共查询到19条相似文献,搜索用时 836 毫秒
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纯铜双层辉光离子临界区渗钛研究 总被引:7,自引:0,他引:7
利用双层辉光离子渗金属技术在纯铜表面制备了铜钛合金层。实验结果表明,合金层由以铜钛化合物为主的表层和钛在铜中α固溶体与弥散分布的Cu4Ti有序相的次表层组成。在源极与工件间距固定的条件下,表层成分受源极电压、工件电压和温度的影响,次表层厚度主要受温度和时间影响。在扩渗初期,轰击离子的强度对钛元素有催渗作用。源极电压与工件电压之比V源/V工≥2,气压选在(25~40)Pa有利于铜钛合金层的形成。纯铜渗钛虽可使材料表面强化,但表面电阻明显增大。 相似文献
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采用双辉等离子表面冶金技术对Ti-6Al-4V合金进行等离子渗铌处理。研究了温度与保温时间对合金层元素含量和渗层厚度的影响,以确定最佳渗金属工艺参数。利用光学图像分析仪以及辉光放电能谱仪观察和测定合金层的金相组织、渗层厚度及成分。结果表明,在极间距和气压恒定的条件下,渗层厚度及成分与温度和保温时间有关。温度过高或保温时间过长均会在Ti-6Al-4V试样表面产生较厚的Nb沉积层。经优化工艺参数,选择850℃保温3 h渗铌,得到一定厚度且与基体为冶金结合的合金层。该合金层可以克服Ti-6Al-4V合金耐磨性差的缺点。 相似文献
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利用双辉等离子渗金属技术,在工业纯铁电极材料表面进行正交渗钼试验,用极差分析方法研究了极间距、温度、时间、源极电压和气压对合金渗层厚度的影响,并对渗钼的工艺参数进行优化。采用光学显微镜、X射线衍射仪(XRD)、显微硬度仪、扫描电镜(SEM)和能谱仪观察合金渗层的金相组织及厚度,测定合金渗层的物相组成和渗层硬度,检测合金渗层的形貌、元素分布。结果表明:渗钼工艺优化参数为源极电压800~850V,保温温度1 020℃,保温时间4h,工作气压35Pa,极间距20mm,可获得满足试验要求的80μm的合金渗层;合金渗层组织为柱状晶,Mo元素在合金渗层中呈梯度分布,合金渗层的物相为Fe(Mo)固溶体和Mo相,合金渗层的硬度呈下降趋势,渗钼后试样的表面硬度为248.5HV0.05。 相似文献
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采用L16正交实验,对0Cr18Ni9Ti奥氏体不锈钢双辉等离子渗铪行为进行研究,分析了影响渗铪合金层厚度的主次因素,取最主要因素进行单因素实验,并分析最优工艺下渗铪合金层的元素分布、物相结构以及硬度。结果表明:影响本试验的因素主次为温度时间电压气压极间距,优化的工艺参数为源极电压790~810 V,保温时间5 h,极间距25 mm,气压35 Pa,最主要因素温度的优化值为1100℃,此工艺下渗层厚度为35μm;表面组织晶粒细小、分布连续致密、无裂纹,由表及里铪元素含量呈梯度降低,硬度亦呈梯度降低,渗层表面硬度为600 HV0.1,比基材硬度提高约3倍,渗层物相主要为Hf2Fe、Hf C、Hf。 相似文献
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利用双层辉光等离子渗金属技术对TiAl合金进行离子渗Nb处理,研究了温度和保温时间对渗层合金元素含量和渗层厚度的影响,确定较合理的渗金属工艺参数。利用图像分析仪和辉光放电光谱仪观察和测定渗层金相组织、渗层厚度及合金层的成分。结果表明,在极间距与工作气压一定的条件下,渗层厚度及成分与温度和保温时间有关。温度过低或保温时间过长均使TiAl试样表面产生Nb沉积层。经优化工艺参数试验,选择1100℃×3h渗Nb,得到一定厚度且与基体结合牢固的合金渗层,这对改善TiAl合金的耐磨性和抗高温氧化性是有利的。 相似文献
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双辉等离子表面冶金Ti-Cu阻燃合金的制备工艺 总被引:11,自引:0,他引:11
为解决整体阻燃钛合金存在的比强度低、加工性差及价格昂贵等问题,利用双层辉光离子渗金属技术,在Ti-6Al-4V的表面渗入Cu元素,在其表面形成Ti-Cu阻燃合金层.研究了温度、保温时间、源极电压、工件电压、极间距等工艺参数对渗层显微组织、成分及厚度的影响,得出了适合的工艺参数.870℃渗铜3.5 h,渗层厚度可达到200μm以上.阻燃合金层的成分呈梯度分布,显微组织为基体组织加弥散分布的Ti2Cu金属间化合物.初步阻燃实验证明,渗Cu合金层起到了预期的阻燃效果. 相似文献
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钛(TA2)及钛合金(TC4)表面等离子渗Nb研究 总被引:3,自引:3,他引:3
采用双层辉光离子渗金属技术进行钛(TA2)及钛合金(TC4)的等离子渗Nb表面改性研究。分析了合金化条件对渗层Nb含量及厚度的影响,在此基础上得到优化的典型工艺条件。研究发现,在1000℃进行合金化时,放电气压对渗层表面Nb含量有显著的影响,在本试验选取的气压范围(20~80Pa)之内,气压为65Pa时可以得到最佳质量的渗层。对此典型条件下渗层的组织形貌及成分分布特征进行了观察与分析,测试了渗层的显微硬度并用划痕法评价了渗层结合强度。结果表明,渗层表面Nb含量可达70%左右,向内逐渐降低,呈梯度分布特征。渗层与基体结合良好,硬度显著提高。 相似文献
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采用双层辉光离子渗金属技术在20钢上进行镍铬共渗处理,对合金元素的溅射和吸收这两个渗金属过程,从放电及溅射等理论角度并结合试验结果进行了分析讨论。结果表明,放电条件对渗层形成效率有很大影响,合金元素的利用率在不同的放电参数下会有悬殊的变化。溅射量决定于溅射电压与气压,利用率则受工件偏压,气压,极间距的共同控制。在一定的溅射量下,利用率的高低决定了渗层质量及形成效率。提高合金元素的利用率是工艺参数造 相似文献
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The effects of ternary elements added to TiAl on the coating layer formed by the pack-aluminizing process was studied with respect to oxidation resistance and mechanical properties. All the TiAl specimens, with various amounts of Nb, Cr, Fe, and V, were pack aluminized under identical conditions using a high-activity process. Among the ternary alloying elements tested, Nb showed the best property of the TiAl3 coating layer formed on the surface and, consequently, the best oxidation resistance. The TiAl3 coating layer becomes thicker and has a finer grain size as the content of Nb or Cr is increased. Microhardness tests revealed that the addition of Nb or Cr improved the toughness of the coating