共查询到19条相似文献,搜索用时 312 毫秒
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为了提高Custom 465马氏体沉淀硬化不锈钢的耐磨性,分别在440、480和520℃对580℃时效后的样品进行了2 h的盐浴渗氮,使用显微硬度计、X射线衍射仪、电化学工作站、球盘式摩擦磨损仪、表面轮廓仪、扫描电镜等设备,研究渗氮温度对Custom 465钢表面物相、硬度、渗层显微形貌、耐蚀性及耐磨性的影响.随着渗氮温度升高,耐蚀性逐渐降低,但表面硬度增加,520℃处理后表面硬度增大到1240 HV,较未处理试样的400 HV明显上升,渗层厚度达到22μm.440℃渗氮后表面物相为氮在马氏体基体中过饱和的α'N,点蚀电位降低约60 m V;480℃时有少量CrN相析出,引起点蚀电位降低约180 mV,同时磨损体积下降约43%;520℃时CrN相的含量明显升高,自腐蚀电位降低约70 mV,无明显的稳态钝化区,磨损体积降低82%,减磨效果明显. 相似文献
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利用SRV-4高温摩擦磨损试验机对0.3C-Cr-W高性能渗氮轴承钢进行了微动磨损试验,分别改变载荷和频率,研究了表面离子渗氮对摩擦磨损性能的影响.结果表明:试验钢表面渗氮后渗层厚度为238.45 μm,其中白亮的化合物层厚度为9μm,主要为γ'-Fe4N和VN两种相;渗氮后试样表面的白亮化合物层具有减小摩擦因数和提高耐磨性的作用;渗氮前后试验钢的磨损机制相同,前期以粘着磨损为主,以磨粒磨损为辅;磨损后期转变为以磨粒磨损为主,以粘着磨损为辅;渗氮前试验钢的磨损体积是渗氮后的3倍以上,表面离子渗氮后试验钢的抗微动磨损性能有明显的提高. 相似文献
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采用等离子弧堆焊技术,在Q235钢表面堆焊镍基合金粉末,通过工艺试验、硬度试验、磨损试验和显微组织观察分析,研究了等离子弧堆焊层的常规性能。试验结果表明:镍基合金粉末堆焊层硬度和耐磨性较基体有显著提高。 相似文献
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齿轮钢中渗氮层深度和含量测定,对衡量渗氮工艺是否合适至关重要。实验以20MnCrS5齿轮钢为试验材料,摸索出电子探针法(EPMA)测定渗氮层的最佳试验参数为:加速电压10 kV,束流100 nA,束斑直径1 μm,步径1 μm。首先,利用电子探针的面扫描功能,对渗氮层从表面到基体进行二维和三维面分布定量化分析,从结果可以看出,表层有一个富集的氮化层,厚度约为10 μm,最高处氮含量(质量分数,下同)达到8.46%,氮化层以内的氮含量在0.84%左右,渗氮层总深度约为600 μm。其次,对比了电子探针线分析法与硬度法的结果,电子探针法测得的渗氮层总深度与硬度法测得的基体硬度值时深度一致,都约为600 μm,且能同时给出不同渗氮层厚度与氮含量的变化曲线。因此,电子探针法作为硬度法的补充方法,可以同时得到准确的渗氮层深度和氮含量,可以作为衡量渗氮工艺是否合适的依据。 相似文献
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齿轮钢中渗氮层深度和含量测定,对衡量渗氮工艺是否合适至关重要。实验以20MnCrS5齿轮钢为试验材料,摸索出电子探针法(EPMA)测定渗氮层的最佳试验参数为:加速电压10 kV,束流100 nA,束斑直径1 μm,步径1 μm。首先,利用电子探针的面扫描功能,对渗氮层从表面到基体进行二维和三维面分布定量化分析,从结果可以看出,表层有一个富集的氮化层,厚度约为10 μm,最高处氮含量(质量分数,下同)达到8.46%,氮化层以内的氮含量在0.84%左右,渗氮层总深度约为600 μm。其次,对比了电子探针线分析法与硬度法的结果,电子探针法测得的渗氮层总深度与硬度法测得的基体硬度值时深度一致,都约为600 μm,且能同时给出不同渗氮层厚度与氮含量的变化曲线。因此,电子探针法作为硬度法的补充方法,可以同时得到准确的渗氮层深度和氮含量,可以作为衡量渗氮工艺是否合适的依据。 相似文献
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采用X射线衍射、扫描电镜及显微硬度等技术,综合比较和分析了H13模具钢在不同热处理状态下经相同气体渗氮处理后表层的组织结构和硬度。结果表明,经淬火+二次回火和淬火+三次回火的试样渗氮后,渗氮层厚度均达到约0.24 mm,致密化合物层厚度达到10 μm以上,表面硬度HV达到950 (约为HRC 67)。这两种热处理状态下渗层中化合物层均由ε相(Fe2N)、γ′相和Fe3O4构成,扩散层均由α Fe相、ε相(Fe3N)、CrN相和γ′相构成,但各相含量有差别。而淬火态和淬火+一次回火态的渗氮试样未能获得具有足够好综合性能的渗层组织。 相似文献
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Effects of the Process Parameters on the Microstructure and Properties of Nitrided 17-4PH Stainless Steel 总被引:1,自引:0,他引:1
Jun Wang Yuanhua Lin Dezhi Zeng Jing Yan Hongyuan Fan 《Metallurgical and Materials Transactions B》2013,44(2):414-422
The effects of process parameters on the microstructure, microhardness, and dry-sliding wear behavior of plasma nitrided 17-4PH stainless steel were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and wear testing. The results show that a wear-resistant nitrided layer was formed on the surface of direct current plasma nitrided 17-4PH martensitic stainless steel. The microstructure and thickness of the nitrided layer is dependent on the treatment temperature rather than process pressure. XRD indicated that a single α N phase was formed during nitriding at 623 K (350 °C). When the temperature increased, the α N phase disappeared and CrN transformed in the nitrided layer. The hardness measurement demonstrated that the hardness of the stainless substrate steel increased from 320 HV0.1 in the untreated condition increasing to about 1275HV0.1 after nitriding 623 K (350 °C)/600 pa/4 hours. The extremely high values of the microhardness achieved by the great misfit-induced stress fields associated with the plenty of dislocation group and stacking fault. Dry-sliding wear resistance was improved by DC plasma nitriding. The best wear-resistance performance of a nitrided sample was obtained after nitriding at 673 K (350 °C), when the single α N-phase was produced and there were no CrN precipitates in the nitrided layer. 相似文献
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Effect of ion nitriding modification on surface hardness, corrosion resistance and magnetostriction of (Tb0.3Dy0.7)Fe1.95 alloy was investigated. Results demonstrated that a 100-200 nm thick nitrided layer was formed on the sample surface by ion nitriding treatment, which improved obviously surface hardness, wear, and corrosion resistance properties of (Tb0.3Dy0.7)Fe1.95 alloys. The surface hardness was increased from HV587 to HV622 after ion nitriding at 650 K for 6 h. Furthermore, ion nitriding treatment had almost no influence on mag-netostrictive performance as the nitrided layer was quite thin and the treatment temperature was not too high. The results might provide us a new approach for surface modification of (Tb0.3Dy0.7)Fe1.95 alloy. 相似文献
