Thermal conductivity of ethylene glycol and water mixture based Fe3O4 nanofluid

Thermal conductivity of ethylene glycol and water mixture based Fe₃O₄ nanofluid has been investigated experimentally. Magnetic Fe₃O₄ nanoparticles were synthesized by chemical co-precipitation method and the nanofluids were prepared by dispersing nanoparticles into different base fluids like 20:80%, 40:60% and 60:40% by weight of the ethylene glycol and water mixture. Experiments were conducted in the temperature range from 20 °C to 60 °C and in the volume concentration range from 0.2% to 2.0%. Results indicate that the thermal conductivity increases with the increase of particle concentration and temperature. The thermal conductivity is enhanced by 46% at 2.0 vol.% of nanoparticles dispersed in 20:80% ethylene glycol and water mixture compared to other base fluids. The theoretical Hamilton–Crosser model failed to predict the thermal conductivity of the nanofluid with the effect of temperature. A new correlation is developed for the estimation of thermal conductivity of nanofluids based on the experimental data.     

Experimental thermal conductivity of ethylene glycol and water mixture based low volume concentration of Al2O3 and CuO nanofluids

Thermal conductivity of ethylene glycol and water mixture based Al₂O₃ and CuO nanofluids has been estimated experimentally at different volume concentrations and temperatures. The base fluid is a mixture of 50:50% (by weight) of ethylene glycol and water (EG/W). The particle concentration up to 0.8% and temperature range from 15 °C–50 °C were considered. Both the nanofluids are exhibiting higher thermal conductivity compared to base fluid. Under same volume concentration and temperature, CuO nanofluid thermal conductivity is more compared to Al₂O₃ nanofluid. A new correlation was developed based on the experimental data for the estimation of thermal conductivity of both the nanofluids.     

Experimental investigation of the thermal transport properties of graphene oxide/Co3O4 hybrid nanofluids

The in-situ growth and chemical co-precipitation method was used for the synthesis of uniform dispersion of Co₃O₄ nanoparticles on the graphene oxide (GO) nanosheet. The reductions of aqueous cobalt chloride in the presence of GO with sodium borohydrate result in the formation of hybrid GO/Co₃O₄ nanoparticles. The synthesized GO/Co₃O₄ nanoparticles were characterized using X-ray power diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, transmission electron microscopy (TEM) and vibrating sample magnetometer (VSM). The hybrid nanofluids were prepared by dispersing synthesized GO/Co₃O₄ nanoparticles in water, ethylene glycol, and ethylene glycol/water mixtures. The properties such as thermal conductivity and viscosity were estimated experimentally at different volume concentrations and temperatures. The thermal conductivity enhancement of water-based nanofluid is 19.14% and ethylene glycol-based nanofluid is 11.85% at 0.2% volume concentration and at a temperature of 60 °C respectively compared to their respective base fluids. Similarly, the viscosity enhancement of water-based nanofluid is 1.70-times and ethylene glycol-based nanofluid is 1.42-times at 0.2% volume concentration and at a temperature of 60 °C respectively. The obtained thermal conductivity and viscosity data is compared with the literature values.     

Rheology and thermal conductivity of non-porous silica (SiO2) in viscous glycerol and ethylene glycol based nanofluids

Nanofluids are advanced fluids with novel properties useful for diverse applications in heat transfer. This article reports the experimental determination of thermal conductivity and viscosity for silica (SiO₂) nanofluids in ethylene glycol (EG) and glycerol (G) as base fluids. A two-step method was applied to disperse the nanoparticles in the base fluids for the particle volume concentration of 0.5–2.0%. The dispersion stability of the nanofluids was evaluated by zeta potential analysis. All the measurements were performed in the temperature interval from 30 °C to 80 °C. It was found that the thermal conductivity increases with temperature. The SiO₂-EG showed higher conductivity enhancement than SiO₂-G nanofluids. Rheological analyses confirm Newtonian behavior for silica nanofluids within shear rate range of 20–100 s^− 1. Viscosity decreases with an increase in operating temperature. The SiO₂-EG demonstrated very weak temperature dependence compared to the SiO₂-G nanofluids. Based on these measured properties, the criterion for heat transfer performance was determined. Furthermore, equations have been proposed with accuracy within ± 10% deviations to predict the thermal conductivity and dynamic viscosity of EG and G-based SiO₂ nanofluids.     

