement with the new approach but is not as good as for the annealed one. The author further suggests to modify K_max in the two-parameter approach.     

Acoustic emission study of fatigue crack closure of physical short and long cracks for aluminum alloy LY12CZ

Crack closure of physical short and long cracks of LY12CZ aluminum alloy during fatigue process was investigated using acoustic emission (AE) technique. Results showed that the effective fatigue crack growth curve (da/dN vs. ΔK_eff) of physical short and long cracks obtained by the AE technique was consistent with the effective fatigue crack growth curve at high stress ratio (R = 0.8), which implied that the AE technique could measure the crack closure level, especially for physical short crack. The growth rate of physical short crack was much higher than that of long crack at the same ΔK, and the lower crack closure level of short crack was the main reason.     

Microstructural characterization and high cycle fatigue behavior of investment cast A357 aluminum alloy

In order to observe the influence of strontium (Sr) modification and hot isostatic pressing (HIP) on an aluminum–silicon cast alloy A357 (AlSi7Mg0.6), the microstructure and the high cycle fatigue behavior of three batches of materials produced by investment casting (IC) were studied. The parts were produced by an advanced IC proprietary process. The main process innovation is to increase the solidification and cooling rate by immersing the mold in cool liquid. Its advantage is to produce finer microstructures. Microstructural characterization showed a dendrite arm spacing (DAS) refinement of 40% when compared with the same part produced by conventional investment casting. Fatigue tests were conducted on hourglass specimens heat treated to T6, under a stress ratio of R = 0.1 and a frequency of 25 Hz. One batch of material was unmodified but two batches were modified with 0.007% and 0.013% Sr addition, from which one batch was submitted to HIP after casting. Results reported in S–N diagrams show that the addition of Sr and the HIP process improve the 10⁶ cycles fatigue strength by 9% and 34% respectively. Scanning electron microscopy (SEM) observation of the fracture surfaces showed a variety of crack initiation mechanisms. In the unmodified alloy, decohesion between the coarse Si particles and the aluminum matrix was mostly observed. On the other hand, in the modified but non HIP-ed alloy, cracks initiated from pores. When the same alloy was subjected to HIP, a competition between crystallographic crack initiations (at persistent slip bands) and decohesion/failure of intermetallic phases was observed. When compared to fatigue strength reported for components produced by permanent mold casting, the studied material are more resistant to fatigue even in the unmodified and non HIP-ed states.     

Diffusion bonding of titanium alloy to micro-duplex stainless steel using a nickel alloy interlayer: Interface microstructure and strength properties

In the present study, diffusion bonding of titanium alloy and micro-duplex stainless steel with a nickel alloy interlayer was carried out in the temperature range of 800–950 °C for 45 min under the compressive stress of 4 MPa in a vacuum. The bond interfaces were characterised by scanning electron microscopy, electron probe microanalyzer and X-ray diffraction analysis. The layer wise Ni₃Ti, NiTi and NiTi₂ intermetallics were observed at the nickel alloy/titanium alloy interface and irregular shaped particles of Fe₂₂Mo₂₀Ni₄₅Ti₁₃ was observed in the Ni₃Ti intermetallic layer. At 950 °C processing temperature, black island of β-Ti phase has been observed in the NiTi₂ intermetallics. However, the stainless steel/nickel alloy interface indicates the free of intermetallics phase. Fracture surface observed that, failure takes place through the NiTi₂ phase at the NiA–TiA interface when bonding was processed up to 900 °C, however, failure takes place through NiTi₂ and β-Ti phase mixture for the diffusion joints processed at 950 °C. Joint strength was evaluated and maximum tensile strength of ∼560 MPa and shear strength of ∼415 MPa along with ∼8.3% ductility were obtained for the diffusion couple processed at 900 °C for 45 min.     

Short cracks initiated in Al 6013-T6 with the focused ion beam (FIB)-technology

The fatigue crack growth behaviour of short corner cracks in the Aluminium alloy Al 6013-T6 was investigated. The aim was to determine the crack growth rates of small corner cracks at a stress ratio of R = 0.1, R = 0.7 and R = 0.8 and to find a possible way to predict these crack growth rates from fatigue crack growth curves determined for long cracks. Corner cracks were introduced into short crack specimens, similar to M(T) – specimens, at one side of a hole (Ø = 4.8 mm) by cyclic compression (R = 20). The precracks were smaller than 100 μm (notch + precrack). A completely new method was used to cut very small notches (10–50 μm) into the specimens with a focussed ion beam. The results of the fatigue crack growth tests with short corner cracks were compared with the long fatigue crack growth test data. The short cracks grew at ΔK-values below the threshold for long cracks at the same stress ratio. They also grew faster than long cracks at the same ΔK-values and the same stress ratios. A model was created on the basis of constant K_max-tests with long cracks that gives a good and conservative estimation of the short crack growth rates.     

