Fluid temperature and velocity effect on fouling

A wide variety of industrial processes involve the transfer of heat energy between fluids in process equipment. As a result of this energy exchange unwanted deposits accumulate on the process surfaces causing a resistance to energy transfer. These deposits reduce the heat recovery and can restrict fluid flow in the exchanger by narrowing the flow area. Prevention and control of fouling is costly and time consuming. In many situations, fouling can be reduced but not necessarily eliminated. Fouling is a major unresolved problem in heat transfer.In general, the heat exchangers evaluated in this study were exposed to untreated lake water for typical conditions. After the prescribed time period the exchangers were taken off line and evaluated. Conclusions and observations regarding fouling of brazed heat exchangers, exposed to once-through lake water, are presented here. Transient observations and photographs of the exchanger surfaces are given. Results are presented that compare these heat exchangers to test plates, also exposed to lake water. The progressive change of surface appearance with increasing immersion times is presented.     

Evaluation of heat exchanger surface coatings

Compact heat exchangers are very popular due to their effectiveness, small footprint and low cost. In order to protect heat exchangers in dirty applications, coatings can be applied to the heat transfer surfaces to extend effectiveness and minimize fouling. Coating selection is extremely important since the wrong coating can decrease unit effectiveness, cause more fouling, and/or erode the surface.An experimental investigation of coating effectiveness in compact plate heat exchangers is presented. New, cleaned and coated plate heat exchangers are considered in this study. Heat exchangers have been exposed to untreated lake water for various time periods. Transient effectiveness results compare the rate of fouling for coated and uncoated heat exchangers. Additional results compare deposit weight gain at the end of the test period and transient observations of heat transfer surface appearance. All heat exchanger combinations showed some deposit accumulation for the period considered.Results indicate that the thermal performance of the unit decreases with time, resulting in an undersized heat exchanger. For the conditions considered here, uncoated plates accumulate deposits up to 50% faster than coated plates and show a decrease in performance of up to 40%. Surface coating, exposure time, fluid velocity and concentration of particles can affect fouling.     

Perfluoropolyethers Coatings Design for Fouling Reduction on Heat Transfer Stainless-Steel Surfaces

The scope of this research is to obtain a film coating on stainless-steel surfaces in order to reduce the interaction between the metal surface and the precipitates, so as to mitigate fouling in heat exchangers. Perfuoropolyethers were used to obtain nano-range fluorinated layers in order to make hydrophobic the stainless-steel surfaces. A pilot plant with two identical heat exchangers was built to investigate the ability of the hydrophobic coating of preventing fouling. The heat exchangers, installed in parallel, operated at the same temperature and pressure conditions, namely, laminar flow regime and inlet flow temperatures of 291–293 K for cold streams and 313–333 K for hot streams. We compared the heat transfer performance of the two heat exchangers. After a 5-month operation, the decrease in the heat transferred was 56% for the coated heat exchanger and 62% for the uncoated heat exchanger. Moreover, the increase of heat transfer resistance due to scale on the uncoated heat exchanger, with respect to the coated one, was three times higher.     

Use of C-factor for monitoring of fouling in a shell and tube heat exchanger

Heat exchangers operating in process industries are fouled during operations and results in decrease in the thermal efficiency of a heat exchanger. Once the thermal efficiency decreases to a minimum acceptable level, cleaning of the equipment becomes necessary to restore the performance. This paper uses C-factor as a tool for investigation of the performance of a heat exchanger due to fouling which consequently gives information regarding the extent of fouling developed on the heat transfer surfaces. The fouling parameters are predicted by measurements of flow rate and pressure drop. In contrast to most conventional methods, the extent of fouling can be detected considering the flow rate and pressure drop when the heat exchanger operates in transient states. The C-Factor is first calculated through out cleaning period and then compared with the clean and the design value. The results show that the proposed tool is very effective in detecting the fouling developed and the corresponding degradation in heat transfer efficiency of a heat exchanger. Hence the results of this work can find applications in predicting the reduction in heat transfer efficiency due to fouling in heat exchangers that are in operation and assist the exchanger operators to plan cleaning schedules.     