Experimental investigation on the thermo-physical properties of Al2O3 nanoparticles suspended in car radiator coolant

Nanofluid is a new type of heat transfer fluid with superior thermal performance characteristics, which is very promising for thermal engineering applications. This paper presents new findings on the thermal conductivity, viscosity, density, and specific heat of Al₂O₃ nanoparticles dispersed into water and ethylene glycol based coolant used in car radiator. The nanofluids were prepared by the two-step method by using an ultrasonic homogenizer with no surfactants. Thermal conductivity, viscosity, density, and specific heat have been measured at different volume concentrations (i.e. 0 to 1 vol.%) of nanoparticles and various temperature ranges (i.e. from 10 °C to 50 °C). It was found that thermal conductivity, viscosity, and density of the nanofluid increased with the increase of volume concentrations. However, specific heat of nanofluid was found to be decreased with the increase of nanoparticle volume concentrations. Moreover, by increasing the temperature, thermal conductivity and specific heat were observed to be intensified, while the viscosity and density were decreased.     

Experimental investigation and development of new correlation for thermal conductivity and viscosity of BioGlycol/water based SiO2 nanofluids

Nanofluids are a new class of engineered heat transfer fluids which exhibit superior thermophysical properties and have potential applications in numerous important fields. In this study, nanofluids have been prepared by dispersing SiO₂ nanoparticles in different base fluids such as 20:80% and 30:70% by volume of BioGlycol (BG)/water (W) mixtures. Thermal conductivity and viscosity experiments have been conducted in temperatures between 30 °C and 80 °C and in volume concentrations between 0.5% and 2.0%. Results show that thermal conductivity of nanofluids increases with increase of volume concentrations and temperatures. Similarly, viscosity of nanofluid increases with increase of volume concentrations but decreases with increase of temperatures. The maximum thermal conductivity enhancement among all the nanofluids was observed for 20:80% BG/W nanofluid about 7.2% in the volume concentration of 2.0% at a temperature of 70 °C. Correspondingly among all the nanofluids maximum viscosity enhancement was observed for 30:70% BG/W nanofluid about 1.38-times in the volume concentration of 2.0% at a temperature of 70 °C. The classical models and semi-empirical correlations failed to predict the thermal conductivity and viscosity of nanofluids with effect of volume concentration and temperatures. Therefore, nonlinear correlations have been proposed with 3% maximum deviation for the estimation of thermal conductivity and viscosity of nanofluids.     

Transport properties of ultra-low concentration CuO–water nanofluids containing non-spherical nanoparticles

CuO–water nanofluids were prepared from non-spherical CuO nanoparticles by dispersing them in water through the aid of ultrasonication along with the use of Tiron as dispersant. Thermal conductivity enhancements of 13% and 44% have been obtained with 0.016 vol% CuO–water nanofluids at 28 °C and 55 °C respectively, which could be attributed to the high aspect ratio and Brownian motion of nanoparticles. Correlations have been developed to predict the influence of temperature (28–55 °C) and nanoparticles volume concentration (<0.016 vol%) on relative viscosity and thermal conductivity ratio. The results indicate the potential of this nanofluid for thermal management applications.     

