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采用反相离子对色谱法-电化学检测测定了废水中的NO_2~-和S~(2-)。对影响分离测定的诸因素进行了研究,建立了最佳色谱分离条件,方法具有快速、灵敏、选择性高等优点。 相似文献
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随这鄂尔多斯经济的迅猛发展,城市规模的不断壮大。鄂尔多斯市制定了引用黄河水的战略措施。使黄河水成为鄂尔多斯城市居民的日常生活水源,所以黄河鄂尔多斯段的水质问题成为当地居民的热议话题。而其中F-、Cl-、NO3 -、SO4 2- 几种离子是作为水源地的必测项目。其水体的基本特点是泥沙含量高,浑浊,有机物含量丰富,因此Cl-、SO4 2-含量比较高,F-、NO3-含量比较小。笔者通过对实际样品有效的预处理,并选择恰当的稀释倍数,用ICS-1500离子色谱一次进样同时测定了F-、Cl-、NO3-、SO4 2-取得了满意的结果。 相似文献
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离子色谱法连续测定地表水中地F^—、NO2—N、NO3—N 总被引:1,自引:0,他引:1
介绍了离子色谱法连续测定地表水中F^-、NO2-N、NO3-N浓度,在实际监测工作中的应用,取得了较好的实验结果。 相似文献
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采用单因素批试验方法优化亚甲蓝络合-分光光度法测定地下水中Cl O4-浓度的实验条件,确定0.2 mol/L硫酸溶液、0.5 mmol/L亚甲蓝溶液、1,2-二氯乙烷、无水硫酸钠的最佳用量分别为1 m L、1.5 m L、5 m L和0.1 g。该方法的相对标准偏差优于4%,加标回收率在95%~108%;检出限为9μg/L,测定下限为31μg/L。实验结果表明NO3-是影响Cl O4-浓度分光光度测定最为显著的干扰离子,其对Cl O4-浓度测定的干扰程度随着溶液中NO3-浓度增加而增强。揭示出NO3-对Cl O4-浓度测定干扰的规律性,吸光度差值与NO3-浓度间显著的相关性(R2=0.988)为解决NO3-的干扰问题提供了有效的途径,拓展了亚甲蓝络合-分光光度法的应用范围。 相似文献
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张昌楠 《辽宁城乡环境科技》2003,23(1):55-56
在双台子河下游潮汐河段NO3^--N的测定,采用酚二磺酸比色法和紫外分光光度比色法,并通过数理统计中的t检验法对比及加标回收率的实验提出;感潮河段应采用紫外分光光度比色不测定水中的NO3^--N。 相似文献
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控制温度35℃,在典型pH值条件下(酸性5.0,碱性9.0)对比研究了NO2-对剩余污泥水解酸化性能的影响.结果表明:投加亚硝酸盐促进了剩余污泥的水解,提高了总可溶性COD(SCOD)产量,且随着时间的进行,酸性时比碱性时水解程度更高,到第28d时,总SCOD浓度由高到低依次为B1(pH=5且加NO2-),B2(pH=9且加NO2-),B4(pH=9且未加NO2-),B3(pH=5且未加NO2-);B1,B2,B3和B4中总挥发性脂肪酸(TVFAs)最高浓度分别为4476,4303,1350和2921mg/L,表明亚硝酸盐同样增强了污泥的酸化程度,并且酸性条件时促进作用更大.除此之外,酸性且投加NO2-的条件可以有效减少氨氮的释放. 相似文献
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利用甲基蓝与亚硝酸根反应,根据双波长处吸光度的加和值与NO2^-浓度的线性关系,提出并建立了测定亚硝酸根含量的新方法。线性范围0.05-1.20mg/L,用于样品中NO2^-的测定均获得满意结果。 相似文献
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W. Kirmse 《Die Naturwissenschaften》1959,46(11):379-379
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北京大气中NO、NO2和O3浓度变化的相关性分析 总被引:13,自引:1,他引:13
臭氧(O3)是城市污染大气中的首要光化学污染物,其变化规律与氮氧化物(NOx=NO NO2)关系密切.采用49C臭氧分析仪和42CTL氮氧化物分析仪对北京城区O3和NOx浓度进行了连续观测,时间为2004-08~2005-07.结果显示,O3和OX(O3 NO2)浓度在午后15:00左右出现峰值,NOx呈双峰态日变化,在07:00和23:00左右出现峰值.不同季节污染物的浓度变化存在差异,O3和NOx浓度分别在夏季和冬季达到最大.NOx浓度存在100×10-9(体积分数)的"分界点",NOx低浓度时以NO2为主,NOx高浓度时NO占大部分.OX区域贡献和局地贡献存在明显的季节变化,前者主要受区域背景O3的影响,在春季最大,后者主要受局地NOx光化学反应的制约,在夏季最强,同时OX组分呈现显著的昼夜差异. 相似文献
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S. K. Sharm A. Datt T. Sau M. Saxen T. K. Mandal Y. N. Ahamme B. C. Arya 《环境科学学报(英文版)》2010,22(7):1023-1028
We present the diurnal and seasonal variability of ambient NH3, NO, NO2 and SO2 over Delhi, India. Ambient NH3, NO and
NO2 were measured continuously during winter, summer and autumn seasons using NH3- and NOx-analyzer, which operates by
chemiluminescence method with a higher estimation e ciency (> 90%) than the chemical trap method (reproducibility 4.7%).
