长坑矿田金,银矿床地球化学特征及形成差异分析

长坑矿田金、银矿体主要产于下石炭统与上三叠统不整合面之下的硅质岩中,金、银矿体分离。金矿体主要为浸染状,富集As、Sb、Hg;银矿体主要为脉状,富集Cu、Pb、Zn。金矿体铅同位素组成与寒武纪—石炭纪地层及硅质岩的相同,银矿体铅同位素组成与金矿体的不同。金、银矿体的氢、氧、碳同位素组成也明显不同。银矿体Rb-Sr等时线年龄为70.4Ma。据上述特征,笔者认为长坑金、银矿床是不同成矿作用形成的,金矿主要是热水沉积形成,银矿主要是燕山期晚期改造形成。     

Isotopic Geochronology of the Late Paleozoic Kanggur Gold Deposit of East Tianshan Mountains, Xinjiang, NW China

Abstract: The Kanggur gold deposit lies in East Tianshan mountains, eastern section of Central Asia orogenic belt. The gold mineralization occurs on the northern margin of the Aqishan‐Yamansu Paleozoic island arc in the Tarim Plate. It was hosted mainly in Middle‐Lower Carboniferous calc‐alkaline volcanic rocks, and controlled by the distributions of syn‐tectonic intrusions and ductile shear zones. In order to determine ore‐forming age of the Kanggur deposit, samples were collected from ores, wall rocks, altered rocks and intrusions. The dating methods include Rb‐Sr isochron and Sm‐Nd isochron, and secondly ⁴⁰Ar/³⁹Ar age spectrum, U‐Pb and Pb‐Pb methods. Based on the mineral assemblage and crosscutting relationship of ore veins, five mineralization stages are identified. This result is confirmed by isotope geochronologic data. The first stage featuring formation of pyrite‐bearing phyllic rock, is mineralogically represented by pyrite, sericite and quartz with poor native gold. The Rb‐Sr isochron age of this stage is 2905 Ma. The second stage represents the main ore‐forming stage and is characterized by native gold–quartz–pyrite–magnetite–chlorite assemblage. Magnetite and pyrite of this stage are dated by Sm‐Nd isochron at 290.47.2 Ma and fluid inclusion in quartz is dated by Rb‐Sr isochron at 282.35 Ma. The third mineralization stage features native gold–quartz–pyrite vein. In the fourth stage, Au‐bearing polymetallic sulfide‐quartz veins formed. Fluid inclusions in quartz are dated by Rb‐Sr isochron method at 25821 Ma. The fifth stage is composed of sulfide‐free quartz–carbonate veins with Rb‐Sr age of 2547 Ma. The first and second stages are related to ductile‐brittle deformation of shear zones, and are named dynamo‐metamorphic hydrothermal period. The third to fifth stages related to intrusive processes of tonalite and brittle fracturing of the shear zones, are called magmato‐hydrothermal mineralization period. The Rb‐Sr isochron age of 2905 Ma of the altered andesite in the Kanggur mine area may reflect timing of regional ductile shear zone. The Rb‐Sr isochron age of 28216 Ma of the quartz‐syenite porphyry and the zircon U‐Pb age of 2757 Ma of tonalite in the north of Kanggur gold mine area are consistent with the age of gold mineralization (290‐254 Ma). This correspondence indicates that the tonalite and subvolcanic rocks may have been related to gold mineralization. The Rb–Sr, Sm‐Nd and U‐Pb ages and regional geology support the hypothesis that the Kanggur gold deposit was formed during collisional orogenesis process in Late Variscan.     

