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机械活化方式对攀枝花钛铁矿浸出强化作用
引用本文:李春,陈胜平,吴子兵,郭灵虹,梁斌.机械活化方式对攀枝花钛铁矿浸出强化作用[J].化工学报,2006,57(4):832-837.
作者姓名:李春  陈胜平  吴子兵  郭灵虹  梁斌
作者单位:四川大学化工学院化工系;四川大学分析测试中心,四川 成都 610065
摘    要:对滚筒球磨、行星球磨和搅拌球磨不同设备机械活化攀枝花钛铁矿及其浸出反应进行了研究.结果表明,机械活化可以强化钛铁矿的浸出过程,搅拌磨强化浸出的效果最好,行星磨次之,滚筒磨最差.活化后的钛铁矿浸出活性与其晶胞在c轴方向的显微应变增大有关,而与a轴和b轴方向的显微应变关系不大.搅拌磨活化时能产生更细小的矿物颗粒,在c轴方向有更大的显微应变以及在颗粒表面有更高的表面活性,浸出活性更高.钛铁矿的浸出效果与有效的活化效果有关,而活化效果与机械力的强度和类型都有关.

关 键 词:钛铁矿浸出  机械活化  活化机理
文章编号:0438-1157(2006)04-0832-06
收稿时间:07 4 2005 12:00AM
修稿时间:2005-07-042005-11-13

Enhancement effects of mechanically milling facilities on dissolution of Panzhihua ilmenite
LI Chun,CHEN Shengping,WU Zibing,GUO Linghong,LIANG Bin.Enhancement effects of mechanically milling facilities on dissolution of Panzhihua ilmenite[J].Journal of Chemical Industry and Engineering(China),2006,57(4):832-837.
Authors:LI Chun  CHEN Shengping  WU Zibing  GUO Linghong  LIANG Bin
Affiliation:1 Department of Chemical Engineering, School of Chemical Engineering, Sichuan University ; 2 Analytical and Testing Center, Sichuan University, Chengdu 610065, Sichuan, China
Abstract:The mechanical activation of Panzhihua ilmenite with tumbling ball mill, planetary ball mill and stirring ball mill, and the dissolution of activated ilmenite were investigated. Milling operation considerably accelerated the leaching reaction of ilmenite in dilute sulfuric acid solutions. Samples activated with stirring ball mill exhibited the highest leaching activity and those activated with planetary ball mill the second, while those activated with tumbling mill showed the least activity improvement. Characterization results suggested that the enhancement of ilmenite leaching was due to the increasing lattice strain in c axis direction of the ilmenite crystal cells. Milling with stirring ball mill produced more fine particles, larger lattice strain in c axis direction, and higher surface activity. It apparently accelerated dissolution. The enhancement effect on leaching reaction relied not only on the strength but also the form of the mechanical force applied.
Keywords:leaching ilmenite  mechanical activation  activation mechanism
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