煤气化－蒸汽联合循环发电（IGCC）技术中的高温煤气热脱硫

本文论述了开发煤气化－蒸汽联合循环发电（ＩＧＣＣ）技术的重要意义。着重分析了国外高温煤气热脱硫方面的研究状况，并结合国内实际情况，指出了我国在开发高温煤气热脱硫技术研究时，应从脱硫剂物系选择、温区划定、反应器选型和实施步骤等方面采取的一系列系统优化政策。     

煤气化—蒸汽联合循环发电（IGCC）技术中的高温煤气热脱硫

本文论述了开发煤气化－蒸汽联合循环发电（ＩＧＣＣ）技术的重要意义。着重分析了国外高温煤气热脱硫方面的研究状况，并结合国内实际情况，指出了我国在开发高温煤气热脱硫技术研究时，应从脱硫剂物系选择、温区划定、反应器选型和实施步骤等方面采取的一系列系统优化政策。     

高温脱硫的研究进展

论述了煤气高温脱硫的重要意义及研究状况，并着重阐述了几种目前国际上普遍关注的高温脱硫剂的研究状况，最后就我国的情况提出一些建议。     

高温脱充的研究进展

论述了煤气高温脱硫的重要意义及研究状况，并着重阐述了几种目前国际上普遍关注的高温脱硫剂的研究状况，最后就我国的情况提出了一些建议。     

热气体净化：硫化氢的脱除

简述了煤气高温脱硫研究状况，并对脱硫剂的性能及制备方法作一介绍。最后就我国的研究现状提出几点看法。     

高温煤气脱硫剂及再生特性研究

高温煤气净化是实现IGCC过程的关键环节，系统地介绍了国内外钙、锌、铜的锰系高温脱硫剂近年来的研究结果，同时结合脱硫剂再生的研究，分析了各种脱硫剂在高温脱硫过程中可能遇到的问题，探讨了各种脱硫剂的再生方法以及相应的尾气处理方案，最后对我国今后高温煤气脱硫剂研究开发提出了几点建议。     

高温煤气铁系脱硫剂的研究

高温煤气脱硫净化是目前先进洁净煤利用技术之一 ,但是以前高温煤气脱硫剂在多次硫化再生循环过程中出现粉化 ,妨碍脱硫剂进一步使用 .本研究选择钢厂赤泥作为脱硫剂原料 ,添加不同活性组分和防粉化结构助剂 ,制备了氧化铁基高温煤气脱硫剂 .经过 1 0次硫化 /再生循环实验 .结果表明 :1 0次循环累计 1 96.98% ,再生后脱硫活性不发生变化 ,具有较高和较稳定的脱硫活性 .再生后脱硫剂的机械强度高于新鲜样品 ,在使用过程中没有出现粉化现象 ,这为氧化铁基高温煤气脱硫剂的工业化研究提供了可靠的依据 .     

高温煤气脱硫剂再生行为气氛效应的研究进展

脱硫剂再生过程是高温煤气脱硫工业化应用必备的关键环节之一。本文重点综述了含氧气氛、水气氛、水氧混合气氛和二氧化硫气氛中高温煤气脱硫剂的再生行为。以硫资源化回收作为高温煤气脱硫剂再生的目标,分析了不同再生气氛以及不同再生操作条件对高温煤气脱硫剂再生行为的影响。最后对今后高温煤气脱硫剂的再生研究提出了几点建议。     

Zn—Ti高温煤气脱硫剂的沉淀法制备

本文针对固相反应组份不均匀性影响高温煤气脱硫剂性能和商业成本的缺陷，研究在反应物以液相混合，用沉淀法制备Ｚｎ－Ｔｉ高温煤气脱硫剂，克服了上述缺点，使脱硫活性提高。     

高温煤气脱硫剂的开发研究

本文对高温煤气脱硫剂的制备及脱硫工艺条件做了研究，并对脱硫剂进行了十五个周期的脱硫再生循环试验。结果表明,制备的脱硫剂在600～620℃、常压及空速为1000h-1的条件下脱硫，脱硫剂强度及硫容没有出现明显下降，也没有出现脱硫剂的粉化现象。     

Desulfurization matching with coal poly-generation system based on dual gas resources