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This study investigates the effect of plasma nitriding parameters on corrosion susceptibility of 17-4 PH stainless steel in 3.5?wt-% NaCl solution. In this regard, 17-4 PH stainless steel was plasma nitrided at 400°C for 5 and 10?h, 450°C for 5?h and 500°C for 5?h. Cross-sectional images after nitriding process showed that a uniform nitrided layer has been formed on steel substrate. Depending on the temperature and time of the nitriding process, different phases were formed in the nitrided layer. This affected general corrosion and pitting corrosion performance of 17-4 PH stainless steel in 3.5?wt-% NaCl solution. While precipitation of chromium nitrides for nitrided specimens at 450°C and higher increased the susceptibility to pitting and general corrosion, formation of expanded martensite (EM) in nitriding at 400°C improved the pitting corrosion resistance of 17-4 PH stainless steel. This is believed to be due to the release of nitrogen atoms from EM phase to form ammonium ions and increase the pH of the solution, supressing pit growth. 相似文献
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Effects of the Treating Time on Microstructure and Erosion Corrosion Behavior of Salt-Bath-Nitrided 17-4PH Stainless Steel 总被引:1,自引:0,他引:1
Jun Wang Yuanhua Lin Mingxing Li Hongyuan Fan Dezhi Zeng Ji Xiong 《Metallurgical and Materials Transactions B》2013,44(4):1010-1016
The effects of salt-bath nitriding time on the microstructure, microhardness, and erosion-corrosion behavior of nitrided 17-4PH stainless steel at 703 K (430 °C) were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and erosion-corrosion testing. The experimental results revealed that the microstructure and phase constituents of the nitrided surface alloy are highly process condition dependent. When 17-4PH stainless steel was subjected to complex salt-bathing nitriding, the main phase of the nitrided layer was expanded martensite (α`), expanded austenite (S), CrN, Fe4N, and Fe2N. The thickness of nitrided layers increased with the treating time. The salt-bath nitriding improves effectively the surface hardness. The maximum values measured from the treated surface are observed to be 1100 HV0.1 for 40 hours approximately, which is about 3.5 times as hard as the untreated material (309 HV0.1). Low-temperature nitriding can improve the erosion-corrosion resistance against two-phase flow. The sample nitrided for 4 hours has the best corrosion resistance. 相似文献
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İbrahim Çelikyürek 《Transactions of the Indian Institute of Metals》2017,70(5):1209-1214
Iron aluminide Fe3Al was produced in a vacuum arc melting furnace. The alloy was heat treated by salt bath nitriding at 580 °C for durations of 3, 6, and 9 h. The nitride layers formed on the surface were characterized with light optical microscopy (LOM), scanning electron microscopy (SEM) equipped with energy dispersive X-ray spectroscopy (EDXS), X-ray diffraction (XRD), and micro hardness measurements. The results showed that the nitride layer thickness increased with an increase in nitriding duration, while the layer hardness did not vary. The nitride layers were composed chiefly of iron nitride and aluminum nitride phases. The dry sliding friction and wear behaviors of nitrided iron aluminides were determined. The results revealed that the wear resistance decreased with increase in the length of nitriding. 相似文献
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Ramona Sola Giorgia Poli Paolo Veronesi Roberto Giovanardi 《Metallurgical and Materials Transactions A》2014,45(6):2827-2833
