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一种新型dmit盐的三阶非线性光学性质研究
引用本文:冯林,王彦玲,任诠,张光辉,杨洪亮,孙香冰.一种新型dmit盐的三阶非线性光学性质研究[J].激光技术,2006,30(5):469-470,475.
作者姓名:冯林  王彦玲  任诠  张光辉  杨洪亮  孙香冰
作者单位:1.山东大学, 光学系, 济南, 250100;
基金项目:国家高技术研究发展计划(863计划);国家自然科学基金
摘    要:为了研究一种新的有机金属配合物dmit盐(tetram ethylammon ium)bis(1,3-dithiole-2-thione-4,5-dithiolato)copper(简称为MeCu)的三阶非线性光学性质,采用单光束z扫描技术,在波长为1064nm、脉宽为30ps条件下对浓度为1.0×10-3mol/L的MeCu/丙酮溶液进行研究。实验结果表明,其三阶非线性折射率n2和二阶分子超极化率γ分别为-2.15×10-11esu和1.94×10-30esu,未发现三阶非线性吸收的存在。表明该材料在全光开关等非线性光学器件的研制上可能具有潜在的应用价值。

关 键 词:非线性光学    三阶非线性    z扫描    有机金属配合物
文章编号:1001-3806(2006)05-0469-02
收稿时间:2005-08-15
修稿时间:2005-08-152006-04-20

Third-order nonlinear optical properties of a novel dmit salt
FENG Lin,WANG Yan-ling,REN Quan,ZHANG Guang-hui,YANG Hong-liang,SUN Xiang-bing.Third-order nonlinear optical properties of a novel dmit salt[J].Laser Technology,2006,30(5):469-470,475.
Authors:FENG Lin  WANG Yan-ling  REN Quan  ZHANG Guang-hui  YANG Hong-liang  SUN Xiang-bing
Abstract:The nonlinear optical properties of a novel dmit2 salt:(tetramethylammonium)bis(1,3-dithiole-2-thione-4,5-dithiolato)copper(abbreviated as MeCu)are studied with z-scan technique at 1064nm with 30ps laser duration. The nonlinear refraction coefficient n2 and the second hyperpolarizability γ have been determined to be -2.15 x 10-11 esu and 1.94 x 10-30 esu,respectively. No nonlinear absorption is observed under this condition. All the results show that McCu is a potential material for nonlinear optical devices such as all-optical switches.
Keywords:nonlinear optics  third-order nonlinearity  z-scan  organometallic complex
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