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黄磷尾气解毒铬渣
引用本文:李先荣,陈宁,董明甫,谢友才,黄玉西,袁小超.黄磷尾气解毒铬渣[J].无机盐工业,2014,46(12):54-56.
作者姓名:李先荣  陈宁  董明甫  谢友才  黄玉西  袁小超
作者单位:四川省银河化学股份有限公司,四川绵阳 622656
摘    要:研究了黄磷尾气解毒铬渣。实验方法及工艺条件:将六价铬(铬酸钠)质量分数为1%的铬渣粉碎至粒度小于75 μm,取5 g样品加入石英管中,加热到600 ℃,反应20 min,然后在黄磷尾气气氛中冷却至200 ℃以下。实验结果表明,在上述条件下可以将铬渣中六价铬质量分数降至0.3 mg/kg,并且铬渣不会返黄。

关 键 词:铬渣  解毒  黄磷尾气  固废  气废  

Detoxification of chromium residue by yellow phosphorus tail gas
Li Xianrong;Chen Ning;Dong Mingfu;Xie Youcai;Huang Yuxi;Yuan Xiaochao.Detoxification of chromium residue by yellow phosphorus tail gas[J].Inorganic Chemicals Industry,2014,46(12):54-56.
Authors:Li Xianrong;Chen Ning;Dong Mingfu;Xie Youcai;Huang Yuxi;Yuan Xiaochao
Affiliation:Sichuan Yinhe Chemical Co.,Ltd.,Mianyang 622656,China
Abstract:The detoxification of chromium residue using yellow phosphorus tail gas was researched. Experimental approach and process conditions: chromium residue, which contained 1% Cr(Ⅵ)[w(Na2CrO4)],was crashed to 75 μm below.Then, 5 g sample was took into quartz tube,reaction occurred in 600 ℃ for 20 min,and reactants was protected in yellow phosphorus tail gas till to cool below 200 ℃.Experiment results showed that,Cr(Ⅵ) in chromium residue could be reduced to 0.3 mg/kg,and had none brightness reversion phenomenon.
Keywords:chromium residue  detoxification  yellow phosphorus tail gas  solid waste  gas waste  
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