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1.
Simulated wastewater containing propylene glycol methyl ether, Ni2+ and Zn2+ was treated using an aerated packed column. An electrochemical cell was also installed beneath the packing support in the bottom section of the column. The flowrate of water through the column was maintained at 8.94 kg m?2 s?1. For 72 h of treatment using aeration alone, the BOD5 was reduced by 43%, 56%, and 54% for air flowrates of 0.00094, 0.00141, and 0.00188 kg m?2 s?1 respectively. On the other hand, when the electrochemical cell was activated without aeration, the BOD5 was reduced by 15%, 17%, and 23% at the applied voltages of 8, 16, and 25 V respectively. When both aeration of the wastewater and a voltage of 25 V were used, the percentage removal of BOD5, on the average, was about 65% for all air flowrates used. The concentrations of Ni2+ and Zn2+ were also reduced by 57% and 61% respectively, in the absence of the supporting electrolyte. The addition of potassium chloride (100 ppm) as the supporting electrolyte enhanced the metal removal by 30%. Copyright © 2003 Society of Chemical Industry  相似文献   

2.
Zn2+, Ni2+ and propylene glycol methyl ether were simultaneously removed from simulated wastewater in a column consisting of an aerated packed bed and an electrochemical cell with a porous aluminium foam cathode and a porous stainless steel anode. After 48 h of sole electrochemical treatment at a liquid rate of 0.00183 m3 m?2 s?1, Zn2+ and Ni2+ were reduced by 95 and 80% respectively. In the turbulent flow regime with liquid rates varied from 0.0137 to 0.0366 m3 m?2 s?1, both Zn2+ and Ni2+ removal decreased by about 15% rather than increased as expected for a mass transfer‐controlled process. This can be attributed to bubble formation at the cathode surface under turbulent flow, which led to a lower active surface area for the electrodeposition of metal ions. Porous electrodes enhanced the metal removal by 17 and 60% for Zn2+ and Ni2+ respectively as compared with flat plate electrodes. Using combined biological and electrochemical treatment at a water rate of 0.00183 m3 m?2 s?1 and an air rate of 0.0518 m3 m?2 s?1, 99% of Zn2+ and 95% of Ni2+ were removed. In addition, the 5 day biological oxygen demand (BOD5) was reduced by 58% concurrently over 72 h of treatment. Copyright © 2006 Society of Chemical Industry  相似文献   

3.
Two identical laboratory‐scale bioreactors were operated simultaneously, each treating an input air flow rate of 1 m3 h?1. The biofilters consisted of multi‐stage columns, each stage packed with a compost‐based filtering material, which was not previously inoculated. The toluene inlet concentration was fixed at 1.5 g m?3 of air. Apart from the necessary carbon, the elements nitrogen, phosphorus, sulfur, potassium and other micro‐elements are also essential for microbial metabolism. These were distributed throughout the filter bed material by periodic ‘irrigations’ with various test nutrient solutions. The performance of each biofilter was quantified by determining its toluene removal efficiency, and elimination capacity. Nutrient solution nitrogen levels were varied from 0 to 6.0 g dm?3, which led to elimination capacities of up to 50 g m?3 h?1 being obtained for a toluene inlet load of 80 g m?3 h?1. A theoretical analysis also confirmed that the optimum nitrogen solution concentration lays in the range 4.0–6.0 g dm?3. Validation of the irrigation mode was achieved by watering each biofilter stage individually. Vertical stage‐by‐stage stratification of the biofilter performance was not detected, ie each filter bed section removed the same amount of pollutant, the elimination capacity per stage being about 16 g m?3 h?1 per section of column. © 2001 Society of Chemical Industry  相似文献   

4.
ABSTRACT

The local clinoptilolite from Bigadis region in Turkiye, was used for air drying in packed column. The effective diffusion coefficient of water in natural zeolite was found as 5×10?10 m2 s?1 from isothermal uptake measurements. Effects of packing height and airvelocity on breakthrough curves were studied.  相似文献   