Heat Exchanger Fouling in Phosphoric Acid Evaporators

Multistage shell and tube evaporators are frequently used in phosphoric acid plants to increase the concentration of dilute phosphoric acid to 52–55 wt% P₂O_5. The concentrated phosphoric acid solution is supersaturated with respect to calcium sulfate. As a result, part of the calcium sulfate in the liquor deposits on the heat exchanger tube walls. Because the thermal conductivity of these scales is very low, thin deposits can create a significant resistance to heat transfer. Therefore, regular cleaning of heat exchangers is required, frequently at shorter than biweekly intervals. As the major costs in modern phosphoric acid plants are the cost of energy, a thorough understanding of the fouling kinetics and of the effects of various operational parameters on the behavior of calcium sulfate is required to improve operation and design of the shell and tube heat exchangers, which are extensively used. In this investigation, a large set of heat exchanger data was collected from shell and tube heat exchangers of the phosphoric acid plant of the Razi Petrochemical Complex in Iran, and the fouling deposits were analyzed with respect to appearance and composition. The overall heat transfer coefficients and fouling resistances were evaluated at different times, and a kinetic model for the crystallization fouling was developed. It is shown that the crystallization rate constant obeys an Arrhenius relationship with an activation energy of 57 kJ/mol. The average absolute error of 12.4% shows that the predictions of the suggested model are in good agreement with the original plant data.     

Online Fouling Detection of Domestic Hot Water Heat Exchangers

Due to hardness of cold water supply in many countries, there is a risk of fouling in domestic hot water (DHW) counterflow plate heat exchangers. The scaling will result in increased resistance to heat transfer, which has negative effects on the economics of the district heating network. A common approach is to clean or change the heat exchanger periodically, which can be expensive if only limited fouling has occurred (unnecessary) or if a higher than expected scaling layer has formed (inefficiency). A better approach is to monitor the state of the heat exchangers and clean them when actually required. This would result in more energy-efficient operation and provide an optimum schedule for heat exchanger cleaning. This can be simple if the heat exchangers are operating under steady-state conditions; however, if large variations in the inlets are experienced, as is the case with the mass flows in DHW heat exchangers, it quickly becomes impossible with standard methods. In this paper it is proposed to monitor the state of the heat exchanger online by using measurements that are easily obtainable under normal operation and applying fast mathematical models to estimate the overall heat transfer coefficient of the heat exchanger. The results show that the methods proposed can be used to detect fouling in DHW heat exchangers.     

Numerical investigation of fouling on cross-flow heat exchanger tubes with conjugated heat transfer approach

Although fouling on heat exchanger tubes is extensively investigated, due to the lack of energy resources, the effects of fouling on heat exchangers is still an important area of study and gaining more and more attention every day. In this study we investigated the effects of fouling on heat transfer and flow structures numerically for cross-flow heat exchanger tube geometry. The distributions of temperature, heat transfer coefficient and heat flux at the surface of fouling were obtained for single and double layer fouling cases. In the analysis, Reynolds number and the blockage ratio were fixed to 100 and 0.1 respectively. We used ANSYS software in our analyses and compared some of our results with the literature.     

Crude Oil Fouling Research: HTRI's Perspective

For 20 years, Heat Transfer Research, Inc. (HTRI), has conducted dedicated, ongoing research into crude oil fouling behavior, specifically on developing test methods to measure fouling resistance over time and comparing fouling tendencies of different crude oils. More than 250 test runs with nineteen crude oils have been conducted. While current methods are sufficient for comparative fouling studies, general methods to predict fouling tendency remain elusive. Recent initiatives have focused our efforts on chemical characterization to screen crude oils and blends for fouling tendency, as well as on identifying thresholds for low fouling. Increasing the shear stress on the heat transfer surface as much as possible can mitigate heat exchanger fouling. Long-term success in controlling fouling depends upon a deeper understanding of the chemical characteristics of an individual crude oil and sound heat exchanger design practices. Current predictive fouling models are limited in their application, but improvements based on chemical characterization look promising.     