Experimental study on the thermo-physical properties of car engine coolant (water/ethylene glycol mixture type) based SiC nanofluids

The engine coolant (water/ethylene glycol mixture type) becomes one of the most commonly used commercial fluids in cooling system of automobiles. However, the heat transfer coefficient of this kind of engine coolant is limited. The rapid developments of nanotechnology have led to emerging of a relatively new class of fluids called nanofluids, which could offer the enhanced thermal conductivity (TC) compared with the conventional coolants. The present study reports the new findings on the thermal conductivity and viscosity of car engine coolants based silicon carbide (SiC) nanofluids. The homogeneous and stable nanofluids with volume fraction up to 0.5 vol.% were prepared by the two-step method with the addition of surfactant (oleic acid). It was found that the thermal conductivity of nanofluids increased with the volume fraction and temperature (10–50 °C), and the highest thermal conductivity enhancement was found to be 53.81% for 0.5 vol.% nanofluid at 50 °C. In addition, the overall effectiveness of the current nanofluids (0.2 vol.%) was found to be ~ 1.6, which indicated that the car engine coolant-based SiC nanofluid prepared in this paper was better compared to the car engine coolant used as base liquid in this study.     

Experimental investigation and model development for thermal conductivity of α-Al2O3-glycerol nanofluids

In order to investigate the effect of nanoparticle volume fraction, nanoparticle size and temperature on the thermal conductivity of glycerol based alumina (α-Al₂O₃) nanofluids, a set of experiments were carried out for temperature ranging from 20 °C to 45 °C. The nanofluids contained α-Al₂O₃ nanoparticles of three different sizes (31 nm, 55 nm and 134 nm) were prepared by two-step method at volume fractions ranging from 0.5% to 4%. The experimental results show that α-Al₂O₃-glycerol nanofluids have substantially higher thermal conductivity than the base fluid and the maximum enhancement of the relative thermal conductivity was 19.5% for the case of 31 nm at 4% volume fraction. The data analyses indicated that the volume fraction and size of the nanoparticles have significant effects on the thermal conductivity ratio (TCR) of Al₂O₃-glycerol nanofluids, while the temperature has almost no significant effect on the data for range of this study. At room temperature, the effective thermal conductivity remains almost constant for 50 h at 4% volume fractions. The comparison of the obtained experimental data and predictions from some existing theoretical and empirical models reveals that the thermal conductivity ratio and its trend could not be accurately explained by the models in open literature. Consequently, a new empirical correlation based on the experimental data has been developed in this study.     

Investigation of thermal conductivity and viscosity of Fe3O4 nanofluid for heat transfer applications

Experimental investigations and theoretical determination of effective thermal conductivity and viscosity of magnetic Fe₃O₄/water nanofluid are reported in this paper. The nanofluid was prepared by synthesizing Fe₃O₄ nanoparticles using the chemical precipitation method, and then dispersed in distilled water using a sonicator. Both experiments were conducted in the volume concentration range 0.0% to 2.0% and the temperature range 20 °C to 60 °C. The thermal conductivity and viscosity of the nanofluid were increased with an increase in the particle volume concentration. Viscosity enhancement was greater compared to thermal conductivity enhancement under at same volume concentration and temperature. Theoretical equations were developed to predict thermal conductivity and viscosity of nanofluids without resorting to the well established Maxwell and Einstein models, respectively. The proposed equations show reasonably good agreement with the experimental results.     

An experimental study on the thermal conductivity and dynamic viscosity of TiO2-SiO2 nanofluids in water: Ethylene glycol mixture

The hybrid nanofluid has been thriving among researchers due to its potential to improve heat transfer performance. Therefore, various studies on heat transfer properties need to be carried out to provide a better understanding on hybrid nanofluid performance. In this paper, the experimental work is focused on the thermal conductivity and dynamic viscosity of TiO₂-SiO₂ nanofluids in a mixture of water and ethylene glycol (EG) with volume ratio of 60:40. The stable suspension of TiO₂-SiO₂ prepared at volume concentrations of 0.5 to 3.0%. The measurements of thermal conductivity and dynamic viscosity were performed at a temperature range of 30 to 80 °C by using KD2 Pro Thermal Properties Analyser and Brookfield LVDV III Ultra Rheometer, respectively. The thermal conductivity of TiO₂-SiO₂ nanofluids was improved by increasing the volume concentration and temperature with 22.8% maximum enhancement. Besides, the viscosity of TiO₂-SiO₂ nanofluids showed evidence of being influenced by nanofluid concentration and temperature. Additionally, the TiO₂-SiO₂ nanofluids behaved as a Newtonian fluid for volume concentration up to 3.0%. The properties enhancement ratio suggested that TiO₂-SiO₂ nanofluids will aid in heat transfer for concentrations of more than 1.5% and within the range of the temperature studied. A new correlation for thermal conductivity and dynamic viscosity of TiO₂-SiO₂ nanofluids were developed and found to be precise.     