22 Cr 5 Ni duplex and 25 Cr 7 Ni superduplex stainless steel: Hydrogen influence on fatigue crack propagation resistance

Duplex stainless steels (DSS) fatigue crack propagation resistance is strongly affected by both microstructure and environment. In this work, environment influence on the fatigue crack propagation in a 22 Cr 5 Ni duplex and in a 25 Cr 7 Ni superduplex stainless steels is investigated considering three different stress ratios (R = K_min/K_max = 0.1, 0.5, 0.75). Tests are performed according to ASTM E 647 standard, both in air and under hydrogen charging conditions (0.1 M H₂SO₄ + 0.01 M KSCN aqueous solution, ?0.9 V/SCE). Crack fracture surfaces are extensively analysed by means of a scanning electron microscope. Furthermore, crack paths are investigated by means of a crack profile analysis performed through a light optical microscope. Nickel coated fracture surface sections obtained for constant ΔK values are considered in order to analyse the loading (R values) and environment influence on fatigue crack paths.     

Effect of heat treatment and Fe content on the microstructure and mechanical properties of die-cast Al–Si–Cu alloys

The effect of solution and ageing heat treatment on the microstructure and mechanical properties of the die-cast Al–9 wt.%Si–3.5 wt.%Cu alloys containing 0.1–1.0 wt.% Fe was investigated. The results showed that the dendritic primary α-Al phase was varied from 20 to 100 μm in size and the globular α-Al grains were smaller than 10 μm in size. The Fe-rich intermetallics exhibited coarse compact or star-like shapes with the sizes from 10 to 20 μm and the fine compact particles at an average size of 0.75 μm. The solution treatment of the alloys could be achieved in a short period of time, typically 30 min at 510 °C, which dissolved the Cu-rich intermetallics into the primary α-Al phase and spheroidised the eutectic Si phase. During the subsequent ageing treatment, numerous fine precipitates of θ′ and Q′ phases were formed to provide effective strengthening to the α-Al phase, significantly improving the mechanical properties. Therefore, Fe content in the die-cast Al–Si–Cu alloys needs to be controlled at a low level in order to obtain the improved ductility and strength under solution and aged condition.     

The effects of texture and grain morphology on the fracture toughness and fatigue crack growth resistance of nanocrystalline platinum films

The fracture toughness and fatigue crack growth resistance of nanocrystalline materials are significantly affected by the thickness of the specimen. In this work we relate the mechanical properties of nanocrystalline platinum films to their texture and grain morphology. Tensile, creep and fatigue testing of annealed, ∼1 μm films resulted in mechanical properties similar to the as-received films (yield strength of ∼1.2 GPa, fracture toughness ∼17.8 MPa √m, and a fatigue crack growth power law exponent of ∼4.2). However, the breakdown of the initially columnar grain morphology had a marked effect on the transition point from an intergranular to transgranular fatigue cracking mode. Finite element modeling suggests that cyclic (fatigue) grain coarsening and the transition from inter- to transgranular cracking modes are a result of the relative importance of dislocation slip accommodation on in-plane and through-thickness oriented slip directions.     

Mechanochemical synthesis of a La0.67Ce0.21Nd0.08Pr0.04Ni5 intermetallic compound

The mechanochemical synthesis of a La_0.67Ce_0.21Nd_0.08Pr_0.04Ni₅ intermetallic is studied. The intermetallic is synthesised from a mixture of LaNi₅ and La_0.25Ce_0.52Nd_0.17Pr_0.06Ni₅. The processes controlling the mechanical alloying are characterised as a function of integrated milling time (t_m). Effects of fracture and cold welding on the sample are identified by scanning electron microscopy. Compositional, microstructural and structural changes are analysed by energy dispersive spectroscopy and X-ray diffraction. The powder obtained has a particle size distribution of 9 ± 1 μm with an average crystallite size of 370 ± 10 Å and strain >10%. The intermetallic compound is annealed in Ar to increase crystallite size and to release strain. The structure is refined by the Rietveld method. Cell parameters are a = 4.982(2) Å and c = 3.980(9) Å, respectively. The advantage of the synthesis method using intermetallics instead of metals/alloys is discussed along with the characteristics of the powder obtained.     

