Effect of fiber orientation on Mode I fracture toughness of CFRP

The effect of fiber orientations on fracture toughness of carbon fiber reinforced plastics (CFRP) in Mode I loading was investigated using double cantilever beam (DCB) specimens, based on mesoscopic mechanics. Mesoscopic interlaminar fracture toughness of 0//0 interphase of CFRP was evaluated with mesoscopic finite element models using experimental data. The fracture surface roughness was observed by confocal laser scanning microscopy. Then the mesoscopic interlaminar fracture toughness of CFRP was correlated with the fracture surface roughness. Additionally, the change of the Mode I macroscopic fracture toughness of CFRP was experimentally measured with changing the numbers of 0 and ±θ layers of DCB specimens. The correlation between the fracture toughness of 0//0 and θ//?θ interphases was discussed and a novel procedure was proposed to predict the macroscopic fracture toughness of θ//?θ interphase using finite element method (FEM). The fracture toughness of θ//?θ interphase analyzed by FEM was finally compared with the experimental results to verify the proposed prediction procedure. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Effect of hybridization on the mode II fracture toughness properties of flax/vinyl ester composites

In this study, flax fiber reinforced and flax/basalt hybridized vinyl ester composites were produced and their interlaminar fracture toughness (mode II) behavior was investigated using the three‐point bend end‐notched flexural (3ENF) testing. From the results, the average of the maximum values for each group of specimen obtained for critical strain energy release rate G _IIC and stress intensity factor K _II for flax/vinyl ester specimens were 1,940 J/m² and 134 kPam^0.5. Similarly, G _IIC and K _II values recorded for hybridized specimens were 2,173 J/m² and 178 kPam^0.5, respectively. The results for the flax/basalt hybridized composites exhibited an improved fracture toughness behavior compared to flax/vinyl ester composites without hybridization. The cohesive zone modeling (CZM) was also used to predict the delamination crack propagation in mode‐II in laminated composite structures. After the experimental study, the 3ENF specimens were modeled and simulated using ANSYS. The CZM/FEA results were in reasonable agreement with the experimental results. POLYM. COMPOS., 38:1732–1740, 2017. © 2015 Society of Plastics Engineers     

The fracture toughness of inorganic glasses

Measuring the fracture toughness (K_Ic) of glasses still remains a difficult task, raising experimental and theoretical problems as well. The available methods to estimate K_Ic are reviewed, with emphasis on their respective advantages and drawbacks. In view of our current understanding, this analysis gives precedence to the SEPB method. The ultimate glass strength, the critical flaw size, and the indentation load for the onset of crack initiation are discussed, in the light of the fundamentals of fracture mechanics and classical background regarding the mechanics of brittle materials. Analytical expressions were further proposed to predict the fracture energy and fracture toughness of glasses from different chemical systems from their nominal compositions. The theoretical values were compared with the experimental ones, as obtained by self‐consistent methods when available. The agreement observed in most cases suggests that measured K_Ic values correspond to the crack propagation regime (as opposed to the crack initiation threshold), and supports previous investigations in glasses and ceramics, which showed that a crack tip is nearly atomically sharp in these materials (but for metallic glasses). Some ideas to design tougher glasses are finally presented.     

High‐temperature fracture toughness of mullite with monoclinic zirconia

Reactive sintering of zircon and alumina and zirconia additions to mullite are well‐established methods for improving the poor fracture toughness of mullite. While it is clear that transformation toughening is responsible for the improved toughness by addition of partially stabilized zirconia, it is not clear why adding unstabilized zirconia increases the toughness although microcracking and crack deflection have been suggested. Therefore, the fracture toughness of a mullite composite with 20 vol% unstabilized zirconia and a monolithic mullite were investigated at ambient conditions and at temperatures up to 1225°C. It was found that monoclinic zirconia increases the toughness at ambient conditions from the monolithic mullite value of 1.9 to 3.9 MPa·m^1/2. The toughness of the composite with zirconia remains relatively constant from ambient to 600°C but then decreases rapidly. The mechanism for the toughness enhancement as well as the reason for its variation with temperature are explained using changes in residual stress state as deduced using the sphere in shell model from the measured thermal expansion behavior.     