Investigation of thermal conductivity and viscosity of Al2O3/water–ethylene glycol mixture nanocoolant for cooling channel of hot-press forming die application

Hot-press forming process is widely used to produce lightweight chassis in automotive industries. The hot-press forming process currently uses water as coolant to quench boron steels in a closed die with a cooling channel. However, to enhance performance of hot-press forming die, the fluid with better thermal properties will be used instead of normal water. This study dispersed Al₂O₃ nanoparticles with an average diameter of 13 nm in three volume percentages base ratios of water (W) to ethylene glycol (EG) (i.e. 60:40, 50:50, and 40:60) by two-step preparation. The two main parameters in cooling rate performance are thermal conductivity and viscosity. The nanocoolant of Al₂O₃/water–ethylene glycol mixture is prepared for the volume concentration range of 0.2 to 1.0%. The thermal conductivity and viscosity are then measured at temperature range of 15 to 55 °C. The highest enhancement of thermal conductivity was observed to be 10% higher than base fluid for 1.0% volume concentration at 55 °C in 60:40 (W/EG). However, the highest enhancement of viscosity was measured to be 39% for 1.0% volume concentration in 40:60 (W/EG) at 25 °C. The convective heat transfer coefficient of 1.0% concentration in 60:40 (W:EG) at 25 °C is enhanced by 25.4% better than that of 50:50 and 40:60 (W:EG) base fluid. Therefore, this study recommends the use of Al₂O₃ in 60:40 (W:EG) mixture with volume concentration of less than 1.0% for application in cooling channel of hot-press forming die. Nanocoolant as cooling agent with higher heat transfer coefficient compared to the base fluid can reduce the cycle time and increase the productivity of hot-press forming process.     

Thermo-physical properties of water based SiC nanofluids for heat transfer applications

The aim of current paper consists in the fabrication, characterization and preparation of water based on SiC nanofluids and the experimental investigation of their thermo-physical properties. Thermal conductivity, viscosity and surface tension of SiC/water nanofluids were measured for two two weight concentrations of nanoparticles 0.5 and 1.0 wt% respectively, within the range 20 °C to 50 °C. Concerning the thermal-properties of studied nanofluids, the experimental results show that the thermal conductivity increases with the increasing both of the weight concentration of the nanoparticles and temperature. Also, the dynamic viscosity of the SiC/water nanofluids increases with increasing nanoparticles concentration and decreases with the increasing temperature. Furthermore, the surface tension of studied nanofluids increases with the increase of the weight concentrations of the nanoparticles, but the results show that at a concentration of the nanoparticles of 0.5 wt%, the surface tension was lower than the surface tension of the water, while at 1.0 wt% nanoparticles, the surface tension of the nanofluids was close to the surface tension of the water. Measurements were compared with experimental data available in literature and theoretical models. Finally, SiC/water nanofluids were used as working fluid inside of the two-phase closed thermosyphon in order to study of the heat transfer from point of view both of operating temperature and the nanoparticles concentration.     