广东长坑金银矿床成矿机制热力学模拟研究

长坑金银矿床为沉积岩中的微细浸染型金矿与交代型银矿构成的矿床组合,金、银矿化与碳酸盐和碎屑岩围岩的硅化蚀变关系密切并呈分带现象,矿石类型主要为含矿硅化岩。矿化温度主要在300～170 C之间,成矿流体的主要成分为K~-、Na~-、Ca~(2+)、Mg~(2+)、Cl~(-)。金属配合物的分配计算显示,金在成矿热液中主要以疏氢配合物迁移,而银、铁、铅、锌则以氯配合物为主,铁、铅、锌在成矿后期的中性-弱碱性环境下可转变为羟基和硫氢配合物。热液-碳酸盐岩反应模拟证实水-岩相互作用是银矿石形成的有效机制。矿物组合的溶解度分析表明,金、银矿物分别在早期弱酸性和后期中-碱性条件下沉淀富集,这是造成金、银矿体分离和分带的主要或有利因素。     

柴北缘赛坝沟金矿深部热液蚀变作用北大核心CSCD

赛坝沟金矿是青海省柴北缘构造带东段重要的金矿床,矿体受NW-NNW向韧-脆性断裂构造组控制,主要赋存于奥陶系英云闪长岩中,矿化蚀变主要有硅化、黄铁矿化、绢英岩化、绿泥石化、绿帘石化和碳酸盐化等。本文在厘定赛坝沟金矿热液蚀变类型、矿物组合特征以及蚀变空间变化关系的基础上,选取Ⅳ-4主矿体在AZK3901钻孔深部见矿岩心及底板蚀变围岩进行研究,通过对蚀变岩及其原岩的地球化学分析,剖析热液蚀变作用过程与机理。研究结果表明,赛坝沟金矿床钻孔深部蚀变中,绿泥石化绿帘石化及强糜棱岩化岩石表现为主量元素K_(2)O、CaO的明显带入和Na_(2)O的带出,大离子亲石元素Pb、Ba、Sr的带出以及过渡族金属元素Bi、Co、Cr的带入;黄铁矿绢英岩化、硅化岩石中,主量元素K_(2)O、SiO_(2),大离子亲石元素Rb、Ba、Cs、Pb以及过渡族金属元素均表现出不同程度的带入;各蚀变岩石中稀土元素以及高场强元素并未表现变化,仅在近矿体处出现了轻重稀土的解耦以及高场强元素Zr元素的带入。综合研究认为,赛坝沟金矿强糜棱岩化绿泥石化英云闪长岩为强烈的韧性剪切和脆性断裂叠加改造作用的产物,对流体成矿物质的运移形成了一定的屏障,使得成矿物质大部分沉淀在硅化、绢英岩化带内,局部发育的方解石细脉与成矿晚期碳酸盐化作用相关。金的沉淀主要是由于含矿流体温度、压力的下降和氧逸度的升高,使得含矿流体与围岩强烈反应形成硅化、绢云母化,同时伴随成矿流体pH值的增大和H^(+)的减少,热液中含硫组分与Fe元素发生反应形成黄铁矿等硫化物,破坏了含金络合物的稳定性,导致金的大量沉淀。     

新疆西天山加曼特金矿床赋矿围岩年代学、地球化学及地质意义

加曼特金矿床是西天山博罗科努多金属成矿带中的一个浅成低温热液金矿床。矿床赋存于晚古生代大哈拉军山组岩屑晶屑凝灰岩和花岗斑岩中。LA ICP MS锆石U Pb同位素定年结果显示岩屑晶屑凝灰岩、花岗斑岩的成岩时代分别为(3659±30) Ma和(3623±43) Ma,结合上覆阿恰勒河组地层中维宪阶生物化石的时代,加曼特金矿的成矿时代被约束在362~331 Ma之间。矿区岩石地球化学分析结果表明：二者均为高钾钙碱性系列岩石,富集轻稀土、Th和大离子亲石元素(Rb、K),亏损Ba、Sr、高场强元素(Nb、Ta、Ti、P)和重稀土元素,具有同源性和岛弧岩浆岩的地球化学亲缘性。岩石形成于古准噶尔洋向伊犁—中天山板块俯冲的活动大陆边缘弧环境,主要是下地壳基性岩石部分熔融的产物,混合了少量洋底沉积物熔体交代地幔楔形成的幔源岩浆。     