Effect of interlaminar toughness on the low‐velocity impact damage in composite laminates

Based on the continuum damage mechanics (CDM) and the cohesive zone model (CZM), a numerical analysis method for the evaluation of damage in composite laminates under low‐velocity impact is proposed. The intraply damage including matrix crack and fiber fracture is represented by the CDM which takes into account the progressive failure behavior in the ply, using the damage variable to describe the intraply damage state. The delamination is characterized by a special contact law including the CZM which takes into account the normal crack and the tangential slip. The effect of the interlaminar toughness on the impact damage is investigated, which is as yet seldom discussed in detail. The results reveal that as the interlaminar fracture toughness enhances, the delamination area and the dissipated energy caused by delamination decrease. The contribution of normal crack and tangential slip to delamination is evaluated numerically, and the later one is the dominant delamination type during the impact process. Meanwhile, the numerical prediction has a good agreement with the experimental results. The study is helpful for the optimal design and application of composite laminates, especially for the design of interlaminar toughness according to certain requirements. POLYM. COMPOS. 37:1085–1092, 2016. © 2014 Society of Plastics Engineers     

Fracture toughness evaluation of polytetrafluoroethylene

The objective of this preliminary work was to explore the fracture resistance of polytetrafluoroethylene (PTFE) (DuPont tradename Teflon) as part of materials characterization work related to the development of “reactive” material projectiles. Little mechanical property data is available on this material since it is commonly used only as a coating material with the dominant properties being its low friction coefficient and high application temperature. Additional end products of the “7C” derivative, however, includes sheet, gaskets, bearing pads, piston rings, and diaphragms. In this work, standard ASTM E1820 fracture toughness specimens were machined from a 14‐mm‐thick sheet of this material obtained from NSWC Dahlgren Laboratory. These specimens were tested at three test temperatures and four test rates to determine if fracture would occur in this material, and if so, how the fracture toughness depends on the test temperature and specimen loading rate. Standard axial tensile specimens were also tested at quasi‐static and elevated loading rates at temperatures from ambient to ?73°C. The major results are that while crack extension is difficult at ambient (20°C) temperature, for temperatures slightly below ambient, a rapid degradation of fracture resistance occurs. This reduction in fracture resistance is enhanced by rapid loading, and the material loses approximately 75% of its toughness (fracture energy absorption ability) at ?18°C if the crack opening loading rate of the C(T) specimen approaches 0.25 m/s. Further reductions in temperature or increases in the loading rate appear to result in a reduced rate of degradation of fracture toughness.     

Effects of indenter angle on micro‐scale fracture toughness measurement by pillar splitting

We present improvements to a recently developed pillar splitting technique that can be used to characterize the fracture toughness of materials at the micrometer scale. Micro‐pillars with different aspect ratios were milled from bulk Si (100) and TiN and CrN thin films, and pillar splitting tests were carried out using four different triangular pyramidal indenters with centerline‐to‐face angles varying from 35.3° to 65.3°. Cohesive zone finite element modeling (CZ‐FEM) was used to evaluate the effect of different material parameters and indenter geometries on the splitting behavior. Pillar splitting experiments revealed a linear relationship between the splitting load and the indenter angle, while CZ‐FEM simulations provided the dimensionless coefficients needed to estimate the fracture toughness from the splitting load. The results provide novel insights into the fracture toughness of materials at small‐scales using the pillar spitting technique and provide a simple and reliable way to measure fracture toughness over a broad range of material properties.     

Effect of high loading rate and low temperature on mode I fracture toughness of ductile polyurethane adhesive

The mode I fracture toughness of an adhesive at low temperatures under high loading rates are studied experimentally. Typical R-curves of the polyurethane adhesive under different loading rates (0.5?mm/min, 50?mm/min, 500?mm/min) at different temperatures (room temperature, ?20?°C, ?40?°C) respectively are obtained. From the experimental results, the mode I fracture toughness of this adhesive is extremely sensitive to the high loading rates and low temperatures. With the increase of the loading rate and decrease of temperature, the mode I fracture toughness of this adhesive decreases significantly. Under the loading rate of 500?mm/min at ?40?°C, the mode I fracture toughness of adhesive is 15% of the value at room temperature (RT) under quasi-static conditions. Through the experiment, the relationship between mode I fracture toughness of this adhesive, nominal strain rate and temperature is obtained.     