Fouling Reduction Characteristics of a No-Distributor-Fluidized-Bed Heat Exchanger for Flue Gas Heat Recovery

Heat exchangers and heat exchanger networks are extensively used for the purpose of recovering energy. In conventional flue gas heat recovery systems, the fouling by fly ashes and the related problems such as corrosion and cleaning are known to be major drawbacks. To overcome these problems, a single-riser no-distributor-fluidized-bed heat exchanger is devised and studied. Fouling and cleaning tests are performed for a uniquely designed fluidized bed-type heat exchanger to demonstrate the effect of particles on the fouling reduction and heat transfer enhancement. The tested heat exchanger model (1 m high and 54 mm internal diameter) is a gas-to-water type and composed of a main vertical tube and four auxiliary tubes through which particles circulate and transfer heat. Through the present study, the fouling on the heat transfer surface could successfully be simulated by controlling air-to-fuel ratios rather than introducing particles through an external feeder, which produced soft deposit layers with 1 to 1.5 mm thickness on the inside pipe wall. Flue gas temperature at the inlet of heat exchanger was maintained at 450°C at the gas volume rate of 0.738 to 0.768 CMM (0.0123 to 0.0128 m³/sec). From the analyses of the measured data, heat transfer performances of the heat exchanger before and after fouling and with and without particles were evaluated. Results showed that soft deposits were easily removed by introducing glass bead particles, and also heat transfer performance increased two times by the particle circulation. In addition, it was found that this type of heat exchanger had high potential to recover heat of waste gases from furnaces, boilers, and incinerators effectively and to reduce fouling related problems.     

Detailed equipment design in heat exchanger networks synthesis and optimisation

In heat exchanger network synthesis, important features like pressure drop and fouling effects are usually neglected. In this work a new methodology is proposed to include these effects in grassroots as in retrofit designs. Heat exchangers are detailed designed during the heat exchanger network synthesis. Pinch analysis is used to obtain the heat exchangers network with the maximum energy recovery, and a new systematic procedure is proposed to the identification and loop breaking. Bell–Delaware method for the shell side is used to design the heat exchangers. An example of the literature was studied and the results show differences between heat exchangers, with and without the detailed design, relative to heat transfer area, fouling and pressure drop. The great contribution of this work is that individual and global heat transfer coefficients are always calculated, in despite of the current literature, where these value are assumed in the design step. Moreover, the methodology proposed to the heat exchangers design assures the minor heat exchanger according to TEMA standards, contributing to the minimisation of the heat exchanger network global annual cost. Finely, the new heat exchanger network considering pressure drops and fouling effects presents values more realistic then those one neglecting the equipment detailed design.     

Most Frequently Used Heat Exchangers from Pioneering Research to Worldwide Applications

Heat exchangers contribute significantly to many energy conversion processes. Applications range from power production, petroleum refining and chemicals, paper and pharmaceutical production, to aviation and transportation industries. A large percentage of world market for heat exchangers is served by the industry workhorse, the shell-and-tube heat exchanger. Recent developments in other exchanger geometries have penetrated in various industry applications; however, the shell-and-tube exchanger by far remains the industry choice where reliability and maintainability are vital. Over the years, significant research and development efforts are devoted to better understand the shell-side geometry. New geometries are introduced for performance enhancement and to improve reliability. The pioneering work published by J. Nemcansky et al. in the Trans. Institute of Chemical Engineers in May, 1990, on helical baffles paved the way to a major shift from a conventional understanding of baffles in a shell-and-tube heat exchanger. Helical baffles serve as guide vanes for shell-side flow as compared to creating flow channels with conventional segmented baffles. In the past decade, ABB Lummus Heat Transfer has extended the understanding of the helical baffle geometry through extensive testing and development. CFD flow simulation studies have further confirmed the helical baffle advantage. Industry feedback on operating Helixchanger® heat exchangers—the shell-and-tube heat exchangers with helical baffles—has demonstrated low fouling characteristics as well as a higher conversion of shell-side pressure drop to heat transfer. In this paper, the characteristics of this novel Helixchanger heat exchanger are discussed. Examples from early installations in the power industry to the major applications in the petro-chemical and refining industries are presented, illustrating the advantages in reducing fouling and increasing reliability while achieving lower total life cycle costs.     

