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水解聚丙烯酰胺盐水溶液表观粘度的数学模拟(Ⅲ)——表观粘度与剪切速率的通用关系式
引用本文:方道斌,聂贵权.水解聚丙烯酰胺盐水溶液表观粘度的数学模拟(Ⅲ)——表观粘度与剪切速率的通用关系式[J].化工学报,1997,48(1):80-84.
作者姓名:方道斌  聂贵权
作者单位:天津大学应用化学系,天津大学应用化学系,天津大学应用化学系,浙江省化工研究院,大庆石油管理局科技处 天津 300072 ,天津 300072 ,天津 300072 ,杭州 310023 ,大庆 163712
摘    要:通过对水解聚丙烯酰胺盐水溶液的流动曲线的分析,提出了两点假设.据此分别建立了Meter-Bird式常数γ_(1/2)和P_α与零剪切粘度η_0间的经验式,及表观粘度η_α和剪切速率γ间的通用 Meter-Bird式.用此方程式与本文(Ⅰ)报通用 MHS方程式和(Ⅱ)报式(4) 联用,模拟水解聚丙烯酰胺盐水溶液的表观粘度,取得了较好的结果.

关 键 词:水解  聚丙烯酰胺  聚电解质  溶液流变学  粘度

MATHEMATICAL SIMULATION OF APPARENT VISCOSITY FOR HYDROLYZED POLYACRYLAMIDE- SALT SOLUTION (III) AN UNIVERSAL RELATIONSHIP BETWEEN APPARENT VISCOSITY AND SHEAR RATE
Fang Daobin,Guo Ruiwei and Zhou ShaogangNie GuiquanCheng Jiecheng.MATHEMATICAL SIMULATION OF APPARENT VISCOSITY FOR HYDROLYZED POLYACRYLAMIDE- SALT SOLUTION (III) AN UNIVERSAL RELATIONSHIP BETWEEN APPARENT VISCOSITY AND SHEAR RATE[J].Journal of Chemical Industry and Engineering(China),1997,48(1):80-84.
Authors:Fang Daobin  Guo Ruiwei and Zhou ShaogangNie GuiquanCheng Jiecheng
Affiliation:Fang Daobin,Guo Ruiwei and Zhou Shaogang(Department of Applied Chemistry,Tianjin University,Tianjin )Nie Guiquan(Zhejiang Research Institute of Chemical industry,Hangzhou )Cheng Jiecheng(Daqing Petroleum Administration Bureau,Daqing )
Abstract:Two assumptions were put forward as a result of analysis of the flow curves of hy-drolyzed polyacrylamide-salt solution. Based on these, the relationships between the constantsγ1/2 and Pα in Meter s equation and zero-shear viscosity η0 were established, and therefore a universal Meters equation relating apparent viscosity ηa with shear rate γ was deduced. The equationand the MHS equation in part ( Ⅰ ) and the equation (4) in part ( Ⅱ ) can be used to simulate theapparent viscosity for the system and good results were obtained.
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