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Selective Detection of Dopamine in Presence of Ascorbic Acid by Use of Glassy‐Carbon Electrode Modified with Amino‐β‐Cyclodextrin and Carbon Nanotubes |
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| Authors: | Aymen Gaied Nejmeddine Jaballah Moncef Tounsi Mohamed Braiek Nicole Jaffrezic‐Renault Mustapha Majdoub |
| Affiliation: | 1. Laboratoire des Interfaces et des Matériaux Avancés (LIMA), Université de Monastir, Faculté des Sciences, Bd. de l'Environnement, 5019 Monastir, Tunisie;2. University of Lyon, Institute of Analytical Sciences, La Doua Street, 69100 Villeurbanne, France |
| Abstract: | A glassy carbon electrode modified with per‐6‐amino‐β‐cyclodextrin (β‐CDNH2) and functionalized single‐walled carbon nanotubes (SWCNT‐COOH) was elaborated. This structure was investigated for the detection of dopamine acid (DA) in presence of ascorbic acid (AA). The sensor behavior was studied by cyclic voltammetry, square wave voltammetry and electrochemical impedance spectroscopy. The analysis results show that the electrode modification with CD derivative improves the sensitivity and selectivity of the DA recognition; the electrochemical response was further improved by introduction of SWCNT‐COOH. The sensor shows good and reversible linear response toward DA within the concentration range of 7×10?7–10?4 M with a detection limit of 5×10?7 M. |
| Keywords: | Cyclodextrins Carbon nanotubes Dopamine Sensor Square wave voltammetry |