西准噶尔萨吾尔地区黑山头金矿点二长岩锆石U-Pb年代学和地球化学特征:对成矿前景的指示

黑山头金矿点是西准噶尔萨吾尔地区最新发现的金矿化点,通过对该金矿点赋矿岩石的LA-ICP-MS锆石U-Pb年龄以及地球化学特征的研究,探讨其构造背景及成因信息。黑山头金矿点赋矿岩石主要为二长岩,矿化区内发育钾长石化、硅化、青磐岩化、碳酸盐化等蚀变。二长岩LA-ICP-MS锆石U-Pb年龄为351.1±3.2 Ma,表明其形成于早石炭世早期。主量元素特征显示其属于钙碱性准铝质岩石,相对洋中脊玄武岩富集Sr、Ba、Th等大离子亲石元素,亏损Nb、Ta、Ti等高场强元素。二长岩为典型的I型花岗岩,区域地质及地球化学特征指示其形成于岛弧环境。矿区内二长岩具有高Sr、Na_2O和Al_2O_3,低Y和HREE等特征,与埃达克岩地球化学特征一致。样品具有较高的ε_(Nd)(t)和较低的(~(87_Sr/~(86)Sr)t,结合它们形成于晚古生代岛弧环境,暗示这些埃达克岩可能由俯冲洋壳熔融形成;而萨吾尔地区早石炭世晚期(340 Ma)中酸性侵入岩可能为玄武质下地壳熔融的产物。本次新发现的埃达克岩为该区进一步寻找斑岩矿床提供了有用线索,并且矿床围岩蚀变特征、矿化特征与斑岩矿床相似,暗示黑山头矿点具有良好的成矿条件和找矿潜力。     

The new gold deposit in the Lower Amur region: Chulbatkan,Khabarovsk region

The main characteristics of the Chulbatkan gold deposit are considered. This deposit consists of steeply dipping plate- and lens-shaped bodies with dessimination-veinlet mineralization in Late Cretaceous plagiogranites (Lower Amur complex) controlled by the NE- and NW-trending faults. The host rocks are affected by hydrothermal and metasomatic processes (beresitization, silicification, and carbonation). The only useful component in low-grade sulfide and non-rush ore is gold, while the silver content is insignificant. The resource potential of the deposit is estimated at 50 tons.     

新疆哈赞布拉克金铜矿成矿地质特征及成因探讨

哈赞布拉克金铜矿位于博罗科努金铜钼铅锌成矿带.矿化产于华力西中期中酸性侵入岩体内及与围岩接触带内,主要蚀变为围岩地层中的角岩化,闪长岩中的钾化、绢云母化、青盤岩化及含矿岩石中的硅化、碳酸盐化等,矿区发现Ⅰ、Ⅱ、Ⅲ号三个矿化带,以Ⅱ号矿化带规模最大,矿床为铜、金共生矿化,矿化成因类型为石英脉型、矽卡岩型、斑岩型,以石英脉型矿化为主,矿化主要受岩浆岩和构造控制,矿床为先期斑岩型矿化,伴矽卡岩型矿化,经后期热液改造叠加的石英脉型矿床.     

Li,F and Rb contents and Ba/Rb and Rb/Sr ratios as indicators of postmagmatic alteration and mineralization in the granitic rocks of the Banke and Ririwai Younger Granite complexes,Northern Nigeria

The Banke and Ririwai complexes have plutonic phases of igneous activity composed mainly of granitic rocks. These granitic ring complexes are associated with Sn-Nb mineralization and are characterized by high Li, F and Rb contents and Rb/Sr ratios, and low Ba and Sr contents and Ba/Rb ratios. — The altered and mineralized granites have variable Rb/Sr and Ba/Rb ratios differing significantly from those of fresh rocks. These ratios as well as the Li, F and Rb concentrations are good indicators of granitic rocks associated with postmagmatic alteration and mineralization providing valuable tools for Sn-Nb exploration within the Nigerian Younger Granite province.     