The coal poly-generation system for the production of alcohol and ether fuels as well as power is one of advanced coal utilization techniques. The team leaded by Professor Xie Kechang is carrying out the research on the poly-generation system to produce the syngas from the combination of gasified and pyrolyzed coal gas (dual gas resources) for the alcohol ether synthesis. Gas desulfurization is one of the key technologies for this system. The desulfurization matching with dual gas resources based poly-generation system for the production of alcohol and ether fuels as well as power is presented according to gas components, sulfur content, sulfur species and desulfurization accuracy in this technology. This matching desulfurization is classified into hot gas desulfurization, normal gas desulfurization, warm gas desulfurization and organic sulfur catalytic conversion. The preparation of H₂S removal sorbents, organic sulfur hydrolysis catalyst and the evaluation of their activities involved in the system were investigated. The H₂S removal efficiencies of the crude and fine desulfurization sorbents prepared for hot gas desulfurization are 90% and 99% at 500 °C in simulating coal gas, and their sulfur capacities are 21.85 wt.% and 24.91 wt.%, respectively. The organic sulfur catalyst shows the high hydrolysis activity, and the hydrolysis conversion of COS is more than that of CS₂ on the same catalyst. The research will provide necessary information for the matching desulfurization technology in the demonstration project on dual gas resources coal poly-generation system.     

Operational characteristics of the pilot-scale coal gasification with filtration and hot fuel gas desulfurization

Experimental research on coal gasification with a filtration and desulfurization system for the development of an integrated gasification combined cycle (IGCC) was performed with Indonesian LG, KPU and Canadian Arch coals. A dry-feeding entrained-bed type gasifier was operated below the fusion temperature of the coal and at 20 bar of pressure. The filtration system was designed for continuous capture and subsequent removal of the fly ash and the unreacted coal residue via a specialty metal filter. The hot fuel gas desulfurization unit (HGD) consisted of a transport desulfurizer, a bubbling regenerator and a multi-cyclone. The research objective was to investigate the feasibility of applying a partial slagging coal gasifier to attain high carbon conversion and cold gas efficiencies as well as to attain an operational capability for combining with filtration and HGD. A Pilot-scale test demonstrated that the coal fines were effectively removed and the overall sulfur removal efficiency of the hot fuel gas desulfurization unit was higher than 95.3%.     

高温煤气脱硫剂的研究

介绍了高温煤气脱硫剂的研制、脱硫工艺条件试验、再生工艺条件试验和长周期考核试验。结果表明,以锌、锰和铁等氧化物为主成分,辅加多种助剂的高温煤气脱硫剂,可在(350～600)℃脱除煤气中的H_2S和COS,脱硫精度高,硫容大,脱硫剂脱硫后可再生。脱硫剂经22次脱硫-再生循环操作后,仍具有高脱硫性能。     

烟气同步脱硫脱硝研究进展

燃煤烟气中的SO2和NOX是大气污染的主要污染物质,目前烟气同步脱硫脱硝技术是研究的热点,本文综述了目前国内外开发的干法、湿法、生物法同步脱硫脱销技术的原理、特点以及最新研究进展,最后对同步脱硫脱销技术发展前景做了展望。     

整体煤气化联合循环（IGCC）中高温煤气脱硫技术进展

在论述整体煤气化联合循环（IGCC）技术的基础上,分析了国外高温煤气脱硫的研究现状和发展趋势,提出了适合中国国情的高温煤气热脱硫技术的研究方向。     

海上平台烟气海水脱硫技术应用研究与进展

利用海水进行废气脱硫是海上平台烟气中硫氧化物治理的典型技术。综述海水烟气脱硫技术的特点、工艺流程及研究进展,总结海上平台固定源类及移动船舶排放烟气的特点及其海水法脱硫技术应用现状,介绍膜吸收法海水脱硫技术、海水烟气脱硫系统、脱硫吸收塔的发展及相关防腐措施,指出纤维膜海水脱硫技术是海上平台烟气脱硫的发展方向。     

Performance of a coal gasification pilot plant with hot fuel gas desulfurization

A coal gasification pilot plant operation with hot fuel gas desulfurization (HGD) was performed taking two coals (Indonesian ABK and MSJ) that differ in their carbon and sulfur contents. A dry-feeding entrained-bed type gasifier was used for gasification with oxygen and capable of operating at 30 bar pressure and 1,550 °C. The HGD unit consisted of a transport desulfurizer, a bubbling regenerator and a multi-cyclone. Attention was focused on attaining high carbon conversion and cold gas efficiency in the entrained bed reactor and the sulfur removal efficiency of the hot fuel gas desulfurization unit. The optimum conditions for achieving high performance of the operation are reported.     

高含硫天然气脱硫工艺概况

介绍了高舍硫天然气中硫的物理沉积和化学沉积原理。叙述了国内外高含硫气田的脱硫技术的状况。认为选择脱硫一DEA脱硫脱碳工艺和MDWA法＋自循环LO—CAT工艺的应用前景比较广泛;在脱硫技术的发展中,还应开展脱水、防腐技术的广泛研究,达到净化天然气．实现操作的安全性。