| 典型陶瓷基体对催化滤芯中催化剂分散及脱硝活性的影响 |
| |
| 引用本文： | 于超,李长明,张喻升,郭凤,余剑,杨运泉,许光文.典型陶瓷基体对催化滤芯中催化剂分散及脱硝活性的影响[J].化工学报,2018,69(2):682-689. |
| |
| 作者姓名： | 于超 李长明 张喻升 郭凤 余剑 杨运泉 许光文 |
| |
| 作者单位： | 1.湘潭大学化工学院, 湖南 湘潭 411105;2.中国科学院过程工程研究所多相复杂系统国家重点实验室, 北京 100190 |
| |
| 基金项目： | 中国科学院STS计划项目（KFJ-SW-STS-149）；政府间国际创新合作项目（2016YFE0128300）；国家自然科学基金项目（21601192）；国家重点研发计划项目（2017YFB0310400）。 |
| |
| 摘 要： | 具有脱硝除尘一体化功能的催化滤芯在小型燃烧烟气处理中具有广泛的应用前景。采用3种典型商用陶瓷滤芯，涂覆V2O5-WO3-MoO3/TiO2脱硝催化剂，制备了具有脱硝除尘一体化功能的催化滤芯材料，考察了陶瓷滤芯的化学成分和孔径结构对NH3-SCR脱硝性能的影响。XRD、XRF、SEM、压汞等分析测试结果表明：碱金属与碱土金属元素含量低且孔径分布均匀的纤维状结构陶瓷滤芯，促进了催化剂分散，提升了脱硝活性，且降低了压降。催化滤芯在220～380℃、过滤面速度1 m·min-1、NH3/NO=1条件下脱硝率大于90%；抗水蒸气（15%，体积分数）和SO2中毒（3×10-2%，体积分数）测试表明催化滤芯在260～450℃温区内依然保持脱硝率大于90%，可满足催化滤芯实际工业应用要求。
|
| 关 键 词： | 陶瓷滤芯 选择催化还原 脱硝除尘一体化 V2O5-WO3-MoO3/TiO2 抗硫 |
| 收稿时间： | 2017-07-24 |
| 修稿时间： | 2017-11-08 |
Effect of ceramic matrices on dispersion of loaded catalyst and DeNOx activity of catalytic filters |
| |
| YU Chao,LI Changming,ZHANG Yusheng,GUO Feng,YU Jian,YANG Yunquan,XU Guangwen.Effect of ceramic matrices on dispersion of loaded catalyst and DeNOx activity of catalytic filters[J].Journal of Chemical Industry and Engineering(China),2018,69(2):682-689. |
| |
| Authors: | YU Chao LI Changming ZHANG Yusheng GUO Feng YU Jian YANG Yunquan XU Guangwen |
| |
| Affiliation: | 1.School of Chemical Engineering, Xiangtan University, Xiangtan 411105, Hunan, China;2.State Key Laboratory of Multi-phase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China |
| |
| Abstract: | There is a wide application prospect for the development of a catalytic filter with simultaneous DeNOx and de-dust function in the DeNOx treatment of flue gas from small furnace. Three kinds of typical commercial ceramic filters were used to prepare catalytic DeNOx filters by coating method, and their catalytic performance were investigated on different flue gas condition. The XRD, XRF, SEM and MIP results demonstrate that the ceramic filter with little alkali/alkaline earth metal and uniform pore distribution will promote the dispersion and DeNOx activity of the catalytic particles as well as the decreased pressure drop. The NO conversion can be above 90% in the temperature range of 220-380℃ (face velocity=1 m·min-1, NH3/NO=1), and the NO conversion can still maintain above 90% after introduction of H2O (15%, vol) and SO2 (3×10-2%, vol) in the temperature range of 260-450℃. The excellent DeNOx performance of the catalytic filter meets well the demands of practical industrial application. |
| |
| Keywords: | ceramic filter SCR DeNOx and dedusting V2O5-WO3-MoO3/TiO2 SO2 resistant |
|
| 点击此处可从《化工学报》浏览原始摘要信息 |
|
点击此处可从《化工学报》下载全文 |
|