治岭头金矿围岩蚀变特征及其意义

治岭头金矿位于浙江省遂昌县,是我国东南沿海的一座大型金矿床。该矿床围岩蚀变发育,类型有硅化、绢云母化、绿泥石化、黄铁矿化、方解石化和菱锰矿化。从矿体到围岩可以划分为4个蚀变带:强硅化带、弱硅化-黄铁绢英岩化带、绢云母化带和绿泥石化带。沿矿体走向,蚀变强度整体上呈波动性变化,与矿体呈透镜状产出特征一致。硅化、黄铁矿化、菱锰矿化与金矿化关系最密切,而且这些蚀变具有相似的变化趋势。绢云母化和绿泥石化与硅化的变化趋势不同,且与矿化关系不密切。另外,矿区还发育方解石化,且强度较弱。金矿化及围岩蚀变均发育在古元古界八都群变质岩中,未进入上覆中生代火山岩盖层,证明治岭头金矿成矿作用与中生代火山活动无关。定量计算结果显示:蚀变过程中Al_2O_3、TiO_2、P_2O_5为惰性组分;SiO_2、CaO、MnO、Au、Ag、Cu、Pb、Zn等为明显带入组分;Fe_2O_3、FeO、MgO、K_2O、Na_2O、Ba、Sr等为明显带出组分。根据围岩蚀变和稳定同位素分析,推断治岭头金矿原始成矿热液流体应是富含Si、Ca、Mn、Au、Ag、Cu、Pb、Zn等组分的岩浆热液,后期有大气降水的加入。     

Age and sources of matter for the Kedrovskoe gold deposit,Northern Transbaikal tegion,Republic of Buryatia: Geochronological and isotopic geochemical constraints

The paper presents new geochronological and isotopic geochemical data on gold mineralization of the Kedrovskoe deposit. The deposit is located in the northeastern part of the Transbaikal metallogenic province, Russia’s largest. The Early Permian age (273 ± 4 Ma) of mineralization based on the results of Rb–Sr study of metasomatic rocks is correlated with the age of the final phases of Hercynian magmatism in the Baikal–Muya Foldbelt. The Sr, Nd, and Pb isotopic geochemical characteristics of mineralization show that the host rocks are involved in the formation of the latter. It has been established that ore lead was supplied to the hydrothermal system of the deposit mainly from a geochemical reservoir represented by the Neoproterozoic juvenile continental crust of the Baikal–Muya Foldbelt.     

胶西北两类金矿田的高钾-钾质脉岩元素地球化学与成岩作用研究

重点研究了胶西北玲珑、尹格庄两类金矿田的高钾－钾质脉岩,根据地质产状、岩性及与金矿化的时空关系,该脉岩可分为三类：（１）粕斑岩;（２）安山玢岩;（３）英安玢岩类,它们分别形成于金矿化早期、同期、晚期。元素地球化学研究表明：主要氧化物成分变民具岩浆分离结晶的一般规律,早期以辉石为主、晚期以角闪石和斜长石为主的矿物相分离结晶作用控制岩浆成分的演化。岩石富碱、高钾低钛,微量和稀土元素强烈富集大离子元素Ｂ     

贵州锦屏新元古界下江群元素地球化学特征及其与金矿的关系

在黔东南出露的一套新元古界下江群浅变质碎屑岩中产出众多石英脉型金矿床(点),有关该类矿床的成因问题,特别是金的物质来源一直是研究的热点,因此下江群地层岩石的含金性以及元素地球化学特征也倍受关注。本文对贵州锦屏地区新元古界下江群浅变质岩及典型矿床的微量及稀土元素进行了系统测试,通过对比分析发现:下江群剖面的每个组均富集As、Ba、Zr、Ti;亏损Cr、Rb、Sr、Ta、Sc等元素,从番召组到平略组,元素组合演化呈明显相似性和继承性。含凝灰质多的番召组和清水江组地层中金含量较高,并且含金高的层位稀土含量较低,地层中Au与壳源特征的Ag、Hg、As等低温元素关系最为密切,该区金的迁移、富集可能与地层的热液活动或区域变质作用有密切的关系。围岩、地层岩石与矿石的微量元素特征及REE组成模式体现了地球化学演化上的一致性及继承性,表明该区金矿成矿物质可能主要来自于地层,而平秋金矿部分含金石英脉矿石表现出与围岩地层不同的地球化学特征,其更接近下地壳或上地幔,说明可能有部分深部流体参与成矿。     