Effect of welding residual stresses on fatigue crack growth thresholds

Fatigue crack growth thresholds ΔK_th were determined for friction stir welded butt joints made from aluminium alloys AA2024 and AA6013. Plotting the thresholds as a function of load ratio R showed distinctly higher amounts for welded joints as compared to those for parent material at small load ratios, but differences became smaller with increasing load ratio, until thresholds became finally identical for the highest R values. Applying Döker’s concept of two controlling parameters, namely ΔK and K_max [1], and plotting ΔK_th versus K_max, however, revealed that the effective threshold ΔK_th,eff determined at very high R ratios was nearly independent on the alloy and, simultaneously, was identical for parent material and respective welded joints. Thus, differences in threshold behaviour were only caused by the second threshold K_max,th, which was significantly higher for welded joints as compared to parent material. Differences in K_max,th coincided with compressive residual stresses determined by cut-compliance measurements in terms of stress intensity factors K_rs acting at the crack tip. Based on the analytical approach described by Döker [1], only one characteristic K_rs value was needed to calculate all thresholds of welded joints for 0 ⩽ R ⩽ 1 provided a base material master curve is available.     

Effects of Si addition on mechanical properties and superelasticity of Ti–7.5Nb–4Mo–2Sn shape memory alloy

Effects of 0–2.1 at.% Si additions on microstructure and mechanical properties of a Ni-free biomedical superelastic β-Ti alloy, Ti–7.5 at.%Nb–4 at.%Mo–2 at.% Sn (Ti–7.5Nb–4Mo–2Sn), were investigated. The alloys after annealing at 973 K mainly contain β and α″. As the concentration of Si is higher than 1 at.%, Ti₅Si₃ particles can be found in the alloys, and the number density of the particles increases with the increasing of silicon’s concentration. The addition of Si promotes the strength of the Ti–7.5Nb–4Mo–2Sn due to the Si solid solution strengthening effect and fine Ti₅Si₃ precipitates. However, as the Si concentration reaches 2.1%, the alloy exhibits a brittle fracture. The 0.5–1.6 at.% Si additions improve the superelasticity of the Ti–7.5Nb–4Mo–2Sn alloy by increasing the critical stress for inducing martensite (σ_SIM).     

The microstructure,hardness and tensile properties of Al–15%Mg2Si in situ composite with yttrium addition

Current study investigates the effect of different concentrations of yttrium (0.1–1.0 wt.%) on the microstructure, hardness and tensile properties of Al–15%Mg₂Si cast composite. The microstructural study of the composite revealed the presence of both primary and secondary Mg₂Si phases in all specimens and also Y-containing intermetallics at higher concentrations of the respected element. It was also found that Y addition does not change the size and morphology of primary Mg₂Si particles considerably, but the pseudo-eutectic Mg₂Si was changed from a flake-like morphology to fine fibrous or rod-like. The results obtained from mechanical testing demonstrated that the addition of Y increases both hardness and ultimate tensile strength (UTS) values. Further investigations on tensile test revealed optimum Y level (0.5 wt.%) for improving both UTS and elongation values. Fracture surfaces via scanning electron microscopy (SEM) revealed that all specimens with large facets of primary Mg₂Si particles succumb to brittle fracture. The large and brittle Mg₂Si phases may act as crack initiators, while fine rod-like morphology of eutectic Mg₂Si in Al–Mg₂Si–0.5Y can be a barrier to the propagation of cracks and thus enhance the elongation values. At higher Y contents, an intermetallic phase (Al₂Y) introduced on eutectic cell boundaries, appears to be the favored path for crack propagation.     

Microstructure and thermal expansion behavior of spray-deposited Al–50Si

The evolution of microstructure and coefficient of thermal expansion (CTE) of the Al–50Si (wt.%) alloy manufactured by spray deposition followed by hot isostatic pressing (HIP) are systematically investigated. The results indicate that the microstructure of the deposited alloy is composed of primary Si with average size of 12.5 ± 0.1 μm and α-Al. The CTE of the deposited alloy is higher than the corresponding alloy produced by casting due to the high solid solubility of Al in Si. After HIP, the CTE is lower than the parent as-deposited alloy owing to the high solid solubility of Si in Al. The residual thermal stress results in a higher CTE during the second heating as a result of the CTE mismatch between the Al matrix and the primary Si particles. Furthermore, the measured CTE value is in good agreement with the Turner model after complete densification by HIP at 843 K.     

Estimation of fatigue crack growth behavior for small-sized C-shaped inside edge-notched tension (CIET) specimen using compliance technique

Being restricted by the relative larger size requirement, traditional and standard fracture specimens are not applicable for the estimation of fatigue crack growth behavior of some very finite-sized components and precious materials. This study develops a small-sized C-shaped inside edge-notched tension (CIET) specimen which has an advantage of specimen minimization and a wide range of adaptability. A systemic compliance technique for estimating fatigue crack growth behavior of CIET specimen has been successfully constructed and experimentally verified. Groups of fatigue crack propagation rate tests of both CIET specimen and CT specimen for 5083-H112 aluminum alloy were carried out. The resulted da/dN ∼ ΔK curves are heavy affected by specimen configuration and load ratio, and the difference between these da/dN ∼ ΔK curves has been successfully removed by introducing the correction of plasticity-induced crack closure effect. Consequently, the feasibility of CIET specimen for estimating fatigue crack propagation behavior for small-sized components and precious materials has been evidently confirmed.     