Use of crude oil fouling threshold data in heat exchanger design

The existence of a `threshold' below which chemical reaction fouling of heat transfer surfaces by crude oil does not occur has been identified by Ebert and Panchal [Fouling Mitigation of Industrial Heat-Exchange Equipment, Begell House, 1997, 451–460] and clearly demonstrated by Knudsen et al. [Understanding Heat Exchanger Fouling and its Mitigation, Begell House, 1999, 265–272]. This phenomenon has important implications for the design and operation of heat exchangers in refinery pre-heat trains used for the processing of crudes. In this paper we show how a consideration of the fouling threshold condition can be incorporated into the design procedures for shell-and-tube heat exchangers. We then proceed to show how fouling can be mitigated through attention to heat exchanger design, particularly the choice of configuration. The cost of improperly designed units, based on the conventional use of `fouling factors', is demonstrated.     

影响换热面结垢诱导期的表面特性研究

换热面结垢是一个普遍存在的问题,而结垢诱导期的长短对污垢形成过程具有重要的影响,即使在相同实验条件下,不同材料换热面的结垢诱导期仍相差较大.因此本文通过对附着在换热面上的半球形污垢晶核进行受力分析,发现污垢晶核与换热面之间的附着力对其结垢诱导期长短起决定性作用,然后根据颗粒与平板间附着力模型,计算了污垢晶核与具有不同表面能的换热面间附着力,并与相应的结垢诱导期进行对比.结果表明:结垢诱导期的长短与换热面的表面能、污垢晶核与换热面间的附着力及表面粗糙度尺度有关.     

Influence of the Apex Angle of Cone-Shaped Tubes on Particulate Fouling of Heat Exchangers

A two-dimensional (2D) cone shape has been added to the normal circular tubes of heat exchangers to minimize the area of stagnation and to streamline the air flow around the heat exchanger tubes. An experimental setup has been developed to study the influence of the apex angle of the cone-shaped tubes on particulate fouling of heat exchangers. Fouling experiments have been performed in which calcium carbonate particles are injected during the experiments and the deposition of particles on the tubes of the heat exchanger is monitored. Four sets of experiments have been performed, in which normal cylindrical tubes and coned tubes with an apex angle of 60°, 90°, and 120° are examined. It was found that particulate fouling ceased if the apex angle of the cone-shaped tubes is smaller than 90°. The attached cones enhance the flow around the tubes of the heat exchanger, by minimizing the stagnation area and keeping the flow attached to the tubes starting from the tip of the attached cone until separation, such that particles that deposit on the top of the tubes of the heat exchanger can be removed by the air flow.     

Experimental Analysis of the Effects of Particulate Fouling on Heat Exchanger Heat Transfer and Air-Side Pressure Drop for a Hybrid Dry Cooler

It is well known that significant fouling by particulate matter can have a deleterious effect on the performance of enhanced surface heat exchangers, and the same is true for hybrid heat exchangers. Hybrid heat exchangers are heat exchangers that are typically run in dry mode to reject heat. When the ambient conditions require more heat rejection than can be provided by sensible heat transfer, a water pump is turned on and water flows over the fins, and the evaporation of water provides a further cooling effect. Fouling in dry-mode operation is physically similar to that of air-cooled heat exchangers, but in evaporative mode the flow of the water over the coil eliminates the impact of fouling. A hybrid dry cooler heat exchanger of 60 cm × 60 cm frontal area has been installed in a well-instrumented wind tunnel to measure the heat exchanger's performance. Hot water flows through the coil to provide the load, and air flows over the coil to provide cooling. During evaporative mode operation another stream of water flows over the outside face of the coil, adhering mainly to the louvered fins. The louvered fins are specially designed for optimized water flow during wetting mode. The fins are made of aluminum, the tubes are copper, and protection against corrosion is realized by a special E-coating. This coil has been tested clean and fouled with ASHRAE standard dust, for both dry and wet operation. Results are presented for the air-side pressure drop and overall heat transfer conductance of the coil under all conditions for which 50% increases in air-side pressure drop are found under heavy fouling. The influence of fouling on heat transfer is small. Also, using the wetting water to wash the fouling off the coil is investigated and is found to be of some limited utility.     