5.
BACKGROUND: A circulating column microbial fuel cell (MFC) with Cu anode and Au? Cu air cathode was used for power generation and chemical oxygen demand (COD) removal from synthetic wastewater. The column was operated in repeated‐fed batch mode using acclimated anaerobic sludge. The contents of the column MFC were circulated while the feed wastewater was fed to the reactor in fed‐batch mode. Effects of feed COD concentration and COD loading rate on voltage difference, power density and percentage COD removal were investigated. RESULTS: The highest voltage difference (650 mV), power density (40 W m?2) were obtained with a feed COD of 6400 mg L?1, yielding 45% COD removal with a COD loading rate of nearly 90 mg h?1. Low COD loadings (<90 mg h?1) caused substrate limitations, and high loadings (>90 mg h?1) resulted in inhibition of COD removal and power generation. The highest percentage COD removal (50%) was obtained with feed COD content of 10.35 g L?1 or a COD loading rate of 145 mg h?1. CONCLUSION: The power densities obtained with the circulating column MFC were considerably higher than those reported in the literature due to elimination of mass transfer limitations by the high circulation rates, proximity of electrodes and small anode surface area used in this study. Further improvements may be possible with optimization of the operating parameters. Copyright © 2009 Society of Chemical Industry  相似文献   

6.
《分离科学与技术》2012,47(7):1293-1302
Abstract

An air‐lift sidestream polymeric multi‐tube membrane module has been investigated to compare the hydraulic performance of an MBR challenged with municipal wastewater and landfill leachate. In both cases the MBRs were operated under the same conditions of membrane aeration rate and sludge retention time, but with hydraulic retention time for the leachate set by scoping trials based on porous pots to 48 hours. Operation under conventional continuous aeration conditions yielded critical flux values, based on classical flux step experiments, of 36–42 l m?2 hr?1 for the sewage‐fed trial compared with ~24 l m?2 hr?1 for the leachate‐fed trial. Substantial improvements in operating flux, between 20 and 100%, were obtained when operating with air pulsing (1s on/s off). Intermittent operation under more conventional conditions (5s on/5s off) yielded no improvement.  相似文献   

7.
Biooxidation of ferrous iron (Fe2+) from strongly acidic industrial wastewater with a high Fe2+ content by Thiobacillus ferrooxidans in a packed bed reactor and subsequent removal of ferric iron (Fe3+) by a crossflow microfiltration (membrane) process have been investigated as functions of wastewater flowrate (54–672 cm3 h?1), Fe2+ concentration (1.01–8.06 g dm?3), and pH (1.5–5.0). A natural (vegetable) sponge, Luffa cylindrica, was used as support matrix material. The fastest kinetic performance achieved was about 40 g Fe2+ dm?3 h?1 at a true dilution rate of 19 h?1 corresponding to a hydraulic retention time of 3.16 min. Steady state conversion was observed to be about 10% higher at pH 2.3 than that at pH 1.5. Increasing the flowrate of the inlet wastewater caused a reduction in conversion rate. The oxidation rate reduced along the reactor height as the wastewater moved towards the exit at the top but conversion showed the opposite trend. Increasing Fe2+ concentration up to a critical point resulted in an increased oxidation rate but beyond the critical point caused the oxidation rate to decrease. Luffa cylindrica displayed suitable characteristics for use as a support matrix for formation of a Thiobacillus ferrooxidans biofilm and showed promising potential as an ecological and sustainable alternative to existing synthetic support materials. Membrane separation was shown to be a very effective means of Fe3+ removal from the wastewater with removal changing from 92% at pH 2.3 to complete removal at pH 5.0. Copyright © 2003 Society of Chemical Industry  相似文献   