Synthesis,characterization, and thermal property measurement of nano-Al95Zn05 dispersed nanofluid prepared by a two-step process

Nanofluids are stable suspension of nanometer sized particles and exhibit extremely attractive thermal properties that make them a potential candidate for application in heat transfer devices ranging from microelectronic gadgets to thermal power plants. In the present study, we have synthesized Al-5wt%Zn nanoparticles by mechanical alloying, characterized these nanoparticles using X-ray diffraction and scanning and transmission electron microscopy. Subsequently, these nanoparticles are dispersed to the tune of 0.01–0.10 vol% in ethylene glycol (base fluid) following a careful mixing protocol. Thermal conductivity of the nanofluids and base fluid has been measured using the transient hot-wire method. It is observed that thermal conductivity of the nanofluids strongly depend on the concentration, particle size, fluid temperature and stability of dispersed nanoparticles in the base fluid. A maximum of 16% enhancement in thermal conductivity has been recorded at a nanoparticle loading of 0.10 vol%. Unlike data reported in some articles, thermal conductivity ratio of Al-5wt%Zn dispersed ethylene glycol based nanofluids is observed to decrease with the increase in crystallite/grain size of the particles.     

Thermal conductivity of Cu/TiO2–water/EG hybrid nanofluid: Experimental data and modeling using artificial neural network and correlation

In the present paper, the thermal conductivity of hybrid nanofluids is experimentally investigated. The studied nanofluid was produced using a two-step method by dispersing Cu and TiO₂ nanoparticles with average diameter of 70 and 40 nm in a binary mixture of water/EG (60:40). The properties of this nanofluid were measured in various solid concentrations (0.1, 0.2, 0.4, 0.8, 1, 1.5, and 2%) and temperatures ranging from 30 to 60 °C. Next, two new correlations for predicting the thermal conductivity of studied hybrid nanofluids, in terms of solid concentration and temperature, are proposed that use an artificial neural network (ANN) and are based on experimental data. The results indicate that these two new models have great ability to predict thermal conductivity and show excellent agreement with the experimental results.     

Direct numerical simulation of thermal conductivity of nanofluids: The effect of temperature two-way coupling and coagulation of particles

An Eulerian–Lagrangian based direct numerical simulations (DNS) model was developed to investigate the effective thermal conductivity of nanofluids. A two-way coupling term to resolve the temperature interactions between the solid particles and fluid field was considered. The model also considered various forces acting on the nanoparticles. Cu/water nanofluids with 100 nm particles and Al₂O₃/water nanofluids with 80 nm particles were simulated at different volume fractions and the effective thermal conductivity of nanofluids was calculated. The present results suggest that the particle conductivity and forces acting on nanoparticle are necessary while predicting the effective thermal conductivity of nanofluids.     

Heat transfer and friction factor of water based TiO2 and SiO2 nanofluids under turbulent flow in a tube

The heat transfer coefficient and friction factor of TiO₂ and SiO₂ water based nanofluids flowing in a circular tube under turbulent flow are investigated experimentally under constant heat flux boundary condition. TiO₂ and SiO₂ nanofluids with an average particle size of 50 nm and 22 nm respectively are used in the working fluid for volume concentrations up to 3.0%. Experiments are conducted at a bulk temperature of 30 °C in the turbulent Reynolds number range of 5000 to 25,000. The enhancements in viscosity and thermal conductivity of TiO₂ are greater than SiO₂ nanofluid. However, a maximum enhancement of 26% in heat transfer coefficients is obtained with TiO₂ nanofluid at 1.0% concentration, while SiO₂ nanofluid gave 33% enhancement at 3.0% concentration. The heat transfer coefficients are lower at all other concentrations. The particle concentration at which the nanofluids give maximum heat transfer has been determined and validated with property enhancement ratio. It is observed that the pressure drop is directly proportional to the density of the nanoparticle.     

