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Cr12MoV钢表面激光熔覆多层Ni基合金涂层的组织及性能
引用本文:沈大臣,叶宏,汪砚青,刘越,李礼,肖鑫羽,佘红艳.Cr12MoV钢表面激光熔覆多层Ni基合金涂层的组织及性能[J].金属热处理,2020,45(12):169-174.
作者姓名:沈大臣  叶宏  汪砚青  刘越  李礼  肖鑫羽  佘红艳
作者单位:1.重庆理工大学 材料科学与工程学院, 重庆 400054;2.重庆市高校模具技术重点实验室, 重庆 400054
基金项目:重庆市大学生创新创业训练计划;重庆理工大学研究生创新基金
摘    要:使用脉冲Nd:YAG激光器在Cr12MoV模具钢表面熔覆了Ni20Cr和Ni60A多层Ni基合金耐磨涂层,并使用X射线衍射仪、扫描电镜及能谱仪分析了涂层的物相和显微组织。同时运用显微维氏硬度计以及高速往复摩擦磨损试验机对比分析了涂层与基体的硬度及耐磨性。结果表明,采用Ni20Cr作为打底层的多层Ni基合金涂层,能有效改善涂层与基体的冶金结合,大大减少涂层中的裂纹、气孔等缺陷。涂层表面物相主要为g-(Fe, Ni)、FeNi3、BNi3、Cr3C2以及Ni-Cr-Fe;涂层底部至表面的组织为胞状树枝晶、柱状树枝晶、择优生长树枝晶以及等轴树枝晶。Ni60A涂层大大提高了Cr12MoV模具钢的表面硬度,涂层表面显微硬度最高可达到1000 HV0.2,是基体的1.6倍。Ni60A涂层耐磨损性能明显优于基体,较基体提高了2.0~3.3倍。在Cr12MoV模具钢表面激光熔覆多层Ni基合金涂层后,形成了Cr3C2、Ni-Cr-Fe等硬质相,可有效提高其表面的硬度和耐磨性,起到降低模具在使用过程中因摩擦磨损而报废的概率,从而进一步延长模具的使用寿命。

关 键 词:Cr12MoV钢  激光熔覆  Ni基涂层  组织  力学性能  
收稿时间:2020-07-11

Microstructure and properties of laser clad multi-layer Ni-based coating on Cr12MoV steel surface
Shen Dachen,Ye Hong,Wang Yanqing,Liu Yue,Li Li,Xiao Xinyu,She Hongyan.Microstructure and properties of laser clad multi-layer Ni-based coating on Cr12MoV steel surface[J].Heat Treatment of Metals,2020,45(12):169-174.
Authors:Shen Dachen  Ye Hong  Wang Yanqing  Liu Yue  Li Li  Xiao Xinyu  She Hongyan
Affiliation:1. School of Materials Science and Engineering, Chongqing University of Technology, Chongqing 400054, China;2. Chongqing Key Laboratory of Mold Technology, Chongqing 400054, China
Abstract:Ni20Cr and Ni60A multi-layer Ni-based alloy wear resistant coating was prepared by laser cladding on the surface of Cr12MoV die steel by pulsed Nd:YAG laser, the phases and microstructure of the coatings were analyzed by using X-ray diffractometer, scanning electron microscope, and energy spectrometer, meanwhile the hardness and wear resistance of both the coating and the substrate were analyzed by using Vickers microhardness tester, high-speed reciprocating friction and wear tester. The results show that using the Ni20Cr as the underlying layer of the multi-layer alloy coating can effectively improve the metallurgical bond between the coating and the substrate, which can greatly reduce the defects such as cracks and pores in the coating. The main phases of the coating surface are g-(Fe, Ni), FeNi3, BNi3, Cr3C2 and Ni-Cr-Fe. The structure of the coating from bottom to surface in turn is cellular dendrites, columnar dendrites, preferentially growing dendrites and equiaxed dendrites. The Ni60A coating can greatly improve the surface microhardness of Cr12MoV die steel, and the microhardness of the coating surface can reach up to 1000 HV0.2, which is about 1.6 times of the substrate. The wear resistance of the Ni60A coating is obviously better than that of the substrate, which is about 2.0 to 3.3 times higher than that of the substrate. After laser cladding of the multi-layer Ni-based alloy coating on the Cr12MoV die steel surface, hard phases such as Cr3C2 and Ni-Cr-Fe can be formed and effectively improve the surface hardness and wear resistance. The probability of scrapping due to friction and wear can be significantly reduced, thereby further extending the service life of the mold.
Keywords:Cr12MoV steel  laser cladding  Ni-based alloy coating  microstructure  mechanical properties  
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