Mechanical and piezo‐resistive properties of styrene–butadiene–styrene copolymer covalently modified with graphene/styrene–butadiene–styrene composites |
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| Authors: | Kailiang Hong Zhe Wang Guoming Lu Lai Wei Zhijuan Yuan Hongqing Wang Zhen Qiao Lun Wang Xue Wang Zewen Li |
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| Affiliation: | Key Laboratory of Chemical Engineering Process and Technology for High‐Efficiency Conversion, College of Heilongjiang Province, School of Chemistry and Materials Science, Heilongjiang University, Harbin, People's Republic of China |
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| Abstract: | As novel piezoelectric materials, carbon‐reinforced polymer composites exhibit excellent piezoelectric properties and flexibility. In this study, we used a styrene–butadiene–styrene triblock copolymer covalently grafted with graphene (SBS‐g‐RGO) to prepare SBS‐g‐RGO/styrene–butadiene–styrene (SBS) composites to enhance the organic solubility of graphene sheets and its dispersion in composites. Once exfoliated from natural graphite, graphene oxide was chemically modified with 1,6‐hexanediamine to functionalize with amino groups (GO–NH2), and this was followed by reduction with hydrazine amine‐functionalized graphene oxide (RGO–NH2)]. SBS‐g‐RGO was finally obtained by the reaction of RGO–NH2 and maleic anhydride grafted SBS. After that, X‐ray diffraction, X‐ray photoelectron spectroscopy, Raman spectroscopy, scanning electron microscopy, transmission electron microscopy, thermogravimetric analysis, and other methods were applied to characterize SBS‐g‐RGO. The results indicate that the SBS molecules were grafted onto the graphene sheets by covalent bonds, and SBS‐g‐RGO was dispersed well. In addition, the mechanical and electrical conductivity properties of the SBS‐g‐RGO/SBS composites showed significant improvements because of the excellent interfacial interactions and homogeneous dispersion of SBS‐g‐RGO in SBS. Moreover, the composites exhibited remarkable piezo resistivity under vertical compression and great repeatability after 10 compression cycles; thus, the composites have the potential to be applied in sensor production. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 46568. |
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| Keywords: | grafting graphene and fullerenes mechanical properties nanotubes sensors and actuators thermoplastics |
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