Design of a novel, intensified heat exchanger for reduced fouling rates

This paper describes an integrated approach into the design and evaluation of a novel tube bundle heat exchanger that achieves higher heat transfer levels at lower levels of pressure drop, while remaining less susceptible to gas-side fouling. The approach combines laboratory scale experiments with industrial observations and numerical simulations of full-scale heat exchangers to study the thermal, hydraulic and fouling characteristics of tube bundle heat exchangers. Three arrangements are compared and the advantages of the proposed novel arrangement are demonstrated. Enhanced heat transfer rates are combined with reduced pressure drop and gas-side fouling rates through careful design of the shape of the tube cross-section and reduced transverse spacing.     

Extending the Induction Period of Crystallization Fouling Through Surface Coating

To minimize the negative effects of scale formation in heat exchangers, new anti-fouling strategies are focusing on the modification of heat transfer surfaces. These modifications should lead to tailor-made surfaces for different technical applications. The aim of this surface modification is the extension of the induction period to minimize the negative effects of fouling and maximize the endurance of the heat exchanger. To achieve this, different surface coatings on stainless steel were investigated with respect to fouling tendency. The effects of flow velocity with respect to Reynolds number on the induction time of CaSO₄ crystallization fouling were tested in different test units. Diamond-like carbon (DLC) coatings extend the induction time at every measured flow velocity. At higher Reynolds numbers, the effect of different surface crystallization due to energetic modification is reduced because of the dominating effect of the low adhesive surface. Thus the induction time can be extended by the factor of 2 for low fluid velocities (DLC or SICON®) and by more than 14 for higher Reynolds numbers (DLC and SICON®). The combination of limited nucleation spots due to electro-chemical treatment of the substrate before coating can give a tailor-made surface with maximum induction time for crystallization fouling.     

“Zero Fouling” Self-Cleaning Heat Exchanger

Conventional shell and tube heat exchangers sometimes have to use two severely fouling process streams, one in the tubes and one in the shell. This paper presents the design of a self-cleaning heat exchanger that applies the self-cleaning mechanism in the tubes of two parallel bundles handling the fouling process streams. For the transfer of heat between both bundles, a small circulating flow of conditioned water is used as an intermediate fluid, a fraction of which evaporates on the outside of the tubes of the high-temperature bundle and condenses on the outside of the tubes of the low-temperature bundle. This novel design, which consists of two parallel bundles in one shell, experiences very high film coefficients at the outside surface of both tube bundles and does not suffer from any fouling. Therefore, it is referred to as a “zero fouling” self-cleaning heat exchanger. In this paper, a conventional severely fouling crude oil preheater will be compared with a zero fouling self-cleaning heat exchanger for the same service.     

Strategy for selection of elements for heat transfer enhancement

The present paper points out that the selection of elements for heat transfer enhancement in heat exchangers requires a methodology to make a direct comparison of the performances of heat exchanger surfaces with different elements. Methods of comparison used in the past are, in many respects, approximate and hence fail to predict accurately the relative performance of conventional heat exchanger surfaces operated with different heat exchanger elements. Owing to the direct use of the Colburn factor for performance assessment, these methods over-predict the relative performance of heat exchangers. In the present paper, a more consistent comparison method is presented and is demonstrated to work by comparison of the performance of an experimentally investigated pin fin heat exchanger with that of a smooth pipe heat exchanger. The method yields results that belong to the volume goodness factors group. It represents a practical approach, as it is applicable to all kinds of heat exchanger surfaces and does not require the conversion of the experimental data in terms of Nusselt number and friction factor for comparison purposes. The present work demonstrates that the suggested method can also be used for performance comparison of existing heat exchanger surfaces with available heat transfer and pressure loss data.     

Editorial

The Donald Q. Kern Award for 2004 was conferred on Dr. Ramesh K. Shah at the Summer Annual Heat Transfer Conference, San Francisco, Calif., on July 19, 2005. Although editorials in Heat Transfer Engineering usually deal with heat transfer processes or heat exchangers, I would like to use this page to salute an outstanding practitioner of heat transfer. First, a few words about Don Kern.