The surface of alloyed carbon steel was subjected to thermochemical modification by nitrocarburizing and nitriding with or without postoxidation in order to improve its mechanical properties, corrosion, and wear resistance. Treated samples were characterized by testing their basic properties (compound layer thickness, nitriding, nitrocarburizing depth, and surface hardness) according to standards. Detailed estimation of the modified metal surface was performed by additional testing: X-ray diffraction, microstructure, surface roughness and topography, and wear and corrosion resistance. The surface layer obtained after nitrocarburizing treatment consists mainly of ε-Fe2-3(N,C) and γ’-Fe4(N,C); similarly, the nitrided surface is formed by ε-Fe2-3N and γ’-Fe4N iron nitrides. The surface layer after postoxidation contains additionally Fe3O4. The results obtained show that nitrocarburization, nitridation, and postoxidation result in better mechanical, wear, and corrosion resistance of 42CrMo4 steel, and postoxidized sample properties are influenced by surface morphology. 相似文献
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M. Mubarak Ali S. Ganesh Sundara Raman S. D. Pathak R. Gnanamoorthy 《Transactions of the Indian Institute of Metals》2009,62(1):59-64
Ti-6Al-4V samples were plasma nitrided at 520°C in two environments (nitrogen and a mixture of nitrogen and hydrogen in the
ratio of 3:1) for two different time periods (4 h and 18 h). Fretting wear tests were conducted on unnitrided and nitrided
samples for 50,000 cycles using two counterbody materials (unnitrided Ti-6Al-4V and alumina). Gross slip prevailed at a normal
load of 4.9 N while mixed stick-slip prevailed at 9.8 N. Tangential force coefficient values of plasma nitrided samples were
lower than those of unnitrided samples. The tangential force coefficient nearly stabilised after thousand cycles in case of
samples tested against Ti-6Al-4V counterbody. On the other hand, it showed a continuously increasing trend in case of specimens
tested against alumina counterbody. The samples nitrided for 4 h exhibited higher hardness and lower tangential force coefficient
compared to the specimens nitrided for 18 h. The samples nitrided in nitrogen-hydrogen mixture environment exhibited higher
hardness and lower tangential force coefficient compared to the specimens nitrided in nitrogen. The samples plasma nitrided
in nitrogen-hydrogen mixture for 4 h exhibited the highest hardness and the lowest tangential force coefficient. The wear
volume of the plasma nitrided samples was lower than that of the unnitrided samples. Owing to tribochemical reactions, the
wear volume of unnitrided and nitrided samples fretted against alumina ball was higher than that of the samples fretted against
Ti-6Al-4V. A consistent trend was not observed regarding which nitriding condition would result in lower wear volume at different
loads. 相似文献
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Wei-Yeh Tang Ming-Hao Chuang Su-Jien Lin Jien-Wei Yeh 《Metallurgical and Materials Transactions A》2012,43(7):2390-2400
This study investigates the effect of plasma nitriding at 798?K (525?°C) on microstructures and the mechanical performance of Al0.3CrFe1.5MnNi0.5 high-entropy alloys (HEAs) obtained using different cast and wrought processing. All the alloys can be well nitride, with a thickness of around 80???m, and attain a peak hardness level around Hv 1300 near the surface. The main nitride phases are CrN, AlN, and (Mn, Fe)4N. Those of the substrates are bcc, fcc, Al-, and Ni-rich B2 precipitates, and ?? phase. Their relative amounts depend on the prior processing and also change under the heat treatment during nitriding. The formation of ?? phase during nitriding could in-situ harden the substrate to attain the suitable level required for wear applications. This gives the advantage in simplifying the processing for making a wear-resistance component or a mold since austenitizing, quench hardening, and tempering required for steels such as SACM and SKD steels are no longer required and final finishing can be accomplished before nitriding. Nitrided Al0.3CrFe1.5MnNi0.5 samples have much better wear resistance than un-nitrided ones by 49 to 80?times and also exhibit superior adhesive wear resistance to conventional nitrided alloys: nitriding steel SACM-645 (AISI 7140), 316 stainless steel, and hot-mold steel SKD-61 (AISI H13) by 22 to 55?times depending on prior processing. The superiority is due to the fact that the present nitrided alloys possess a much thicker highly hardened layer than the conventional alloys. 相似文献