8.
BACKGROUND: This study focused on the effectiveness of the zero‐valent iron (ZVI) pre‐treatment for enhancing the biodegradability of 2‐chloronitrobenzene (2‐ClNB), and further to evaluate the performance and mechanism of a coupled ZVI column–sequencing batch reactor (SBR) system treating 2‐ClNB contained wastewater. RESULTS: 2‐ClNB was readily transformed into 2‐chloroaniline (2‐ClAn) with the efficiency over 99.9% by ZVI column, and its biodegradability was significantly enhanced via ZVI pretreatment. The transformed effluent was subsequently fed into the SBR followed by 2‐ClAn loading of 3.4–117.2 g m?3 d?1 and COD loading around 1000 g m?3 d?1. A 2‐ClAn removal efficiency over 99.9% and COD removal efficiency of 82.0–98.1% were obtained. Moreover, 91.9 ± 0.1% TOC removal efficiency and 107.1 ± 6.0% chloride recovery efficiency during one cycle confirmed the complete biodegradation of 2‐ClAn in the coupled system. 16S rDNA PCR‐DGGE analysis suggested that ZVI pretreatment enhanced the diversity of the microbial community and promoted enrichment of the functional microorganisms degrading 2‐ClAn in the following SBR. CONCLUSION: ZVI pretreatment significantly enhanced the biodegradability of 2‐ClNB, and the coupled ZVI–SBR system demonstrated excellent performance when treating wastewater containing 2‐ClNB. Copyright © 2011 Society of Chemical Industry  相似文献   

9.
Various measures were tested at a full‐scale wastewater treatment plant to control sludge bulking by type 0041 and 0675 filamentous microorganisms, instigated by highly variable wastewater loadings from a food‐processing facility. Intermittent aeration on a 1‐h on 1‐h off basis was found to effect a marginal improvement in sludge settling characteristics, as reflected by about an 11–36% reduction in the Sludge Volume Index (SVI) to 118 cm?3 g?1. At BOD loadings of 1500 kg d?1 which marginally exceeded the design capacity of the plant of 1200 kg d?1, SVI rose sharply to 230 cm?3 g?1 in less than a week. The anoxic selector effected a reduction in SVI to 170 cm?3 g?1 within 3 weeks of operation at temperatures of 8–12 °C. The aerobic selector was most effective, reducing SVIs further to 79 cm?3 g?1 in 2 weeks. Sludge settleablity was found to be inversely proportional to the aerobic selector food‐to‐microorganism ratio. The optimum aerobic selector loading was found to be 1.8–2.7 kgBOD5 kgMLVSS d?1, with corresponding SVIs in the range of 80–120 cm?3 g?1. © 2003 Society of Chemical Industry  相似文献   

10.
This work reports the viability and modelling of the removal of Cr(VI) from polluted groundwaters by means of ion exchange using the resin Lewatit MP‐64. Feed groundwaters that contained Cr(VI) at an average concentration of 2431 mg dm?3 and 1187 mg dm?3 of chloride and 1735 mg dm?3 of sulfate as main anions were acidified to a pH of 2.0 prior to the removal process. Dynamic experiments were carried out in a fixed bed column with feed waters at flow rates in the range of 2.78 × 10?7 m3 s?1 to 5.55 × 10?7 m3 s?1. Regeneration was achieved with NaOH (2 mol dm?3). From the experimental results, the equilibrium of the ion exchange reaction was successfully modelled, obtaining an equilibrium constant (KAB) = 44.90. Finally, a mass balance that included mass transfer resistances in the liquid and solid phases was developed and from the comparison between simulated and experimental data the value of the effective intraparticle diffusivity (Ds) was determined as 1.43 × 10?12 m2 s?1. Copyright © 2004 Society of Chemical Industry  相似文献   