Prominent diurnal, day-to-day and seasonal variations of ambient mixing ratio of NH3, NO, NO2 and SO2 were observed during
the study period. Seasonal variation with higher mixing ratio in winter was observed for all measured trace gases except NO. Day-night
variation of all measured trace gases observed was higher in winter in comparison with summer. Late morning increase in NO2 mixing
ratio might be attributed to conversion of NO to NO2 with the interaction of O3. 相似文献
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《Atmospheric Environment. Part B. Urban Atmosphere》1992,26(3):369-377
A stochastic approach to the problem of incorporating variable emission events in indoor air quality models is proposed. A nonstationary Poisson process is used to account for the occurrence of range-top burner use. The combination of this emission event sequence with a simple one-compartment mass-balance model results in output that qualitatively agrees with measured concentrations in two occupied townhouses. Improved monitoring of stove usage times, gas flow rates and emission factors under field conditions would allow more effective estimation of model input parameters and more accurate prediction of concentration distributions. 相似文献
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《Atmospheric Environment. Part A. General Topics》1992,26(2):211-217
A commercial Differential Optical Absorption Spectrometer (DOAS), measuring trace gases absorbing in the u.v./vis region was used for obtaining information on aerosol parameters (e.g. total surface) based on the observed Mie scattering. This procedure allows simultaneous measurements of trace gas concentrations and aerosol parameters within the same air volume. A series of measurements of HNO2, NO2, NO, SO2 and aerosol parameters was performed at Ispra in northern Italy. The observations show a rapid formation of gaseous HNO2 during foggy episodes and give direct evidence of an important contribution of reactions on wet aerosols to the transformation of tropospheric NOx into HNO2. 相似文献
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Nicholas J. Gingerysty Charles A. Odame-Ankrah Nick Jordan Hans D. Osthoff 《环境科学学报(英文版)》2021,33(9):184-193
The reference method to quantify mixing ratios of the criteria air pollutant nitrogen dioxide (NO2) is NO-O3 chemiluminescence (CL), in which mixing ratios of nitric oxide (NO) are measured by sampling ambient air directly, and mixing ratios of NOx (= sum of NO and NO2) are measured by converting NO2 to NO using, for example, heated molybdenum catalyst or, more selectively, photolytic conversion (P-CL). In this work, the nitrous acid (HONO) interference in the measurement of NO2 by P-CL was investigated. Results with two photolytic NO2 converters are presented. The first used radiation centered at 395 nm, a wavelength region commonly utilized in P-CL. The second used light at 415 nm, where the overlap with the HONO absorption spectrum and hence its photolysis rate are less. Mixing ratios of NO2, NOx and HONO entering and exiting the converters were quantified by Thermal Dissociation Cavity Ring-down Spectroscopy (TD-CRDS). Both converters exhibited high NO2 conversion efficiency (CFNO2; > 90%) and partial conversion of HONO. Plots of CF against flow rate were consistent with photolysis frequencies of 4.2 s-1 and 2.9 s-1 for NO2 and 0.25 s-1 and 0.10 s?1 for HONO at 395 nm and 415 nm, respectively. CFHONO was larger than predicted from the overlap of the emission and HONO absorption spectra. The results imply that measurements of NO2 by P-CL marginally but systematically overestimate true NO2 concentrations, and that this interference should be considered in environments with high HONO:NO2 ratios such as the marine boundary layer or in biomass burning plumes. 相似文献
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Mechanism of NO reduction with non-thermal plasma 总被引:4,自引:2,他引:2
Non-thermal plasma has been proved to be an effective and competitive technology for removing NO in flue gas since 1970. In this paper, the NO reduction mechanism of the non-thermal plasma reaction in NO/N2/O2 system was investigated using the method of spectral analysis and quantum chemistry. By the establishment of NO reduction and gas discharge plasma emission spectrum measuring system, the NO reduction results, gas discharge emission spectra of NO/N2/O2 and pure N2 were obtained, and then the model of molecular orbit of N2 either in ground state or its excited state was worked out using the method of molecular orbit Ab initio in SelfConsistent Field(SCF). It was found that NO reduction in NO/N2 gas discharge plasma was achieved mainly through a series of fast elementary reactions and the N(E6) at excited state was the base for NO reduction. 相似文献
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