Improvement in interfacial shear strength and fracture toughness for carbon fiber reinforced epoxy composite by fiber sizing

Carbon fiber was sized by a thermoplastic polymer solution mixed with a compatible amine monomer. The effect of sizing agent on tensile strength was studied by single fiber strength testing. Interfacial properties of re‐sized carbon fiber/epoxy composite were investigated, with special emphasis on the improvement in both interfacial shear strength and interfacial fracture toughness. The interfacial fracture toughness of composites was characterized by calculating the effective interphase fracture energy rate through the information obtained from the force–displacement curve in the micro‐bond test. Fracture topography of micro‐bond specimen was observed to discuss the interfacial fracture mechanism. POLYM. COMPOS., 35:482–488, 2014. © 2013 Society of Plastics Engineers     

Predicting environmental degradation of adhesive joints using a cohesive zone finite element model based on accelerated fracture tests

A framework was developed to predict the fracture toughness of degraded adhesive joints by incorporating a cohesive zone finite element (FE) model with fracture data of accelerated aging tests. The developed framework addresses two major issues in the fracture toughness prediction of degraded joints by significant reduction of exposure time using open-faced technique and by the ability to incorporate the spatial variation of degradation with the aid of a 3D FE model. A cohesive zone model with triangular traction-separation law was adapted to model the adhesive layer. The degraded cohesive parameters were determined using the relationship between the fracture toughness, from open-faced DCB (ODCB) specimens, and an exposure index (EI), the time integration of the water concentration. Degraded fracture toughness predictions were done by calculating the EI values and thereby the degraded cohesive parameters across the width of the closed joints. The framework was validated by comparing the FE predictions against the fracture experiment results of degraded closed DCB (CDCB) joints. Good agreement was observed between the FE predictions and the experimental fracture toughness values, when both ODCB and CDBC were aged in the same temperature and humidity conditions. It was also shown that at a given temperature, predictions can be made with reasonable accuracy by extending the knowledge of degradation behavior from one humidity level to another.     

Simultaneous effects of silanized coal fly ash and nano/micro glass fiber on fracture toughness and mechanical properties of carbon fiber‐reinforced vinyl ester resin composites

In this study, the simultaneous effects of both silanized coal fly ash (S‐CFA) and nano/micro glass fiber (nGF) on fracture toughness and mechanical properties of vinyl ester (VE) resin filled with carbon fiber‐based composite materials were investigated. The CFA was treated with (3‐trimethoxysilyl) propyl methacrylate to introduce the methacryloxy groups into the surface of CFA, and was confirmed by using FTIR technique. The nGF and S‐CFA with different weight ratios were well mixed with VE resin by using of high‐speed mechanical stirrer, and ultrasonic technique before using as matrices for fabrication of carbon fiber‐based composite materials via sheet molding compound (SMC) method and hot curing processing. Many characteristics of both cured VE resin composites and carbon fiber‐based composite were examined such as mechanical properties, fracture toughness, and morphology. The results showed that by adding of both 0.1 wt% nGF and 1 wt% S‐CFA into VE resin the tensile strength, tensile modulus, flexural strength, K_IC, impact strength as well as the Mode I interlaminar fracture toughness (G_IC) of VE composites and carbon fiber based composites get optimum values and increased about 61.39%; 39.83%; 36.21%; 103.1%; 81.79%; 48.61%, respectively when compared with pristine materials. POLYM. ENG. SCI., 59:584–591, 2019. © 2018 Society of Plastics Engineers     

Interlaminar fracture toughness of woven fabric composite laminates with carbon nanotube/epoxy interleaf films

The Mode I interlaminar fracture behavior of woven carbon fiber/epoxy composite laminates incorporating partially cured carbon nanotube/epoxy composite films has been investigated. Laminates with films containing carbon nanotubes (CNTs) in the as‐received state and functionalized with polyamidoamine were evaluated, as well as laminates with neat epoxy films. Double‐cantilever beam (DCB) specimens were used to measure G_Ic, the critical strain energy release rate (fracture toughness) versus crack length. Post‐fracture microscopic inspection of the fracture surfaces was performed. Results show that initial fracture toughness was improved with the amino‐functionalized CNT/epoxy interleaf films, but the important factor appears to be the polyamidoamine functionalization, not the CNTs. The initial fracture toughness remained relatively unaffected with the incorporation of neat epoxy and as‐received CNT/epoxy interleaf films. Plateau fracture toughness was unchanged with the use of functionalized CNT/epoxy interleaf films, and was reduced with the use of neat epoxy and as‐received CNT/epoxy interleaf films. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

