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Droplet breakage and coalescence in liquid–liquid dispersions: Comparison of different kernels with EQMOM and QMOM
Authors:Dongyue Li  Zhengming Gao  Antonio Buffo  Wioletta Podgorska  Daniele L Marchisio
Affiliation:1. State Key Laboratory of Chemical Resource Engineering, School of Chemical Engineering, Beijing University of Chemical Technology, Beijing, China;2. Dept. of Biotechnology and Chemical Technology, Aalto University, Espoo, Finland;3. Faculty of Chemical and Process Engineering, Warsaw University of Technology, Warsaw, Poland;4. Dept. of Applied Science and Technology, Institute of Chemical Engineering, Politecnico di Torino, Torino, Italy
Abstract:Droplet coalescence and breakage in turbulent liquid–liquid dispersions is simulated by using computational fluid dynamics (CFD) and population balance modeling. The multifractal (MF) formalism that takes into account internal intermittency was here used for the first time to describe breakage and coalescence in a surfactant‐free dispersion. The log‐normal Extended Quadrature Method of Moments (EQMOM) was for the first time coupled with a CFD multiphase solver. To assess the accuracy of the model, predictions are compared with experiments and other models (i.e., Coulalogou and Tavlarides kernels and Quadrature Method of Moments QMOM]). EQMOM and QMOM resulted in similar predictions, but EQMOM provides a continuous reconstruction of the droplet‐size distribution. Transient predictions obtained with the MF kernels result in a better agreement with the experiments. © 2016 American Institute of Chemical Engineers AIChE J, 63: 2293–2311, 2017
Keywords:computational fluid dynamics  multiphase flow  quadrature‐based moment methods  coalescence  breakage  QMOM  EQMOM
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