11.
Pseudomonas putida (ATCC 17484) has been grown in a pure culture, slime layer inside a continuous packed-column bioreactor. The bioreactor has been characterized in terms of liquid holdup, dispersion, air stripping, fixed biomass concentration, and degradation rate capabilities. The experimental data has been used to develop a predictive model using mechanistic equations for the operation of packed columns and the biokinetics of pure culture phenol degradation. The liquid holdup, dispersion and liquid-to-air mass transfer coefficients were found to be correlated by power law equations commonly used for packed column absorption and stripping equipment. The microorganisms developed a uniform slime layer over the 3-mm diameter glass spheres, measured to be 200 μm thick. Phenol inlet concentrations of 500 ppm were degraded 100% and at rates up to 1.2 × 10?3 kg m?3 s?1. These results compare favorably with the best biodegradation results reported elsewhere in the literature for other bioreactor designs. The packed-column bioreactor has the advantages of no moving parts and the need for minimum aeration (air fluxes less than 0.001 ms?1), thereby reducing volatile stripping losses. A computer model of the bioreactor was found to predict accurately the experimental trend in biodegradation capacities and rates with liquid flux. It is shown to be a useful model for studying design parameter changes or for determining scale-up characteristics due to its simplicity and mechanistic basis.  相似文献   

12.
《分离科学与技术》2012,47(9):1715-1742
Abstract

The effect of hydraulic loading, surfactant concentration, and air flow rate on the removal of Cr(III), Ni(II), and Zn(II) from chromium stream electroplating wastewater by adsorbing colloid flotation using a sodium dodecylsulfate/dodecanoic acid mixture was investigated. Typically, heavy metal concentrations of 81 ppm Cr(III), 55 ppm Ni(II), and 3.3 ppm Zn(II) were reduced to 1.2 ppm Cr(III), 3.2 ppm Ni(II), and 0.05 ppm Zn(II) at a hydraulic loading of 22.9 m3/m2·h (3 L·min?1), an air flow rate of 45.8 m3/m2·h (6 L·min?1), 40 ppm dodecanoic acid, and 80 ppm sodium dodecylsulfate, and using a 10-cm inner diameter column. A novel mode of operation (high liquid carryover) was used whereby a large proportion of the liquid entering the column leaves the column with the foam.  相似文献   

13.
An Intermittent Cycle Extended Aeration System (ICEAS) offers advantages for treating sewage; such as easy operation, process flexibility, and low capital cost. A laboratory‐scale study was made with synthetic‐domestic wastewater (COD = 300 mg dm−3; BOD = 210 mg dm−3) to investigate appropriate conditions for reduced operating cost. The results from this study indicated that the maximum hydraulic loading and organic loading were 3.5 m3 m−3 d−1 and 0.735 kg BOD m−3d−1 respectively. The BOD and COD of effluent were 15.5 mg dm−3 and 29.6 mg dm−3 for the cycle time and aeration time of 3.4 h and 2.65 h. It was not necessary to supply external artificial substrates in the reactor to deal with low wastewater flow that caused the starvation of sludge. Specific oxygen uptake rate (SOUR) was used as the index of microbial activity. The study indicated that the microbial activity could be restored (SOUR = 20.5 mg g−1 MLVSS h−1) after 5–6 days of cultivation when the sludge was deprived of substrate for 17 days. © 1999 Society of Chemical Industry  相似文献   

14.
The nitrifying component of a micro‐ecological life support system alternative (MELISSA) based on microorganisms and higher plants was studied. The MELISSA system consists of an interconnected loop of bioreactors to allow the recycling of the organic wastes generated in a closed environment. Conversion of ammonia into nitrates in such a system was improved by selection of microorganisms, immobilization techniques, reactor type and operation conditions. An axenic mixed culture of Nitrosomonas europaea and Nitrobacter winogradskyi, immobilized by surface attachment on polystyrene beads, was used for nitrification in packed‐bed reactors at both bench and pilot scale. Hydrodynamics, mass transfer and nitrification capacity of the reactors were analysed. Mixing and mass transfer rate were enhanced by recirculation of the liquid phase and aeration flow‐rate, achieving a liquid flow distribution close to a well‐mixed tank and without oxygen limitation for standard operational conditions of the nitrifying unit. Ammonium conversion ranged from 95 to 100% when the oxygen concentration was maintained above 80% of saturation. The maximum surface removal rates were measured as 1.91 gN‐NH4+ m?2 day?1 at pilot scale and 1.77 gN‐NH4+ m?2 day?1 at bench scale. Successful scale‐up of a packed‐bed bioreactor has been carried out. Good stability and reproducibility were observed for more than 400 days. Copyright © 2004 Society of Chemical Industry  相似文献   