Strength prediction of adhesively bonded repairs on carbon‐epoxy laminates by the single and double‐strap techniques

This work proposes a numerical technique for the strength prediction of composite structures repaired with adhesively bonded patches, using the finite element method (FEM). This technique is based on the use of cohesive elements including mixed‐mode criteria to simulate a cohesive fracture of the adhesive layer. Trapezoidal traction‐separation laws were used. Experimental validation of this procedure is accomplished by a parametric study on adhesively bonded single‐strap (SS) and double‐strap (DS) repairs on carbon fiber reinforced polymer (CFRP) laminates under different loadings (tension, compression, and bending). From the test results and simulations the numerical technique was validated and some design tendencies emerged for efficient repairs. POLYM. COMPOS., © 2011 Society of Plastics Engineers.     

Effect of graphene oxide on the interlaminar fracture toughness of carbon fiber/epoxy composites

Graphene oxide (GO) nanoparticles were introduced in the interlaminar region of carbon fiber–epoxy composites by dispersing it in a thermoplastic polymer carrier such as polyvinylpyrrolidone (PVP). Mode‐I fracture toughness (G_IC) was investigated using double cantilever beam testing to evaluate the effect of the GO on the delamination behavior of the composite. The GO content was varied from 0% to 7% by weight as a function of the PVP content. Improvement of ～100% in the Mode I fracture toughness (G_IC) was observed compared to composites with no GO. The optimum amount of nanoparticles for improving the interlaminar fracture toughness was found to be ～0.007% by weight of the composite. The increase in the value of flexural strength value was also observed. Scanning electron microscopy of fracture surfaces, X‐ray diffraction, and transmission electron microscopy, and reflectance Fourier transform infrared spectra, as well as Raman spectroscopy results, are presented to support the conclusions. POLYM. ENG. SCI., 59:1199–1208 2019. © 2019 Society of Plastics Engineers     

Effects of poling state and pores on fracture toughness of Pb(Zr0·95Ti0·05)O3 ferroelectric ceramics

Abstract

Abstract

The effects of poling state and pores on the fracture toughness of Pb(Zr_0·95Ti_0·05)O₃ (PZT 95/5) ferroelectric ceramics were investigated. X-ray diffraction analysis and piezoelectric constant measurements reveal that the phase structures of PZT 95/5 ceramics change with the poling state, which significantly affects the fracture toughness. The poled PZT 95/5 ceramics demonstrate higher fracture toughness than the unpoled ceramics, and their fracture toughness significantly increases after the pressure depoling. As the porosity of ceramics increases with addition of poreformer during preparation, their fracture toughnesses all decrease accordingly either in poled state or unpoled state. The effect of pore size on the fracture toughness is subtle for the poled ceramics, but for the hydrostatic pressure depoled porous PZT 95/5 ceramics, their fracture toughness increases with the increase in pore size. A new stress model is proposed to explain the pore size effect on the fracture toughness of hydrostatic pressure depoled PZT 95/5 ceramics.     

Fracture toughness of epoxy-based stepped functionally graded materials reinforced with carbon nanotubes

The aim of this work is to investigate the fracture characteristics of the epoxy-based stepped functionally graded materials (FGM) reinforced with carbon nanotubes (CNTs). The effects regarding fracture toughness in mode I were also studied. The specimens were fabricated with three different mass percentages of 0.1, 0.2 and 0.3%. An ultrasonic device was used to disperse the carbon nanotubes to have a uniform mixture without agglomeration of the CNT particles. Using the ASTM standard D-5045, the fracture toughness was obtained in the experiments. Some compact tension specimens were tested in a tensile machine in mode I. Two different notches were investigated to calculate the fracture toughness. For each notch, there were different fracture toughness and fracture forces values. The experiments showed that there is an improvement in the fracture resistance of FGMs and non-graded composite materials by increase in the CNTs content. The materials with the same content of carbon nanotubes do not have the same properties. It is seen that high fracture toughness can be obtained from different CNT content materials in each notch. In fact, the size of the notch affects the results. Comparing the fracture toughness values and fracture forces results showed that there is no specified rule to predict the increase in the fracture characteristics by increasing carbon nanotubes content. Fracture characteristics depend on the important parameters such as the size of the notch, CNTs content and dispersion of the carbon nanotubes.     