甘肃省迭部县加勒克金矿地质特征及成因探讨

加勒克金矿呈脉状、不规则囊状或漏斗状产于西秦岭造山带古道岭组灰岩中,矿化受到NWW向和近EW向断裂严格控制,矿石矿物以赤铁矿、自然金和黄铁矿为主,蚀变以硅化、绢云母化和褐（赤）铁矿化为特征。矿石主要为碎裂岩型、硅化碎裂斑岩型、碎裂灰岩型。成矿作用方式主要为热液渗滤交代、构造裂隙等有限空间的充填沉淀作用,构成比较完整的热液交代-充填-沉淀成矿体系经历了原生热液成矿期和表生氧化-次生富集期。成矿环境为近地表,成矿时代为印支晚期,成矿物质来源与印支期陆内造山阶段酸性岩浆活动密切有关,金矿化和岩浆岩可能是统一的受深部构造制约的印支期构造-岩浆-热液活动体系的系列演化产物。     

青海东昆仑西藏大沟金矿床花岗闪长斑岩锆石U-Pb年龄、地球化学及其成矿意义

利用LA-ICP-MS锆石U-Pb定年,对位于东昆仑地区巴颜喀拉成矿带的西藏大沟金矿床进行研究,首次获得与成矿有密切关系的花岗闪长斑岩加权平均年龄为（225.0±1.2）Ma,厘定为晚三叠世;岩石明显富集大离子亲石元素（Rb、Sr、Ba、K）、轻稀土元素和Pb,明显亏损高场强元素（如Nb、Ta、P、Ti）,显示轻稀土元素强烈富集的右倾式稀土配分型式。结合东昆仑地区区域构造演化及金矿成矿年代学资料分析认为,西藏大沟金矿床花岗闪长斑岩形成于挤压向伸展转换阶段,西藏大沟金矿床成矿时间应介于225.0~218.6 Ma,属晚三叠世。      

黑龙江省塔河县宝兴沟金矿床中生代侵入岩及其对成矿作用的制约

宝兴沟金矿床为近年来在漠河前陆盆地南缘新发现的大型金矿床。区内发育石英闪长岩、闪长玢岩、花岗细晶岩等侵入岩,矿体主要产于石英闪长岩、闪长玢岩内部及其与二十二站组砂岩的内外接触带中。地球化学研究表明,石英闪长岩具高钾、低钛、富碱特征,花岗细晶岩具高硅、高钾、低钛、富碱特征,二者均为高钾钙碱性系列岩石,富集大离子亲石元素Rb、Ba、Sr等,亏损高场强元素Nb、Ta、Ti和重稀土元素Yb、Y,但二者稀土元素特征和配分曲线差异较大,不具成因联系。矿石与石英闪长岩、闪长玢岩具有相似的微量元素、稀土元素组成和稀土元素配分曲线,表明石英闪长岩、闪长玢岩为成矿提供了热液和成矿物质等,与成矿具有密切的成因联系。LA-ICP-MS锆石U-Pb同位素测年结果显示,石英闪长岩成岩时间为118.13~121.77 Ma,限定了宝兴沟金矿床的形成时间不早于118Ma,为早白垩世,形成于太平洋板块俯冲后的伸展环境。漠河前陆盆地除中-晚侏罗世侵入岩外,早白垩世中酸性侵入岩对区域成矿也具有重要的作用,是今后找矿的重要方向之一。     

湖北随州黑龙潭-汪家塆地区金矿地质特征及成因初探

黑龙潭-汪家塆金矿床受控于区内北西向断裂带。矿体呈透镜状、脉状和似层状产出。围岩蚀变主要为石英化、绢云母化及黄铁矿化。矿石类型可分为蚀变岩型、蚀变碎裂岩型及石英脉型三种。根据矿石包裹体成分、同位素特征及稀土元素组成的研究,认为该矿床成矿物质系来自围岩和七尖峰花岗岩体,属地下热（卤）水混合热液成因。     