New thermophysical properties of water based TiO2 nanofluid—The hysteresis phenomenon revisited

Homogeneous stable suspensions acquired by dispersing dry Al₂O₃ and TiO₂ nanoparticles in controlled pH solution and distilled water, respectively, were prepared and investigated in this study. First of all, the mean nanoparticle diameters were studied by dynamic light scattering (DLS) technique, and the nanofluid stability was analyzed by zeta potential measurements. The nano-crystalline structures were characterized by scanning electron microscope and transmission electron microscope. The rheological behavior was determined for both nanofluids at nanoparticle volume concentrations up to 0.3%. The effect of temperature for the heating and cooling phases was analyzed from 25 °C to 80 °C. Furthermore, the influence of temperature, pressure drop, pumping power, zeta potential, size and densities were analyzed for fresh prepared samples as well as for samples used in a flat plate solar collector over a period of 30 days. The thermal conductivity enhancement of the two nanofluids demonstrated a nonlinear relationship with respect to temperature and volume fraction, with increases in the volume fraction and temperature. All resulted in an increase in the measured enhancement. Existence of a critical temperature was observed beyond which the particle suspension properties altered drastically, which in turn triggered a hysteresis phenomenon. The hysteresis phenomenon on viscosity measurement, which is believed to be the first observed for Al₂O₃/water and TiO₂/water-based nanofluids, has raised serious concerns about the use of nanofluids for heat transfer enhancement. The pressure drop and pumping power of the nanofluid flows are found to be very close to those of the base liquid for low volume concentration. It may be concluded that nanofluids can be utilized as a working medium with a negligible effect of enhanced viscosity and/or density. Our findings provide a view on the thermo physical properties of nanofluids that is compared with that in the literature, and new findings (such as viscosity, hysteresis phenomenon and pumping power) have been presented, which are not available in literature as yet.     

The effect of alumina/water nanofluid particle size on thermal conductivity

This study examines the effect of particle size, temperature, and weight fraction on the thermal conductivity ratio of alumina(Al₂O₃)/water nanofluids. A Al₂O₃/water nanofluid produced by the direct synthesis method served as the experimental sample, and nanoparticles, each of a different nominal diameter (20, 50, and 100 nm), were dispersed into four different concentrations (0.5, 1.0, 1.5, and 2.0 wt%). This experiment measured the thermal conductivity of nanofluids with different particle sizes, weight fractions, and working temperatures (10, 30, 50 °C). The results showed a correlation between high thermal conductivity ratios and enhanced sensitivity, and small nanoparticle size and higher temperature. This research utilized experimental data to construct a new empirical equation, taking the nanoparticle size, temperature, and lower weight fraction of the nanofluid into consideration. Comparing the regression results with the experimental values, the margin of error was within ?3.5% to +2.7%. The proposed empirical equation showed reasonably good agreement with our experimental results.     

Experimental investigation of the thermophysical properties of AL2O3-nanofluid and its effect on a flat plate solar collector

Experimental investigations have been carried out for obtaining the thermophysical properties of 60:40 (by mass) ethylene glycol/water mixture and water based alumina nanofluids. The effect of density and viscosity on the pumping power for flat plate solar collector has been investigated as well. Nanofluids of 0.05–0.1%v/v concentrations were prepared and characterized. Water based alumina nanofluids were found more preferable against sedimentation and aggregation than ethylene glycol/water mixture based nanofluids. The measured thermal conductivities of both types of the nanofluids increased almost linearly with concentration and are consistent in their overall trend with previous works done at lower concentrations by different researchers. In contrast to thermal conductivity, viscosity measurements showed that the viscosity of the Al₂O₃–water nanofluids exponentially decreases with increasing temperature. Furthermore, the measured viscosities of the Al₂O₃–water nanofluids showed a non-linear relation with concentration even in the low volume concentration except 0.05%v/v at below 40 °C. On the other hand, Al₂O₃–EG/water mixture exhibited Newtonian behavior. Existence of a critical temperature was observed beyond which the particle suspension properties altered drastically, which in turn triggered a hysteresis phenomenon. The hysteresis phenomenon on viscosity measurement, which is believed to be the first observed for EG/water-based nanofluids, has raised serious concerns regarding the use of nanofluids for heat transfer enhancement purposes. Results suggest that nanofluids can be used as a working medium with a negligible effect of enhanced viscosity and/or density. Results also show that the pressure drop and pumping power of the nanofluid flows are very close to that of the base liquid for low volume concentration.