Comparison of laboratory techniques for evaluating the fracture toughness of glassy polymers

Several test methods were employed to determine polymer fracture toughness (??_Ic, the opening-mode strain energy release rate) at room temperature. The materials used included DGEBA epoxies and those modified by the addition of CTBN elastomers. Double-cantilever beam specimens were used to determine the fracture toughness both of bulk resins and of an adhesive layer bonded between two aluminum half-beams. The adhesive fracture toughness of a 0.025-cm bond was slightly less than the bulk ??_Ic value, attributed to the bond thickness effect. Fracture toughness of bulk resins was also evaluated by using both rectangular and round compact tension specimens. The results, when compared with those obtained with the bulk double-cantilever beams, are quite acceptable. The thickness of compact tension specimens, ranging from 0.64 to 1.0 cm, might not give pure plane-strain conditions, and thus some plane-stress contribution to ??_Ic should be expected for the tougher materials. Izod impact tests were also carried out to determine sample fracture toughness at high loading rate.     

Influence of graphene nanoplatelets (GNPs) on mode I fracture toughness of an epoxy adhesive under thermal fatigue

Abstract

The contribution of graphene nanoplatelets (GNPs) for enhancing the fracture toughness of a commonly used room-cured epoxy, used to bond E-glass/epoxy composite adherends, is evaluated. A comprehensive experimental investigation is conducted to examine the performance and degradation of adhesively bonded joints subject to cyclic thermal loading using the standard double cantilever beam (DCB) specimens. Several groups of DCB specimens were fabricated using the adhesive reinforced with four different GNPs weight-percentages (i.e. 0.0, 0.25, 0.5 and 1%). The specimens are subsequently subjected to various numbers of thermal cycles (to a maximum of 1000 heating/cooling cycles), and then tested, and the resulting mode I fracture toughness values are evaluated and compared. The extent and modes of damage captured through microscopy and scanning electron microscopy images are presented and discussed. In addition, a computational framework, using the cohesive zone modeling technique, is developed for predicting the response of the adhesives and their damage evolution.     

Enhancement of interlaminar fracture toughness of carbon fiber–epoxy composites using polyamide‐6,6 electrospun nanofibers

In this study, carbon fiber–epoxy composites are interleaved with electrospun polyamide‐6,6 (PA 66) nanofibers to improve their Mode‐I fracture toughness. These nanofibers are directly deposited onto carbon fabrics before composite manufacturing via vacuum infusion. Three‐point bending, tensile, compression, interlaminar shear strength, Charpy impact, and double cantilever beam tests are performed on the reference and PA 66 interleaved specimens to evaluate the effects of PA 66 nanofibers on the mechanical properties of composites. To investigate the effect of nanofiber areal weight density (AWD), nanointerlayers with various AWD are prepared by changing the electrospinning duration. It is found that the electrospun PA 66 nanofibers are very effective in improving Mode‐I toughness and impact resistance, compressive strength, flexural modulus, and strength of the composites. However, these nanofibers cause a decrease in the tensile strength of the composites. The glass‐transition temperature of the composites is not affected by the addition of PA 66 nanofibers. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 45244.     

Impact fracture toughness and morphology of diatomite‐filled polypropylene composites

Impact fracture strength is an important characterization for impact toughness of materials. A polypropylene (PP) filled with diatomite with different diameter (5, 7, and 13 μm) was fabricated by means a twin‐screw extruder. The impact fracture strength of these composites was measured at room temperature to identify the effects of diatomite content and diameter on impact fracture strength of filled polypropylene composites. The results showed that the influence of diatomite on the notched impact strength was significant. When the volume fraction of the diatomite (?_f) was less than 10%, the notched impact strength (σ_I) increased quickly with an addition of ?_f, and then the variation of σ_I was slight. The notched impact strength of the composite with the diatomite diameter of 7 μm is the highest when ?_f was 10%. Furthermore, the impact fracture surface was observed by using a scanning electronic microscope (SEM) to study the toughening mechanisms. POLYM. ENG. SCI., 2009. © 2009 Society of Plastics Engineers