Microstructural development of diffusion-brazed austenitic stainless steel to magnesium alloy using a nickel interlayer

The differences in physical and metallurgical properties of stainless steels and magnesium alloys make them difficult to join using conventional fusion welding processes. Therefore, the diffusion brazing of 316L steel to magnesium alloy (AZ31) was performed using a double stage bonding process. To join these dissimilar alloys, the solid-state diffusion bonding of 316L steel to a Ni interlayer was carried out at 900 °C followed by diffusion brazing to AZ31 at 510 °C. Metallographic and compositional analyses show that a metallurgical bond was achieved with a shear strength of 54 MPa. However, during the diffusion brazing stage B₂ intermetallic compounds form within the joint and these intermetallics are pushed ahead of the solid/liquid interface during isothermal solidification of the joint. These intermetallics had a detrimental effect on joint strengths when the joint was held at the diffusion brazing temperature for longer than 20 min.     

The ambient and high temperature deformation behavior of Al–Si–Cu–Mg alloy with minor Ti,Zr, Ni additions

The principal aim of the present work was to investigate the effects of minor additions of nickel and zirconium on the strength of cast aluminum alloy 354 at ambient and high temperatures. Tensile properties of the as-cast and heat-treated alloys were determined at room temperature and at high temperatures (190 °C, 250 °C, 350 °C). The results show that Zr reacts only with Ti, Si and Al. From the quality index charts constructed for these alloys, the quality index attains minimum and maximum values of 259 MPa and 459 MPa, in the as-cast and solution-treated conditions; also, maximum and minimum values of yield strength are observed at 345 MPa and 80 MPa, respectively, within the series of aging treatments applied. A decrease in tensile properties of ∼10% with the addition of 0.4 wt.% nickel is attributed to a nickel–copper reaction. The reduction in mechanical properties due to addition of different elements is attributed principally to the increase in the percentage of intermetallic phase particles formed during solidification; such particles act as stress concentrators, decreasing the alloy ductility. Tensile test results at ambient temperatures show a slight increase (∼10%) in alloys with Zr and Zr/Ni additions, particularly at aging temperatures above 240 °C. Additions of Zr and Zr + Ni increase the high temperature tensile properties, in particular for the alloy containing 0.2 wt.% Zr + 0.2 wt.% Ni, which exhibits an increase of more than 30% in the tensile properties at 300 °C compared with the base 354 alloy.     

Dry sliding wear behaviour of hypereutectic Al–Si piston alloys containing iron-rich intermetallics

The effect of iron-rich intermetallics on the wear behaviour of Al–Si hypereutectic alloys has been studied. Dry sliding wear tests have been conducted using a pin-on-disk machine under different normal loads of 18, 51, 74 and 100 N and at a constant sliding speed of 0.3 m/s. The addition of 1.2 wt.% Fe to the LM28 alloy increased the wear rate due to the formation of needle beta intermetallics. Introducing 0.6 wt.% Mn to the iron-rich alloy changed the beta intermetallics into the modified alpha phases, and therefore reduced the detrimental effect of iron. TIG welding method as a surface melting process was applied on the iron and manganese containing alloy and led to a fine microstructure and increased the wear resistance.     

Effect of grain size on fatigue-crack growth in 2524 aluminium alloy

In this study, industrial 2524 aluminium alloy plates with various grain sizes (0.8–298 μm) were prepared by cold rolling and heat treatment. The fatigue-crack-growth rate was studied as a function of grain size through fatigue tests and microstructural observations. The results showed that grain refinement led to a decrease in the resistance against fatigue-crack growth. Besides, the levels of crack closure in coarse-grained samples were higher than those in fine-grained ones at low values of the range of the stress intensity factor K, ΔK. This phenomenon was predicted and explained well by the crack-deflection model.     

Effects of solidification structure on fatigue crack growth in rheocast and thixocast Al–Si–Mg alloys

Fatigue crack growth test was performed for rheocast and thixocast Al–Si–Mg aluminum alloys. At small stress intensity factor range (ΔK), fatigue crack growth (FCG) rate of sample with coarse acicular Si particles decreased slightly compared with specimen with small acicular Si particles. However, at large ΔK, fatigue crack growth rate of specimen with coarse acicular Si particles drastically increased. This is because large acicular Si particles induce high strain hardening at small ΔK, but such particles are easily cracked with the increase in ΔK. Morphology of the Si particles strongly affects striation formation.