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ZrSiO4 对低温陶瓷结合剂预熔玻璃料结构与性能的影响
引用本文:田久根,侯永改.ZrSiO4 对低温陶瓷结合剂预熔玻璃料结构与性能的影响[J].金刚石与磨料磨具工程,2019,39(6):48-52.
作者姓名:田久根  侯永改
作者单位:郑州力弘超硬材料有限公司,郑州 450001;河南工业大学,郑州 450001
摘    要:在Al2O3-B2O3-SiO2系低温陶瓷结合剂中添加不同含量的ZrSiO4添加剂,用差示扫描热分析仪、X射线衍射仪、扫描电镜等研究ZrSiO4含量对低温陶瓷结合剂结构与性能的影响。结果表明:ZrSiO4含量增加,陶瓷结合剂耐火度无明显增加,其热膨胀系数在一定范围内降低;且当ZrSiO4质量分数为4%时,陶瓷结合剂结构致密,微观状态均匀,陶瓷结合剂的综合性能最佳,其抗折强度为57.37 MPa,显微硬度为855.59 MPa。 

关 键 词:陶瓷结合剂  ZrSiO4  力学性能

Effect of ZrSiO4on properties and structures of low temperature vitrified bond
TIAN Jiugen,HOU Yonggai.Effect of ZrSiO4on properties and structures of low temperature vitrified bond[J].Diamond & Abrasives Engineering,2019,39(6):48-52.
Authors:TIAN Jiugen  HOU Yonggai
Affiliation:1. Zhengzhou Lihong Superhard Materials Co., Ltd., Zhengzhou 450001, China;2. Henan University of Technology, Zhengzhou 450001, China
Abstract:Different contents of ZrSiO4 additives were added to Al2O3-B2O3-SiO2 low temperature vitrified bond. The effect of ZrSiO4 content on the structures and properties of low temperature ceramic bond was studied by differential scanning calorimeter, X-ray diffractometer and scanning electron microscope (SEM).The results show that with the increase of ZrSiO4 content, the refractoriness of the ceramic bond does not increase significantly, and its coefficient of thermal expansion decreases within a certain range. When the mass fraction of ZrSiO4 is 4%, the structure of the vitrified bond is compact with uniform distribution and the comprehensive performance of the vitrified bond is the best, which is flexural strength of 57.37 MPa and microhardness of 855.59 MPa. 
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