嵩县东湾金矿地质特征及深部盲矿预测

河南嵩县东湾金矿受构造蚀变带控制,矿体形态呈脉状或透镜状.矿石呈浸染状、细脉-浸染状、脉状-网脉状和蜂窝状等.围岩主要蚀变类型包括硅化、绢云母化、高岭石化、碳酸盐化、钾长石化、黄铁矿化.成矿阶段可分为4段：（1）硅化（黄铁矿）阶段;（2）石英-粗粒黄铁矿阶段;（3）石英-细粒黄铁矿阶段;（4）碳酸盐铅锌阶段.各阶段自然金矿物生成顺序是：自然金→银金矿→自然银→硫盐矿物.文中利用构造叠加晕原理,建立了河南嵩县东湾金矿构造叠加晕模式,并利用该模式对东湾金矿进行了成矿预测.     

广西苍梧社洞钨钼矿床花岗岩类岩石的地球化学特征及其与成矿关系

广西苍梧社洞钨钼矿是与花岗岩类有关的矿床。矿区主要花岗岩类包括加里东期花岗闪长岩、花岗闪长斑岩和燕山晚期花岗斑岩。加里东期花岗闪长岩、花岗闪长斑岩具有低Si、K,富Na、Al和基性组分特征,属于强过铝质的正常钙碱性系列岩石;稀土总量低,轻重稀土分馏明显,弱负Eu异常(δEu=0.62~0.70);Ti、Nb、Ta亏损,Th、U、Pb、Zr、Hf富集,Rb/Sr平均值为0.78,明显富集W、Cu、Mo,属于I型花岗岩,为陆内造山带碰撞早期挤压背景下岩浆活动的产物,表现为对钨、钼、铜的成矿专属性。燕山晚期花岗斑岩具有高Si、K,贫Na、Ca和基性组分,属于强过铝质的高钾-中钾钙碱性系列岩石;稀土总量高,轻重稀土分馏不明显,强负Eu异常(δEu=0.03~0.06);Ti、Ba、K、Eu亏损,Th、U、Sm、Dy、Y、Ho、Yb、Lu富集程度更高,Rb/Sr平均值为7.56,明显富集Sn、Bi,属于燕山晚期岩浆演化程度较高的S型花岗岩,为碰撞后伸展环境的板内花岗岩,表现为对锡、金的成矿专属性。     

Geological and Geochemical Constraints on the Newly Discovered Yangchongli Gold Deposit in Tongling Region, Lower Yangtze Metallogenic Belt

The newly discovered Yangchongli gold deposit is a unique independent gold deposit in the Tongling ore-cluster region controlled by the tectonic alteration firstly discovered in the Lower Yangtze Metallogenic Belt(LYMB). The host magmatic rocks mainly consist of monzodiorite and K-feldspar granite. The LA-ICP-MS U-Pb zircons dating yielded weighted mean ~(206)Pb/~(238)U ages of 140.7 ± 1.8 Ma and 126.4 ± 1.2 Ma for the monzodiorite and K-feldspar granite, respectively. Monzodiorites are enriched in Sr, Ba, Rb, and depleted in Y, Yb with high Sr/Y and La/Yb ratios, similar to the geochemical features of adakite, considered as products of differentiation of mafic magmas originating from lithospheric mantle melt/fluids caused by metasomatism during paleo-Pacific Plate subduction in the Mesozic. In contrast, the compositions of K-feldspar granites are A-type granites, indicating an extensional tectonic background. Gold ores hosted in the fracture zone occurred as quartz vein within cataclastic rock. Sulfur and lead isotopes from pyrites show crust-mantle mixing characteristics. Metal components from strata also took part in the gold mineralization, and resulted from two episodes of magmatism that were probably related to tectonic transition from a compressive to an extensional setting between 140–126 Ma, which led to the Mesozoic large-scale polymetallic mineralization events in eastern China.