15.
BACKGROUND: Previously, tachyplesin gene (tac) has been successfully transferred into Undaria pinnatifida gametophytes using the method of microprojectile bombardment transformation. The objectives of this study were to compare and evaluate the performance of bubble‐column and airlift bioreactors to determine a preferred configuration of bioreactor for vegetative propagation of transgenic U. pinnatifida gametophytes, and to then investigate the influence of light on vegetative propagation of these gametophytes, including incident light intensity, photoperiod and light quality to resolve the problems of rapid vegetative propagation within the selected bioreactor. RESULTS: Experimental results showed that final dry cell density in the airlift bioreactor was 12.7% higher than that in the bubble‐column bioreactor under the optimal aeration rate of 1.2 L air min?1 L?1 culture. And a maximum final dry cell density of 2830 mg L?1 was obtained within the airlift bioreactor using blue light at 40 µmol m?2 s?1 with a light/dark cycle of 14/10 (h). Polymerase chain reaction (PCR) analysis indicated that genes (bar and tac) were not lost during rapid vegetative propagation within the airlift bioreactor. CONCLUSION: The airlift bioreactor was shown to be much more suitable for rapid vegetative propagation of transgenic U. pinnatifida gametophytes than the bubble‐column bioreactor in the laboratory. The use of blue light allows improvement of vegetative propagation of transgenic U. pinnatifida gametophytes. Copyright © 2009 Society of Chemical Industry  相似文献   

16.
A packed bed external loop airlift bioreactor (PBELAB) was proposed as an alternative treatment system for wastewater containing ammonia and nitrate compounds. The 60L PBELAB consisted of aeration and non-aeration zones, both of which were packed with plastic bioballs to enhance the surface area for the attachment of bacteria. The system was able to achieve complete removal of all nitrogen compounds with simultaneous nitrification and denitrification, i.e., ammonia was decomposed in the aeration zone and nitrate was biodegraded in the non-aeration zone. At normal operation, the nitrification rate obtained from the system was in the range of 0.14-0.87 gNH3-N/m2d and the denitrification rate was 0.04 gNO3-N/m2d. The factors found to have great influence on the system included dissolved oxygen concentration and biofilm thickness. In addition, PBELAB was proven to perform well under nitrate shock load condition.  相似文献   

17.
The performance of a modified bioreactor inside a light enclosure for carbon dioxide biofixation by Chlorella vulgaris was investigated. The influence of different light intensities on the CO2 biofixation and biomass production rates was evaluated. The results showed that the photon flux available to the microalgal cultures can be a key issue in optimizing the microalgae photobioreactor performance, particularly at high cell concentrations. Although the optimal pH values for C. vulgaris are in the range of 6–8, cell growth can take place even at pH 4 and 10. Batch microalgae cultivation in the photobioreactor was used to investigate the effect of different light intensities. The maximum biomass concentration of 1.83 g L?1 was obtained at a light intensity of 100 μmol m?2s?1 and under aeration with 2 L min?1 of 2 % CO2‐enriched air.  相似文献   

18.
The performance of an upflow anaerobic filter (UAF) treating a chemical synthesis‐based pharmaceutical wastewater was evaluated under various operating conditions. During start‐up, the UAF was initially fed by glucose till an organic loading rate (OLR) of approximately 7.5 kg COD m?3 day?1 with a hydraulic retention time of 2.3 days. A soluble COD removal efficiency of 98% was achieved before the addition of the wastewater. Initially, the filter inertia was acclimatized to the wastewater by sequential feeding of 10% (w/v), 30% (w/v) and 70% (w/v) of the pre‐aerated wastewater mixed with glucose followed by a 100% (w/v) pre‐aerated wastewater. During the operation, the COD removal efficiency and methane yield decreased to 75% and 0.30 m3 CH4 kg?1 CODremoved respectively. As the UAF became accustomed to the pre‐aerated wastewater, raw wastewater was fed in increasing ratios of 20% (w/v), 60% (w/v) and 80% (w/v) with the pre‐aerated wastewater as the remaining part. During this stage of the operation, a COD removal efficiency in a range of 77–86% was achieved and the methane yield decreased to 0.24 m3 CH4 kg?1 CODremoved. Finally, 100% (w/v) raw wastewater was fed and a COD removal efficiency of 65% was achieved with a methane yield of 0.20 m3 CH4 kg?1 CODremoved. At the end of the operation, acetoclastic methanogenic activity was only measured in the bottom section of the UAF, this showed a 90% reduction in comparison with activity of inoculation sludge. Microscopic examinations revealed that rod‐shaped methanogens remained as the dominant species whereas Methanosarcina‐like species and filaments were present only in insignificant numbers along the UAF. © 2002 Society of Chemical Industry  相似文献   