layer and thus improved the cracking resistance. Cyclic oxidation tests showed that the TiAl3 coating layer formed on the TiAl alloy has better oxidation resistance with increasing Nb content. The ductility and oxidation resistance of the TiAl3 coating layers improved with Nb addition, which contributes to the grain refinement of TiAl3. The Nb present in the TiAl3 coating layer inhibits grain growth by the solute-drag effect and retards inward diffusion of Al to the TiAl matrix by forming (Nb, Ti)Al3 precipitates during high-temperature oxidation. 相似文献
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Ni—Cr—Mo—Nb合金的阴极溅射行为 总被引:2,自引:2,他引:0
研究了双层辉光放电条件下镍基合金Inconel625的阴极溅射行为,结果表明:多组元镍基合金由于各组元溅射率不同,产生择优溅射现象。Mo,Nb等低溅射率元素在阴极表面富集,Ni,Cr等高溅射率元素在阴极表面贫化,使阴极表面发生相变,形成含Mo,Nb奋斗高的金属间化合物析出相P相和Laves相,随着阴极溅射电压的增加,阴极合金元素溅射率增加;并且随着阴极温度升高,阴极溅射率也随之增加。 相似文献
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TiAl合金激光表面原位TiC颗粒增强涂层及高温抗氧化性能 总被引:4,自引:0,他引:4
以高纯石墨粉和C Nb混合粉末为原料,对Ti-46Al-2Cr-1.5Nb-1V合金进行了激光表面合金化处理,对激光改性层的显微组织以及成分进行了观察与分析,并对该合金原始组织及经C和C Nb激光表面改性层的高温抗氧化性能进行了对比分析研究。结果表明,C和C Nb激光表面合金化处理后,在合金表面均“原位”形成了TiC颗粒,Nb以固溶原子形式存在于表面改性层中,TiC颗粒的大小,形态及分布强烈取决于激光工艺参数;激光表面处理后的合金的抗氧化性能明显高于未经激光处理的铸态组织,而且在石墨粉中掺杂Nb粉,处理后的合金具有最佳的抗氧化性能。 相似文献
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The influence of laser surface alloying (LSA) with niobium (Nb) on the corrosion and mechanical properties of Zircaloy-4 was
examined by potentiodynamic polarization testing in a chloride solution at 80°C and microhardness testing. The results are
discussed with the structural and compositional variations in the LSA layer determined by X-ray diffraction (XRD), a scanning
electron microscope (SEM) and a wavelength dispersive spectrometer (WDS). The LSA on Zircaloy-4 precoated with Nb produced
a Nb-alloyed layer 200~300 μrn thick with 1.3~2.5 wt.% Nb, depending on the laser beam power. The alloyed layer was composed
of a mixed structure of α-Zr and β-Zr phases with the (β-Zr phase increasing with the Nb content in the alloyed layer. The
LSA with Nb increased the microhardness of Zircaloy-4, which was attributed primarily to the grain-size refinement of rapid
cooling and, also, to the solid solution hardening with Nb. The resistance to the localized corrosion of Zircaloy-4 in a chloride
solution significantly improved through LSA with Nb, which was attributed to the combined effects of the fine rapidly cooled
microstructure and to the Nb alloying. 相似文献
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The surface of pure copper alloyed with Ti using double glow discharge process was investigated. The morphology, structure and forming mechanism of the Cu-Ti alloying layer were analyzed. The microhardness and wear resistance of the Cu-Ti alloying layer were measured, and compared with those of pure copper. The results in-dicate that the surface of copper activated by Ar and Ti ions bombardment is favorable to absorption and diffusion of Ti element. In current experimental temperature, as the Ti content increases, the liquid phase occurs between the deposited layer and diffused layer, which makes the Ti ions and atoms easy to dissolve and the thickness of Cu-Ti al-loying layer increase rapidly. After cooling, the structure of the alloying layer is composed of CuTi, Cu4Ti and Cu(Ti) solid solution. The solid solution strengthening and precipitation strengthening effects of Ti result in high surface hardness and wear resistance. 相似文献