19.
To study the effect of limited artificial aeration on domestic wastewater treatment in the constructed wetlands (CWs), four pilot-scale horizontal subsurface flow CWs were operated from October 2006 to September 2007. The types of the four units include aerated and planted CW (APCW), planted CW (PCW), aerated CW (ACW) and CW, and all the units have the identical dimensions of 3 m in length, 0.7 m in width and 1 m in depth. The automated aeration was activated when the oxygen concentrations in the units were lower than 0.2 mg/L and ceased when the oxygen concentrations in the CWs were higher than 0.6 mg/L. More stable alkaline pH values were found in aeration units than that in the non-aeration units. APCW, in which the removal efficiencies of BOD, NH4+-N and TN were 94.4% (16.7 g BOD d− 1 m− 2), 89.1% (4.54 g NH4+-N d− 1 m− 2), and 86.0%( 4.99 g TN d− 1 m− 2) respectively, was more effective at pollutant removal than the other three units. There were no significant differences in TP removal between the aeration units and non-aeration units. Less surface area is needed due to high removal efficiency in APCW and the additional cost of operation is quite little. The results from this experiment indicated that limited artificial aeration in constructed wetlands is a cost-effective method for treating domestic wastewater.  相似文献   

20.
The performance of the hydrolyzation film bed and biological aerated filter (HFB–BAF) combined system in pilot scale (with a daily treatment quantity of 600–1300 m3 d?1), operated for 234 days, for low‐strength domestic sewage was assessed using different amounts of aeration, reflux ratios and hydraulic loading rates (HLR). In steady state it was found that the average removal efficiency of chemical oxygen demand (COD) and biological oxygen demand at 5 days (BOD5) were 82.0% and 82.2% and the average effluent concentrations were 15.8 mg L?1 and 9.4 mg L?1 respectively as the HFB was running at an HLR of 1.25–1.77 m3 m?2 h?1 and the BAF was running at an HLR of 1.56–2.21 m3 m?2 h?1. In general, the removal efficiency of total nitrogen (TN) fluctuated with the HLR, gas–water ratio and reflux ratio, so the ratio of gas to water should be controlled from 2:1 to 3:1 and the reflux ratio should be as high as possible. The effluent concentration of TN was 10.4 mg L?1 and the TN removal averaged 34.3% when the gas–water ratio was greater than 3:1 and the reflux ratio was 0.5. The effluent concentration and removal efficiency of NH4+‐N averaged respectively 2.3 mg L?1 and 78.5%. The overall reduction of total phosphorus (TP) was 30% and the average effluent concentration was 0.95 mg L?1. The removal efficiency of linear alkylbenzene sulfonates (LAS) reached 83.8% and the average effluent concentration was almost 0.9 mg L?1. The effluent concentration and removal efficiency of polychlorinated biphenyls (PCBs) were 0.0654 µ g L?1 and 37.05% respectively when the influent concentration was 0.1039 µ g L?1. The excess sludge containing water (volume 15 m3) was discharged once every 3 months. The power consumption of aeration was 0.06–0.09 kWh of sewage treated. The results show that the HFB–BAF combined technology is suitable for the treatment of low‐concentration municipal sewage in south China. Copyright © 2005 Society of Chemical Industry  相似文献   

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